公开(公告)号：US07550246B2

公开(公告)日：2009-06-23

申请号：US10573780

申请日：2004-09-24

申请人： Shunichi Fukuzumi ,  Seiji Ogo ,  Tomoyoshi Suenobu

发明人： Shunichi Fukuzumi ,  Seiji Ogo ,  Tomoyoshi Suenobu

IPC分类号： G03F7/00 ,  G03F7/004

CPC分类号： C07D213/89 ,  C07F17/02 ,  G03F7/0045

摘要： A photoacid generator comprising a metal hydride complex represented by the formula (I): wherein X represents a metal atom. The iridium hydride complex of the present invention can be used as an acid generator for chemically-amplified photoresists or color filters for liquid crystal, and in addition, can be widely applied in photographic-related or printing-related fields, or the like.

摘要翻译： 一种光酸产生剂，其包含由式（I）表示的金属氢化物络合物：其中X表示金属原子。 本发明的铱氢化物络合物可以用作化学放大型光致抗蚀剂或液晶用滤色器的酸发生剂，另外也可广泛应用于照相相关或印刷相关领域等。

公开(公告)号：US07939461B2

公开(公告)日：2011-05-10

申请号：US12515357

申请日：2007-05-17

申请人： Shunichi Fukuzumi ,  Tomoyoshi Suenobu ,  Seiji Ogo

发明人： Shunichi Fukuzumi ,  Tomoyoshi Suenobu ,  Seiji Ogo

IPC分类号： C01B3/22 ,  C01B3/02 ,  C07F15/00 ,  B01J10/00 ,  B01J27/13 ,  B01J31/00

CPC分类号： B01J31/1815 ,  B01J31/2295 ,  B01J2531/0219 ,  B01J2531/821 ,  B01J2531/827 ,  C01B3/22 ,  C01B3/32 ,  C01B2203/0277 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1211

摘要： A catalyst for the decomposition of formic acid including a dinuclear metal complex represented by a formula (1) below, a tautomer or stereoisomer thereof, or any of their salts, where M1 and M2 are transition metals; Ar is a ligand having aromaticity and may be unsubstituted or substituted; R1 to R27 are each independently a hydrogen atom, an alkyl group, or the like, or R15 and R16 may together form a —CH═CH—, where Hs in the —CH═CH— may be each independently replaced by an alkyl group or the like, and R23 and R24 may together form a —CH═CH—, where Hs in the —CH═CH— may be each independently replaced by an alkyl group or the like; L is an arbitrary ligand or is absent; and m is a positive integer, 0, or a negative integer.

摘要翻译： 一种用于分解甲酸的催化剂，包括由下式（1）表示的双核金属络​​合物，其互变异构体或立体异构体或其任何盐，其中M1和M2为过渡金属; Ar是具有芳香性的配体，可以是未取代的或取代的; R 1至R 27各自独立地为氢原子，烷基等，或者R 15和R 16可以一起形成-CH = CH-，其中-CH = CH-中的H可各自独立地被烷基取代 R 23和R 24可以一起形成-CH = CH-，其中-CH = CH-中的H可各自独立地被烷基等取代; L是任意的配体或不存在; 并且m是正整数，0或负整数。

公开(公告)号：US20100034733A1

公开(公告)日：2010-02-11

申请号：US12515357

申请日：2007-05-17

申请人： Shunichi Fukuzumi ,  Tomoyoshi Suenobu ,  Seiji Ogo

发明人： Shunichi Fukuzumi ,  Tomoyoshi Suenobu ,  Seiji Ogo

IPC分类号： C01B3/22 ,  C07F15/00 ,  C01B3/02 ,  B01J10/00

CPC分类号： B01J31/1815 ,  B01J31/2295 ,  B01J2531/0219 ,  B01J2531/821 ,  B01J2531/827 ,  C01B3/22 ,  C01B3/32 ,  C01B2203/0277 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1211

摘要： The present invention provides a catalyst for the decomposition of formic acid including a dinuclear metal complex represented by a formula (1) below, a tautomer or stereoisomer thereof, or any of their salts, where M1 and M2 are transition metals and may be the same or different; Ar is a ligand having aromaticity and may be unsubstituted or substituted by one or more substituents; R1 to R27 are each independently a hydrogen atom, an alkyl group, or the like, or R15 and R16 may together form a —CH═CH—, where Hs in the —CH═CH— may be each independently replaced by an alkyl group or the like, and R23 and R24 may together form a —CH═CH—, where Hs in the —CH═CH— may be each independently replaced by an alkyl group or the like; L is an arbitrary ligand or is absent; and m is a positive integer, 0, or a negative integer.

摘要翻译： 本发明提供一种用于分解甲酸的催化剂，其包括由下式（1）表示的二核金属络合物，其互变异构体或立体异构体或其任何盐，其中M1和M2为过渡金属并且可以相同 或不同; Ar是具有芳香性的配体，可以是未取代的或被一个或多个取代基取代; R 1至R 27各自独立地为氢原子，烷基等，或者R 15和R 16可以一起形成-CH-CH-，其中-CH-CH-中的H可各自独立地被烷基取代 R 23和R 24可以一起形成-CH-CH-，其中-CH-CH-中的Hs可以各自独立地被烷基等取代; L是任意的配体或不存在; 并且m是正整数，0或负整数。

公开(公告)号：US20070059633A1

公开(公告)日：2007-03-15

申请号：US10573780

申请日：2004-09-24

申请人： Shunichi Fukuzumi ,  Seiji Ogo ,  Tomoyoshi Suenobu

发明人： Shunichi Fukuzumi ,  Seiji Ogo ,  Tomoyoshi Suenobu

IPC分类号： G03C1/00

CPC分类号： C07D213/89 ,  C07F17/02 ,  G03F7/0045

摘要： A photoacid generator comprising a metal hydride complex represented by the formula (I): wherein X represents a metal atom. The iridium hydride complex of the present invention can be used as an acid generator for chemically-amplified photoresists or color filters for liquid crystal, and in addition, can be widely applied in photographic-related or printing-related fields, or the like.

摘要翻译： 一种光酸产生剂，其包含由式（I）表示的金属氢化物络合物：其中X表示金属原子。 本发明的铱氢化物络合物可以用作化学放大型光致抗蚀剂或液晶用滤色器的酸发生剂，另外也可广泛应用于照相相关或印刷相关领域等。

公开(公告)号：US20070290129A1

公开(公告)日：2007-12-20

申请号：US10590939

申请日：2005-02-23

申请人： Seiji Ogo ,  Shunichi Fukuzumi ,  Yoshihito Watanabe

发明人： Seiji Ogo ,  Shunichi Fukuzumi ,  Yoshihito Watanabe

IPC分类号： G01N27/62 ,  G01N21/25 ,  H01J49/10

CPC分类号： G01J3/443 ,  G01N21/31 ,  G01N21/33 ,  G01N21/35 ,  G01N21/3504 ,  G01N21/64 ,  G01N21/65 ,  H01J49/0468 ,  H01J49/165

摘要： An ionization chamber of an analytical apparatus (10) in which high concentration test sample ions are evaporated is provided with an ion introduction control means (8) to control the quantity of the test sample ions introduced to an ion attracting electrode (9). Therefore, an analytical apparatus can be provided that is capable of substantially simultaneous mass spectrometry and absorption, emission, and scattering spectroscopy. The apparatus also includes: a low temperature bath (106) which cools the test sample solution before it is introduced to the sprayer (104); and a cooling gas introduction tube (108), constructed separately from the sprayer, which cools the sprayer and the test sample solution introduced to the sprayer (104). The inclusion enables effective restriction of test sample heating upon high voltage application. Mass spectrometry and absorption, emission, and scattering spectroscopy can be substantially simultaneously carried out even when the test sample used is stable only at extremely low temperatures.

摘要翻译： 提供高浓度测试样品离子蒸发的分析装置（10）的电离室设置有离子引入控制装置（8），以控制引入离子吸引电极（9）的测试样品离子的量。 因此，可以提供能够基本上同时进行质谱分析和吸收，发射和散射光谱学的分析装置。 所述设备还包括：在将测试样品溶液引入喷雾器（104）之前将测试样品溶液冷却的低温浴（106）; 以及冷却气体引入管（108），其与喷雾器分开构成，其冷却喷雾器和引入喷雾器（104）的测试样品溶液。 包含能够在高压施加时有效限制测试样品加热。 即使使用的测试样品仅在极低温度下稳定，也可以基本上同时进行质谱和吸收，发射和散射光谱学。

公开(公告)号：US20070036706A1

公开(公告)日：2007-02-15

申请号：US10572376

申请日：2004-09-10

申请人： Seiji Ogo ,  Shuichi Fukuzumi

发明人： Seiji Ogo ,  Shuichi Fukuzumi

IPC分类号： C01B31/18

CPC分类号： C07C51/00 ,  B01J31/1815 ,  B01J31/2256 ,  B01J31/2295 ,  B01J2231/625 ,  B01J2531/821

摘要： Carbon dioxide and water are mixed with an organometallic complex represented by general formula (1) below where R1, R2, R3, R4, R5, and R6 independently represent a hydrogen atom or a lower alkyl group, M represents an element that can be coordinated to the benzene ring, X1 and X2 represent nitrogen-containing ligands, X3 represents a hydrogen atom, a carboxylic acid residue, or H2O, X1 and X2 may be bonded to each other, Y represents an anion species, K represents a valency of a cation species, L represents a valency of an anion species, K and L independently represent 1 or 2, and K, m, L, and n are related to one another by K×m=L×n. This makes it possible to directly reduce carbon dioxide in water.

摘要翻译： 将二氧化碳和水与由下式（1）表示的有机金属络合物混合，其中R 1，R 2，R 3，R 3，R 3， R 4，R 5和R 6独立地表示氢原子或低级烷基，M表示可以与 苯环，X 1和X 2代表含氮配体，X 3表示氢原子，羧酸残基或H“ O 2，X 1和X 2可以彼此键合，Y表示阴离子种类，K表示阳离子种类的化合价， L表示阴离子种类的化合价，K和L独立地表示1或2，K，m，L和n通过Kxm = Lxn彼此相关。 这使得可以直接减少水中的二氧化碳。

公开(公告)号：US20090216044A1

公开(公告)日：2009-08-27

申请号：US12066491

申请日：2006-09-13

申请人： Seiji Ogo ,  Shun-ichi Fukuzumi

发明人： Seiji Ogo ,  Shun-ichi Fukuzumi

IPC分类号： C07C51/347

CPC分类号： C07C51/373 ,  B01J31/181 ,  B01J31/2295 ,  B01J2531/0247 ,  B01J2531/821 ,  B01J2531/822 ,  C07C67/313 ,  C07C227/04 ,  C07C229/08 ,  C07C59/347 ,  C07C69/716

摘要： An object of the present invention is to provide a method for synthesis of keto acids by hydration of an acetylene compound (acetylene-carboxylic acids) under mild conditions free from harmful mercury catalysts and a method for synthesis of amino acids from acetylene-carboxylic acids in a single container (one-pot or tandem synthesis). In one embodiment of the method according to the present invention for synthesis of keto acids, acetylene-carboxylic acids is hydrated in the presence of a metal salt represented by General Formula (1), where M1 represents an element in Group VIII, IX, or X of the periodic table, and X1, X2, or X3 ligand represents halogen, H2O, or a solvent molecule, and k represents a valence of a cation species, and Y represents an anion species, and L represents a valence of the anion species, and each of K and L independently represents 1 or 2, and k×m=L×n.

摘要翻译： 本发明的目的是提供一种通过在不含有害汞催化剂的温和条件下乙炔化合物（乙炔 - 羧酸）的水合合成酮酸的方法和由乙炔 - 羧酸合成氨基酸的方法 单一容器（一锅或串联合成）。 在根据本发明的用于合成酮酸的方法的一个实施方案中，乙炔 - 羧酸在通式（1）表示的金属盐存在下水合，其中M1表示VIII族，IX族或 X，X 1，X 2或X 3配体表示卤素，H 2 O或溶剂分子，k表示阳离子种类的化合价，Y表示阴离子种类，L表示阴离子种类的化合价 ，K和L各自独立地表示1或2，kxm = Lxn。

公开(公告)号：US07479570B2

公开(公告)日：2009-01-20

申请号：US10572376

申请日：2004-09-10

申请人： Seiji Ogo ,  Shuichi Fukuzumi

发明人： Seiji Ogo ,  Shuichi Fukuzumi

IPC分类号： C07C53/00

CPC分类号： C07C51/00 ,  B01J31/1815 ,  B01J31/2256 ,  B01J31/2295 ,  B01J2231/625 ,  B01J2531/821

摘要： Carbon dioxide and water are mixed with an organometallic complex represented by general formula (1) below where R1, R2, R3, R4, R5, and R6 independently represent a hydrogen atom or a lower alkyl group, M represents an element that can be coordinated to the benzene ring, X1 and X2 represent nitrogen-containing ligands, X3 represents a hydrogen atom, a carboxylic acid residue, or H2O, X1 and X2 may be bonded to each other, Y represents an anion species, K represents a valency of a cation species, L represents a valency of an anion species, K and L independently represent 1 or 2, and K, m, L, and n are related to one another by K×m=L×n. This makes it possible to directly reduce carbon dioxide in water.

摘要翻译： 将二氧化碳和水与由下式（1）表示的有机金属络合物混合，其中R1，R2，R3，R4，R5和R6独立地表示氢原子或低级烷基，M表示可以配位的元素 对于苯环，X 1和X 2表示含氮配体，X 3表示氢原子，羧酸残基或H 2 O，X 1和X 2可以彼此键合，Y表示阴离子种类，K表示 阳离子种类，L表示阴离子种类的化合价，K和L独立地表示1或2，K，m，L和n通过Kxm = Lxn彼此相关。 这使得可以直接减少水中的二氧化碳。

公开(公告)号：US20120100462A1

公开(公告)日：2012-04-26

申请号：US13377327

申请日：2010-06-09

申请人： Seiji Ogo

发明人： Seiji Ogo

IPC分类号： H01M4/90

CPC分类号： H01M4/9008

摘要： To provide an economical fuel cell electrode catalyst which can be used in place of platinum as a simple substance or a platinum alloy and has easy-to-control catalytic power, a molecular metal complex is used as a fuel cell electrode catalyst which molecular metal complex is a mononuclear or multinuclear coordination compound that has a particular structure, that is not a polymer compound, and that does not have a layered structure.

摘要翻译： 为了提供一种经济的燃料电池电极催化剂，其可以用作代替铂作为单质或铂合金，并且具有易于控制的催化能力，分子金属络合物用作燃料电池电极催化剂，其分子金属络合物 是具有特定结构的单核或多核配位化合物，不是高分子化合物，并且不具有层状结构。

公开(公告)号：US08153839B2

公开(公告)日：2012-04-10

申请号：US12066491

申请日：2006-09-13

申请人： Seiji Ogo ,  Shun-ichi Fukuzumi

发明人： Seiji Ogo ,  Shun-ichi Fukuzumi

IPC分类号： C07C61/00 ,  C07C205/00

CPC分类号： C07C51/373 ,  B01J31/181 ,  B01J31/2295 ,  B01J2531/0247 ,  B01J2531/821 ,  B01J2531/822 ,  C07C67/313 ,  C07C227/04 ,  C07C229/08 ,  C07C59/347 ,  C07C69/716

摘要： An object of the present invention is to provide a method for synthesis of keto acids by hydration of an acetylene compound (acetylene-carboxylic acids) under mild conditions free from harmful mercury catalysts and a method for synthesis of amino acids from acetylene-carboxylic acids in a single container (one-pot or tandem synthesis). In one embodiment of the method according to the present invention for synthesis of keto acids, acetylene-carboxylic acids is hydrated in the presence of a metal salt represented by General Formula (1), where M1 represents an element in Group VIII, IX, or X of the periodic table, and X1, X2, or X3 ligand represents halogen, H2O, or a solvent molecule, and k represents a valence of a cation species, and Y represents an anion species, and L represents a valence of the anion species, and each of K and L independently represents 1 or 2, and k×m=L×n.

摘要翻译： 本发明的目的是提供一种通过在不含有害汞催化剂的温和条件下乙炔化合物（乙炔 - 羧酸）的水合合成酮酸的方法和由乙炔 - 羧酸合成氨基酸的方法 单一容器（一锅或串联合成）。 在根据本发明的用于合成酮酸的方法的一个实施方案中，乙炔 - 羧酸在通式（1）表示的金属盐存在下水合，其中M1表示VIII族，IX族或 X，X 1，X 2或X 3配体表示卤素，H 2 O或溶剂分子，k表示阳离子种类的化合价，Y表示阴离子种类，L表示阴离子种类的化合价 ，K和L各自独立地表示1或2，k×m = L×n。