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1.发明授权
公开(公告)号：US4769315A
公开(公告)日：1988-09-06
申请号：US7367
申请日：1987-01-27
申请人： Yoshihiko Suda , Syoji Matsuzaka , Yasuo Tosaka , Yukio Ohya
发明人： Yoshihiko Suda , Syoji Matsuzaka , Yasuo Tosaka , Yukio Ohya
CPC分类号： G03C1/035
摘要： Disclosed are a silver halide grain comprising 8 or 12 concavities on the surface, and a photographical light-sensitive material containing a silver halide grain having 8 to 12 concavities on the surface.According to the present invention, there can be obtained silver halide grains having still higher sensitivity and also improved in the relationship of sensitivity-fog as compared with those of the prior art, and also a light-sensitive silver halide material by use of an emulsion containing said grains.
摘要翻译： 公开了一种在表面上包含8或12个凹面的卤化银颗粒，以及含有在表面上具有8至12个凹面的卤化银颗粒的照相感光材料。 根据本发明，与现有技术相比，可以获得具有更高灵敏度的卤化银颗粒和敏感性 - 雾度的关系，并且还使用通过使用乳液的感光卤化银材料 含有所述谷物。
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公开(公告)号：US4758504A
公开(公告)日：1988-07-19
申请号：US945306
申请日：1986-12-22
申请人： Yukio Ohya , Syoji Matsuzaka , Yasuo Tosaka , Yoshihiko Suda
发明人： Yukio Ohya , Syoji Matsuzaka , Yasuo Tosaka , Yoshihiko Suda
CPC分类号： G03C1/035
摘要： Disclosed are silver halide grains which have crystal faces defined by Miller indices of (nnl) where n.gtoreq.2 and comprising a silver halide composition consisting substantially of silver chlorobromide; a light-sensitive silver halide photographic material having, on a support, light-sensitive silver halide emulsion layers at least one of which contain the above silver halide grains; and a method for preparing silver halide photographic emulsion containing the above silver halide grains having the steps of mixing a silver ion solution and a halide ion solution in the presence of a protective colloid and then forming and growing silver halide grains having a silver halide composition of 2 mole % or less of silver iodide, 1 to 99 mole % of silver chloride and 99 mole % or less of silver bromide, wherein the silver ion solution comprises an ammoniacal silver nitrate solution and formation and growing of the silver halide grains are carried out in the presence of at least one selected from the compounds represented by the formula (I), (II), (III) or (IV) shown below and the compounds having the recurring units represented by the formula (V) shown below: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3, which may be either the same or different, each represent a hydrogen atom, a halogen atom, a hydroxyl group, an amino group, a derivative of an amino group, an alkyl group, a derivative of an alkyl group, an aryl group, a derivative of an aryl group, a cycloalkyl group, a derivative of a cycloalkyl group, a mercapto group, a derivative of an mercapto group or --CONH--R.sub.4 (R.sub.4 is a hydrogen atom, an amino group, a derivative of an alkyl group, a derivative of an amino group, a halogen atom, a cycloalkyl group, a derivative of a cycloalkyl group, an aryl group or a derivative of an aryl group), R.sub.1 and R.sub.2 may be bonded together to form a ring, R.sub.5 represents a hydrogen atom or an alkyl group, X represents a monovalent group formed by eliminating one hydrogen atom from the compounds represented by the formula (I), (II), (III) or (IV), and J represents a divalent linking group.
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3.发明授权
公开(公告)号：US5106725A
公开(公告)日：1992-04-21
申请号：US758410
申请日：1991-08-30
申请人： Syoji Matsuzaka , Yukio Ohya
发明人： Syoji Matsuzaka , Yukio Ohya
CPC分类号： G03C1/035
摘要： Silver halide grains for use in silver halide photography having a regular crystal shape and including at most two irregularly grown crystal faces and a silver halide photo-sensitive material containing these silver halide grains are disclosed.
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4.发明授权Silver halide emulsions with silver halide grain groups of different desensitizing agent content 失效具有不同脱敏剂含量的卤化银颗粒组的卤化银乳剂
公开(公告)号：US5039601A
公开(公告)日：1991-08-13
申请号：US579255
申请日：1990-09-05
申请人： Yukio Ohya , Syoji Matsuzaka , Hirofumi Ohtani , Yoshiro Ito , Mineko Ito
发明人： Yukio Ohya , Syoji Matsuzaka , Hirofumi Ohtani , Yoshiro Ito , Mineko Ito
CPC分类号： G03C7/30 , G03C1/035 , G03C7/3022 , G03C2001/03564
摘要： A silver halide color negative photographic light-sensitive material is disclosed which is improved on stability to fluctuation of processing conditions applied thereon, and has a sufficient wide exposure latitude. The photographic material is also improved on standing stability of silver halide emulsion in the course of manufacturing thereof. The photographic material comprises a support having thereon photographic component layers including at least one silver halide emulsion layer containing at least two groups of silver halide grains each being substantially different in desensitizing agent content from each other.
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公开(公告)号：US5340710A
公开(公告)日：1994-08-23
申请号：US86571
申请日：1993-07-06
申请人： Yukio Ohya , Syoji Matsuzaka , Yasushi Irie , Shuji Murakami , Satomi Asano , Hiroshi Okusa , Hirofumi Ohtani
发明人： Yukio Ohya , Syoji Matsuzaka , Yasushi Irie , Shuji Murakami , Satomi Asano , Hiroshi Okusa , Hirofumi Ohtani
摘要： A photosensitive silver halide photographic material having a support and, provided thereon, the photographic component layers including at least one silver halide emulsion layer containing silver halide grains (1) having at least two kinds of halogens, is disclosed. The silver halide grains (1) are grown to in a system in the presence of silver halide grains (2) coexisting:with silver halide grains which are growing to the silver halide grains (1),for at least some portion of period that said silver halide grains are growing in the system,and comprising solubility product less than that of said growing silver halide grains.
摘要翻译： 公开了一种光敏卤化银照相材料，其具有支撑体，并且在其上设置包括至少一个含有卤化银颗粒（1）的卤化银乳剂层的照相组分层，所述卤化银乳剂层具有至少两种卤素。 卤化银颗粒（1）在卤化银颗粒（2）共存的系统中生长至卤化银颗粒（1）的卤化银颗粒至少部分时间段 卤化银颗粒在系统中生长，并且包含小于所述生长卤化银颗粒的溶解度积。
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公开(公告)号：US4710453A
公开(公告)日：1987-12-01
申请号：US830180
申请日：1986-02-18
CPC分类号： G03C7/3225
摘要： A silver halide color photographic material is disclosed. Said material has formed on a base photographic layers including a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer, wherein said blue-sensitive silver halide emulsion layer contains at least one highly reactive yellow coupler having a relative coupling reaction rate of 0.3 or more, said green-sensitive silver halide emulsion layer containing at least one compound of Formula (I): ##STR1## wherein X is a halogen atom or a monovalent organic group capable of leaving upon coupling reaction with the oxidized product of a developing agent; R.sub.1 to R.sub.3 which may be the same or different each represents a hydrogen atom, a halogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, a sulfinyl group, a phosphonyl group, a carbamoyl group, a sulfamoyl group, a cyan group, a spiro compound residual group, a bridged hydrocarbon compound residual group, an alkoxy group, an aryloxy group, a heterocyclic oxy group, a siloxy group, an acyloxy group, a carbamoyloxy group, an amino group, an acylamino group, a sulfonamido group, an imido group, a ureido group, a sulfamoylamino group, an alkoxycarbonylamino group, an aryloxycarbonylamino group, an aryloxycarbonylamino group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkylthio group, an arylthio group or a heterocyclic thio group, provided that at least two of R.sub.1 to R.sub.3 are other than a hydrogen atom; and R.sub.4 is a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an acylamino group, analkylamino group, an anilino group, an alkoxycarbonyl group or an alkylthio group.
摘要翻译： 公开了一种卤化银彩色照相材料。 所述材料形成在包括感蓝卤化银乳剂层，感绿卤化银乳剂层和感红卤化银乳剂层的基底照相层上，其中所述感蓝卤化银乳剂层含有至少一种 所述感绿卤化银乳剂层含有至少一种式（I）的化合物：其中X是卤素原子或一价有机物 能够与显影剂的氧化产物偶联反应的基团; 可以相同或不同的R 1〜R 3各自表示氢原子，卤素原子，烷基，环烷基，烯基，环烯基，炔基，芳基，杂环基，酰基 基团，磺酰基，亚磺酰基，膦酰基，氨基甲酰基，氨磺酰基，青基，螺环化合物残基，桥连烃化合物残基，烷氧基，芳氧基，杂环氧基 基团，甲硅烷氧基，酰氧基，氨基甲酰氧基，氨基，酰氨基，亚磺酰氨基，亚氨基，脲基，氨磺酰基氨基，烷氧基羰基氨基，芳氧基羰基氨基，芳氧基羰基氨基， 烷氧基羰基，芳氧基羰基，烷硫基，芳硫基或杂环硫基，条件是R 1至R 3中的至少两个不是氢原子; R4为氢原子，烷基，芳基，杂环基，酰氨基，烷基氨基，苯胺基，烷氧基羰基或烷硫基。
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公开(公告)号：US4894322A
公开(公告)日：1990-01-16
申请号：US831993
申请日：1986-02-20
IPC分类号： C07D487/04 , G03C7/30 , G03C7/38
CPC分类号： G03C7/3022 , G03C2001/03511 , G03C2007/3025 , G03C7/38
摘要： A light-sensitive silver halide color photographic material having photographic constituent layers including a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer on a support, wherein the content of silver bromide of the silver halides in the green-sensitive silver halide emulsion layer and red-sensitive silver halide emulsion layer is 5 to 65 mole %, and the green-sensitive silver halide emulsion layer contains at least one of the compounds represented by the formula shown below: ##STR1## wherein X represents a halogen atom or a monovalent organic group eliminable through coupling reaction with an oxidized product of a developing agent; R.sub.1 to R.sub.3, which may be either identical or different, each represent a hydrogen atom, a halogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, an alkynyl group, an aryl group, a heterocyclic group, an acyl group, a sulfonyl group, a sulfinyl group, a phosphonyl group, a carbamoyl group, a sulfamoyl group, a cyano group, a spiro compound residue, a bridged hydrocarbon compound residue, an alkoxy group, an aryloxy group, a heterocycloxy group, a siloxy group, an acyloxy group, a carbamoyloxy group, an amino group, an acylamino group, a sulfonamide group, an imide group, a ureido group, a sulfamoylamino group, an alkoxycarbonylamino group, an aryloxycarbonylamino group, an alkoxycarbonyl group, an aryloxycarboynyl group, an alkylthio group, an arylthio group or a heterocyclic thio group, with proviso that at least two of R.sub.1 to R.sub.3 are not hydrogen atoms; R.sub.4 represents a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an acylamino group, an alkylamino group, an anilino group, an alkoxycarbonyl group or an alkylthio group.According to the light-sensitive silver halide color photographic material of this invention, rapid developing processing is possible with improvement of processing stability in the rapid developing processing, and yet saving of silver is possible, simultaneously with inhibition of generation of fog, and moreover color image with good light resistance can be obtained.
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8.发明授权
公开(公告)号：US4285939A
公开(公告)日：1981-08-25
申请号：US137753
申请日：1980-04-07
申请人： Yoshimasa Machida , Isao Saito , Motosuke Yamanaka , Seiichiro Nomoto , Shigeto Negi , Kyosuke Kitoh , Kanemasa Katsu , Yukio Ohya , Takeshi Suzuki , Kyoko Koizumi
发明人： Yoshimasa Machida , Isao Saito , Motosuke Yamanaka , Seiichiro Nomoto , Shigeto Negi , Kyosuke Kitoh , Kanemasa Katsu , Yukio Ohya , Takeshi Suzuki , Kyoko Koizumi
IPC分类号： C07D501/22 , A61K31/545 , A61K31/546 , A61P31/04 , C07D311/22 , C07D501/34 , C07D501/20
CPC分类号： C07D311/22
摘要： New cephalosporin derivatives represented by the general formula: ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 each represents hydroxy, acyloxy, and hydrogen provided that two or three of R.sub.1, R.sub.2, and R.sub.3 are not hydrogen at the same time, and their salts, and processes for the preparation thereof. The cephalosporin derivatives of the present invention are useful as antibacterial drugs.
摘要翻译： 由以下通式表示的新型头孢菌素衍生物：其中R 1，R 2和R 3各自表示羟基，酰氧基和氢，条件是R 1，R 2和R 3中的两个或三个不同时为氢， ，及其制备方法。 本发明的头孢菌素衍生物可用作抗菌药物。
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公开(公告)号：US5405739A
公开(公告)日：1995-04-11
申请号：US146522
申请日：1993-11-01
申请人： Yukio Ohya , Masato Okuyama
发明人： Yukio Ohya , Masato Okuyama
摘要： A silver halide photographic light-sensitive material comprises a support and provided thereon, a silver halide emulsion layer containing silver halide grains and a macrocyclic compound in an amount of 1.times.10.sup.-6 to 1.times.10.sup.-1 mol per mol of silver, said macrocyclic compound comprising a 9- or more-membered ring containing at least one of a nitrogen atom, an oxygen atom, a sulfur atom and a selenium atom, and said silver halide grains having a silver chloride content of not less than 90 mol % and containing at least one metal selected from the group consisting of metals of VIB group, VIIB group, VIII group, IIB group, IIIA group and IVA group from the Periodic Table.
摘要翻译： 卤化银照相感光材料包括载体，其上含有卤化银颗粒和每摩尔银1×10-6至1×10-1摩尔量的大环化合物的卤化银乳剂层，所述大环化合物包含 包含氮原子，氧原子，硫原子和硒原子中的至少一个的9元或更多元环，所述卤化银粒子的氯化银含量为90摩尔％以上且含有至少一个 选自元素周期表中的VIB族，VIIB族，VIII族，IIB族，IIIA族和IVA族金属的金属。
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公开(公告)号：US5508159A
公开(公告)日：1996-04-16
申请号：US373497
申请日：1995-01-17
申请人： Masato Okuyama , Yukio Ohya
发明人： Masato Okuyama , Yukio Ohya
摘要： A silver halide photographic light-sensitive material is disclosed, which comprises a support and provided thereon, a silver halide emulsion layer containing a crown ether having a 18-membered ring condensed with at least one aromatic ring and silver halide grains having a (100) face and satisfying the following inequality:15.ltoreq.Kwherein K is defined to be (intensity of a diffraction line attributed to a (200) face)/(intensity of a diffraction line attributed to a (222) face).
摘要翻译： 公开了一种卤化银照相感光材料，其包含载体并在其上提供含有具有与至少一个芳族环稠合的18元环的冠醚的卤化银乳剂层和具有（100） 并且满足以下不等式：其中K定义为（归因于（200）面的衍射线的强度）/（归因于（222）面的衍射线的强度）。
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