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公开(公告)号：US4600504A
公开(公告)日：1986-07-15
申请号：US695786
申请日：1985-01-28
CPC分类号： C10G45/08
摘要： At least one decomposable compound selected from the group consisting of compounds of the metals of Group IIB and Group IIIB of the Periodic Table is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing such decomposable compound is then contacted in a hydrofining process with a catalyst composition comprising a support selected from the group consisting of alumina, silica and silica-alumina and a promoter comprising at least one metal selected from Group VIB, Group VIIB and Group VIII of the Periodic Table. The introduction of the decomposable compound may be commenced when the catalyst is new, partially deactivated or spent with a beneficial result occurring in each case.
摘要翻译： 将选自由周期表IIB族和IIIB族金属的化合物组成的组中的至少一种可分解化合物与含烃进料流混合。 然后将含有这种可分解化合物的含烃进料流在加氢精制过程中与包含选自氧化铝，二氧化硅和二氧化硅 - 氧化铝的载体的催化剂组合物和包含至少一种选自VIB族的金属的促进剂接触， 第VIIB和第八组。 当催化剂是新的，部分失活的或者在每种情况下都有有益的结果消耗时，可以开始引入可分解的化合物。
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公开(公告)号：US4885080A
公开(公告)日：1989-12-05
申请号：US198767
申请日：1988-05-25
IPC分类号： C10G65/16
CPC分类号： C10G65/16
摘要： A heavy crude oil is fractionated into at least three liquid fractions which include a distillate fraction boiling in the 400.degree. F.-650.degree. F. range and a 650.degree. F.+ boiling range residuum. The distillate cut is hydrodesulfurized and the residuum is hydrodemetallized. The cuts thus hydrotreated, and at least a part of the third liquid fraction, are then combined to form an upgraded synthetic crude oil of relatively low sulfur content and relatively low vanadium and nickel content.
摘要翻译： 重质原油分馏成至少三种液体馏分，其中包括在400°F-650°F范围内沸腾的馏出物馏分和650°F +沸点残渣。 蒸馏馏分加氢脱硫，渣油加氢脱金属。 然后将如此加氢处理的切口和至少一部分第三液体馏分组合以形成相对低的硫含量和相对低的钒和镍含量的升级的合成原油。
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公开(公告)号：US4578180A
公开(公告)日：1986-03-25
申请号：US596983
申请日：1984-04-05
摘要： At least one decomposable compound selected from the group consisting of dimanganese decacarbonyl and chromium hexacarbonyl is mixed with a hydrocarbon-containing feed stream. The hydrocarbon containing feed stream containing such decomposable compound is then contacted in a hydrofining process with a catalyst composition comprising a support selected from the group consisting of alumina, silica and silica-alumina and a promoter comprising at least one metal selected from Group VIB, Group VIIB and Group VIII of the Periodic Table. The introduction of the decomposable compound may be commenced when the catalyst is new, partially deactivated or spent with a beneficial result occurring in each case.
摘要翻译： 将至少一种选自二醛黑半胱氨酸和六羰基铬的可分解化合物与含烃进料流混合。 然后将含有这种可分解化合物的含烃进料流在加氢精制过程中与包含选自氧化铝，二氧化硅和二氧化硅 - 氧化铝的载体的催化剂组合物和包含至少一种选自组VIB， VIIB和第八期。 当催化剂是新的，部分失活的或者在每种情况下都有有益的结果消耗时，可以开始引入可分解的化合物。
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公开(公告)号：US4612110A
公开(公告)日：1986-09-16
申请号：US589362
申请日：1984-03-14
摘要： At least one decomposable molybdenum dithiocarbamate compound is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing such decomposable molybdenum dithiocarbamate compound is then contacted in a hydrofining process with a catalyst composition comprising a support selected from the group consisting of alumina, silica and silica-alumina and a promoter comprising at least one metal selected from Group VIB, Group VIIB and Group VIII of the Periodic Table. The introduction of the decomposable molybdenum dithiocarbamate compound may be commenced when the catalyst is new, partially deactivated or spent with a beneficial result occurring in each case.
摘要翻译： 将至少一种可分解的二硫代氨基甲酸钼化合物与含烃进料流混合。 然后将含有这种可分解的二硫代氨基甲酸钼化合物的含烃进料流在加氢精制过程中与包含选自氧化铝，二氧化硅和二氧化硅 - 氧化铝的载体的催化剂组合物和包含至少一种选自组 VIB，VIIB和VIII组。 当可催化的新二硫代氨基甲酸酯化合物引入时，可以在每一种情况下发生有益的结果，部分失活或消耗。
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公开(公告)号：US4582594A
公开(公告)日：1986-04-15
申请号：US647220
申请日：1984-09-04
摘要： The reaction product of a mercaptoalcohol and a molybdenum compound selected from the group consisting of molybdic acids, alkali metal salts of molybdic acids and ammonium salts of molybdic acids is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing such reaction product is then contacted in a hydrofining process with a catalyst composition comprising a support selected from the group consisting of Al.sub.2 O.sub.3, SiO.sub.2, Al.sub.2 O.sub.3 --SiO.sub.2, Al.sub.2 O.sub.3 --TiO.sub.2, Al.sub.2 O.sub.3 --P.sub.2 O.sub.5, Al.sub.2 O.sub.3 --BPO.sub.4, Al.sub.2 O.sub.3 --AlPO.sub.4, Al.sub.2 O.sub.3 --Zr.sub.3 (PO.sub.4).sub.4, Al.sub.2 O.sub.3 --SnO.sub.2 and Al.sub.2 O.sub.3 --ZnO and a promoter comprising at least one metal selected from Group VIB, Group VIIB and Group VIII of the Periodic Table. The introduction of the reaction product may be commenced when the catalyst is new, partially deactivated or spent with a beneficial result occuring in each case.
摘要翻译： 巯基醇和选自钼酸，钼酸的碱金属盐和钼酸铵盐的钼化合物的反应产物与含烃进料流混合。 含有该反应产物的含烃进料流然后在加氢精制过程中与包含选自Al2O3，SiO2，Al2O3-SiO2，Al2O3-TiO2，Al2O3-P2O5，Al2O3-BPO4， Al2O3-AlPO4，Al2O3-Zr3（PO4）4，Al2O3-SnO2和Al2O3-ZnO，以及包含选自元素周期表第VIB族，第VIIB族和第VIII族中的至少一种金属的促进剂。 反应产物的引入可以在催化剂是新的，部分失活的或在每一种情况下产生有益结果的情况下消耗或开始。
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公开(公告)号：US4560468A
公开(公告)日：1985-12-24
申请号：US596982
申请日：1984-04-05
摘要： At least one decomposable molybdenum dithiophosphate compound is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing such decomposable molybdenum dithiophosphate compound is then contacted in a hydrofining process with a catalyst composition comprising a support selected from the group consisting of alumina, silica and silica-alumina and a promoter comprising at least one metal selected from Group VIB, Group VIIB and Group VIII of the Periodic Table. The introduction of the decomposable molybdenum dithiophosphate compound may be commenced when the catalyst is new, partially deactivated or spent with a beneficial result occuring in each case.
摘要翻译： 将至少一种可分解的二硫代磷酸钼化合物与含烃进料流混合。 然后将含有这种可分解的二硫代磷酸钼化合物的含烃进料流在加氢精制过程中与包含选自氧化铝，二氧化硅和二氧化硅 - 氧化铝的载体的催化剂组合物和包含至少一种选自组 VIB，VIIB和VIII组。 当可催化的新二硫代磷酸酯化合物引入时，可以在每种情况下产生有益效果的部分失活或消耗。
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公开(公告)号：US4557823A
公开(公告)日：1985-12-10
申请号：US623665
申请日：1984-06-22
CPC分类号： C10G45/02
摘要： At least one decomposable compound selected from the group consisting of compounds of the metals of Group IVB of the Periodic Table is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing such decomposable compound is then contacted in a hydrofining process with a catalyst composition comprising a support selected from the group consisting of alumina, silica and silica-alumina and a promoter comprising at least one metal selected from Group VIB, Group VIIB and Group VIII of the Periodic Table. The introduction of the decomposable compound may be commenced when the catalyst is new, partially deactivated or spent with a beneficial result occuring in each case.
摘要翻译： 将选自元素周期表IVB族金属的化合物的至少一种可分解化合物与含烃进料流混合。 然后将含有这种可分解化合物的含烃进料流在加氢精制过程中与包含选自氧化铝，二氧化硅和二氧化硅 - 氧化铝的载体的催化剂组合物和包含至少一种选自VIB族的金属的促进剂接触， 第VIIB和第八组。 当催化剂是新的，部分失活的或者在每种情况下产生有益结果的情况下，可以引入可分解化合物。
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8.发明授权Mixture of a molybdenum carboxylate and a molybdenum dithiophosphate or a molybdenum dithiocarbamate for use in a hydrovisbreaking process 失效钼酸钼和二硫代磷酸钼或二硫代氨基甲酸钼的混合物用于加氢脱硫工艺
公开(公告)号：US4705766A
公开(公告)日：1987-11-10
申请号：US866552
申请日：1986-05-23
申请人： Jerald A. Howell , Simon G. Kukes
发明人： Jerald A. Howell , Simon G. Kukes
CPC分类号： C07C53/126 , C07C61/06 , C07C61/08 , C10G47/22 , C10G9/007
摘要： A decomposable molybdenum compound selected from the group consisting of a mixture of a molybdenum dithiophosphate and a molybdenum carboxylate and a mixture of a molybdenum dithiocarbamate and a molybdenum carboxylate is disclosed. The decomposable molybdenum compound may be added, in a hydrovisbreaking process, to a hydrocarbon-containing feed stream prior to contacting the feed stream with hydrogen under suitable hydrovisbreaking conditions.
摘要翻译： 公开了一种可分解的钼化合物，其选自二硫代磷酸钼和羧酸钼的混合物以及二硫代氨基甲酸钼和钼酸钼的混合物。 在加氢脱硫工艺中，可分解的钼化合物可以在合适的加氢脱硫条件下将进料流与氢气接触之前加入含烃进料流中。
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公开(公告)号：US4708784A
公开(公告)日：1987-11-24
申请号：US18690
申请日：1987-02-25
申请人： Jerald A. Howell , Simon G. Kukes
发明人： Jerald A. Howell , Simon G. Kukes
CPC分类号： C10G47/26
摘要： A hydrotreating (hydrovisbreaking) process comprises the step of contacting under suitable reaction conditions (A) a substantially liquid hydrocarbon-containing feed stream which contains more than 0.1 weight-% Ramsbottom carbon residue, (B) a free hydrogen-containing gas and (C) a catalyst composition comprising alkyl molybdate and/or molybdenum sulfonate.
摘要翻译： 加氢处理（加氢脱硫）方法包括在合适的反应条件（A）下接触的步骤（A）基本上液体含烃的进料流，其含有大于0.1重量％的Ramsbottom碳残余物，（B）游离含氢气体和（C ）包含钼酸烷基酯和/或磺酸钼的催化剂组合物。
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公开(公告)号：US4608152A
公开(公告)日：1986-08-26
申请号：US677134
申请日：1984-11-30
申请人： Jerald A. Howell , Simon G. Kukes
发明人： Jerald A. Howell , Simon G. Kukes
IPC分类号： C10G45/08 , B01J27/19 , B01J27/20 , B01J27/24 , B01J31/02 , C07C53/126 , C07C61/06 , C07C61/08 , C10G9/00 , C10G45/04 , C10G47/22 , C10G45/60 , C10G47/02 , C10G49/04
CPC分类号： C07C61/08 , C07C53/126 , C07C61/06 , C10G47/22 , C10G9/007
摘要： At least one decomposable molybdenum additive selected from the group consisting of a mixture of a molybdenum dithiophosphate and a molybdenum carboxylate and a mixture of a molybdenum dithiocarbamate and a molybdenum carboxylate is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing such decomposable molybdenum additive is then contacted in a hydrovisbreaking process with hydrogen under suitable hydrovisbreaking conditions.
摘要翻译： 将选自二硫代磷酸钼和羧酸钼的混合物和二硫代氨基甲酸钼和钼酸钼的混合物的至少一种可分解的钼添加剂与含烃进料流混合。 然后将含有这种可分解的钼添加剂的含烃进料流在加氢脱硫工艺中与合适的加氢脱硫条件下的氢气接触。
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