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公开(公告)号:US4407846A
公开(公告)日:1983-10-04
申请号:US311032
申请日:1981-10-13
申请人: Sueo Machi , Isao Ishigaki , Takanobu Sugo , Kazuo Murata , Shiro Tanso , Keizi Senoo
发明人: Sueo Machi , Isao Ishigaki , Takanobu Sugo , Kazuo Murata , Shiro Tanso , Keizi Senoo
IPC分类号: B01D67/00 , C08F255/02 , C08J7/18 , B05D3/06
CPC分类号: B01D67/0093 , C08J7/18 , B01D2323/385 , C08J2323/06
摘要: A method of producing a hydrophilic membrane from a polyethylene base film by first irradiating the film with ionizing radiation in air or an oxygen atmosphere and then grafting acrylic acid and/or methacrylic acid onto the irradiated film at low temperatures.
摘要翻译: 通过首先在空气或氧气氛中用电离辐射照射膜,然后在低温下将丙烯酸和/或甲基丙烯酸接枝到照射的膜上,从聚乙烯基膜制备亲水膜的方法。
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公开(公告)号:US4287272A
公开(公告)日:1981-09-01
申请号:US142621
申请日:1980-04-21
申请人: Sueo Machi , Isao Ishigaki , Takanobu Sugo , Toshio Okada , Kazuo Murata , Shiro Tanso , Keizi Senoo
发明人: Sueo Machi , Isao Ishigaki , Takanobu Sugo , Toshio Okada , Kazuo Murata , Shiro Tanso , Keizi Senoo
CPC分类号: H01M2/1653 , H01M2/14 , H01M4/70 , H01M6/12 , H01M6/40
摘要: There is disclosed a novel cell separator made of a grafted membrane comprising a polyethylene film which is graft-copolymerized with a monomer having an ion exchange group, characterized in that said membrane has an area which is not grafted at all or an area of low degree grafting. By making use of this membrane, a small size and thin cell having excellent performance as well as satisfactory mechanical strength can be produced at low cost with great advantages.
摘要翻译: 公开了一种由接枝膜制成的新型细胞分离器,其包括与具有离子交换基团的单体接枝共聚的聚乙烯膜,其特征在于所述膜具有全部不接枝或低度区域 嫁接。 通过利用该膜,可以以低成本制造具有优异性能以及令人满意的机械强度的小尺寸和细小电池,具有很大的优点。
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公开(公告)号:US4376794A
公开(公告)日:1983-03-15
申请号:US308904
申请日:1981-10-05
申请人: Sueo Machi , Isao Ishigaki , Takanobu Sugo , Kazuo Murata , Shiro Tanso , Keizi Senoo
发明人: Sueo Machi , Isao Ishigaki , Takanobu Sugo , Kazuo Murata , Shiro Tanso , Keizi Senoo
IPC分类号: C08F255/02 , H01M2/16 , B05D3/06
CPC分类号: H01M2/1653 , C08F255/02
摘要: A novel process for the production of a separator for use in a cell to prevent the short-circuiting of positive active material and negative active material comprises irradiating a polyolefin film 150 .mu.m or less thick with ionizing radiation at a dose rate of 5.times.10.sup.4 -10.sup.7 rads/sec. to give a total dose of 1 Mrad or more, contacting the irradiated film with an aqueous solution of a terminally unsaturated monomer such as acrylic acid, methacrylic acid and the like at a temperature of 10.degree. C.-60.degree. C. to thereby cause grafting of the monomer onto the polyolefin film before the grafted polymer film is treated with an aqueous alkaline solution to finally obtain the separator for use in a cell, which is substantially improved in that it shows low electrical resistance and is excellent both in its acid resistance and mechanical strength.
摘要翻译: 用于制造用于电池中的隔板的新颖方法,以防止正极活性物质和负极活性物质的短路,包括以5×104-107的剂量率的电离辐射照射150μm以下的聚烯烃膜 拉德/秒。 总共剂量为1Mrad或更多,在10℃-60℃的温度下使照射的膜与诸如丙烯酸,甲基丙烯酸等的末端不饱和单体的水溶液接触,从而导致 在接枝聚合物膜用碱性水溶液处理之前将单体接枝到聚烯烃膜上,最终获得用于电池的隔膜,其实质上改善了,因为它显示出低的电阻,并且耐酸性优异 和机械强度。
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公开(公告)号:US4273840A
公开(公告)日:1981-06-16
申请号:US118100
申请日:1980-02-04
申请人: Sueo Machi , Isao Ishigaki , Takanobu Sugo , Kazuo Murata , Shiro Tanso , Keizi Senoo
发明人: Sueo Machi , Isao Ishigaki , Takanobu Sugo , Kazuo Murata , Shiro Tanso , Keizi Senoo
IPC分类号: H01M2/16
CPC分类号: H01M2/1653 , H01M2/1666 , H01M2300/0014
摘要: A battery separator composed of a composite sheet of film to which a monomer having a hydrophilic or electrolytic group is grafted is disclosed. Said film consists of a first polymeric layer containing a substance capable of catching a metal ion dissolved from a positive or negative active material and a second polymeric layer integrally bonded to either one or both sides of the first polymeric layer and which contains no such substance or contains it in a smaller amount that that contained in said first polymeric layer. Also disclosed is a method of producing a battery separator by irradiating such composite sheet of film with ionizing radiation and immersing the irradiated film in a solution of a monomer containing a hydrophilic or electrolytic group or bringing it into contact with the monomer solution to thereby graft the monomer to the film.
摘要翻译: 公开了一种由具有亲水性或电解质基团的单体的复合膜复合体构成的电池隔膜。 所述膜由含有能够捕获从正极或负极活性材料溶解的金属离子的物质的第一聚合物层和与第一聚合物层的一侧或两侧整体结合并且不含此类物质的第二聚合物层组成, 含有较少的量,其含有在所述第一聚合物层中。 还公开了一种通过用电离辐射照射这种薄膜复合片材并将照射的膜浸入含有亲水或电解基团的单体的溶液中或使其与单体溶液接触从而将 单体到膜。
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公开(公告)号:US4283442A
公开(公告)日:1981-08-11
申请号:US118103
申请日:1980-02-04
申请人: Sueo Machi , Isao Ishigaki , Takanobu Sugo , Kazuo Murata , Shiro Tanso , Keizi Senoo
发明人: Sueo Machi , Isao Ishigaki , Takanobu Sugo , Kazuo Murata , Shiro Tanso , Keizi Senoo
CPC分类号: C08J7/18 , H01M2/1653 , C08J2323/06 , H01M2300/0014
摘要: A method of producing a dimensionally stable battery separator characterized by grafting acrylic acid and/or methacrylic acid onto a polyethylene film, treating the resulting membrane with an aqueous alkaline solution, and drying the treated membrane under application of tension.
摘要翻译: 一种制造尺寸稳定的电池隔板的方法,其特征在于将丙烯酸和/或甲基丙烯酸接枝到聚乙烯膜上,用碱性水溶液处理所得的膜,并在施加张力下干燥处理过的膜。
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公开(公告)号:US4076902A
公开(公告)日:1978-02-28
申请号:US732770
申请日:1976-10-15
申请人: Keizi Senoo
发明人: Keizi Senoo
CPC分类号: H01M10/3909
摘要: A sodium-sulfur storage battery having a sealed housing which contains a solid electrolyte incorporating an anodic reactant such as sodium, a cathodic current collector (which may be the housing) extending in a direction generally parallel to the solid electrolyte and cathodic electro-conductive material disposed between and in contact with the solid electrolyte and the cathodic current collector. The cathodic electro-conductive material is impregnated with a cathodic reactant and includes a fiber content, the individual fibers of which have a direction normal to the direction of the cathodic current collector. One suitable material for the cathodic electro-conductive material is a graphite felt and which is impregnated with sodium polysulfide or sulfur.
摘要翻译: 一种具有密封壳体的钠硫蓄电池,其包含含有阳极反应物如钠的固体电解质,阴极集电器(可以是壳体),其沿大致平行于固体电解质的方向延伸,阴极导电材料 设置在固体电解质和阴极集电器之间并与之接触。 阴极导电材料用阴极反应物浸渍,并且包括纤维含量,其各自的纤维具有与阴极集电体的方向垂直的方向。 用于阴极导电材料的一种合适的材料是石墨毡,并且其被多硫化钠或硫磺浸渍。
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