摘要:
A phthalocyanine dye of formula (I) is provided: wherein M is a metal group or is absent; Ar1, Ar2, Ar3, Ar4, Ar5, Ar6, Ar7 and Ar8 are selected from phenyl, naphthyl, pyridyl, furanyl, pyrollyl or thiophenyl, each of Ar1, Ar2, Ar3, Ar4, Ar5, Ar6, Ar7 and Ar8 being optionally substituted with 1, 2, 3, 4 or 5 groups, the or each group being independently selected from C1-12alkyl, C1-12alkoxy, C1-12arylalkyl, C1-12 arylalkoxy, —(OCH2CH2)dORd, cyano, halogen, amino, hydroxyl, thiol, —SRv, —NRuRv, nitro, phenyl, phenoxy, —CO2Rv, —C(O)Rv, —OCORv, —SO2Rv, —OSO2Rv, —NHC(O)Rv, —CONRuRv, —CONRuRv, sulfonic acid, sulfonic acid salt and sulfonamide; d is an integer from 2 to 5000; Rd is H, C1-8alkyl or C(O)C1-8alkyl; Ru and Rv are independently selected from hydrogen, C1-12alkyl, phenyl or phenyl-C1-8alkyl; wherein at least one of Ar1, Ar2, Ar3, Ar4, Ar5, Ar6, Ar7 and Ar8 is substituted with a sulfonic acid, a sulfonic acid salt or a sulfonamide group. Dyes of this type are especially suitable for use in netpage and Hyperlabel™ systems.
摘要:
A phthalocyanine dye of formula (I) is provided: wherein: M is a metal group or is absent; n is 1 or 2; X is selected from —CHR3—, —NR3—, —O— or —S—; R1, R2 and R3 are independently selected from hydrogen, C1-8 alkyl, C1-8 alkoxy, carboxy, carboxy-C1-8 alkyl, hydroxyl, hydroxy-C1-8 alkyl; or R1 and R2, or R2 and R3 together are joined to form a C4-12 aryl or C3-12 heteroaryl group, optionally substituted with 1, 2, 3 or 4 substituent groups, the or each substituent group being independently selected from C1-12 alkyl, C1-12 alkoxy, phenyl-C1-8 alkyl, phenyl-C1-8 alkoxy, —(OCH2CH2)dORd, cyano, halogen, amino, hydroxyl, thiol, —SRv, —NRuRv, nitro, phenyl, phenoxy, —CO2Rv, —C(O)Rv, —OCORv, —SO2Rv, —OSO2Rv, —NHC(O)Rv, —CONRuRv, —CONRuRv, sulfonic acid, sulfonic acid salt and sulfonamide; d is an integer from 2 to 5000; Rd is H, C1-8 alkyl or C(O)C1-8 alkyl and Ru and Rv are independently selected from hydrogen, C1-12 alkyl, phenyl or phenyl-C1-8 alkyl. Dyes of this type are especially suitable for use in netpage and Hyperlabel™ systems.
摘要:
The present invention provides an inkjet ink comprising an IR-absorbing naphthalocyanine dye of formula (I): wherein M is selected from Si(A1)(A2), Ge(A1)(A2), Ga(A1), Mg, Al(A1), TiO, Ti(A1)(A2), ZrO, Zr(A1)(A2), VO, V(A1)(A2), Mn, Mn(A1), Fe, Fe(A1), Co, Ni, Cu, Zn, Sn, Sn(A1)(A2), Pb, Pb(A1)(A2), Pd and Pt; A1 and A2 are axial ligands, which may be the same or different, and are selected from —OH, halogen or —OR3; R1 and R2 are selected from H or C1-12 alkoxy; R3 is selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl or Si(Rx)(Ry)(Rz); and Rx, Ry and Rz may be the same or different and are selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl, C1-12 alkoxy, C5-12 aryloxy or C5-12 arylalkoxy; W is selected from a sulfonic acid group (including salts thereof) or a sulfonamide group; n1 is 0, 1, 2 or 3; n2 is 0, 1, 2 or 3; n3 is 0, 1, 2 or 3; n4 is 0, 1, 2 or 3; provided that at least one of n1, n2, n3 or n4 is greater than 0. Inks of this type are especially suitable for use in netpage and Hyperlabel systems.
摘要:
An ink comprising an IR-absorbing naphthalocyanine dye of formula (I) is described: Wherein M is Ga(A1); A1 is an axial ligand selected from —OH, halogen, —OR3, —OC(O)R4; R1 and R2 may be the same or different and are selected from hydrogen or C1-12 alkoxy; R3 is selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl or Si(Rx)(Ry)(Rz); and R4 is selected from C1-12 alkyl, C5-12 aryl or C5-12 arylalkyl Rx, Ry and Rz may be the same or different and are selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl, C1-12 alkoxy, C5-12 aryloxy or C5-12 arylalkoxy; and W is a sulfonic acid group, including salts thereof.
摘要翻译:描述了包含式(I)的IR吸收萘酞菁染料的油墨:其中M是Ga(A 1 SUP 1); A 1是选自-OH,卤素,-OR 3,-OC(O)R 4的轴向配体; R 1和R 2可以相同或不同,并且选自氢或C 1-12烷氧基; R 3选自C 1-12烷基,C 5-12芳基,C 5-12芳基烷基 或Si(R x X s)(R y y)(R z)); 并且R 4选自C 1-12烷基,C 5-12芳基或C 5-12 - 芳基烷基R x,R y和R z可以相同或不同,并且选自C 1-12 SUB 烷基,C 5-12芳基,C 5-12芳烷基,C 1-12烷氧基,C 5-12烷基, 芳基或C 5-12芳基烷氧基; W是磺酸基,包括其盐。
摘要:
The present invention provides an IR-absorbing metal-cyanine dye, said metal having at least one axial ligand bound thereto, wherein said axial ligand comprises a moiety suitable for reducing intermolecular interactions between adjacent dye molecules, thereby minimizing absorption of visible light. Dyes of this type are especially suitable for use in netpage and Hyperlabel systems.
摘要:
An IR-absorbing naphthalocyanine dye of formula (1) is described: wherein M is Ga(A1); A1 is an axial ligand selected from —OH halogen, —OR3, —OC(O)R4; R1 and R2 may be the same or different and are selected from hydrogen or C1-12 alkoxy; R3 is selected from C1-12 alkyl, C3-12 aryl, C5-12 arylalkyl or Si(Rx)(Ry)(Rz); and R4 is selected from C1-12 alkyl, C5-12 aryl or C5-12 arylalkyl Rx, Ry and Rz may be the same or different and are selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl, C1-12 alkoxy, C5-12 aryloxy or C5-12 arylalkoxy; and W is a sulfonic acid group, including salts thereof.
摘要翻译:描述了式(1)的IR吸收萘酞菁染料:其中M是Ga(A 1 SUP); A 1是选自-OH卤素,-OR 3,-OC(O)R 4的轴向配体; R 1和R 2可以相同或不同,并且选自氢或C 1-12烷氧基; R 3选自C 1-12烷基,C 3-12-12芳基,C 5-12-12芳基烷基 或Si(R x X s)(R y y)(R z)); 并且R 4选自C 1-12烷基,C 5-12芳基或C 5-12 - 芳基烷基R x,R y和R z可以相同或不同,并且选自C 1-12 SUB 烷基,C 5-12芳基,C 5-12芳烷基,C 1-12烷氧基,C 5-12烷基, 芳基或C 5-12芳基烷氧基; W是磺酸基,包括其盐。
摘要:
There is provided an inkjet ink comprising an IR-absorbing dye of formula (I): wherein M is Ga(A1); A1 is an axial ligand selected from —OH, halogen, —OR3, —OC(O)R4, a hydrophilic ligand and/or a ligand suitable for reducing cofacial interactions; R1 and R2 may be the same or different and are selected from hydrogen or C1-12 alkoxy; R3 is selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl or Si(Rx)(Ry)(Rz); and R4 is selected from C1-12 alkyl, C5-12 aryl or C5-12 arylalkyl Rx, Ry and Rz may be the same or different and are selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl, C1-12 alkoxy, C5-12 aryloxy or C5-12 arylalkoxy; W is a hydrophilic group, each W group being independently selected from a substituent comprising a sulfonic acid group (including salts thereof), or a substituent comprising a sulfonamide group; n1 is 0, 1, 2 or 3; n2 is 0, 2, or 3; n3 is 0, 1, 2 or 3; n4 is 0, 1, 2 or 3; provided that at least one of n1, n2, n3 or n4 is greater than 0. Such inks are suitable for use in netpage, Hyperlabel and other applications.
摘要:
The present invention provides an IR-absorbing naphthalocyanine dye of formula (I): wherein M is selected from Ga(A1); A1 is an axial ligand selected from —OH, halogen (preferably Cl), —OR3, a hydrophilic ligand and/or a ligand suitable for reducing cofacial interactions; R1 and R2 may be the same or different and are selected from hydrogen or C1-12 alkoxy (preferably C1-6 alkoxy); R3 is selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl or Si(Rx)(Ry)(Rz); and Rx, Ry and Rz may be the same or different and are selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl, C1-12 alkoxy, C5-12 aryloxy or C5-12 arylalkoxy; W is a hydrophilic group; n1 is 0, 1, 2 or 3; n2 is 0, 1, 2 or 3; n3 is 0, 1, 2 or 3; n4 is 0, 1, 2 or 3; provided that at least one of n1, n2, n3 or n4 is greater than 0. Dyes of this type are especially suitable for use in netpage and Hyperlabel™ systems.
摘要翻译:本发明提供式(I)的IR吸收萘酞菁染料:其中M选自Ga(A 1); A 1是选自-OH,卤素(优选Cl),-OR 3 3,亲水性配体和/或适合于还原亲合相互作用的配体的轴向配体; R 1和R 2可以相同或不同,并且选自氢或C 1-12烷氧基(优选C 1〜 -6个烷氧基); R 3选自C 1-12烷基,C 5-12芳基,C 5-12芳基烷基 或Si(R x X s)(R y y)(R z)); 且R x,R y和R z可以相同或不同,并且选自C 1-12 SUB 烷基,C 5-12芳基,C 5-12芳烷基,C 1-12烷氧基,C 5-12烷基, 芳基或C 5-12芳基烷氧基; W是亲水基团; n1为0,1,2或3; n2为0,1,2或3; n3为0,1,2或3; n4为0,1,2或3; 条件是n1,n2,n3或n4中的至少一个大于0.这种类型的染料特别适用于网页和超标记(TM)系统。
摘要:
The present invention provides a method of minimizing absorption of visible light in an ink composition comprising an IR-absorbing metal cyanine dye, said method comprising preselecting said dye such that said metal has at least one axial ligand bound thereto, wherein said axial ligand comprises a moiety suitable for reducing intermolecular interactions between adjacent dye molecules. The method is especially suitable for use in connection with netpage and Hyperlabel systems.
摘要:
A naphthalocyanine dye of formula (I) is provided: wherein M is a metal group or is absent; R1 and R2 are independently selected from hydrogen or C1-12 alkoxy; X is selected from O, S or —NH—; Ar1, Ar2, Ar3, Ar4, Ar5, Ar6, Ar7 and Ar8 are selected from phenyl, naphthyl, pyridyl, furanyl, pyrollyl, thiophenyl, each of Ar1, Ar2, Ar3, Ar4, Ar5, Ar6, Ar7 and Ar8 being optionally substituted with 1, 2, 3, 4 or 5 groups, the or each group being independently selected from C1-12 alkyl, C1-12 alkoxy, C1-12 arylalkyl, C1-12 arylalkoxy, —(OCH2CH2)dORd, cyano, halogen, amino, hydroxyl, thiol, —SRv, —NRuRv, nitro, phenyl, phenoxy, —CO2Rv, —C(O)Rv, —OCORv, —SO2Rv, —OSO2Rv, —NHC(O)Rv, —CONRuRv, —CONRuRv, sulfonic acid, sulfonic acid salt and sulfonamide; d is an integer from 2 to 5000; Rd is H, C1-8 alkyl or C(O)C1-8 alkyl; and Ru and Rv are independently selected from hydrogen, C1-12 alkyl, phenyl or phenyl-C1-8 alkyl. Dyes of this type are especially suitable for use in netpage and Hyperlabel™ systems.