公开(公告)号：US5106725A

公开(公告)日：1992-04-21

申请号：US758410

申请日：1991-08-30

申请人： Syoji Matsuzaka ,  Yukio Ohya

发明人： Syoji Matsuzaka ,  Yukio Ohya

IPC分类号： G03C1/015 ,  G03C1/035

CPC分类号： G03C1/035

摘要： Silver halide grains for use in silver halide photography having a regular crystal shape and including at most two irregularly grown crystal faces and a silver halide photo-sensitive material containing these silver halide grains are disclosed.

公开(公告)号：US5039601A

公开(公告)日：1991-08-13

申请号：US579255

申请日：1990-09-05

申请人： Yukio Ohya ,  Syoji Matsuzaka ,  Hirofumi Ohtani ,  Yoshiro Ito ,  Mineko Ito

发明人： Yukio Ohya ,  Syoji Matsuzaka ,  Hirofumi Ohtani ,  Yoshiro Ito ,  Mineko Ito

IPC分类号： G03C1/36 ,  G03C1/035 ,  G03C7/26 ,  G03C7/30

CPC分类号： G03C7/30 ,  G03C1/035 ,  G03C7/3022 ,  G03C2001/03564

摘要： A silver halide color negative photographic light-sensitive material is disclosed which is improved on stability to fluctuation of processing conditions applied thereon, and has a sufficient wide exposure latitude. The photographic material is also improved on standing stability of silver halide emulsion in the course of manufacturing thereof. The photographic material comprises a support having thereon photographic component layers including at least one silver halide emulsion layer containing at least two groups of silver halide grains each being substantially different in desensitizing agent content from each other.

公开(公告)号：US4894322A

公开(公告)日：1990-01-16

申请号：US831993

申请日：1986-02-20

申请人： Shigeto Hirabayashi ,  Syoji Matsuzaka ,  Yukio Ohya ,  Yoshiyuki Nonaka

发明人： Shigeto Hirabayashi ,  Syoji Matsuzaka ,  Yukio Ohya ,  Yoshiyuki Nonaka

IPC分类号： C07D487/04 ,  G03C7/30 ,  G03C7/38

CPC分类号： G03C7/3022 ,  G03C2001/03511 ,  G03C2007/3025 ,  G03C7/38

摘要： A light-sensitive silver halide color photographic material having photographic constituent layers including a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer on a support, wherein the content of silver bromide of the silver halides in the green-sensitive silver halide emulsion layer and red-sensitive silver halide emulsion layer is 5 to 65 mole %, and the green-sensitive silver halide emulsion layer contains at least one of the compounds represented by the formula shown below: ##STR1## wherein X represents a halogen atom or a monovalent organic group eliminable through coupling reaction with an oxidized product of a developing agent; R.sub.1 to R.sub.3, which may be either identical or different, each represent a hydrogen atom, a halogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, a sulfinyl group, a phosphonyl group, a carbamoyl group, a sulfamoyl group, a cyano group, a spiro compound residue, a bridged hydrocarbon compound residue, an alkoxy group, an aryloxy group, a heterocycloxy group, a siloxy group, an acyloxy group, a carbamoyloxy group, an amino group, an acylamino group, a sulfonamide group, an imide group, a ureido group, a sulfamoylamino group, an alkoxycarbonylamino group, an aryloxycarbonylamino group, an alkoxycarbonyl group, an aryloxycarboynyl group, an alkylthio group, an arylthio group or a heterocyclic thio group, with proviso that at least two of R.sub.1 to R.sub.3 are not hydrogen atoms; R.sub.4 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an acylamino group, an alkylamino group, an anilino group, an alkoxycarbonyl group or an alkylthio group.According to the light-sensitive silver halide color photographic material of this invention, rapid developing processing is possible with improvement of processing stability in the rapid developing processing, and yet saving of silver is possible, simultaneously with inhibition of generation of fog, and moreover color image with good light resistance can be obtained.

公开(公告)号：US4758504A

公开(公告)日：1988-07-19

申请号：US945306

申请日：1986-12-22

申请人： Yukio Ohya ,  Syoji Matsuzaka ,  Yasuo Tosaka ,  Yoshihiko Suda

发明人： Yukio Ohya ,  Syoji Matsuzaka ,  Yasuo Tosaka ,  Yoshihiko Suda

IPC分类号： G03C1/005 ,  G03C1/035 ,  G03C1/02

CPC分类号： G03C1/035

摘要： Disclosed are silver halide grains which have crystal faces defined by Miller indices of (nnl) where n.gtoreq.2 and comprising a silver halide composition consisting substantially of silver chlorobromide; a light-sensitive silver halide photographic material having, on a support, light-sensitive silver halide emulsion layers at least one of which contain the above silver halide grains; and a method for preparing silver halide photographic emulsion containing the above silver halide grains having the steps of mixing a silver ion solution and a halide ion solution in the presence of a protective colloid and then forming and growing silver halide grains having a silver halide composition of 2 mole % or less of silver iodide, 1 to 99 mole % of silver chloride and 99 mole % or less of silver bromide, wherein the silver ion solution comprises an ammoniacal silver nitrate solution and formation and growing of the silver halide grains are carried out in the presence of at least one selected from the compounds represented by the formula (I), (II), (III) or (IV) shown below and the compounds having the recurring units represented by the formula (V) shown below: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3, which may be either the same or different, each represent a hydrogen atom, a halogen atom, a hydroxyl group, an amino group, a derivative of an amino group, an alkyl group, a derivative of an alkyl group, an aryl group, a derivative of an aryl group, a cycloalkyl group, a derivative of a cycloalkyl group, a mercapto group, a derivative of an mercapto group or --CONH--R.sub.4 (R.sub.4 is a hydrogen atom, an amino group, a derivative of an alkyl group, a derivative of an amino group, a halogen atom, a cycloalkyl group, a derivative of a cycloalkyl group, an aryl group or a derivative of an aryl group), R.sub.1 and R.sub.2 may be bonded together to form a ring, R.sub.5 represents a hydrogen atom or an alkyl group, X represents a monovalent group formed by eliminating one hydrogen atom from the compounds represented by the formula (I), (II), (III) or (IV), and J represents a divalent linking group.

公开(公告)号：US5340710A

公开(公告)日：1994-08-23

申请号：US86571

申请日：1993-07-06

申请人： Yukio Ohya ,  Syoji Matsuzaka ,  Yasushi Irie ,  Shuji Murakami ,  Satomi Asano ,  Hiroshi Okusa ,  Hirofumi Ohtani

发明人： Yukio Ohya ,  Syoji Matsuzaka ,  Yasushi Irie ,  Shuji Murakami ,  Satomi Asano ,  Hiroshi Okusa ,  Hirofumi Ohtani

IPC分类号： G03C1/015 ,  G03C1/12 ,  G03C1/035

CPC分类号： G03C1/12 ,  G03C1/015

摘要： A photosensitive silver halide photographic material having a support and, provided thereon, the photographic component layers including at least one silver halide emulsion layer containing silver halide grains (1) having at least two kinds of halogens, is disclosed. The silver halide grains (1) are grown to in a system in the presence of silver halide grains (2) coexisting:with silver halide grains which are growing to the silver halide grains (1),for at least some portion of period that said silver halide grains are growing in the system,and comprising solubility product less than that of said growing silver halide grains.

摘要翻译： 公开了一种光敏卤化银照相材料，其具有支撑体，并且在其上设置包括至少一个含有卤化银颗粒（1）的卤化银乳剂层的照相组分层，所述卤化银乳剂层具有至少两种卤素。 卤化银颗粒（1）在卤化银颗粒（2）共存的系统中生长至卤化银颗粒（1）的卤化银颗粒至少部分时间段 卤化银颗粒在系统中生长，并且包含小于所述生长卤化银颗粒的溶解度积。

公开(公告)号：US4769315A

公开(公告)日：1988-09-06

申请号：US7367

申请日：1987-01-27

申请人： Yoshihiko Suda ,  Syoji Matsuzaka ,  Yasuo Tosaka ,  Yukio Ohya

发明人： Yoshihiko Suda ,  Syoji Matsuzaka ,  Yasuo Tosaka ,  Yukio Ohya

IPC分类号： C01G5/02 ,  G03C1/005 ,  G03C1/015 ,  G03C1/035 ,  G03C1/46 ,  G03C1/02

CPC分类号： G03C1/035

摘要： Disclosed are a silver halide grain comprising 8 or 12 concavities on the surface, and a photographical light-sensitive material containing a silver halide grain having 8 to 12 concavities on the surface.According to the present invention, there can be obtained silver halide grains having still higher sensitivity and also improved in the relationship of sensitivity-fog as compared with those of the prior art, and also a light-sensitive silver halide material by use of an emulsion containing said grains.

摘要翻译： 公开了一种在表面上包含8或12个凹面的卤化银颗粒，以及含有在表面上具有8至12个凹面的卤化银颗粒的照相感光材料。 根据本发明，与现有技术相比，可以获得具有更高灵敏度的卤化银颗粒和敏感性 - 雾度的关系，并且还使用通过使用乳液的感光卤化银材料 含有所述谷物。

公开(公告)号：US4710453A

公开(公告)日：1987-12-01

申请号：US830180

申请日：1986-02-18

申请人： Shigeto Hirabayashi ,  Syoji Matsuzaka ,  Yukio Ohya ,  Yoshiyuki Nonaka

发明人： Shigeto Hirabayashi ,  Syoji Matsuzaka ,  Yukio Ohya ,  Yoshiyuki Nonaka

IPC分类号： G03C7/38 ,  G03C7/32 ,  G03C7/36

CPC分类号： G03C7/3225

摘要： A silver halide color photographic material is disclosed. Said material has formed on a base photographic layers including a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer, wherein said blue-sensitive silver halide emulsion layer contains at least one highly reactive yellow coupler having a relative coupling reaction rate of 0.3 or more, said green-sensitive silver halide emulsion layer containing at least one compound of Formula (I): ##STR1## wherein X is a halogen atom or a monovalent organic group capable of leaving upon coupling reaction with the oxidized product of a developing agent; R.sub.1 to R.sub.3 which may be the same or different each represents a hydrogen atom, a halogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, a sulfinyl group, a phosphonyl group, a carbamoyl group, a sulfamoyl group, a cyan group, a spiro compound residual group, a bridged hydrocarbon compound residual group, an alkoxy group, an aryloxy group, a heterocyclic oxy group, a siloxy group, an acyloxy group, a carbamoyloxy group, an amino group, an acylamino group, a sulfonamido group, an imido group, a ureido group, a sulfamoylamino group, an alkoxycarbonylamino group, an aryloxycarbonylamino group, an aryloxycarbonylamino group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkylthio group, an arylthio group or a heterocyclic thio group, provided that at least two of R.sub.1 to R.sub.3 are other than a hydrogen atom; and R.sub.4 is a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an acylamino group, analkylamino group, an anilino group, an alkoxycarbonyl group or an alkylthio group.

摘要翻译： 公开了一种卤化银彩色照相材料。 所述材料形成在包括感蓝卤化银乳剂层，感绿卤化银乳剂层和感红卤化银乳剂层的基底照相层上，其中所述感蓝卤化银乳剂层含有至少一种 所述感绿卤化银乳剂层含有至少一种式（I）的化合物：其中X是卤素原子或一价有机物 能够与显影剂的氧化产物偶联反应的基团; 可以相同或不同的R 1〜R 3各自表示氢原子，卤素原子，烷基，环烷基，烯基，环烯基，炔基，芳基，杂环基，酰基 基团，磺酰基，亚磺酰基，膦酰基，氨基甲酰基，氨磺酰基，青基，螺环化合物残基，桥连烃化合物残基，烷氧基，芳氧基，杂环氧基 基团，甲硅烷氧基，酰氧基，氨基甲酰氧基，氨基，酰氨基，亚磺酰氨基，亚氨基，脲基，氨磺酰基氨基，烷氧基羰基氨基，芳氧基羰基氨基，芳氧基羰基氨基， 烷氧基羰基，芳氧基羰基，烷硫基，芳硫基或杂环硫基，条件是R 1至R 3中的至少两个不是氢原子; R4为氢原子，烷基，芳基，杂环基，酰氨基，烷基氨基，苯胺基，烷氧基羰基或烷硫基。

公开(公告)号：US5478716A

公开(公告)日：1995-12-26

申请号：US308396

申请日：1994-09-19

申请人： Tadanobu Sekiya ,  Yasuo Honta ,  Syoji Matsuzaka

发明人： Tadanobu Sekiya ,  Yasuo Honta ,  Syoji Matsuzaka

IPC分类号： G03C1/015 ,  G03C1/005 ,  G03C1/035 ,  G03C7/26

CPC分类号： G03C1/0051

摘要： A silver halide emulsion is provided, which comprises silver halide twinned-crystal grains and satisfy the following requirements (1) and (2):(1) the longest distance between twin planes is within the range of 10 to 100 .ANG. on the average,(2) said silver halide grains each comprise a core comprising silver iodobromide having a silver iodide content of not less than 7 mol % and a shell comprising one or more layers different in halide composition from each other, in which at least one layer of the shell comprises silver iodobromide or silver bromide, the outermost layer having a silver iodide content of 0 to 4 mol %.

摘要翻译： 提供了一种卤化银乳剂，其包含卤化银双晶晶粒并且满足以下要求（1）和（2）：（1）平面之间的双平面之间的最长距离在10至100安培的范围内， （2）所述卤化银颗粒各自包含含有碘化银含量不小于7mol％的碘溴化银的核心和包含卤化物组合物彼此不同的一层或多层的壳，其中至少一层 壳包含碘溴化银或溴化银，最外层的碘化银含量为0〜4mol％。

公开(公告)号：US5002865A

公开(公告)日：1991-03-26

申请号：US489747

申请日：1990-02-26

申请人： Kenji Kumashiro ,  Hiroshi Kashiwagi ,  Syoji Matsuzaka ,  Toshifumi Iijima

发明人： Kenji Kumashiro ,  Hiroshi Kashiwagi ,  Syoji Matsuzaka ,  Toshifumi Iijima

IPC分类号： G03C7/26 ,  G03C1/005 ,  G03C1/035 ,  G03C7/38

CPC分类号： G03C1/035 ,  G03C7/3825

摘要： A silver halide photographic material is disclosed, said material having silver halide emulsion layers on a support, the emulsion in said silver halide emulsion layers containing magenta coupler represented by the following formula (I), said emulsion containing silver halide grains which have a (110) plane and/or a crystal plane having an edge running through substantially the center of a (110) plane, the silver halide composition of said grains being substantially made of silver bromide and/or silver iodobromide: ##STR1## where Z represents a group of the non-metallic atoms necessary for forming a nitrogen-containing hetero ring which may have a substituent; X is a hydrogen atom or a substituent which is capable of being eliminated upon reaction with the oxidation product of a color developing agent; and R is a hydrogen atom or a substituent.

摘要翻译： 公开了一种卤化银照相材料，所述材料在载体上具有卤化银乳剂层，所述卤化银乳剂层中的乳液含有下式（I）表示的品红成色剂，所述乳液含有卤化银颗粒，其具有（110） ）平面和/或具有延伸穿过（110）面的中心的边缘的晶面，所述晶粒的卤化银组合物基本上由溴化银和/或碘溴化银制成：其中Z 表示形成可以具有取代基的含氮杂环所必需的一组非金属原子; X是氢原子或与彩色显影剂的氧化产物反应时能够被除去的取代基; R为氢原子或取代基。

公开(公告)号：US4507386A

公开(公告)日：1985-03-26

申请号：US530020

申请日：1983-09-07

申请人： Syoji Matsuzaka ,  Makoto Kajiwara ,  Masanobu Miyoshi ,  Kiyoshi Yamashita

发明人： Syoji Matsuzaka ,  Makoto Kajiwara ,  Masanobu Miyoshi ,  Kiyoshi Yamashita

IPC分类号： G03C7/26 ,  G03C1/005 ,  G03C1/035

CPC分类号： G03C1/035 ,  G03C2001/03511 ,  G03C2001/03535

摘要： A silver halide photographic emulsion containing a coupler for photography, comprising silver halide particles in said emulsion consisting essentially of 2 mole % or less of silver iodide, 50 to 97 mole % of silver bromide and 1 to 50 mole % of silver chloride, and said particles are core/shell type silver halide particles containing a higher content of said 50 to 97 mole % silver bromide in the surface layers of said particles than in the inner portions thereof, the surface layer of said particles containing 70 to 100 mole % of silver bromide and the inner portion containing 40 to 70 mole % of silver bromide.

摘要翻译： 一种含有用于摄影的成色剂的卤化银照相乳剂，其中所述乳液中的卤化银颗粒基本上由2％（摩尔）或更少的碘化银，50-97％（摩尔）的溴化银和1％至50％的氯化银组成，所述 颗粒是核/壳型卤化银颗粒，其在所述颗粒的表面层中含有比所述颗粒的表面层更高含量的所述50-97摩尔％溴化银，所述颗粒的表面层含有70-100摩尔％的银 溴化物，内部含有40〜70摩尔％的溴化银。