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公开(公告)号：US07550246B2
公开(公告)日：2009-06-23
申请号：US10573780
申请日：2004-09-24
申请人： Shunichi Fukuzumi , Seiji Ogo , Tomoyoshi Suenobu
发明人： Shunichi Fukuzumi , Seiji Ogo , Tomoyoshi Suenobu
CPC分类号： C07D213/89 , C07F17/02 , G03F7/0045
摘要： A photoacid generator comprising a metal hydride complex represented by the formula (I): wherein X represents a metal atom. The iridium hydride complex of the present invention can be used as an acid generator for chemically-amplified photoresists or color filters for liquid crystal, and in addition, can be widely applied in photographic-related or printing-related fields, or the like.
摘要翻译： 一种光酸产生剂，其包含由式（I）表示的金属氢化物络合物：其中X表示金属原子。 本发明的铱氢化物络合物可以用作化学放大型光致抗蚀剂或液晶用滤色器的酸发生剂，另外也可广泛应用于照相相关或印刷相关领域等。
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2.发明授权公开(公告)号：US07939461B2
公开(公告)日：2011-05-10
申请号：US12515357
申请日：2007-05-17
申请人： Shunichi Fukuzumi , Tomoyoshi Suenobu , Seiji Ogo
发明人： Shunichi Fukuzumi , Tomoyoshi Suenobu , Seiji Ogo
CPC分类号： B01J31/1815 , B01J31/2295 , B01J2531/0219 , B01J2531/821 , B01J2531/827 , C01B3/22 , C01B3/32 , C01B2203/0277 , C01B2203/1041 , C01B2203/1047 , C01B2203/1211
摘要： A catalyst for the decomposition of formic acid including a dinuclear metal complex represented by a formula (1) below, a tautomer or stereoisomer thereof, or any of their salts, where M1 and M2 are transition metals; Ar is a ligand having aromaticity and may be unsubstituted or substituted; R1 to R27 are each independently a hydrogen atom, an alkyl group, or the like, or R15 and R16 may together form a —CH═CH—, where Hs in the —CH═CH— may be each independently replaced by an alkyl group or the like, and R23 and R24 may together form a —CH═CH—, where Hs in the —CH═CH— may be each independently replaced by an alkyl group or the like; L is an arbitrary ligand or is absent; and m is a positive integer, 0, or a negative integer.
摘要翻译： 一种用于分解甲酸的催化剂，包括由下式（1）表示的双核金属络合物，其互变异构体或立体异构体或其任何盐，其中M1和M2为过渡金属; Ar是具有芳香性的配体，可以是未取代的或取代的; R 1至R 27各自独立地为氢原子，烷基等，或者R 15和R 16可以一起形成-CH = CH-，其中-CH = CH-中的H可各自独立地被烷基取代 R 23和R 24可以一起形成-CH = CH-，其中-CH = CH-中的H可各自独立地被烷基等取代; L是任意的配体或不存在; 并且m是正整数，0或负整数。
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3.发明申请CATALYST FOR DECOMPOSITION OF FORMIC ACID, METHOD FOR DECOMPOSING FORMIC ACID, PROCESS FOR PRODUCING HYDROGEN, APPARATUS FOR PRODUCING AND DECOMPOSING FORMIC ACID, AND METHOD FOR STORING AND GENERATING HYDROGEN 失效用于分解形式酸的催化剂，用于分解形式酸的方法，用于生产氢的方法，用于生产和分解形式酸的装置，以及用于储存和产生氢的方法公开(公告)号：US20100034733A1
公开(公告)日：2010-02-11
申请号：US12515357
申请日：2007-05-17
申请人： Shunichi Fukuzumi , Tomoyoshi Suenobu , Seiji Ogo
发明人： Shunichi Fukuzumi , Tomoyoshi Suenobu , Seiji Ogo
CPC分类号： B01J31/1815 , B01J31/2295 , B01J2531/0219 , B01J2531/821 , B01J2531/827 , C01B3/22 , C01B3/32 , C01B2203/0277 , C01B2203/1041 , C01B2203/1047 , C01B2203/1211
摘要： The present invention provides a catalyst for the decomposition of formic acid including a dinuclear metal complex represented by a formula (1) below, a tautomer or stereoisomer thereof, or any of their salts, where M1 and M2 are transition metals and may be the same or different; Ar is a ligand having aromaticity and may be unsubstituted or substituted by one or more substituents; R1 to R27 are each independently a hydrogen atom, an alkyl group, or the like, or R15 and R16 may together form a —CH═CH—, where Hs in the —CH═CH— may be each independently replaced by an alkyl group or the like, and R23 and R24 may together form a —CH═CH—, where Hs in the —CH═CH— may be each independently replaced by an alkyl group or the like; L is an arbitrary ligand or is absent; and m is a positive integer, 0, or a negative integer.
摘要翻译： 本发明提供一种用于分解甲酸的催化剂，其包括由下式（1）表示的二核金属络合物，其互变异构体或立体异构体或其任何盐，其中M1和M2为过渡金属并且可以相同 或不同; Ar是具有芳香性的配体，可以是未取代的或被一个或多个取代基取代; R 1至R 27各自独立地为氢原子，烷基等，或者R 15和R 16可以一起形成-CH-CH-，其中-CH-CH-中的H可各自独立地被烷基取代 R 23和R 24可以一起形成-CH-CH-，其中-CH-CH-中的Hs可以各自独立地被烷基等取代; L是任意的配体或不存在; 并且m是正整数，0或负整数。
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公开(公告)号：US20070059633A1
公开(公告)日：2007-03-15
申请号：US10573780
申请日：2004-09-24
申请人： Shunichi Fukuzumi , Seiji Ogo , Tomoyoshi Suenobu
发明人： Shunichi Fukuzumi , Seiji Ogo , Tomoyoshi Suenobu
IPC分类号： G03C1/00
CPC分类号： C07D213/89 , C07F17/02 , G03F7/0045
摘要： A photoacid generator comprising a metal hydride complex represented by the formula (I): wherein X represents a metal atom. The iridium hydride complex of the present invention can be used as an acid generator for chemically-amplified photoresists or color filters for liquid crystal, and in addition, can be widely applied in photographic-related or printing-related fields, or the like.
摘要翻译： 一种光酸产生剂，其包含由式（I）表示的金属氢化物络合物：其中X表示金属原子。 本发明的铱氢化物络合物可以用作化学放大型光致抗蚀剂或液晶用滤色器的酸发生剂，另外也可广泛应用于照相相关或印刷相关领域等。
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5.发明授权Mononuclear metal complex, hydrogenation reduction catalyst, dehydrogenation catalyst, method for producing hydrogenation reduction product, method for producing hydrogen (H2), and method for producing dehydrogenation reaction product 有权单核金属络合物，氢化还原催化剂，脱氢催化剂，氢化还原产物的制造方法，氢气的制造方法（H2）以及脱氢反应产物的制造方法公开(公告)号：US09169281B2
公开(公告)日：2015-10-27
申请号：US13582653
申请日：2011-03-04
CPC分类号： C07F15/0033 , B01J31/0252 , B01J31/1815 , B01J31/2295 , B01J2231/625 , B01J2531/827 , B01J2540/12 , B01J2540/32 , C07F17/02
摘要： The present invention provides: a mononuclear metal complex that has high catalytic activity and can be used as a hydrogenation reduction catalyst that allows efficient hydrogenation reduction of a substance to be reduced; a tautomer or stereoisomer thereof; or a salt thereof. Provided is the mononuclear metal complex represented by the following formula (1), a tautomer or stereoisomer thereof; or a salt thereof. In the formula (1), Ar1 is an aromatic anionic ligand or an aromatic ligand, or is not present, Ar2 is a ligand having aromaticity and may or may not be substituted, and when Ar2 is substituted, the number of substituents may be one or more, M is an atom or ion of a transition metal, A1 and A2 are both carbon atoms, or one of A1 and A2 is a carbon atom and the other is a nitrogen atom, Y is an anionic group or a cationic group, or is not present, L is any ligand or is not present, and m is a positive integer, 0, or a negative integer.
摘要翻译： 本发明提供：具有高催化活性并可用作氢化还原催化剂的单核金属络合物，其允许有待降低的物质的氢化还原; 其互变异构体或立体异构体; 或其盐。 提供由下式（1）表示的单核金属络合物，其互变异构体或立体异构体; 或其盐。 在式（1）中，Ar 1为芳族阴离子配位体或芳香族配体，或不存在，Ar 2为具有芳香性的配位体，可以或不具有取代基，当Ar 2被取代时，取代基数为1个 以上，M为过渡金属的原子或离子，A1和A2均为碳原子，A1和A2中的一个为碳原子，另一个为氮原子，Y为阴离子基团或阳离子基团， 或不存在，L为任何配体或不存在，m为正整数，0或负整数。
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6.发明申请METHOD FOR PRODUCING HYDROGEN PEROXIDE, KIT FOR PRODUCING HYDROGEN PEROXIDE, AND FUEL BATTERY 审中-公开生产过氧化氢的方法，生产过氧化氢的工具包和燃料电池公开(公告)号：US20140141346A1
公开(公告)日：2014-05-22
申请号：US14129001
申请日：2012-06-25
CPC分类号： B01J19/127 , B01J31/1815 , B01J31/183 , B01J31/2295 , B01J2531/821 , C01B15/027 , H01M8/06 , H01M8/0606 , H01M8/20 , Y02E60/528
摘要： The present invention provides a method and a kit for producing hydrogen peroxide, capable of producing hydrogen peroxide at low cost. The present invention further provides a fuel battery capable of utilizing hydrogen peroxide as a low-cost fuel. The method for producing hydrogen peroxide of the present invention includes a hydrogen peroxide generation step of irradiating a reaction system containing water, a water oxidation catalyst, a transition metal complex, and oxygen (O2) with light to generate hydrogen peroxide. The kit of the present invention includes the transition metal complex and the water oxidation catalyst that are used in the method for producing hydrogen peroxide of the present invention. The fuel battery of the present invention includes a fuel container and a fuel battery cell, and the fuel container contains the transition metal complex and the water oxidation catalyst that are used in the method for producing hydrogen peroxide of the present invention.
摘要翻译： 本发明提供能够以低成本生产过氧化氢的过氧化氢的制造方法和试剂盒。 本发明还提供一种能够使用过氧化氢作为低成本燃料的燃料电池。 本发明的过氧化氢的制造方法包括：过氧化氢的生成步骤，用光照射含有水的反应体系，水氧化催化剂，过渡金属配合物和氧（O 2），生成过氧化氢。 本发明的试剂盒包括在本发明的过氧化氢的制造方法中使用的过渡金属络合物和水氧化催化剂。 本发明的燃料电池包括燃料容器和燃料电池单体，燃料容器含有本发明的过氧化氢的制造方法中使用的过渡金属络合物和水氧化催化剂。
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7.发明申请MONONUCLEAR METAL COMPLEX, HYDROGENATION REDUCTION CATALYST, DEHYDROGENATION CATALYST, METHOD FOR PRODUCING HYDROGENATION REDUCTION PRODUCT, METHOD FOR PRODUCING HYDROGEN (H2), AND METHOD FOR PRODUCING DEHYDROGENATION REACTION 有权单体金属络合物，氢化还原催化剂，脱氢催化剂，生产氢化还原产物的方法，用于生产氢气（H 2）的方法和用于生产脱氢反应的方法公开(公告)号：US20120321550A1
公开(公告)日：2012-12-20
申请号：US13582653
申请日：2011-03-04
CPC分类号： C07F15/0033 , B01J31/0252 , B01J31/1815 , B01J31/2295 , B01J2231/625 , B01J2531/827 , B01J2540/12 , B01J2540/32 , C07F17/02
摘要： The present invention provides: a mononuclear metal complex that has high catalytic activity and can be used as a hydrogenation reduction catalyst that allows efficient hydrogenation reduction of a substance to be reduced; a tautomer or stereoisomer thereof; or a salt thereof. Provided is the mononuclear metal complex represented by the following formula (1), a tautomer or stereoisomer thereof; or a salt thereof. In the formula (1), Ar1 is an aromatic anionic ligand or an aromatic ligand, or is not present, Ar2 is a ligand having aromaticity and may or may not be substituted, and when Ar2 is substituted, the number of substituents may be one or more, M is an atom or ion of a transition metal, A1 and A2 are both carbon atoms, or one of A1 and A2 is a carbon atom and the other is a nitrogen atom, Y is an anionic group or a cationic group, or is not present, L is any ligand or is not present, and m is a positive integer, 0, or a negative integer.
摘要翻译： 本发明提供：具有高催化活性并可用作氢化还原催化剂的单核金属络合物，其允许有待降低的物质的氢化还原; 其互变异构体或立体异构体; 或其盐。 提供由下式（1）表示的单核金属络合物，其互变异构体或立体异构体; 或其盐。 在式（1）中，Ar 1为芳族阴离子配位体或芳香族配体，或不存在，Ar 2为具有芳香性的配位体，可以或不具有取代基，当Ar 2被取代时，取代基数为1个 以上，M为过渡金属的原子或离子，A1和A2均为碳原子，A1和A2中的一个为碳原子，另一个为氮原子，Y为阴离子基团或阳离子基团， 或不存在，L为任何配体或不存在，m为正整数，0或负整数。
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