公开(公告)号：US20110207895A1

公开(公告)日：2011-08-25

申请号：US12951797

申请日：2010-11-22

申请人： Steven A. Rosenburg ,  Hong Yao ,  Thomas Bove ,  Adrian Van Maurik ,  Hans Peter Tschan ,  Norman Blank

发明人： Steven A. Rosenburg ,  Hong Yao ,  Thomas Bove ,  Adrian Van Maurik ,  Hans Peter Tschan ,  Norman Blank

IPC分类号： C09J175/08

CPC分类号： C09J175/04 ,  C08G18/10 ,  C08G18/12 ,  C08G18/307 ,  C08G18/289

摘要： A polyurethane adhesive which is useful in bonding porous and non-porous surfaces is provided. The adhesive is especially useful in bonding windshield glass into automotive frames under a variety of environmental conditions, particularly in after market windshield replacement applications. The polyurethane includes at least one urethane prepolymer which is based on at least one thermoplastic polyol. In one embodiment, the urethane prepolymer may be formed from one or more polyisocyanates, one or more polyetherpolyols and one or more thermoplastic polyesterpolyols, wherein the prepolymer has a free isocyanate content of from about 0.6 to about 3.5% by weight, based on the weight of the polyurethane. In another embodiment, a one-part adhesive composition is provided which includes an isocyanate-functional and thermoplastic polyurethane prepolymer having a free isocyanate content of from about 0.6 to about 3.5% by weight, based on the weight of the polyurethane, and a combination of several catalysts which are capable of catalyzing the reaction of isocyanate moieties with isocyanate-reactive moieties while providing less temperature dependent catalyzing of the reaction between isocyanate moieties and water. Also provided is a process for bonding two or more substrates together utilizing the polyurethane adhesive. In automotive windshield replacement applications, the polyurethane adhesive allows for a sufficient working time and development of green strength to provide a safe drive-away time within 1 hour at a temperature from about 0 to about 100° C.

摘要翻译： 提供了可用于粘合多孔和无孔表面的聚氨酯粘合剂。 粘合剂特别适用于在各种环境条件下将挡风玻璃粘合到汽车框架中，特别是在后市场挡风玻璃更换应用中。 聚氨酯包括至少一种基于至少一种热塑性多元醇的氨基甲酸酯预聚物。 在一个实施方案中，氨基甲酸酯预聚物可以由一种或多种多异氰酸酯，一种或多种聚醚多元醇和一种或多种热塑性聚酯多元醇形成，其中预聚物的游离异氰酸酯含量为约0.6至约3.5重量％，基于重量 的聚氨酯。 在另一个实施方案中，提供了一部分粘合剂组合物，其包括异氰酸酯官能和热塑性聚氨酯预聚物，其具有约0.6至约3.5重量％的游离异氰酸酯含量，基于聚氨酯的重量，以及 能够催化异氰酸酯部分与异氰酸酯反应性部分的反应的几种催化剂，同时提供较少的温度依赖性催化异氰酸酯部分与水之间的反应。 还提供了使用聚氨酯粘合剂将两个或更多个基材结合在一起的方法。 在汽车挡风玻璃更换应用中，聚氨酯粘合剂允许足够的工作时间和绿色强度的发展，以在约0至约100℃的温度下在1小时内提供安全的驱走时间。

公开(公告)号：US08747602B2

公开(公告)日：2014-06-10

申请号：US12951797

申请日：2010-11-22

申请人： Steven Rosenberg ,  Hong Yao ,  Thomas Bove ,  Adrian Van Maurik ,  Hans Peter Tschan ,  Norman Blank

发明人： Steven Rosenberg ,  Hong Yao ,  Thomas Bove ,  Adrian Van Maurik ,  Hans Peter Tschan ,  Norman Blank

IPC分类号： B60J1/00 ,  E06B3/00 ,  E06B5/00 ,  E06B7/00 ,  C04B37/00 ,  C09J4/00 ,  C09J101/00 ,  C09J201/00 ,  C08G18/08 ,  C08G18/18 ,  C08G18/00

CPC分类号： C09J175/04 ,  C08G18/10 ,  C08G18/12 ,  C08G18/307 ,  C08G18/289

摘要： A polyurethane adhesive which is useful in bonding porous and non-porous surfaces is provided. The adhesive is especially useful in bonding windshield glass into automotive frames under a variety of environmental conditions, particularly in after market windshield replacement applications. The polyurethane includes at least one urethane prepolymer which is based on at least one thermoplastic polyol. In one embodiment, the urethane prepolymer may be formed from one or more polyisocyanates, one or more polyetherpolyols and one or more thermoplastic polyesterpolyols, wherein the prepolymer has a free isocyanate content of from about 0.6 to about 3.5% by weight, based on the weight of the polyurethane. In another embodiment, a one-part adhesive composition is provided which includes an isocyanate-functional and thermoplastic polyurethane prepolymer having a free isocyanate content of from about 0.6 to about 3.5% by weight, based on the weight of the polyurethane, and a combination of several catalysts which are capable of catalyzing the reaction of isocyanate moieties with isocyanate-reactive moieties while providing less temperature dependent catalyzing of the reaction between isocyanate moieties and water. Also provided is a process for bonding two or more substrates together utilizing the polyurethane adhesive. In automotive windshield replacement applications, the polyurethane adhesive allows for a sufficient working time and development of green strength to provide a safe drive-away time within 1 hour at a temperature from about 0 to about 100° C.

摘要翻译： 提供了可用于粘合多孔和无孔表面的聚氨酯粘合剂。 粘合剂特别适用于在各种环境条件下将挡风玻璃粘合到汽车框架中，特别是在后市场挡风玻璃更换应用中。 聚氨酯包括至少一种基于至少一种热塑性多元醇的氨基甲酸酯预聚物。 在一个实施方案中，氨基甲酸酯预聚物可以由一种或多种多异氰酸酯，一种或多种聚醚多元醇和一种或多种热塑性聚酯多元醇形成，其中预聚物的游离异氰酸酯含量为约0.6至约3.5重量％，基于重量 的聚氨酯。 在另一个实施方案中，提供了一部分粘合剂组合物，其包括异氰酸酯官能和热塑性聚氨酯预聚物，其具有约0.6至约3.5重量％的游离异氰酸酯含量，基于聚氨酯的重量，以及 能够催化异氰酸酯部分与异氰酸酯反应性部分的反应的几种催化剂，同时提供较少的温度依赖性催化异氰酸酯部分与水之间的反应。 还提供了使用聚氨酯粘合剂将两个或更多个基材结合在一起的方法。 在汽车挡风玻璃更换应用中，聚氨酯粘合剂允许足够的工作时间和绿色强度的发展，以在约0至约100℃的温度下在1小时内提供安全的驱走时间。

公开(公告)号：US08512506B2

公开(公告)日：2013-08-20

申请号：US12974879

申请日：2010-12-21

申请人： Steven A. Rosenberg ,  Hong Yao ,  Thomas Bove ,  Adrian Van Maurik ,  Hans Peter Tschan ,  Norman Blank

发明人： Steven A. Rosenberg ,  Hong Yao ,  Thomas Bove ,  Adrian Van Maurik ,  Hans Peter Tschan ,  Norman Blank

IPC分类号： B60J1/00 ,  E06B3/00 ,  E06B5/00 ,  E06B7/00 ,  C04B37/00 ,  C09J4/00 ,  C09J101/00 ,  C09J201/00 ,  C08G18/08 ,  C08G18/18 ,  C08G18/00

CPC分类号： C09J175/04 ,  C08G18/10 ,  C08G18/12 ,  C08G18/307 ,  C08G18/289

摘要： An automotive windshield replacement method which includes: a) applying an adhesive to an automotive windshield and/or an automobile body substrate, said adhesive including at least one urethane prepolymer formed from reaction materials including: i) isophorone diisocyanate and/or 4,4′-diphenylmethanediisocyanate; ii) an ethylene oxide-end-capped triol having a weight average molecular weight of about 4500 to about 5000; and iii) hexanediol adipate; b) contacting the substrates together, within the working time of the adhesive, along at least a portion of the substrate(s) to which the adhesive has been applied; and c) allowing the adhesive to bond the substrates together.

摘要翻译： 一种汽车挡风玻璃置换方法，其包括：a）将粘合剂施加到汽车挡风玻璃和/或汽车车身基材上，所述粘合剂包括由反应材料形成的至少一种氨基甲酸酯预聚物，所述反应材料包括：i）异佛尔酮二异氰酸酯和/或4,4' 二苯基甲烷二异氰酸酯; ii）重均分子量为约4500至约5000的环氧乙烷封端的三醇; 和iii）己二醇己二酸酯; b）在粘合剂的工作时间内沿着已经施加有粘合剂的基底的至少一部分接触基底; 和c）允许粘合剂将基底粘合在一起。

公开(公告)号：US20110168321A1

公开(公告)日：2011-07-14

申请号：US12974879

申请日：2010-12-21

申请人： Steven A. Rosenberg ,  Hong Yao ,  Thomas Bove ,  Adrian Van Maurik ,  Hans Peter Tschan ,  Norman Blank

发明人： Steven A. Rosenberg ,  Hong Yao ,  Thomas Bove ,  Adrian Van Maurik ,  Hans Peter Tschan ,  Norman Blank

IPC分类号： B32B37/12 ,  B32B37/02 ,  B32B37/14 ,  B32B37/30

CPC分类号： C09J175/04 ,  C08G18/10 ,  C08G18/12 ,  C08G18/307 ,  C08G18/289

摘要： A polyurethane adhesive which is useful in bonding porous and non-porous surfaces is provided. The adhesive is especially useful in bonding windshield glass into automotive frames under a variety of environmental conditions, particularly in after market windshield replacement applications. The polyurethane includes at least one urethane prepolymer which is based on at least one thermoplastic polyol. In one embodiment, the urethane prepolymer may be formed from one or more polyisocyanates, one or more polyetherpolyols and one or more thermoplastic polyesterpolyols, wherein the prepolymer has a free isocyanate content of from about 0.6 to about 3.5% by weight, based on the weight of the polyurethane. In another embodiment, a one-part adhesive composition is provided which includes an isocyanate-functional and thermoplastic polyurethane prepolymer having a free isocyanate content of from about 0.6 to about 3.5% by weight, based on the weight of the polyurethane, and a combination of several catalysts which are capable of catalyzing the reaction of isocyanate moieties with isocyanate-reactive moieties while providing less temperature dependent catalyzing of the reaction between isocyanate moieties and water. Also provided is a process for bonding two or more substrates together utilizing the polyurethane adhesive. In automotive windshield replacement applications, the polyurethane adhesive allows for a sufficient working time and development of green strength to provide a safe drive-away time within 1 hour at a temperature from about 0 to about 100° C.

公开(公告)号：US07226523B2

公开(公告)日：2007-06-05

申请号：US10144803

申请日：2002-05-15

申请人： Steven A. Rosenberg ,  Hong Yao ,  Thomas Bove ,  Adrian Van Maurik ,  Hans Peter Tschan ,  Norman Blank

发明人： Steven A. Rosenberg ,  Hong Yao ,  Thomas Bove ,  Adrian Van Maurik ,  Hans Peter Tschan ,  Norman Blank

IPC分类号： C08G18/30

CPC分类号： C09J175/04 ,  C08G18/10 ,  C08G18/12 ,  C08G18/307 ,  C08G18/289

摘要： A polyurethane adhesive which is useful in bonding porous and non-porous surfaces is provided. The adhesive is especially useful in bonding windshield glass into automotive frames under a variety of environmental conditions, particularly in after market windshield replacement applications. The polyurethane includes at least one urethane prepolymer which is based on at least one thermoplastic polyol. In one embodiment, the urethane prepolymer may be formed from one or more polyisocyanates, one or more polyetherpolyols and one or more thermoplastic polyesterpolyols, wherein the prepolymer has a free isocyanate content of from about 0.6 to about 3.5% by weight, based on the weight of the polyurethane. In another embodiment, a one-part adhesive composition is provided which includes an isocyanate-functional and thermoplastic polyurethane prepolymer having a free isocyanate content of from about 0.6 to about 3.5% by weight, based on the weight of the polyurethane, and a combination of several catalysts which are capable of catalyzing the reaction of isocyanate moieties with isocyanate-reactive moieties while providing less temperature dependent catalyzing of the reaction between isocyanate moieties and water. Also provided is a process for bonding two or more substrates together utilizing the polyurethane adhesive. In automotive windshield replacement applications, the polyurethane adhesive allows for a sufficient working time and development of green strength to provide a safe drive-away time within 1 hour at a temperature from about 0 to about 100° C.

摘要翻译： 提供了可用于粘合多孔和无孔表面的聚氨酯粘合剂。 粘合剂特别适用于在各种环境条件下将挡风玻璃粘合到汽车框架中，特别是在后市场挡风玻璃更换应用中。 聚氨酯包括至少一种基于至少一种热塑性多元醇的氨基甲酸酯预聚物。 在一个实施方案中，氨基甲酸酯预聚物可以由一种或多种多异氰酸酯，一种或多种聚醚多元醇和一种或多种热塑性聚酯多元醇形成，其中预聚物的游离异氰酸酯含量为约0.6至约3.5重量％，基于重量 的聚氨酯。 在另一个实施方案中，提供了一部分粘合剂组合物，其包括异氰酸酯官能和热塑性聚氨酯预聚物，其具有约0.6至约3.5重量％的游离异氰酸酯含量，基于聚氨酯的重量，以及 能够催化异氰酸酯部分与异氰酸酯反应性部分的反应的几种催化剂，同时提供较少的温度依赖性催化异氰酸酯部分与水之间的反应。 还提供了使用聚氨酯粘合剂将两个或更多个基材结合在一起的方法。 在汽车挡风玻璃更换应用中，聚氨酯粘合剂允许足够的工作时间和绿色强度的发展，以在约0至约100℃的温度下在1小时内提供安全的驱走时间。

公开(公告)号：US20070251629A1

公开(公告)日：2007-11-01

申请号：US11790572

申请日：2007-04-26

申请人： Steven Rosenberg ,  Hong Yao ,  Thomas Bove ,  Adrian Van Maurik ,  Hans Tschan ,  Norman Blank

发明人： Steven Rosenberg ,  Hong Yao ,  Thomas Bove ,  Adrian Van Maurik ,  Hans Tschan ,  Norman Blank

IPC分类号： E06B3/56

CPC分类号： C09J175/04 ,  C08G18/10 ,  C08G18/12 ,  C08G18/307 ,  C08G18/289

摘要： A polyurethane adhesive which is useful in bonding porous and non-porous surfaces is provided. The adhesive is especially useful in bonding windshield glass into automotive frames under a variety of environmental conditions, particularly in after market windshield replacement applications. The polyurethane includes at least one urethane prepolymer which is based on at least one thermoplastic polyol. In one embodiment, the urethane prepolymer may be formed from one or more polyisocyanates, one or more polyetherpolyols and one or more thermoplastic polyesterpolyols, wherein the prepolymer has a free isocyanate content of from about 0.6 to about 3.5% by weight, based on the weight of the polyurethane. In another embodiment, a one-part adhesive composition is provided which includes an isocyanate-functional and thermoplastic polyurethane prepolymer having a free isocyanate content of from about 0.6 to about 3.5% by weight, based on the weight of the polyurethane, and a combination of several catalysts which are capable of catalyzing the reaction of isocyanate moieties with isocyanate-reactive moieties while providing less temperature dependent catalyzing of the reaction between isocyanate moieties and water. Also provided is a process for bonding two or more substrates together utilizing the polyurethane adhesive. In automotive windshield replacement applications, the polyurethane adhesive allows for a sufficient working time and development of green strength to provide a safe drive-away time within 1 hour at a temperature from about 0 to about 100° C.