公开(公告)号：US5338721A

公开(公告)日：1994-08-16

申请号：US884137

申请日：1992-05-18

申请人： Susumu Yamamoto ,  Teruyuki Murai ,  Nozomu Kawabe ,  Tomoyuki Awazu ,  Shuji Yazu ,  Tetsuji Jodai

发明人： Susumu Yamamoto ,  Teruyuki Murai ,  Nozomu Kawabe ,  Tomoyuki Awazu ,  Shuji Yazu ,  Tetsuji Jodai

IPC分类号： B21C1/00 ,  B28B1/00 ,  C01G1/00 ,  C04B35/00 ,  C04B35/45 ,  H01B12/04 ,  H01B13/00 ,  H01L39/24 ,  B32B9/00

CPC分类号： H01L39/143 ,  H01L39/248 ,  Y10S428/93 ,  Y10S505/701 ,  Y10S505/702 ,  Y10S505/703 ,  Y10S505/704 ,  Y10T29/49014 ,  Y10T428/31678

摘要： A superconducting composite comprising a compound oxide type superconductor and an outer metal pipe on which said superconductor is supported, characterized in that (i) said outer metal pipe is made of at least one of metals selected from a group comprising gold, silver and platinum metals and their alloys or (ii) an intermediate layer made of these precious metals is interposed between the compound oxide and the metal pipe.The composite may be in a form of a solid pipe or a hollow pipe having a superconducting thin layer deposited on an inner surface of the metal pipe.

摘要翻译： 一种超导复合体，其包含复合氧化物型超导体和外部金属管，所述超导体被支撑在所述外部金属管上，其特征在于，（i）所述外部金属管由选自金，银和铂金属的金属中的至少一种制成 并且它们的合金或（ii）由这些贵金属制成的中间层插入在复合氧化物和金属管之间。 复合材料可以是固体管或中空管的形式，其具有沉积在金属管的内表面上的超导薄层。

公开(公告)号：US5424282A

公开(公告)日：1995-06-13

申请号：US200540

申请日：1994-02-22

申请人： Susumu Yamamoto ,  Teruyuki Murai ,  Nozomu Kawabe ,  Tomoyuki Awazu ,  Shuji Yazu ,  Tetsuji Jodai

发明人： Susumu Yamamoto ,  Teruyuki Murai ,  Nozomu Kawabe ,  Tomoyuki Awazu ,  Shuji Yazu ,  Tetsuji Jodai

IPC分类号： B21C1/00 ,  B28B1/00 ,  C01G1/00 ,  C04B35/00 ,  C04B35/45 ,  H01B12/04 ,  H01B13/00 ,  H01L39/24

CPC分类号： H01L39/143 ,  H01L39/248 ,  Y10S428/93 ,  Y10S505/701 ,  Y10S505/702 ,  Y10S505/703 ,  Y10S505/704 ,  Y10T29/49014 ,  Y10T428/31678

摘要： A process for producing a composite oxide superconducting wire is disclosed, which comprises the steps of compacting material powder for an oxide superconductor in a noble metal pipe; heating the metal pipe filled with the material powder at a temperature ranging between an upper limit corresponding to the lowest melting point of any one of constituent components in the material powder and a lower limit which is lower by 100.degree. C. than said upper limit to sinter the material powder and cooling the product at a cooling velocity of less than 50.degree. C./min, and further including a series of wire-drawing, annealing and sintering steps. Furthermore, an intermediate layer of noble metal can be interposed between the oxide superconductor and the metal pipe.

摘要翻译： 公开了一种生产复合氧化物超导线的方法，其包括在贵金属管中压制氧化物超导体的材料粉末的步骤; 在与材料粉末中的任何一种构成成分的最低熔点相对应的上限和比所述上限低100℃的下限的温度范围内加热填充有材料粉末的金属管， 烧结材料粉末并以低于50℃/ min的冷却速度冷却产品，并进一步包括一系列拉丝，退火和烧结步骤。 此外，贵金属的中间层可以介于氧化物超导体和金属管之间。

公开(公告)号：US5122507A

公开(公告)日：1992-06-16

申请号：US189366

申请日：1988-05-02

申请人： Susumu Yamamoto ,  Teruyuki Murai ,  Nozomu Kawabe ,  Tomoyuki Awazu ,  Shuji Yazu ,  Tetsuji Jodai

发明人： Susumu Yamamoto ,  Teruyuki Murai ,  Nozomu Kawabe ,  Tomoyuki Awazu ,  Shuji Yazu ,  Tetsuji Jodai

IPC分类号： B21C1/00 ,  B28B1/00 ,  C01G1/00 ,  C04B35/00 ,  C04B35/45 ,  H01B12/04 ,  H01B13/00 ,  H01L39/24

CPC分类号： H01L39/143 ,  H01L39/248 ,  Y10S428/93 ,  Y10S505/701 ,  Y10S505/702 ,  Y10S505/703 ,  Y10S505/704 ,  Y10T29/49014 ,  Y10T428/31678

摘要： A superconducting composite comprising a compound oxide type superconductor and an outer metal pipe on which said superconductor is supported, characterized in that (i) said outer metal pipe is made of at least one of metals selected from a group comprising gold, silver and platinum metals and their alloys or (ii) an intermidiate layer made of these precious metals is interposed between the compound oxide and the metal pipe.The composite may be in a form of a solid pipe or a hollow pipe having a superconducting thin layer deposited on an inner surface of the metal pipe.

公开(公告)号：US06301774B1

公开(公告)日：2001-10-16

申请号：US08906855

申请日：1997-08-06

申请人： Susumu Yamamoto ,  Teruyuki Murai ,  Nozomu Kawabe ,  Tomoyuki Awazu ,  Shuji Yazu ,  Tetsuji Jodai

发明人： Susumu Yamamoto ,  Teruyuki Murai ,  Nozomu Kawabe ,  Tomoyuki Awazu ,  Shuji Yazu ,  Tetsuji Jodai

IPC分类号： H01L3924

CPC分类号： H01L39/143 ,  H01L39/248 ,  Y10S428/93 ,  Y10S505/701 ,  Y10S505/702 ,  Y10S505/703 ,  Y10S505/704 ,  Y10T29/49014 ,  Y10T428/31678

摘要： A superconducting composite comprising a compound oxide type superconductor and an outer metal pipe on which said superconductor is supported, characterized in that (i) said outer metal pipe is made of at least one of metals selected from a group comprising gold, silver and platinum metals and their alloys or (ii) an intermediate layer made of these precious metals is interposed between the compound oxide and the metal pipe. The composite may be in a form of a solid pipe or a hollow pipe having a superconducting thin layer deposited on an inner surface of the metal pipe.

摘要翻译： 一种超导复合体，其包含复合氧化物型超导体和外部金属管，所述超导体被支撑在所述外部金属管上，其特征在于，（i）所述外部金属管由选自金，银和铂金属的金属中的至少一种制成 并且它们的合金或（ii）由这些贵金属制成的中间层插入在复合氧化物和金属管之间。复合材料可以是固体管或中空管的形式，其具有沉积在内部的超导薄层 金属管表面。

公开(公告)号：US5304602A

公开(公告)日：1994-04-19

申请号：US182489

申请日：1988-04-18

申请人： Susumu Yamamoto ,  Teruyuki Murai ,  Nozomu Kawabe ,  Shuji Yazu ,  Tetsuji Jodai

发明人： Susumu Yamamoto ,  Teruyuki Murai ,  Nozomu Kawabe ,  Shuji Yazu ,  Tetsuji Jodai

IPC分类号： C04B35/45 ,  H01L39/24 ,  H01L39/12

CPC分类号： C04B35/45 ,  H01L39/248 ,  Y10S505/74 ,  Y10T29/49014

摘要： A process for producing a sintered ceramic wire, particularly a superconducting wire, by the steps of filling a metal pipe with a material powder of ceramic, wire drawing the metal pipe filled with the material powder by means of roller dies and then subjecting a composite of the metal pipe and the material powder to a heating operation to sinter the ceramic powder.

摘要翻译： 一种烧结陶瓷丝，特别是超导线的制造方法，其特征在于，通过以陶瓷的材料粉末填充金属管的步骤，通过辊模拉出填充有材料粉末的金属管，然后使复合材料 金属管和材料粉末进行加热操作以烧结陶瓷粉末。

公开(公告)号：US5169831A

公开(公告)日：1992-12-08

申请号：US825578

申请日：1992-01-24

申请人： Susumu Yamamoto ,  Teruyuki Murai ,  Nozumu Kawabe ,  Tomoyuki Awazu ,  Shuji Yazu ,  Tetsuji Jodai

发明人： Susumu Yamamoto ,  Teruyuki Murai ,  Nozumu Kawabe ,  Tomoyuki Awazu ,  Shuji Yazu ,  Tetsuji Jodai

IPC分类号： B21C1/00 ,  B28B1/00 ,  C01G1/00 ,  C04B35/00 ,  C04B35/45 ,  H01B12/04 ,  H01B13/00 ,  H01L39/24

CPC分类号： H01L39/143 ,  H01L39/248 ,  Y10S428/93 ,  Y10S505/701 ,  Y10S505/702 ,  Y10S505/703 ,  Y10S505/704 ,  Y10T29/49014 ,  Y10T428/31678

摘要： A superconducting composite comprising a compound oxide type superconductor and an outer metal pipe on which said superconductor is supported, characterized in that (i) said outer metal pipe is made of at least one of metals selected from a group comprising gold, silver and platinum metals and their alloys or (ii) an intermediate layer made of these precious metals is interposed between the compound oxide and the metal pipe.The composite may be in a form of a solid pipe or a hollow pipe having a superconducting thin layer deposited on an inner surface of the metal pipe.

摘要翻译： 一种超导复合体，其包含复合氧化物型超导体和外部金属管，所述超导体被支撑在所述外部金属管上，其特征在于，（i）所述外部金属管由选自金，银和铂金属的金属中的至少一种制成 并且它们的合金或（ii）由这些贵金属制成的中间层插入在复合氧化物和金属管之间。 复合材料可以是固体管或中空管的形式，其具有沉积在金属管的内表面上的超导薄层。

公开(公告)号：US5981444A

公开(公告)日：1999-11-09

申请号：US851312

申请日：1997-05-05

申请人： Kazuo Sawada ,  Kazuhiko Hayasi ,  Sigeki Isojima ,  Susumu Yamamoto ,  Teruyuki Murai ,  Nozomu Kawabe ,  Hideo Itozaki ,  Nobuhiko Fujita ,  Kenichiro Sibata ,  Nobuyuki Sasaki ,  Shuji Yazu ,  Tetsuji Jodai

发明人： Kazuo Sawada ,  Kazuhiko Hayasi ,  Sigeki Isojima ,  Susumu Yamamoto ,  Teruyuki Murai ,  Nozomu Kawabe ,  Hideo Itozaki ,  Nobuhiko Fujita ,  Kenichiro Sibata ,  Nobuyuki Sasaki ,  Shuji Yazu ,  Tetsuji Jodai

IPC分类号： C04B35/45 ,  B21C1/00 ,  B28B1/00 ,  H01B12/02 ,  H01B12/04 ,  H01B13/00 ,  H01L39/24

CPC分类号： H01L39/248 ,  C04B35/4504 ,  C04B35/4521 ,  Y10T29/49014

摘要： A process for manufacturing a superconducting elongated article such as a superconducting wire which is applicable for manufacturing a superconducting coil or the like. The process includes steps comprising filling a metal pipe with material powder of ceramic consisting of compound oxide having superconductivity, performing plastic deformation of the metal pipe filled with the ceramic metal powder to reduce the cross section of the metal pipe, and then subjecting the deformed metal pipe to heat-treatment to sinter the ceramic material powder filled in the metal pipe. The ceramic material powder may contain compound oxide having Perovskite-type crystal structure exhibiting superconductivity.The metal pipe may selected from a group comprising metals of Ag, Au, Pt, Pd, Rh, Ir, Ru, Os, Cu, Al, Fe, Ni, Cr, Ti, Mo, W and Ta and alloys including these metals as the base. The heat-treatment may be carried out at a temperature ranging from 700 to 1,000.degree. C., The plastic deformation of the metal pipe filled with the ceramic metal powder may be performed in such manner that the cross section of the metal pipe is reduced at a dimensional reduction ratio ranging from 16% to 92% by wire-drawing or forging by means of dies, roller dies, or extruder.

摘要翻译： 一种用于制造可应用于制造超导线圈等的超导细长物品例如超导线材的方法。 该方法包括以下步骤：用金属管填充由具有超导性的复合氧化物组成的陶瓷材料粉末，对填充有陶瓷金属粉末的金属管进行塑性变形，以减小金属管的横截面，然后对变形的金属 管道进行热处理以烧结填充在金属管中的陶瓷材料粉末。 陶瓷材料粉末可以含有具有超导性的钙钛矿型晶体结构的复合氧化物。 金属管可以选自Ag，Au，Pt，Pd，Rh，Ir，Ru，Os，Cu，Al，Fe，Ni，Cr，Ti，Mo，W和Ta的金属和包括这些金属的合金 的基地。 热处理可以在700〜1000℃的温度下进行。填充有陶瓷金属粉末的金属管的塑性变形可以以使金属管的截面减小的方式进行 通过模具，辊模或挤出机进行拉丝或锻造，尺寸减小率为16％至92％。

公开(公告)号：US5030616A

公开(公告)日：1991-07-09

申请号：US225207

申请日：1988-07-28

申请人： Susumu Yamamoto ,  Nozomu Kawabe ,  Shuji Yazu ,  Tetsuji Jodai

发明人： Susumu Yamamoto ,  Nozomu Kawabe ,  Shuji Yazu ,  Tetsuji Jodai

IPC分类号： C04B35/45 ,  C04B35/64 ,  H01L39/24

CPC分类号： H01L39/248 ,  C04B35/4504 ,  C04B35/4512 ,  C04B35/4521 ,  C04B35/64 ,  Y10S505/705 ,  Y10T29/49014 ,  Y10T29/49906

摘要： Improvement in a method for producing a sintered elongated article by the steps comprising filling a metal pipe with a material powder, carrying out plastic deformation of the metal pipe and then subjecting the material powder in deformed metal pipe to sintering. In the invention, a netting of metallic wire (1) whose melting point is higher than a melting point of the material powder (3) is arranged around the metal pipe (2) before the sintering.

公开(公告)号：US5409890A

公开(公告)日：1995-04-25

申请号：US122178

申请日：1993-09-17

申请人： Susumu Yamamoto ,  Nozomu Kawabe ,  Tomoyuki Awazu ,  Teruyuki Murai

发明人： Susumu Yamamoto ,  Nozomu Kawabe ,  Tomoyuki Awazu ,  Teruyuki Murai

IPC分类号： B21C1/00 ,  B22F3/02 ,  B22F5/12 ,  B28B1/00 ,  C04B35/45 ,  C04B35/64 ,  H01B12/04 ,  H01B13/00 ,  H01L39/24

CPC分类号： H01L39/248 ,  C04B35/4504 ,  C04B35/4512 ,  C04B35/4521 ,  C04B35/64 ,  H01L39/2419 ,  Y10T29/49014

摘要： Improvement in a process for producing a sintered elongated article by the steps comprising filling a metal pipe with a material powder, carrying out plastic deformation of the metal pipe and then subjecting the material powder in deformed metal pipe to sintering. In the invention, the step of the plastic deformation includes at least one deformation satge carried out under a hot condition.

摘要翻译： 通过以下步骤制造烧结细长制品的方法的改进包括用金属材料粉末填充金属管，进行金属管的塑性变形，然后使变形的金属管中的材料粉末烧结。 在本发明中，塑性变形的步骤包括在热条件下进行的至少一个变形饱和。

公开(公告)号：US5244874A

公开(公告)日：1993-09-14

申请号：US877372

申请日：1992-04-29

申请人： Susumu Yamamoto ,  Nozomu Kawabe ,  Tomoyuki Awazu

发明人： Susumu Yamamoto ,  Nozomu Kawabe ,  Tomoyuki Awazu

IPC分类号： C04B35/45 ,  H01L39/14 ,  H01L39/24

CPC分类号： H01L39/2419 ,  C04B35/4504 ,  C04B35/4512 ,  C04B35/4521 ,  H01L39/143 ,  Y10S505/705 ,  Y10T29/49014

摘要： Improvement in a method for producing a superconducting wire of compound oxide such as YBa.sub.2 Cu.sub.3 O.sub.7-.delta. by the steps comprising filling a metal pipe with a material powder, carrying out plastic deformation of the metal pipe and then subjecting the material powder in deformed metal pipe to sintering operation. The present invention is characterized in that the heat-treatment is carried out in the coexist of silver oxide: Ag.sub.2 O placed inside the metal pipe.

摘要翻译： 通过以下步骤制造复合氧化物超导线材的方法的改进，包括用金属材料粉末填充金属管，进行金属管的塑性变形，然后使变形的金属管中的材料粉末烧结 操作。 本发明的特征在于，在金属管内放置氧化银Ag 2 O 3共存的情况下进行热处理。