Staged synthesis of diiodoperfluoro-C3 to C7-alkanes

    公开(公告)号:US09637430B2

    公开(公告)日:2017-05-02

    申请号:US15053699

    申请日:2016-02-25

    CPC classification number: C07C17/272 C07C17/093 C07C17/204 C07C17/26 C07C19/16

    Abstract: The process is provided for forming the reaction product comprising the homologue mixture of I(CF2)nI, wherein n is 3 to 7, which may contain at least one of the contaminants ICF2I and I(CF2)2I, by the steps comprising (a) reacting iodine with hexafluoropropylene oxide at a temperature of 150° C. to 210° C. in a reactor, the amount of said hexafluoro-propylene oxide being a portion of the total amount of hexafluoropropylene oxide to be reacted with said iodine, thereby forming a reaction product containing gaseous perfluoroacetyl fluoride as a reaction by-product, (b) cooling said reaction product to become liquid except for said gaseous perfluoroacetyl fluoride, (c) venting said perfluoroacetyl fluoride from said reactor, and (d) repeating said steps (a), (b), and (c) until said total amount of said HFPO is reacted with said iodine.

    Synthesis of diiodoperfluoro-C3 to C7-alkanes
    3.
    发明授权
    Synthesis of diiodoperfluoro-C3 to C7-alkanes 有权
    二碘全氟-C3至C7-烷烃的合成

    公开(公告)号:US09505687B2

    公开(公告)日:2016-11-29

    申请号:US15053634

    申请日:2016-02-25

    Abstract: The present invention is the process comprising forming a stable mixture comprising I(CF2)nI, wherein n is at least 3 and at least one of I(CF2)nI, wherein n is 1 or 2, as a contaminant in said mixture and heating said mixture to a temperature of at least 220° C. to reduce the amount of said contaminant to be no greater than 1% when said contaminant is ICF2I (n=1) and no greater than 0.1% when said contaminant is ICF2CF2I (n=2).

    Abstract translation: 本发明包括形成包含I(CF 2)n I的稳定混合物,其中n为至少3,并且I(CF 2)n I,其中n为1或2的至少一种作为所述混合物中的污染物和加热 所述混合物至少为220℃,当所述污染物为ICF2I(n = 1)时,将所述污染物的量减少至不大于1%,当所述污染物为ICF2CF2I时,所述污染物的量不大于0.1%(n = 2)。

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