Toner having negative triboelectric chargeability and image forming method
    2.
    发明授权
    Toner having negative triboelectric chargeability and image forming method 有权
    具有负摩擦带电性和图像形成方法的调色剂

    公开(公告)号:US06232027B1

    公开(公告)日:2001-05-15

    申请号:US09318776

    申请日:1999-05-26

    IPC分类号: G03G9087

    摘要: A toner having a negative triboelectric chargeability is constituted by at least a binder resin, a colorant and an organic metal compound. The toner is characterized by: (a) the organic metal compound is an organic zirconium compound comprising a coordination or/and a bonding of zirconium and an aromatic compound as a ligand or/and an acid source selected from the group consisting of aromatic diols, aromatic hydroxycarboxylic acids, aromatic monocarboxylic acids, and aromatic polycarboxylic acids, (b) the binder resin is a resin selected from the group consisting of (i) a polyester resin and (ii) a hybrid resin component comprising a polyester unit and a vinyl polymer unit, (c) the binder resin has an acid value of 2-50 mgKOH/g, and (d) the toner contains a TFT (tetrahydrofuran)-soluble content providing a GPC (gel permeation chromatography) chromatogram exhibiting a main peak in a molecular weight range of 3,000-20,000 and including 3-25% of a component having molecular weights of at least 5×105.

    摘要翻译: 具有负摩擦带电性的调色剂至少由粘合剂树脂,着色剂和有机金属化合物构成。 调色剂的特征在于:(a)有机金属化合物是一种有机锆化合物,其包含锆和作为配体的芳族化合物的配位或/和键合,和/或选自芳族二醇, (b)粘合剂树脂是选自(i)聚酯树脂和(ii)包含聚酯单元和乙烯基聚合物的杂化树脂组分的树脂中的一种树脂 单元,(c)粘合剂树脂的酸值为2-50mgKOH / g,(d)调色剂含有提供GPC(凝胶渗透色谱)色谱的TFT(四氢呋喃) - 可溶性含量, 分子量范围为3,000-20,000,并且包括3-25%的分子量至少为5×10 5的成分。

    Toner and image forming method
    3.
    发明授权
    Toner and image forming method 有权
    调色剂和成像方法

    公开(公告)号:US5976752A

    公开(公告)日:1999-11-02

    申请号:US135167

    申请日:1998-08-18

    IPC分类号: G03G9/087 G03G9/097 G03G13/22

    摘要: An electrophotographic toner is composed of at least a binder resin, a colorant, and a wax. The binder resin (a) comprises a polyester resin, a vinyl resin and a hybrid resin component comprising a polyester unit and a vinyl polymer unit, (b) has a THF (tetrahydrofuran)-soluble content (W1) of 50-85 wt. % and a THF-insoluble content (W2) of 5-50 wt. %, an ethyl acetate-soluble content (W3) of 40-98 wt. % and an ethyl acetate-insoluble content (W4) of 2-60 wt. %, a chloroform-soluble content (W5) of 55-90 wt. % and a chloroform-insoluble content (W6) of 10-45 wt. %, respectively after 10 hours of Soxhlet extraction with respective solvents, giving a ratio W4/S6 of 1.1-4.0, and contains a THF-soluble content providing a GPC (gel permeation chromatography) chromatogram exhibiting a main peak in a molecular weight range of 4000-9000, including 35.0-65.0% (A1) of a component haing molecular weights in a range of 500 to below 1.times.10.sup.4, 25.0-45.0% (A2) of a component having molecular weights in a range of 1.times.10.sup.4 to below 1.times.10.sup.5 and 10.0-30.0% (A3) of a component having molecular weights of at least 1.times.10.sup.5 giving a ratio A1/A2 of 1.05-2.00. The binder resin shows good dispersibility of wax and colorant.

    摘要翻译: 电子照相调色剂由至少粘合剂树脂,着色剂和蜡组成。 粘合剂树脂(a)包括聚酯树脂,乙烯基树脂和包含聚酯单元和乙烯基聚合物单元的混合树脂组分,(b)具有50-85重量%的THF(四氢呋喃) - 可溶成分(W1) %和THF不溶物含量(W2)为5-50wt。 %,40-98重量%的乙酸乙酯可溶物含量(W3) %,乙酸乙酯不溶物含量(W4)为2-60wt。 %,55-90重量%的氯仿可溶物含量(W5) %,氯仿不溶物含量(W6)为10-45wt。 %,分别用各自的溶剂提取索氏提取10小时后,得到比例W4 / S6为1.1-4.0,并含有THF可溶性成分,提供在分子量范围内显示主峰的GPC(凝胶渗透色谱)色谱图 4000-9000,包括分子量在500至低于1×10 4范围内的分子量为35.0-65.0%(A1),分子量为1×104至低于1×10 5的组分的25.0-45.0%(A2)和10.0 -30.0%(A3)的分子量为至少1×10 5的组分,其A1 / A2比为1.05-2.00。 粘合剂树脂表现出良好的蜡和着色剂的分散性。

    Toner for developing electrostatic image containing specified double
oxide particles
    4.
    发明授权
    Toner for developing electrostatic image containing specified double oxide particles 失效
    用于显影含有特定双氧化物颗粒的静电图像的调色剂

    公开(公告)号:US5858597A

    公开(公告)日:1999-01-12

    申请号:US697877

    申请日:1996-08-30

    IPC分类号: G03G9/093 G03G9/097

    CPC分类号: G03G9/09385 G03G9/09708

    摘要: A toner for developing an electrostatic image is constituted by toner particles containing at least a binder resin and a colorant, and particles containing at least one double oxide. The double oxide includes a double oxide (A) represented by the following formula (1):M.sub.a Si.sub.b O.sub.c (1),wherein M denotes a metallic element selected from the group consisting of Sr, Mg, Zn, Co, Mn and Ce; a is an integer of 1-9; b is an integer of 1-9; and c is an integer of 3-9. The above particles including a double oxide (A) are effective in improving flowability and triboelectric chargeability of the toner and providing a resultant image with excellent image qualities.

    摘要翻译: 用于显影静电图像的调色剂由至少含有粘合剂树脂和着色剂的调色剂颗粒以及含有至少一种双氧化物的颗粒构成。 双氧化物包括由下式(1)表示的双氧化物(A):MaSibOc(1),其中M表示选自Sr,Mg,Zn,Co,Mn和Ce的金属元素; a是1-9的整数; b是1-9的整数; 且c为3-9的整数。 包括双氧化物(A)的上述颗粒在改善调色剂的流动性和摩擦带电性方面是有效的,并提供具有优异图像质量的所得图像。

    Toner for developing electrostatic image, image forming method and
process-cartridge
    5.
    发明授权
    Toner for developing electrostatic image, image forming method and process-cartridge 失效
    用于显影静电图像,成像方法和处理盒的调色剂

    公开(公告)号:US5695902A

    公开(公告)日:1997-12-09

    申请号:US749635

    申请日:1996-11-15

    IPC分类号: G03G9/097 G03G13/22

    CPC分类号: G03G9/09716 G03G9/09708

    摘要: A toner for developing an electrostatic image is formed as a mixture of toner particles containing at least a binder resin and a colorant, and inorganic fine powder. The inorganic fine powder includes: (A) inorganic fine powder (A) treated at least with silicone oil, and (B) inorganic fine powder (B) comprising a composite metal oxide including at least Si as a constituent element and having a weight-average particle size of 0.3-5 .mu.m. Because of the inclusion of the two types of inorganic fine powders (A) and (B), the toner is stably provided with a high flowability and a high triboelectric charge under various environmental conditions including low-humidity to high-humidity conditions. The toner is suitably used in an image forming system including a contact-charging means, a contact-transfer means and a film (or surf)-fixing system.

    摘要翻译: 作为静电图像显影用调色剂形成为至少含有粘合剂树脂和着色剂的调色剂颗粒和无机细粉末的混合物。 无机细粉末包括:(A)至少用硅油处理的无机细粉末(A)和(B)无机细粉末(B),其包含至少包含Si作为构成元素的复合金属氧化物, 平均粒径0.3-5μm。 由于包含两种类型的无机细粉(A)和(B),调色剂在包括低湿度至高湿条件的各种环境条件下稳定地具有高流动性和高摩擦电荷。 调色剂适用于包括接触充电装置,接触转移装置和膜(或冲洗) - 混合系统的图像形成系统。