摘要:
There is disclosed an aluminum electroplating method, which compriss using a low melting composition comprising a mixture of 20 to 80 mole % of an aluminum halide and 80 to 20 mole % of an onium halide of a nitrogen-containing compound selected from the group consisting of bicyclic quaternary amidinium halides, 1-alkylaminopyridinium halides, trialkylimidazolium halides, benzimidazolium halides, alicyclic quaternary ammonium halides and asymmetric tetraalkylammonium halides.
摘要:
There is disclosed a method for producing an ambient temperature molten salt comprising at least one of 1,3-dialkylimidazolium halide, 1,2,3-trialkylimidazolium halide and N-alkylpyridinium halide, and an aluminum halide, which comprises suspending the above starting materials in an inert solvent having a low boiling point to carry out a complex forming reaction.
摘要:
There is disclosed a non-aqueous electrolytic aluminum plating bath composition comprising an aluminum halide and a nitrogen-containing heterocyclic onium halide compound and containing an additive selected from the group consisting of an inorganic halide compound, aromatic aldehyde, ketone or carboxylic acid, an unsaturated heterocyclic compound containing more than one nitrogen atom, an unsaturated heterocyclic compound containing a sulfur atom, an aromatic hydrocarbon compound containing a sulfur atom, an aromatic hydrocarbon compound containing an amino group and an aromatic amine; and further optionally an organic polymer. The bath composition is easy in maintenance, has good covering power, and enables smooth plating with low current density.
摘要:
In the plating for electrodeposition of aluminum using a non-aqueous solution, a plating bath is prepared to comprise a low-melting plating bath, which comprises a molten mixture comprising an aluminum halide and a dialkyl-and/or trialkylpyridinium halide represented by the following formula: ##STR1## wherein R.sup.1 represents an alkyl group having 1 to 12 carbon atoms, R.sup.2 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, R.sup.3 represents an alkyl group having 1 to 6 carbon atoms, and X represents a halogen atom; and said alkyl groups each refer to a straight-chain hydrocarbon group, a branched hydrocarbon group, an alicyclic hydrocarbon group, or any of these further partly containing an aromatic hydrocarbon group,by which the bath life, operability in handling, conductivity, and current efficiency can be improved.
摘要:
An electrolyte for use in an aluminum electrolytic capacitor is described. The electrolyte comprises a solution of a quaternary phosphonium salt as a solute dissolved in an aprotic solvent. The electrolyte can reduce internal resistance of the electrolytic capacitor and broaden the temperature range over which the electrolytic capacitor can be used.
摘要:
A process for producing quaternary salts of high purity is disclosed, comprising reacting a tertiary amine or phosphine with a carbonic acid diester to form a corresponding quaternary carbonate and further mixing it with an acid to perform decarboxylation. The quaternary salts thus obtained are useful compounds which can be used in wide fields as various catalysts, electrolytes, additives, medicaments, etc.
摘要:
An electrolyte for aluminum electrolytic capacitor is described, comprising a solution of, as a solute, a quaternary ammonium salt having as an anion component the conjugated base of an inorganic acid compound selected from the group consisting of(1) boric acid,(2) phosphoric acid,(3) phosphorous acid and phosphorous acid monoesters, and phosphonic acids, and phosphonic acid monoesters,(4) hypophosphorous acid and phosphinic acids,(5) alkylboric acids and arylboric acids,(6) silicic acid, and(7) carbonic acid and carbonic acid monoesters, dissolved in an aprotic solvent mainly composed of .gamma.-butyrolactone.This electrolyte can reduce the internal resistance of the electrolytic cpacitor and broaden the temperature range over which the electrolytic capacitor can be used.
摘要:
A nonaqueous electrolytic solution cell having a negative electrode containing lithium as an active material, a positive electrode, a nonaqueous electrolytic solution consisting of solute and organic solvent, a separator, and an outer can, wherein the organic solvent contains a compound having an S—O bond, and a current collector for the positive electrode and an electrolytic solution-contacting portion on the positive electrode side of the outer can are made of valve metal or alloy thereof is disclosed. The nonaqueous electrolytic solution cell of the present invention is excellent in low-temperature characteristics and long-term stability, and also in cycle characteristics for use as a secondary battery.
摘要:
Disclosed are an electrode material for a non-aqueous solvent secondary battery, which comprises a composite carbonaceous material in which to the surface of a graphite carbonaceous material is attached a carbonized material of an organic substance in an amount to give a carbon residue of 12 parts by weight or less and 0.1 part by weight or more based on 100 parts by weight of the graphite carbonaceous material, and a process for preparing an electrode material for a non-aqueous solvent secondary battery, which comprises the steps of introducing a slurry obtained by adding an aromatic organic solvent to a mixture of graphite carbonaceous material particles and an organic substance and adjusting viscosity to 10000 cp or lower into a mixing and stirring apparatus having a reaction room which has a paddle rotatable by a shaft in an inner portion thereof, the inner wall surface of the reaction room being formed substantially along the outermost line of rotation of the paddle and also, being provided a mechanism of deaerating a solvent, heating it to a temperature of the boiling point of the solvent or higher and lower than 600.degree. C. while stirring to prepare a solid intermediate and heating said intermediate to 600.degree. C. or higher under inert gas atmosphere to effect carbonization. According to the non-aqueous solvent secondary battery electrode material of the present invention, there can be provided a non-aqueous solvent secondary battery in which good electric characteristics that while maintaining discharging capacity which is as high as graphite, irreversible capacity can be suppressed to extremely low and charging efficiency is excellent can be obtained and further stability to an electrolyte is improved. Also, according to the preparation process of the present invention, a composite carbonaceous material having such high characteristics and uniform characteristics can be prepared stably with good efficiency.
摘要:
A dibenzylidenesorbitol derivative having at least one nuclear substituent selected from an ester group represented by --COOR.sup.1 and an amido group represented by --CONR.sup.2 R.sup.3, wherein R.sup.1 represents a hydrocarbon group having 1 to 20 carbon atoms, and R.sup.2 and R.sup.3 are identical or different and each independently represents a hydrogen atom, an alkyl group, an aryl group or an aralkyl group.