公开(公告)号：US4137137A

公开(公告)日：1979-01-30

申请号：US815423

申请日：1977-07-13

申请人： Sueo Machi ,  Takanobu Sugo ,  Akio Sugishita ,  Sakunobu Kanai ,  Hiroshi Fujiwara

发明人： Sueo Machi ,  Takanobu Sugo ,  Akio Sugishita ,  Sakunobu Kanai ,  Hiroshi Fujiwara

IPC分类号： B01D5/00 ,  B01D67/00 ,  B01D71/82 ,  C08F2/46 ,  C08F255/00 ,  C08F257/02 ,  C08F259/00 ,  C08F259/08 ,  C08F291/00 ,  C08J5/22 ,  C08J7/18 ,  C08F8/00

CPC分类号： B01D67/0093 ,  B01D5/0012 ,  B01D71/82 ,  C08F255/00 ,  C08F257/02 ,  C08F259/08 ,  C08J5/225 ,  B01D2323/385 ,  C08J2325/04

摘要： A graft copolymer membrane prepared by co-grafting a mixture of monomers consisting essentially of acyloxystyrene and/or hydroxystyrene, a polyene compound and at least one member selected from the group consisting of acrylic acid, methacrylic acid and esters of these acids onto a hydrocarbon type of fluorine-containing type polymer by means of ionizing radiation exhibits improved mechanical strength and reduced electrical resistance and provides an excellent ion-exchange membrane.

摘要翻译： 通过将基本上由酰氧基苯乙烯和/或羟基苯乙烯组成的单体的混合物，多烯化合物和选自丙烯酸，甲基丙烯酸和这些酸的酯中的至少一种共聚合到烃类上而制备的接枝共聚物膜 的含氟类聚合物通过电离辐射显示出改进的机械强度和降低的电阻，并提供优异的离子交换膜。

公开(公告)号：US4129617A

公开(公告)日：1978-12-12

申请号：US849442

申请日：1977-11-07

申请人： Sueo Machi ,  Yasushi Matsui ,  Akio Sugishita ,  Takanobu Sugo ,  Hiroaki Taniguchi ,  Koichi Asano ,  Hiroshi Fujiwara

发明人： Sueo Machi ,  Yasushi Matsui ,  Akio Sugishita ,  Takanobu Sugo ,  Hiroaki Taniguchi ,  Koichi Asano ,  Hiroshi Fujiwara

IPC分类号： C08F259/08 ,  C08L27/12 ,  C08L27/16 ,  C08L27/18

CPC分类号： C08F259/08

摘要： A novel graft copolymer and a process for the production thereof is disclosed, said graft copolymer comprising a backbone chain of a fluoropolymer and side chains grafted thereon consisting essentially of at least a member selected from the group consisting of acyloxystyrene, diacyloxystyrene, hydroxystyrene and dihydroxystyrene or consisting essentially of a mixture of at least a member selected from the group mentioned above and a polyene compound. The grafting is conveniently carried out with the aid of an ionizing radiation. The novel graft copolymer has a wide variety of uses due to its improved characteristic properties such as, for example, improved adhesion properties, improved dyeing properties, improved reactivity to other compounds and the like.

摘要翻译： 公开了一种新颖的接枝共聚物及其制备方法，所述接枝共聚物包括含氟聚合物的主链和其上接枝的侧链，其基本上由至少一种选自酰氧基苯乙烯，二酰氧基苯乙烯，羟基苯乙烯和二羟基苯乙烯的成员组成， 基本上由至少选自上述基团的成员和多烯化合物的混合物组成。 借助电离辐射方便地进行接枝。 新颖的接枝共聚物由于其改进的特性，例如改进的粘合性能，改进的染色性能，改善的对其它化合物的反应性等而具有广泛的用途。

公开(公告)号：US3970534A

公开(公告)日：1976-07-20

申请号：US540789

申请日：1975-01-13

申请人： Hiroshi Fujiwara ,  Koichi Asano ,  Akio Sugishita ,  Asao Takahashi

发明人： Hiroshi Fujiwara ,  Koichi Asano ,  Akio Sugishita ,  Asao Takahashi

IPC分类号： C08F2/46 ,  C08F8/00 ,  C08F255/00 ,  C08F257/00 ,  C08J5/22 ,  C08J7/12 ,  C08J7/18 ,  C08F257/02

CPC分类号： C08J7/18 ,  C08F255/00 ,  C08F257/00 ,  C08F8/00 ,  C08J5/2243 ,  C08J7/12 ,  C08J2323/08 ,  C08J2353/02

摘要： A graft copolymer comprising a hydrocarbon polymer main chain and a side chain composed mainly of a styrene compound of the following formula (I) ##SPC1##wherein R is a hydrogen atom or an R'CO group, in which R' is a hydrocarbon group having 1 to 20 carbon atoms, and a polyene compound grafted to the hydrocarbon polymer main chain and a process for preparing the graft copolymer comprising graft-copolymerizing the above copolymer components with the hydrocarbon polymer by ionizing radiation. The graft copolymer is especially suitable as an ion-exchange membrane or a basic polymer matrix for an ion-exchange membrane.

摘要翻译： 一种接枝共聚物，其包含烃聚合物主链和主要由下式（I）的苯乙烯化合物组成的侧链，其中R是氢原子或R'CO基团，其中R'是具有1〜 20个碳原子和接枝到烃聚合物主链上的多烯化合物和制备接枝共聚物的方法，其包括通过电离辐射将上述共聚物组分与烃聚合物接枝共聚。 接枝共聚物特别适合用作离子交换膜的离子交换膜或碱性聚合物基质。

公开(公告)号：US4011147A

公开(公告)日：1977-03-08

申请号：US616114

申请日：1975-09-23

申请人： Hiroshi Fujiwara ,  Koichi Asano ,  Asao Takahashi ,  Akio Sugishita

发明人： Hiroshi Fujiwara ,  Koichi Asano ,  Asao Takahashi ,  Akio Sugishita

IPC分类号： C08F255/00 ,  C08F257/00 ,  C08J5/22 ,  C25B1/16 ,  C25B1/26 ,  C25B13/08

CPC分类号： C08J5/2268 ,  C08F255/00 ,  C08F257/00 ,  C08J2323/02 ,  C08J2325/04

摘要： A method for diaphragm electrolysis of an alkali metal halide which comprises electrolyzing an alkali metal halide solution by passing an electric current through an anode compartment and a cathode compartment of an electrolytic cell containing the alkali metal halide solution with an ion-exchange membrane of a graft copolymer of a polyolefin main chain and a side chain composed mainly of hydroxystyrene and grafted to the polyolefin main chain separating the anode compartment and the cathode compartment.