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1.发明授权
公开(公告)号：US5633171A
公开(公告)日：1997-05-27
申请号：US397998
申请日：1995-03-03
申请人： Hamish Small , John M. Riviello , Steven B. Rabin
发明人： Hamish Small , John M. Riviello , Steven B. Rabin
CPC分类号： G01N30/96 , G01N2030/965 , Y10T436/25125
摘要： A method and apparatus for ion analysis by ion chromatography uses periodic electrolytic regeneration of a packed bed suppressor. First and second sets of columns, suppressors and detectors connected in series are linked by appropriate valving so that the effluent from the second suppressor can be passed to the first suppressor to be used in the electrolytic regeneration of the first suppressor after detection of analyte in the second detector.
摘要翻译： 通过离子色谱法进行离子分析的方法和装置使用填充床抑制剂的周期性电解再生。 串联连接的第一和第二组柱，抑制器和检测器通过适当的阀门连接，使得来自第二抑制器的流出物可以被传递到第一抑制器以用于在检测到第一抑制器的分析物的电解再生中 第二检测器。
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2.发明授权
公开(公告)号：US5773615A
公开(公告)日：1998-06-30
申请号：US600856
申请日：1996-02-13
申请人： Hamish Small , John M. Riviello , Steven B. Rabin
发明人： Hamish Small , John M. Riviello , Steven B. Rabin
CPC分类号： G01N30/96 , G01N2030/965 , Y10T436/25125
摘要： Method and apparatus for ion chromatography including passage of sample through a chromatographic separation column, through a suppressor column containing a resin with exchangeable ions, and then through a detector. The suppressor column is equipped with an electrical potential supplying device to electrolyze water and regenerate the suppressor column.
摘要翻译： 用于离子色谱法的方法和装置，包括样品通过色谱分离柱，通过含有可交换离子的树脂的抑制柱，然后通过检测器。 抑制柱配备有电解水并且再生抑制柱的电位供给装置。
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3.发明授权
公开(公告)号：US5569365A
公开(公告)日：1996-10-29
申请号：US398147
申请日：1995-03-03
申请人： Steven B. Rabin , Hamish Small , John M. Riviello
发明人： Steven B. Rabin , Hamish Small , John M. Riviello
CPC分类号： G01N30/96 , G01N2030/965
摘要： A method and apparatus using suppression of eluents for the analysis of anions or cations in ion chromatography. The invention relates to the intermittent use of the electric field during electrochemical suppression to minimize background noise during detection of the ionic species caused by the application of an electric field using an electrolytic membrane suppressor. Using this intermittent electrochemical suppression system allows the detection of the analyte in the absence of the electric field. The system finds particular benefit in reducing background noise created during electrochemical suppression, and in reducing the baseline interference when analyzing organic solvent-containing samples.
摘要翻译： 在离子色谱法中使用抑制洗脱液进行阴离子或阳离子分析的方法和装置。 本发明涉及在电化学抑制期间间歇地使用电场，以使由使用电解膜抑制器的电场施加引起的离子物质检测期间的背景噪声最小化。 使用这种间歇电化学抑制系统允许在没有电场的情况下检测分析物。 该系统在减少电化学抑制期间产生的背景噪声以及在分析含有机溶剂的样品时降低基线干扰方面具有特别的益处。
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4.发明授权Ion chromatography system using electrochemical suppression and detector effluent recycle 失效离子色谱系统使用电化学抑制和检测器废水循环
公开(公告)号：US5248426A
公开(公告)日：1993-09-28
申请号：US968246
申请日：1992-10-29
CPC分类号： G01N30/96 , G01N2030/965 , G01N30/02
摘要： A method of streamlining and lowering the cost of operation of ion chromatography as well as improving detection limits is disclosed. The apparatus includes chromatographic separating means through which a sample is eluted in an eluent solution including an electrolyte. The apparatus includes suppressor means having a chromatography effluent compartment means separated from a detector effluent compartment means by an ion exchange membrane, forming a chromatography effluent flow channel and a detector effluent channel, respectively. Electrode means are disposed in communication with both flow channels for passing an electric current transverse to the solution that is passing through them. The chromatography effluent flows through the chromatography effluent flow channel of the suppressor and through detector means which detects resolved ionic species therein. The effluent from the detector means is then recycled through the detector effluent flow channel and forms a sump for electrolyte ions passing across the chromatography effluent as well as supplying the water for the electrolysis reaction generating acid (or base) for suppression.
摘要翻译： 公开了精简和降低离子色谱操作成本以及提高检测限的方法。 该装置包括色谱分离装置，样品在包括电解质的洗脱溶液中洗脱。 该装置包括抑制装置，其具有分别通过离子交换膜从检测器流出物室装置分离的色谱流出物隔室装置，分别形成色谱流出物流动通道和检测器流出通道。 电极装置设置成与两个流动通道连通，以使横向于通过它们的溶液的电流通过。 色谱流出液流过抑制器的色谱流出物流动通道，并通过检测其中的分离离子物质的检测器装置。 来自检测器装置的流出物然后通过检测器流出物流动通道再循环，并形成用于通过色谱流出物的电解质离子的池，以及供应用于产生酸（或碱）的电解反应用于抑制的水。
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5.发明授权Ion chromatography system using electrochemical suppression and detector effluent recycle 失效离子色谱系统使用电化学抑制和检测器废水循环
公开(公告)号：US5352360A
公开(公告)日：1994-10-04
申请号：US86560
申请日：1993-07-01
CPC分类号： G01N30/96 , G01N2030/965 , G01N30/02
摘要： A method of streamlining and lowering the cost of operation of ion chromatography as well as improving detection limits is disclosed. The apparatus includes chromatographic separating means through which a sample is eluted in an eluent solution including an electrolyte. The apparatus includes suppressor means having a chromatography effluent compartment means separated from a detector effluent compartment means by an ion exchange membrane, forming a chromatography effluent flow channel and a detector effluent channel, respectively. Electrode means are disposed in communication with both flow channels for passing an electric current transverse to the solution that is passing through them. The chromatography effluent flows through the chromatography effluent flow channel of the suppressor and through detector means which detects resolved ionic species therein. The effluent from the detector means is then recycled through the detector effluent flow channel and forms a sump for electrolyte ions passing across the chromatography effluent as well as supplying the water for the electrolysis reaction generating acid (or base) for suppression.
摘要翻译： 公开了精简和降低离子色谱操作成本以及提高检测限的方法。 该装置包括色谱分离装置，样品在包括电解质的洗脱溶液中洗脱。 该装置包括抑制装置，其具有分别通过离子交换膜从检测器流出物室装置分离的色谱流出物隔室装置，分别形成色谱流出物流动通道和检测器流出通道。 电极装置设置成与两个流动通道连通，以使横向于通过它们的溶液的电流通过。 色谱流出液流过抑制器的色谱流出物流动通道，并通过检测其中的分离离子物质的检测器装置。 来自检测器装置的流出物然后通过检测器流出物流动通道再循环，并形成用于通过色谱流出物的电解质离子的池，以及供应用于产生酸（或碱）的电解反应用于抑制的水。
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