Process for production of separators for use in cells
    3.
    发明授权
    Process for production of separators for use in cells 失效
    用于生产细胞分离器的方法

    公开(公告)号:US4376794A

    公开(公告)日:1983-03-15

    申请号:US308904

    申请日:1981-10-05

    IPC分类号: C08F255/02 H01M2/16 B05D3/06

    CPC分类号: H01M2/1653 C08F255/02

    摘要: A novel process for the production of a separator for use in a cell to prevent the short-circuiting of positive active material and negative active material comprises irradiating a polyolefin film 150 .mu.m or less thick with ionizing radiation at a dose rate of 5.times.10.sup.4 -10.sup.7 rads/sec. to give a total dose of 1 Mrad or more, contacting the irradiated film with an aqueous solution of a terminally unsaturated monomer such as acrylic acid, methacrylic acid and the like at a temperature of 10.degree. C.-60.degree. C. to thereby cause grafting of the monomer onto the polyolefin film before the grafted polymer film is treated with an aqueous alkaline solution to finally obtain the separator for use in a cell, which is substantially improved in that it shows low electrical resistance and is excellent both in its acid resistance and mechanical strength.

    摘要翻译: 用于制造用于电池中的隔板的新颖方法,以防止正极活性物质和负极活性物质的短路,包括以5×104-107的剂量率的电离辐射照射150μm以下的聚烯烃膜 拉德/秒。 总共剂量为1Mrad或更多,在10℃-60℃的温度下使照射的膜与诸如丙烯酸,甲基丙烯酸等的末端不饱和单体的水溶液接触,从而导致 在接枝聚合物膜用碱性水溶液处理之前将单体接枝到聚烯烃膜上,最终获得用于电池的隔膜,其实质上改善了,因为它显示出低的电阻,并且耐酸性优异 和机械强度。

    Battery separator and method of producing the same
    4.
    发明授权
    Battery separator and method of producing the same 失效
    电池分离器及其制造方法

    公开(公告)号:US4273840A

    公开(公告)日:1981-06-16

    申请号:US118100

    申请日:1980-02-04

    IPC分类号: H01M2/16

    摘要: A battery separator composed of a composite sheet of film to which a monomer having a hydrophilic or electrolytic group is grafted is disclosed. Said film consists of a first polymeric layer containing a substance capable of catching a metal ion dissolved from a positive or negative active material and a second polymeric layer integrally bonded to either one or both sides of the first polymeric layer and which contains no such substance or contains it in a smaller amount that that contained in said first polymeric layer. Also disclosed is a method of producing a battery separator by irradiating such composite sheet of film with ionizing radiation and immersing the irradiated film in a solution of a monomer containing a hydrophilic or electrolytic group or bringing it into contact with the monomer solution to thereby graft the monomer to the film.

    摘要翻译: 公开了一种由具有亲水性或电解质基团的单体的复合膜复合体构成的电池隔膜。 所述膜由含有能够捕获从正极或负极活性材料溶解的金属离子的物质的第一聚合物层和与第一聚合物层的一侧或两侧整体结合并且不含此类物质的第二聚合物层组成, 含有较少的量,其含有在所述第一聚合物层中。 还公开了一种通过用电离辐射照射这种薄膜复合片材并将照射的膜浸入含有亲水或电解基团的单体的溶液中或使其与单体溶液接触从而将 单体到膜。

    Sodium-sulfur storage battery
    6.
    发明授权
    Sodium-sulfur storage battery 失效
    钠硫蓄电池

    公开(公告)号:US4076902A

    公开(公告)日:1978-02-28

    申请号:US732770

    申请日:1976-10-15

    申请人: Keizi Senoo

    发明人: Keizi Senoo

    IPC分类号: H01M4/80 H01M10/39

    CPC分类号: H01M10/3909

    摘要: A sodium-sulfur storage battery having a sealed housing which contains a solid electrolyte incorporating an anodic reactant such as sodium, a cathodic current collector (which may be the housing) extending in a direction generally parallel to the solid electrolyte and cathodic electro-conductive material disposed between and in contact with the solid electrolyte and the cathodic current collector. The cathodic electro-conductive material is impregnated with a cathodic reactant and includes a fiber content, the individual fibers of which have a direction normal to the direction of the cathodic current collector. One suitable material for the cathodic electro-conductive material is a graphite felt and which is impregnated with sodium polysulfide or sulfur.

    摘要翻译: 一种具有密封壳体的钠硫蓄电池,其包含含有阳极反应物如钠的固体电解质,阴极集电器(可以是壳体),其沿大致平行于固体电解质的方向延伸,阴极导电材料 设置在固体电解质和阴极集电器之间并与之接触。 阴极导电材料用阴极反应物浸渍,并且包括纤维含量,其各自的纤维具有与阴极集电体的方向垂直的方向。 用于阴极导电材料的一种合适的材料是石墨毡,并且其被多硫化钠或硫磺浸渍。