摘要:
The present invention relates to zeolites having the crystal structure of chabazite (CHA) and having small crystallite size, to processes using the small crystallite CHA as a catalyst, and to gas separation processes using the small crystallite CHA.
摘要:
A process for reduction of oxides of nitrogen contained in a gas stream comprising contacting the gas stream with a boron-containing molecular sieve, the boron-containing molecular sieve having the CHA crystal structure and comprising (1) silicon oxide and (2) boron oxide or a combination of boron oxide and aluminum oxide, iron oxide, titanium oxide, gallium oxide and mixtures thereof; and wherein the mole-ratio of silicon oxide to boron oxide in said boron-containing molecular sieve is between 15 and 125. A method for reduction of oxides of nitrogen, comprising a) selecting the boron-containing molecular sieve; and b) contacting a gas stream with the molecular sieve. A method for reduction of oxides, comprising: a) selecting the boron-containing molecular sieve containing a metal or metal ions capable of catalyzing the reduction of the oxides of nitrogen; and b) contacting an exhaust stream of an internal combustion engine with the molecular sieve.
摘要:
A boron-containing molecular sieve having the CHA crystal structure and comprising (1) silicon oxide and (2) boron oxide or a combination of boron oxide and aluminum oxide, iron oxide, titanium oxide, gallium oxide and mixtures thereof is prepared using a quaternary ammonium cation derived from 1-adamantamine, 3-quinuclidinol or 2-exo-aminonorbornane as structure directing agent. The molecular sieve can be used for gas separation or in catalysts to prepare methylamine or dimethylamine, to convert oxygenates (e.g., methanol) to light olefins, or for the reduction of oxides of nitrogen n a gas stream (e.g., automotive exhaust).
摘要:
A process for producing methylamine or dimethylamine comprising reacting methanol, dimethyl ether or a mixture thereof, and ammonia in the gaseous phase in the presence of a catalyst comprising a boron-containing molecular sieve having the CHA crystal structure; and comprising (1) silicon oxide and (2) boron oxide or a combination of boron oxide and aluminum oxide, iron oxide, titanium oxide, gallium oxide and mixtures thereof; and wherein the mole ratio of silicon oxide to boron oxide in said boron-containing molecular sieve is between 15, and 125. Also a method for producing methylamine or dimethylamine comprising selecting the boron-containing molecular sieve having the CHA crystal structure and the desired mole ratio of silicon oxide to boron oxide and reacting methanol, dimethyl ether or a mixture thereof and ammonia in the presence of the catalyst.
摘要:
A process for the production of light olefins from a feedstock comprising an oxygenate or mixture of oxygenates, the process comprising reacting the feedstock at effective conditions over a catalyst comprising boron-containing molecular sieve having the CHA crystal structure and comprising (1) silicon oxide and (2) boron oxide or a combination of boron oxide and aluminum oxide, iron oxide, titanium oxide, gallium oxide and mixtures thereof; and wherein the mole ratio of silicon oxide to boron oxide in said boron-containing molecular sieve is between 15 and 125. A method for production of light olefins, comprising selecting the catalyst and reacting a feedstock comprising an oxygenate or mixture of oxygenates, at effective conditions, over the catalyst. Also, a method for production of light olefins, comprising selecting the catalyst, selecting the oxygenate feedstock, and reacting the feedstock at effective conditions over the catalyst.
摘要:
A boron-containing molecular sieve having the CHA crystal structure and comprising (1) silicon oxide and (2) boron oxide or a combination of boron oxide and aluminum oxide, iron oxide, titanium oxide, gallium oxide and mixtures thereof is prepared using a quaternary ammonium cation derived from 1-adamantamine, 3-quinuclidinol or 2-exo-aminonorbornane as structure directing agent.
摘要:
A boron-containing molecular sieve having the CHA crystal structure and comprising (1) silicon oxide and (2) boron oxide or a combination of boron oxide and aluminum oxide, iron oxide, titanium oxide, gallium oxide and mixtures thereof; and wherein the mole ratio of silicon oxide to boron oxide in said boron-containing molecular sieve is between 15 and 125. Also, a boron-containing molecular sieve, having a CHA crystal structure containing oxides only of (1) silicon and (2) boron; and wherein the mole ratio of silicon oxide to boron oxide in said boron-containing molecular sieve is between 15 and 125.
摘要:
A process for producing methylamine or dimethylamine comprising reacting methanol, dimethyl ether or a mixture thereof, and ammonia in the gaseous phase in the presence of a catalyst comprising a boron-containing molecular sieve having the CHA crystal structure; and comprising (1) silicon oxide and (2) boron oxide or a combination of boron oxide and aluminum oxide, iron oxide, titanium oxide, gallium oxide and mixtures thereof; and wherein the mole ratio of silicon oxide to boron oxide in said boron-containing molecular sieve is between 15 and 125. Also a method for producing methylamine or dimethylamine comprising selecting the boron-containing molecular sieve having the CHA crystal structure and the desired mole ratio of silicon oxide to boron oxide and reacting methanol, diemethyl ether or a mixture thereof and ammonia in the presence of the catalyst.