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公开(公告)号：US3954699A
公开(公告)日：1976-05-04
申请号：US501864
申请日：1974-08-30
申请人： Shoichi Matsumura , Itaru Hatano
发明人： Shoichi Matsumura , Itaru Hatano
CPC分类号： C08G61/08
摘要： A Process for polymerizing cycloolefins by ring opening reaction using heterogeneous catalyst containing tungsten trioxide and Lewis acid or tungsten trioxide, Lewis acid and organoaluminum compound as the polymerization catalyst.
摘要翻译： 一种使用含有三氧化钨和路易斯酸或三氧化钨的路易斯酸和有机铝化合物作为聚合催化剂的多相催化剂通过开环反应聚合环烯烃的方法。
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公开(公告)号：US4880861A
公开(公告)日：1989-11-14
申请号：US320646
申请日：1989-03-08
申请人： Shoichi Matsumura , Toshiro Nanbu , Hisao Furukawa
发明人： Shoichi Matsumura , Toshiro Nanbu , Hisao Furukawa
IPC分类号： C09D137/00 , C09D143/04 , C09D157/06 , C09D201/02 , C09D201/10
CPC分类号： C09D157/06 , C09D143/04 , C09D201/10
摘要： A coating composition comprising:(A) 100 parts by weight of a vinyl polymer having on the main polymer chain end or a side chain thereof at least one silyl group containing a silicon atom to which a hydrolyzable group is linked, per one polymer molecule, the main chain of the vinyl polymer consisting essentially of a polymer of a vinyl monomer,(B) 0 to 10 parts by weight of a curing catalyst,(C) 0 to 10 parts by weight of a hydrolyzable ester compound, and(D) 0.5 to 100 parts by weight of a dialkyl ester of dibasic acid having the formula (1): ##STR1## The coating composition of the present invention has excellent adhesion to under coats, and therefore it is suitable for use of automotive refinishing paints and industrial coatings.
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公开(公告)号：US5753737A
公开(公告)日：1998-05-19
申请号：US761519
申请日：1996-12-09
IPC分类号： C08L63/00 , C09D143/04 , C08K5/10
CPC分类号： C09D143/04 , C08L63/00
摘要： A coating composition containing (A) a silyl group-containing vinyl polymer which has on the polymer chain ends or side chain thereof at least one silicon atom, to which a hydrolyzable group is linked, per polymer molecule, (B) a reaction product of an aminosilane compound with an epoxy compound (C) a hydrolyzable ester compound and (D) an inorganic pigment. The coating composition of the present invention has excellent film properties such as appearance, moisture resistance and grindability and is suitable for use as an undercoating and a primer coating.
摘要翻译： 一种涂料组合物，其含有（A）含有甲硅烷基的乙烯基聚合物，聚合物链末端或侧链上至少有一个可水解基团连接的硅原子，每个聚合物分子，（B）反应产物 具有环氧化合物的氨基硅烷化合物（C）可水解酯化合物和（D）无机颜料。 本发明的涂料组合物具有优异的膜性能，如外观，耐湿性和可磨性，适合用作底涂和底漆。
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公开(公告)号：US3941757A
公开(公告)日：1976-03-02
申请号：US493387
申请日：1974-07-31
CPC分类号： C08G61/08
摘要： Method of producing a copolymer of cyclopentene comprising the steps of preliminarily mixing in an inert solvent a polycyclic olefin having at least one double bond in a ring, with a metallic compound containing tungsten or molybdenum as a catalyst, to form a complex compound with each other; polymerizing cyclopentene in an inert solvent in the presence of a catalyst system comprising a metallic compound of tungsten or molybdenum and an organo metallic compound of Group I-IV of the Periodic Table, and then adding the complex compound to the polymerizing cyclopentene system, thereby to produce a novel copolymer of cyclopentene.
摘要翻译： 制备环戊烯共聚物的方法，包括以下步骤：在惰性溶剂中将环中具有至少一个双键的多环烯烃与含有钨或钼作为催化剂的金属化合物预先混合以形成配位化合物 ; 在包含钨或钼的金属化合物和元素周期表I-IV族有机金属化合物的催化剂体系的存在下，在惰性溶剂中聚合环戊烯，然后将配位化合物加入到聚合环戊烯体系中，从而 产生环戊烯的新型共聚物。
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公开(公告)号：US4310640A
公开(公告)日：1982-01-12
申请号：US150638
申请日：1980-05-16
IPC分类号： C08K5/00 , C08F8/00 , C08F8/42 , C08G63/00 , C08G63/68 , C08G63/695 , C08G63/91 , C08K3/22 , C08K5/17 , C08K5/54 , C08L33/00 , C08L33/02 , C08L43/04 , C08L67/00 , C08L77/00 , C08L101/00 , C08L101/02 , C08L101/10 , C09D167/00 , C09D183/04 , C09D201/00 , C09D201/02 , C09J167/00 , C09K3/10 , C08C19/00
CPC分类号： C08L101/02 , C08F8/00 , C08F8/42 , C08G63/695 , C08G63/6954 , C08G63/91 , C08K3/20 , C08K3/22 , C08K5/17 , C08K5/54 , C08L43/04 , C09D167/00 , C09K3/10
摘要： A composition comprising (a) an organic compound having at least one hydrolyzable silyl group and (b) an organic amine and/or an alkali metal hydroxide. The composition is curable upon exposure to moisture, and has superior properties, such as hardness, toughness and stain resistance, when used for example as a coating. The composition can be utilized as a coating material.
摘要翻译： 一种组合物，其包含（a）具有至少一个可水解甲硅烷基的有机化合物和（b）有机胺和/或碱金属氢氧化物。 该组合物在暴露于水分时可固化，并且当用作例如涂层时具有优异的性能，例如硬度，韧性和耐污渍性。 组合物可以用作涂料。
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公开(公告)号：US4826904A
公开(公告)日：1989-05-02
申请号：US124237
申请日：1987-11-23
申请人： Shoichi Matsumura , Toshiro Nanbu , Hisao Furukawa
发明人： Shoichi Matsumura , Toshiro Nanbu , Hisao Furukawa
IPC分类号： C09D137/00 , C09D143/04 , C09D157/06 , C09D201/02 , C09D201/10 , C08K5/11
CPC分类号： C09D157/06 , C09D143/04 , C09D201/10
摘要： A coating composition comprising:(A) 100 parts by weight of a vinyl polymer having on the main polymer chain end or a side chain thereof at least one silyl group containing a silicon atom to which a hydrolyzable group is linked, per one polymer molecule, the main chain of the vinyl polymer consisting essentially of a polymer of a vinyl monomer,(B) 0 to 10 parts by weight of a curing catalyst,(C) 0 to 10 parts by weight of a hydrolyzable ester compound, and(D) 0.5 to 100 parts by weight of a dialkyl ester of dibasic acid having the formula (1): ##STR1## The coating composition of the present invention has excellent adhesion to under coats, and therefore it is suitable for use as automotive refinishing paints and industrial coatings.
摘要翻译： 一种涂料组合物，其包含：（A）100重量份在每个聚合物分子上在主聚合物链末端或其侧链上含有至少一个含有可水解基团的硅原子的甲硅烷基的乙烯基聚合物， 乙烯基聚合物的主链基本上由乙烯基单体的聚合物组成，（B）0至10重量份的固化催化剂，（C）0至10重量份的可水解的酯化合物，和（D） 0.5〜100重量份具有式（1）的二元酸二烷基酯：（1）本发明的涂料组合物与涂层下的粘合性优异，因此适用于汽车修补 涂料和工业涂料。
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7.发明授权
公开(公告)号：US4415708A
公开(公告)日：1983-11-15
申请号：US302754
申请日：1981-09-16
IPC分类号： C08F279/02 , C08F285/00 , C08F279/04
CPC分类号： C08F279/02 , C08F285/00
摘要： A nitrile based resin produced by graft polymerizing in the presence of a rubber, a first group of monomers in a first polymerization step, then a second group of monomers in a second polymerization step, and then a third group of monomers in a third polymerization step; wherein the resin comprises (A) 5 to 25 parts by weight of the rubber and (B) 75 to 95 parts by weight of (I) 5 to 40 weight percent of the product of the first polymerization step comprising .lambda. weight percent unsaturated nitrile and 100-X weight percent vinyl compound having aromatic vinyl compound as an essential element; (II) 2 to 35 weight percent of the product of the second polymerization step comprising Y weight percent unsaturated nitrile and 100-Y weight percent vinyl compound having aromatic vinyl compound as an essential element; and (III) 25 to 93 weight percent of the product of the third polymerization step comprising Z weight percent unsaturated nitrile and 100-Z weight percent vinyl compound having aromatic vinyl compound as an essential element, wherein30.ltoreq.X
摘要翻译： 一种腈基树脂，其通过在第一聚合步骤中在橡胶存在下接枝聚合，第一组单体，然后在第二聚合步骤中接着第二组单体，然后在第三聚合步骤中接着第三组单体 ; 其中所述树脂包含（A）5至25重量份的所述橡胶和（B）75至95重量份的（I）5至40重量％的所述第一聚合步骤的产物包含λ重量％的不饱和腈和 具有芳族乙烯基化合物作为必需元素的100-X重量百分比乙烯基化合物; （II）2重量％〜35重量％的第二聚合步骤的产物包含Y重量百分比不饱和腈和100-Y重量百分数的具有芳香族乙烯基化合物作为必需元素的乙烯基化合物; 和（III）含有Z重量％不饱和腈的第三聚合步骤的产物的25-93％（重量）和具有芳香族乙烯基化合物作为必需元素的100-Z重量百分数的乙烯基化合物，其中30
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公开(公告)号：US5175206A
公开(公告)日：1992-12-29
申请号：US607631
申请日：1990-10-31
IPC分类号： C08F299/04
CPC分类号： C08F299/0478
摘要： A silyl group-containing, polyester-modified vinyl resin comprising(A) 3 to 45% by weight of units of a polyester resin including a polymerizable unsaturated group,(B) 5 to 30% by weight of units having a group of the formula (I): ##STR1## wherein R.sup.1 is hydrogen atom or a monovalent hydrolyzable group having 1 to 10 carbon atoms selected from the group consisting of an alkyl group, an aryl group and an aralkyl group, R.sup.2 is an organic residue having a polymerizable double bond, X is a hydrolyzable group and n is an integer of 1 to 3, and(C) 25 to 92% by weight of units of a copolymerizable vinyl monomer. The vinyl resin has excellent dispersibility, color match stability and storage stability.
摘要翻译： 含有甲硅烷基的聚酯改性乙烯基树脂，其包含（A）3〜45重量％的包含可聚合不饱和基团的聚酯树脂的单元，（B）5-30重量％的具有式 （I）化合物：其中R 1为氢原子或选自烷基，芳基和芳烷基的碳原子数为1〜10的一价可水解基团，R 2为具有 可聚合双键，X为可水解基团，n为1〜3的整数，（C）为可共聚乙烯基单体的单元的25〜92重量％。 乙烯基树脂具有优异的分散性，颜色匹配稳定性和储存稳定性。
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公开(公告)号：US4478982A
公开(公告)日：1984-10-23
申请号：US302182
申请日：1981-09-14
IPC分类号： C08F279/04 , C08F285/00
CPC分类号： C08F279/04 , C08F285/00
摘要： A high nitrile content based resin produced by graft polymerizing in the presence of a rubber, a first group of monomers in a first polymerization step, then a second group of monomers in a second polymerization step, wherein the resin comprises (A) 5 to 25 parts by weight of said rubber; (B) 5 to 40 parts by weight of the product of said first polymerization step comprising 30 to 60 weight percent unsaturated nitrile and 70 to 40 weight percent vinyl compound having aromatic vinyl compound as an essential element; and (C) 35 to 90 parts by weight of the product of said second polymerization step comprising 60 to 85 weight percent unsaturated nitrile and 40 to 15 weight percent vinyl compound having aromatic vinyl compound an alkyl methacrylate and/or alkyl acrylate; wherein the resin has higher impact resistance, excellent processibility together with the properties of excellent gas barrier and chemical resistance.
摘要翻译： 在第一聚合步骤中，在橡胶存在下，第一组单体，然后第二聚合步骤中的第二组单体接枝聚合制备的高腈含量基树脂，其中所述树脂包含（A）5至25 所述橡胶重量份; （B）5〜40重量份的所述第一聚合步骤的产物包含30-60重量％的不饱和腈和70-40重量％的具有芳族乙烯基化合物作为必需元素的乙烯基化合物; 和（C）35至90重量份的所述第二聚合步骤的产物包含60至85重量％的不饱和腈和40至15重量％的具有芳族乙烯基化合物的乙烯基化合物，甲基丙烯酸烷基酯和/或丙烯酸烷基酯; 其中树脂具有较高的抗冲击性，优异的加工性以及优异的阻气性和耐化学性的特性。
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公开(公告)号：US3994986A
公开(公告)日：1976-11-30
申请号：US567835
申请日：1975-04-14
IPC分类号： C07C7/148 , B01J23/00 , C07B61/00 , C07C1/00 , C07C4/22 , C07C5/05 , C07C7/04 , C07C13/12 , C07C67/00 , C07C3/00
CPC分类号： C07C13/12 , C07C4/22 , C07C5/05 , C07C7/04 , C07C2101/10 , C07C2521/04 , C07C2521/08 , C07C2521/10 , C07C2523/26 , C07C2523/44 , C07C2523/745
摘要： A method of producing cyclopentene comprising the steps of depolymerizing dicyclopentadiene to produce raw cyclopentadiene; feeding the raw cyclopentadiene to a distillation tower having an upper part cooled to a temperature near the boiling point of the cyclopentadiene and an outlet maintained at 35.degree. to 60.degree. C and a lower part at a temperature of 40.degree. to 150.degree. C; thereby to produce highly pure gaseous cyclopentadiene at the top outlet and impure components having high boiling point at the lower outlet which are removed continuously; mixing the highly pure cyclopentadiene obtained thereby with hydrogen and reacting in a first hydrogenation reactor using a palladium containing catalyst, then mixing the resulting product with hydrogen and reacting in a second hydrogenation reactor with a palladium containing catalyst; cooling the resulting product and separating the liquid phase from the gas phase and recirculating the gas phase for use in the hydrogenation reactions.
摘要翻译： 一种生产环戊烯的方法，包括使二环戊二烯解聚以产生生的环戊二烯的步骤; 将原料环戊二烯加入到具有冷却至接近环戊二烯沸点的温度的上部的蒸馏塔和保持在35℃至60℃的出口和在40℃至150℃的温度下部的蒸馏塔; 从而在顶部出口处产生高纯度的气态环戊二烯，并且在下部出口处具有高沸点的不纯的组分被连续除去; 将由此获得的高纯度环戊二烯与氢气混合，并在第一氢化反应器中使用含钯催化剂进行反应，然后将所得产物与氢气混合，并在第二氢化反应器中与含钯催化剂反应; 冷却所得产物并将液相与气相分离并再循环气相以用于氢化反应。
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