Cyanine dye having multifunctional peripreral groups

    公开(公告)号:US20060030705A1

    公开(公告)日:2006-02-09

    申请号:US10913378

    申请日:2004-08-09

    IPC分类号: C07D487/22

    CPC分类号: C09B47/0675

    摘要: The present invention provides an IR-absorbing dye of formula (I) or (II) wherein R10, R13, R20, R23, R30, R33, R40 and R43 are independently selected from a C1-12 alkyl group bearing a hydrophilic or hydrophilizable group; R11, R12, R21, R22, R31, R32, R41 and R42 are independently selected from H or a C1-30 hydrocarbyl group, or each of R11/R12, R21/R22, R31/R32, and R41/R42 are together joined to form a C3-30 hydrocarbylene group; M is selected from Si(A1)(A2), Ge(A1)(A2), Ga(A1), Mg, Al(A1), TiO, Ti(A1)(A2), ZrO, Zr(A1)(A2), VO, V(A1)(A2), Mn, Mn(A1), Fe, Fe(A1), Co, Ni, Cu, Zn, Sn, Sn(A1)(A2), Pb, Pb(A1)(A2), Pd and Pt; A1 and A2 are axial ligands, which may be the same or different, and are selected from —OH, halogen, —OR3, a hydrophilic ligand and/or a ligand suitable for reducing intermolecular interactions; R3 is a selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl or Si(Rx)(Ry)(Rz); and Rx, Ry and Rz may be the same or different and are selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl, C1-12 alkoxy, C5-12 aryloxy or C5-12 arylalkoxy. Dyes of this type are especially suitable for use in netpage and Hyperlabel systems.

    Hydrophilizable and hydrophilic cyanine dyes
    7.
    发明申请
    Hydrophilizable and hydrophilic cyanine dyes 有权
    可亲水亲水花青染料

    公开(公告)号:US20060030701A1

    公开(公告)日:2006-02-09

    申请号:US10913377

    申请日:2004-08-09

    IPC分类号: C07D487/14 C09D11/00

    CPC分类号: C09B47/0675 C09D11/32

    摘要: The present invention provides an IR-absorbing dye of formula (I) or (II): Q1, Q2, Q3 and Q4 are the same or different and are independently selected from a C3-20 heteroarylene group comprising at least one N atom; M is selected from Si(A1)(A2), Ge(A1)(A2), Ga(A1), Mg, Al(A1), TiO, Ti(A1)(A2), ZrO, Zr(A1)(A2), VO, V(A1)(A2), Mn, Mn(A1), Fe, Fe(A1), Co, Ni, Cu, Zn, Sn, Sn(A1)(A2), Pb, Pb(A1)(A2), Pd and Pt; A1 and A2 are axial ligands, which may be the same or different, and are selected from —OH, halogen, —OR3, a hydrophilic ligand and/or a ligand suitable for reducing cofacial interactions; R3 is a selected from C1-12 alky, C5-12 aryl, C5-12 arylalkyl or Si(Rx)(Ry)(Rz); and Rx, Ry and Rz may be the same or different and are selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl, C1-12 alkoxy, C5-12 aryloxy or C5-12 arylalkoxy. Dyes of this type are especially suitable for use in netpage and Hyperlabel systems.

    摘要翻译: 本发明提供式(I)或(II)的IR吸收染料:Q 1,Q 2,Q 3,Q 3 4个相同或不同,并且独立地选自包含至少一个N原子的C 3-20亚芳基; Ge选自Si(A 1)(A 2),Ge(A 1)2(S 2 O 2) ),Ga(A 1),Mg,Al(A 1 H 2),TiO,Ti(A 1) ),ZrO,Zr(A 1)(VO 2),VO,V(A 1 SUP)(A SUP) > 2),Mn,Mn(A 1),Fe,Fe(A 1),Co,Ni,Cu,Zn,Sn,Sn( (A 2),(Pb 2+)(A 2),Pd和(C 1 H 2) 铂 A 1和A 2是轴配体,其可以相同或不同,并且选自-OH,卤素,-OR 3, ,亲水性配体和/或适于降低亲合相互作用的配体; R 3选自C 1-12烷基,C 5-12芳基,C 5-12 - 芳基烷基或Si(R x X s)(R y y)(R z)); 且R x,R y和R z可以相同或不同,并且选自C 1-12