公开(公告)号：US20240308938A1

公开(公告)日：2024-09-19

申请号：US18575940

申请日：2022-07-05

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Saurabh S. Maduskar ,  Keith H. Kuechler ,  Xiaoying Bao

IPC: C07C5/32 ,  B01J8/02 ,  B01J23/02 ,  B01J23/62 ,  B01J35/30 ,  C07C7/00

CPC classification number: C07C5/325 ,  B01J8/0278 ,  B01J8/0285 ,  B01J23/02 ,  B01J23/626 ,  B01J35/394 ,  C07C7/005 ,  B01J2208/00362 ,  C07C2521/10 ,  C07C2523/62

Abstract: A method for forming an olefin, the method including: introducing a hydrocarbon feed stream into a reactor including a dehydrogenation catalyst; reacting the hydrocarbon feed stream with a dehydrogenation catalyst in the reactor to form a high temperature dehydrogenated product, the high temperature dehydrogenated product including at least a portion of the dehydrogenation catalyst; separating at least a portion of the dehydrogenation catalyst from the high temperature dehydrogenated product in a primary separation device and a secondary separation device downstream of and in fluid communication with the primary separation device; following the exit of high temperature dehydrogenation product from the secondary separation device, combining the high temperature dehydrogenation product with a quench stream to cool the high temperature dehydrogenation product and form an intermediate temperature dehydrogenation product, wherein the quench stream includes a hydrocarbon; and cooling the intermediate temperature dehydrogenation product to form a cooled dehydrogenation product.

公开(公告)号：US11795123B2

公开(公告)日：2023-10-24

申请号：US16834972

申请日：2020-03-30

Applicant: Lummus Technology LLC

Inventor： Joel M. Cizeron ,  Erik C. Scher ,  Fabio R. Zurcher ,  Wayne P. Schammel ,  Greg Nyce ,  Anja Rumplecker ,  Jarod McCormick ,  Marian Alcid ,  Joel Gamoras ,  Daniel Rosenberg ,  Erik-Jan Ras

IPC: C07C2/84 ,  B01J23/00 ,  B01J23/34 ,  B01J23/54 ,  B01J23/76 ,  B01J37/03 ,  B01J23/63 ,  B01J23/83 ,  B01J19/00 ,  B01J37/08 ,  B01J23/10 ,  B01J23/889 ,  B01J21/06 ,  B01J21/08 ,  B01J27/16 ,  B01J35/00 ,  C07C11/04

CPC classification number: C07C2/84 ,  B01J19/0046 ,  B01J21/066 ,  B01J21/08 ,  B01J23/002 ,  B01J23/10 ,  B01J23/34 ,  B01J23/54 ,  B01J23/63 ,  B01J23/76 ,  B01J23/83 ,  B01J23/8892 ,  B01J27/16 ,  B01J35/0006 ,  B01J37/031 ,  B01J37/035 ,  B01J37/08 ,  C07C11/04 ,  B01J2219/00527 ,  B01J2219/00536 ,  B01J2219/00702 ,  B01J2219/00747 ,  B01J2523/00 ,  C07C2521/10 ,  C07C2521/14 ,  C07C2523/10 ,  C07C2523/18 ,  C07C2523/34 ,  C07C2529/072 ,  C07C2529/076 ,  C07C2529/89 ,  Y02P20/52 ,  B01J2523/00 ,  B01J2523/24 ,  B01J2523/3706 ,  B01J2523/3725 ,  B01J2523/00 ,  B01J2523/24 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/3725 ,  B01J2523/00 ,  B01J2523/24 ,  B01J2523/3706 ,  B01J2523/54 ,  B01J2523/00 ,  B01J2523/24 ,  B01J2523/3725 ,  B01J2523/00 ,  B01J2523/24 ,  B01J2523/3706 ,  B01J2523/00 ,  B01J2523/24 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/3725 ,  B01J2523/54 ,  B01J2523/00 ,  B01J2523/23 ,  B01J2523/24 ,  B01J2523/3725 ,  B01J2523/00 ,  B01J2523/11 ,  B01J2523/22 ,  B01J2523/305 ,  B01J2523/72 ,  B01J2523/00 ,  B01J2523/11 ,  B01J2523/22 ,  B01J2523/305 ,  B01J2523/72 ,  B01J2523/845 ,  B01J2523/00 ,  B01J2523/11 ,  B01J2523/12 ,  B01J2523/22 ,  B01J2523/305 ,  B01J2523/72 ,  B01J2523/845 ,  B01J2523/00 ,  B01J2523/11 ,  B01J2523/12 ,  B01J2523/22 ,  B01J2523/305 ,  B01J2523/72 ,  B01J2523/00 ,  B01J2523/12 ,  B01J2523/69 ,  B01J2523/72 ,  C07C2/84 ,  C07C11/04

Abstract: Metal oxide catalysts comprising various dopants are provided. The catalysts are useful as heterogenous catalysts in a variety of catalytic reactions, for example, the oxidative coupling of methane to C2 hydrocarbons such as ethane and ethylene. Related methods for use and manufacture of the same are also disclosed.

公开(公告)号：US20230265029A1

公开(公告)日：2023-08-24

申请号：US18040992

申请日：2020-09-25

Applicant: UOP LLC ,  CHINA PETROLEUM & CHEMICAL CORPORATION

Inventor： Richard LONG ,  Tian RUAN ,  Jinbiao GUO

IPC: C07C29/34

CPC classification number: C07C29/34 ,  C07C2521/04 ,  C07C2521/10

Abstract: A process for isobutanol synthesis is described. Ethanol and synthesis gas (syngas) are reacted in the presence of a heterogeneous catalyst in a first reaction zone. The products of the first reaction can be separated into one or more streams comprising methanol and propanol. The methanol and propanol from the first reaction are reacted in the presence of a second catalyst to form isobutanol in a second reaction zone.

公开(公告)号：US20190055175A1

公开(公告)日：2019-02-21

申请号：US15678405

申请日：2017-08-16

Applicant: Saudi Arabian Oil Company

Inventor： Faisal H. Alshafei ,  Miao Sun ,  Munir D. Khokhar ,  Zhonglin Zhang ,  Sohel K. Shaikh ,  Mark P. Kaminsky

IPC: C07C5/48 ,  B01J23/30 ,  B01J37/02 ,  B01J37/08 ,  B01J35/00 ,  B01J21/10 ,  B01J35/10 ,  B01J8/02

CPC classification number: C07C5/48 ,  B01J8/0278 ,  B01J21/08 ,  B01J21/10 ,  B01J23/30 ,  B01J35/0006 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/0244 ,  B01J37/0248 ,  B01J37/082 ,  B01J37/088 ,  B01J2208/024 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2521/14 ,  C07C2523/30 ,  C07C11/167

Abstract: Processes, systems, and catalysts for the conversion of 2-butene to 1,3-butaidene without the use of steam or, in some embodiments, with a reduced use of steam as compared to prior art processes are provided. The catalyst includes tungsten trioxide (WO3) on an inorganic support includes activated magnesium oxide (MgO) and may be referred to as a “dual catalyst” or a “co-catalyst.” Embodiments of the catalyst. A process for the production of 1,3-butadiene may include contacting a feed stream of 2-butene with a WO3-inorganic support catalyst or a MgO and WO3-inorganic support catalyst and may be performed without steam in the feed stream.

公开(公告)号：US20180201553A1

公开(公告)日：2018-07-19

申请号：US15744266

申请日：2016-07-05

Applicant: IFP Energies Nouvelles ,  Compagnie Generale Des Etablissements Michelin

Inventor： Nicolas CADRAN ,  Alexandra CHAUMONNOT

IPC: C07C1/20 ,  B01J23/20 ,  B01J23/68 ,  B01J35/10

CPC classification number: C07C1/20 ,  B01J23/20 ,  B01J23/682 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/0203 ,  B01J2523/00 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/06 ,  C07C2523/14 ,  C07C2523/20 ,  C07C2523/68 ,  B01J2523/27 ,  B01J2523/3706 ,  B01J2523/41 ,  B01J2523/57 ,  B01J2523/23 ,  B01J2523/22 ,  B01J2523/43 ,  B01J2523/3712 ,  B01J2523/18 ,  C07C11/167

Abstract: The invention relates to a catalyst that comprises at least the tantalum element, at least an aldolizing element and at least a mesoporous oxide matrix, with the tantalum mass being between 0.1 and 30% of the mesoporous oxide matrix mass, the mass of the at least one aldolizing element being between 0.02 and 4% of the mesoporous oxide matrix mass, and use thereof.

公开(公告)号：US10005079B2

公开(公告)日：2018-06-26

申请号：US15314853

申请日：2015-05-27

Applicant: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude ,  Centre National de la Recherche Scientifique

Inventor： Marie Basin ,  Caroline Bertail ,  Pascal Del-Gallo ,  Daniel Gary ,  Amara Fezoua ,  Nik Lygeros ,  Clémence Nikitine ,  Isabelle Pitault ,  Frédéric Bornette

IPC: B01J21/04 ,  B01J23/04 ,  B01J23/10 ,  B01J23/28 ,  B01J23/42 ,  B01J23/44 ,  B01J23/72 ,  B01J23/745 ,  B01J23/755 ,  B01J23/881 ,  B01J23/882 ,  B01J23/883 ,  B01J23/885 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10

CPC classification number: B01J35/026 ,  B01J8/0214 ,  B01J19/30 ,  B01J23/28 ,  B01J23/56 ,  B01J23/74 ,  B01J35/023 ,  B01J35/04 ,  B01J35/10 ,  B01J35/1028 ,  B01J2208/00539 ,  B01J2219/30265 ,  B01J2219/30416 ,  B01J2219/30475 ,  B01J2219/3083 ,  B01J2219/312 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0266 ,  C01B2203/1217 ,  C01B2203/1223 ,  C01B2203/1229 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/1247 ,  C07C1/0425 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/10 ,  C07C2523/28 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/72 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C10G35/06 ,  C10G35/085 ,  Y02P20/142 ,  Y02P20/52 ,  C07C9/04

Abstract: A catalyst for catalytic reactors of which the outer shape is a helix with n blades, where n is greater than or equal to 1, wherein the stack void fraction percentage is between 75% and 85% and the surface area/volume ratio is greater than 1000 square meters/square meters.

公开(公告)号：US09895676B2

公开(公告)日：2018-02-20

申请号：US14398891

申请日：2013-05-06

Applicant: Sajet Development LLC

Inventor： Jorge Miller ,  Luisa Kling Miller ,  Barry L. Stucky

IPC: B01J21/16 ,  B01J8/08 ,  B01J8/12 ,  B01J8/18 ,  C07C1/26 ,  B01J37/04 ,  B01J23/02 ,  B01J29/08 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/14 ,  C07C1/30 ,  B01J37/06 ,  B01J37/08 ,  B01J38/30 ,  B01J23/06 ,  B01J23/92 ,  B01J29/90 ,  B01J35/08

CPC classification number: B01J21/16 ,  B01J8/085 ,  B01J8/125 ,  B01J8/1809 ,  B01J23/02 ,  B01J23/06 ,  B01J23/92 ,  B01J29/082 ,  B01J29/90 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/0093 ,  B01J35/023 ,  B01J35/026 ,  B01J35/08 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0063 ,  B01J37/0072 ,  B01J37/04 ,  B01J37/06 ,  B01J37/086 ,  B01J37/088 ,  B01J37/14 ,  B01J38/30 ,  B01J2208/00274 ,  C07C1/26 ,  C07C1/30 ,  C07C2521/10 ,  C07C2521/16 ,  C07C2527/232 ,  Y02P20/584 ,  C07C11/02 ,  C07C11/08

Abstract: Generally, regenerable, encapsulated metal oxide catalysts comprising a ceramic matrix and metal catalysts may be used to convert alkanes to alkenes. The encapsulated metal oxide catalyst may be tailored to produce a variety of alkenes including ethylene, butylene, and propylene. Further, the encapsulated metal oxide catalysts advantageously allow for regeneration and reactant recovery for cost effective and environmentally friendly processes.

公开(公告)号：US20170305816A1

公开(公告)日：2017-10-26

申请号：US15515703

申请日：2016-01-29

Applicant: SMH Co., Ltd

Inventor： Kongkiat SURIYE ,  Burin KHEMTHONG ,  Mathukorn SANWANICH

IPC: C07C6/04 ,  B01J23/30 ,  B01J37/08 ,  B01J37/02 ,  B01J37/04

CPC classification number: C07C6/04 ,  B01J23/007 ,  B01J23/02 ,  B01J23/24 ,  B01J23/30 ,  B01J23/32 ,  B01J27/232 ,  B01J27/25 ,  B01J29/076 ,  B01J29/163 ,  B01J29/166 ,  B01J29/48 ,  B01J29/69 ,  B01J29/7815 ,  B01J29/7876 ,  B01J37/0201 ,  B01J37/04 ,  B01J37/08 ,  B01J38/12 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2523/30 ,  C07C2527/232 ,  C07C2529/08 ,  C07C2529/16 ,  Y02P20/52 ,  Y02P20/584 ,  C07C11/06

Abstract: The present invention provides a catalyst comprising a transition metal, an inorganic support, a zeolite, and a layered double hydroxide. Using of the catalyst according to the present invention in an olefin production process exhibits high activity and high selectivity with decreased deactivation rate, therefore longer reaction cycle can be performed and catalyst life is prolonged.

公开(公告)号：US09789477B2

公开(公告)日：2017-10-17

申请号：US14399094

申请日：2013-06-07

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Machteld M. W. Mertens

IPC: C01B39/48 ,  B01J29/70 ,  B01J29/72 ,  B01J29/74 ,  B01J29/78 ,  B01J35/00 ,  B01J35/02 ,  C07C5/22 ,  C07C6/12 ,  C10G35/095 ,  C10G45/12 ,  C10G45/64 ,  C10G45/68 ,  C10G47/16 ,  C10G50/00 ,  C10G3/00 ,  C10G11/05 ,  C01B39/46 ,  C07C4/02

CPC classification number: B01J29/7023 ,  B01J29/7246 ,  B01J29/7446 ,  B01J29/7846 ,  B01J35/0013 ,  B01J35/023 ,  B01J2229/18 ,  C01B39/46 ,  C01B39/48 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/52 ,  C01P2004/60 ,  C01P2004/61 ,  C07C4/02 ,  C07C5/22 ,  C07C6/123 ,  C07C6/126 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2521/16 ,  C07C2529/70 ,  C10G3/49 ,  C10G11/05 ,  C10G35/095 ,  C10G45/12 ,  C10G45/64 ,  C10G45/68 ,  C10G47/16 ,  C10G50/00 ,  Y02P30/20

Abstract: In a process for the synthesis of a crystalline molecular sieve material having the EUO framework type, a synthesis mixture is provided suitable for the formation of an EUO framework type molecular sieve and comprising N,N,N,N′,N′,N′-hexamethylhexanediammonium, Q, cations and a colloidal suspension of seed crystals of an EUO framework type molecular sieve. The synthesis mixture is crystallized and an EUO framework type molecular sieve in the form individual crystals and/or aggregates of crystals having an average size, d50, as measured by laser scattering, of less than 15 μm is recovered from the synthesis mixture.

公开(公告)号：US09764317B2

公开(公告)日：2017-09-19

申请号：US14414085

申请日：2013-07-11

Applicant: Shanghai Bi Ke Clean Energy Technology Co., Ltd.

Inventor： Guo Rui ,  Yongsheng Gan ,  Simon Zhang ,  Yanning Luo

IPC: B01J35/08 ,  B01J23/78 ,  B01J23/80 ,  B01J23/83 ,  C07C5/48 ,  B01J23/847 ,  B01J23/889 ,  B01J23/00 ,  B01J23/843 ,  B01J23/86 ,  B01J37/00 ,  B01J37/08 ,  B01J37/12 ,  B01J37/03 ,  B01J37/06

CPC classification number: B01J35/08 ,  B01J23/002 ,  B01J23/78 ,  B01J23/80 ,  B01J23/83 ,  B01J23/8437 ,  B01J23/8472 ,  B01J23/862 ,  B01J23/868 ,  B01J23/8892 ,  B01J23/8898 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/0063 ,  B01J37/031 ,  B01J37/06 ,  B01J37/08 ,  B01J37/12 ,  B01J2523/00 ,  C07C5/48 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/06 ,  C07C2523/18 ,  C07C2523/28 ,  C07C2523/34 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2523/78 ,  C07C2523/80 ,  C07C2523/83 ,  C07C2523/843 ,  C07C2523/847 ,  C07C2523/86 ,  C07C2523/889 ,  C07C11/167 ,  B01J2523/27 ,  B01J2523/72 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/17 ,  B01J2523/25 ,  B01J2523/22 ,  B01J2523/54 ,  B01J2523/847 ,  B01J2523/23 ,  B01J2523/43 ,  B01J2523/3706 ,  B01J2523/24 ,  B01J2523/48 ,  B01J2523/68 ,  B01J2523/67 ,  B01J2523/55

Abstract: The invention relates to a catalyst for preparation of butadiene by oxydehydrogenation of butene in a fluidized bed reactor, a method of preparing the same, and use of the same, wherein a method according to an embodiment of the invention comprises: reacting a metal precursor with an alkaline substance to obtain a slurry containing insoluble compound, followed by filtering and washing the slurry; adding a binder and deionized water, followed by agitation to regulate the solid content of the slurry to 10-50%; subjecting the slurry to spray drying granulation, wherein the temperature at the feed port is controlled between 200-400° C., and the temperature at the discharge port is controlled between 100-160° C., to obtain catalyst microspheres; and drying the catalyst microspheres at 80-200° C. for 1-24 h, and then calcining the catalyst microspheres at 500-900° C. for 4-24 h to obtain a catalyst having a general formula of FeXaYbZcOd, comprising Fe, Mg, Zn, Bi, Mo, Mn, Ni, Co, Ba, Ca, and other metals. The catalyst microspheres prepared according to the exemplary method exhibit high mobility, desirable particle size distribution, extremely high mechanical strength and catalytic activity, and are applicable to industrial production of butadiene by oxydehydrogenation of butene in a fluidized bed. When this catalyst is used to prepare butadiene by oxydehydrogenation of butene, the yield of butadiene is 76-86%, and the selectivity to butadiene is 94-97%.