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    Toner for developing electrostatic image
    1.
    发明授权
    Toner for developing electrostatic image 失效
    用于显影静电图像的调色剂

    公开(公告)号：US06623901B1

    公开(公告)日：2003-09-23

    申请号：US08992427

    申请日：1997-12-18

    申请人： Takaaki Kohtaki ,  Makoto Unno ,  Yushi Mikuriya ,  Tadashi Doujo

    发明人： Takaaki Kohtaki ,  Makoto Unno ,  Yushi Mikuriya ,  Tadashi Doujo

    IPC分类号： G03G9083

    CPC分类号： G03G9/08795 ,  G03G9/08755 ,  G03G9/09733

    摘要： A toner for developing an electrostatic image is constituted by a binder resin and a long-chain compound. The binder resin is a polyester resin or vinyl resin respectively having an acid value of preferably 25-70 mgKOH/g. The long-chain compound is a long-chain alkyl alcohol having an OH value of 10-120 mgKOH/g or a long-chain alkyl carboxylic acid having an acid value of 5-120 mgKOH/g and is contained so as to satisfy a condition of the following formula (1) or formula (2): Formula (1) acid value of binder resin +OH value of long-chain alkyl alcohol >(¼)×OH value of binder resin, or Formula (2) acid value of binder resin +acid value of long-chain alkyl carboxylic acid >(¼)×OH value of binder resin. The toner is characterized by a good balance between fixing performances and developing performances suitable for a variety of models of image forming apparatus and in wide ranges of environmental conditions.

    摘要翻译： 用于显影静电图像的调色剂由粘合剂树脂和长链化合物构成。 粘合剂树脂是分别具有优选25-70mgKOH / g的酸值的聚酯树脂或乙烯基树脂。 长链化合物是OH值为10〜120mgKOH / g的长链烷基醇或酸值为5-120mgKOH / g的长链烷基羧酸，其含有以满足 下式（1）或式（2）的条件：式（1）粘合剂树脂的酸值+长链烷基醇的OH值>（¼）粘合剂树脂的xOH值，或式（2）粘合剂的酸值 树脂+长链烷基羧酸的酸值>（¼）xOH值的粘合剂树脂。 调色剂的特征在于适用于多种型号的图像形成装置的定影性能和显影性能之间的良好平衡以及广泛的环境条件。

    Toner for developing electrostatic image
    3.
    发明授权
    Toner for developing electrostatic image 失效
    用于显影静电图像的调色剂

    公开(公告)号：US06783910B2

    公开(公告)日：2004-08-31

    申请号：US10316948

    申请日：2002-12-12

    申请人： Takaaki Kohtaki ,  Makoto Unno ,  Yushi Mikuriya ,  Tadashi Doujo

    发明人： Takaaki Kohtaki ,  Makoto Unno ,  Yushi Mikuriya ,  Tadashi Doujo

    IPC分类号： G03G9087

    CPC分类号： G03G9/08795 ,  G03G9/08755 ,  G03G9/09733

    摘要： A toner for electrostatic imaging has a vinyl resin binder with an acid value of 2.5-70 mgKOH/g and (i) a long-chain alcohol with an OH value of 10-120 mg/KOH/g or (ii) a long-chain alkyl carboxylic acid with an acid value of 5-120 mg/KOH/g, wherein the acid value of the resin binder+either (i) OH value of the alcohol or (ii) acid value of the acid>(¼)×OH value of the binder.

    摘要翻译： 用于静电成像的调色剂具有酸值为2.5-70mgKOH / g的乙烯基树脂粘合剂和（i）OH值为10-120mg / KOH / g的长链醇，或（ii） 链烷酸羧酸，酸值为5-120mg / KOH / g，其中树脂粘合剂的酸值+（i）醇的OH值或（ii）酸的酸值>（¼）xOH 粘合剂的价值。

    Toner for developing electrostatic image
    5.
    发明授权
    Toner for developing electrostatic image 失效
    用于显影静电图像的调色剂

    公开(公告)号：US5660963A

    公开(公告)日：1997-08-26

    申请号：US563290

    申请日：1995-11-28

    申请人： Tadashi Doujo ,  Takaaki Kohtaki ,  Makoto Unno ,  Yushi Mikuriya

    发明人： Tadashi Doujo ,  Takaaki Kohtaki ,  Makoto Unno ,  Yushi Mikuriya

    IPC分类号： G03G9/087 ,  G03G9/097

    CPC分类号： G03G9/08782 ,  G03G9/08755 ,  G03G9/09733

    摘要： A toner for developing an electrostatic image is constituted by a resin composition and a colorant. The resin composition includes a high-softening point polyester resin (I) having a softening point of 120.degree.-180.degree. C. a low-softening point polyester resin (II) having a softening point of 80.degree.-120.degree. C., and a long-chain alkyl compound selected from the group consisting of-a long-chain alkyl alcohol principally comprising long-chain alkyl alcohol components having long-chain alkyl groups of 23 to 252 carbon atoms and a long-chain alkyl carboxylic acid principally comprising long-chain alkyl carboxylic acid components having long-chain alkyl groups of 22 to 251 carbon atoms. The resin composition preferably includes a tetrahydrofuran (THF)-soluble content providing a gel permeation chromatogram showing a weight-average molecular weight (Mw) of at least 10.sup.5, a ratio of Mw to number-average molecular weight (Mn) of at least 35 and an areal percentage of at least 5% of a region of molecular weight of at least 2.times.10.sup.5.

    摘要翻译： 用于显影静电图像的调色剂由树脂组合物和着色剂构成。 树脂组合物包括软化点为120-180℃的高软化点聚酯树脂（I），软化点为80-120℃的低软化点聚酯树脂（II），以及 选自长链烷基醇的长链烷基化合物，其主要包含长链烷基醇组分，其长链烷基为23至252个碳原子，长链烷基羧酸主要包含长链烷基醇 链烷基羧酸组分，其具有22至251个碳原子的长链烷基。 树脂组合物优选包括提供凝胶渗透色谱的四氢呋喃（THF）可溶成分，其显示重均分子量（Mw）至少为105，Mw与数均分子量（Mn）的比例至少为35 并且分子量至少为5×10 5的区域的至少5％的面积百分比。

    Toner for developing electrostatic image containing specified double oxide particles
    6.
    发明授权
    Toner for developing electrostatic image containing specified double oxide particles 失效
    用于显影含有特定双氧化物颗粒的静电图像的调色剂

    公开(公告)号：US5858597A

    公开(公告)日：1999-01-12

    申请号：US697877

    申请日：1996-08-30

    申请人： Yuichi Mizoh ,  Takaaki Kohtaki ,  Yushi Mikuriya ,  Tadashi Doujo

    发明人： Yuichi Mizoh ,  Takaaki Kohtaki ,  Yushi Mikuriya ,  Tadashi Doujo

    IPC分类号： G03G9/093 ,  G03G9/097

    CPC分类号： G03G9/09385 ,  G03G9/09708

    摘要： A toner for developing an electrostatic image is constituted by toner particles containing at least a binder resin and a colorant, and particles containing at least one double oxide. The double oxide includes a double oxide (A) represented by the following formula (1):M.sub.a Si.sub.b O.sub.c (1),wherein M denotes a metallic element selected from the group consisting of Sr, Mg, Zn, Co, Mn and Ce; a is an integer of 1-9; b is an integer of 1-9; and c is an integer of 3-9. The above particles including a double oxide (A) are effective in improving flowability and triboelectric chargeability of the toner and providing a resultant image with excellent image qualities.

    摘要翻译： 用于显影静电图像的调色剂由至少含有粘合剂树脂和着色剂的调色剂颗粒以及含有至少一种双氧化物的颗粒构成。 双氧化物包括由下式（1）表示的双氧化物（A）：MaSibOc（1），其中M表示选自Sr，Mg，Zn，Co，Mn和Ce的金属元素; a是1-9的整数; b是1-9的整数; 且c为3-9的整数。 包括双氧化物（A）的上述颗粒在改善调色剂的流动性和摩擦带电性方面是有效的，并提供具有优异图像质量的所得图像。

    Toner for developing an electrostatic image
    7.
    发明授权
    Toner for developing an electrostatic image 失效
    用于显影静电图像的调色剂

    公开(公告)号：US6017669A

    公开(公告)日：2000-01-25

    申请号：US715433

    申请日：1996-09-18

    申请人： Makoto Unno ,  Takaaki Kotaki ,  Yushi Mikuriya ,  Tadashi Doujo

    发明人： Makoto Unno ,  Takaaki Kotaki ,  Yushi Mikuriya ,  Tadashi Doujo

    IPC分类号： G03G9/087

    CPC分类号： G03G9/08706 ,  G03G9/08711 ,  G03G9/08755 ,  G03G9/08782 ,  G03G9/08795 ,  G03G9/08797

    摘要： The toner for developing an electrostatic image has toner particles containing at least binder resin and colorant. The resin components of a range of 2,000 to 100,000 in molecular weight, prepared by preparatory liquid chromatograph from the binder resin, exhibit an M/S ratio of 200 or greater and are 50% to 90% in abundance. The M and S stand for a weight average molecular weight (M) measured by means of light scattering method and an inertia radius (S) measured by means of light scattering method, respectively.

    摘要翻译： 用于显影静电图像的调色剂具有至少包含粘合剂树脂和着色剂的调色剂颗粒。 通过由粘合剂树脂制备的液相色谱法制备的分子量为2,000至100,000的树脂组分的M / S比为200或更大并且丰度为50％至90％。 M和S分别表示通过光散射法测量的重均分子量（M）和通过光散射法测量的惯性半径（S）。

    Toner for developing electrostatic images
    8.
    发明授权
    Toner for developing electrostatic images 失效
    用于显影静电图像的调色剂

    公开(公告)号：US5773183A

    公开(公告)日：1998-06-30

    申请号：US749640

    申请日：1996-11-15

    申请人： Tadashi Doujo ,  Yuichi Mizoo ,  Takaaki Kotaki ,  Yushi Mikuriya

    发明人： Tadashi Doujo ,  Yuichi Mizoo ,  Takaaki Kotaki ,  Yushi Mikuriya

    IPC分类号： G03G9/083 ,  G03G9/087 ,  G03G9/09

    CPC分类号： G03G9/091 ,  G03G9/08755 ,  G03G9/08795 ,  G03G9/0833 ,  G03G9/08782

    摘要： A toner for developing an electrostatic image has a binder resin, a colorant and a charge control agent. The binder resin has a polyester resin having an acid value of from 15 to 40 and a hydroxyl value of 45 or less. The toner has, in its molecular weight distribution as measured by gel permeation chromatography, tetrahydrofuran-soluble matter having a weight average molecular weight Mw of 100,000 or more, having a ratio of weight average molecular weight Mw to number average molecular weight Mn, Mw/Mn, of not less than 35, containing from 70% to 94% of a low-molecular weight region component having a molecular weight of less than 150,000, containing from 1% to 10% of a medium-molecular weight region component having a molecular weight of from 150,000 to 500,000, and containing from 5% to 25% of a high-molecular weight region component having a molecular weight of more than 500,000. The high-molecular weight region component is more than the medium-molecular weight region component.

    摘要翻译： 用于显影静电图像的调色剂具有粘合剂树脂，着色剂和电荷控制剂。 粘合剂树脂具有酸值为15〜40，羟值为45以下的聚酯树脂。 调色剂在通过凝胶渗透色谱法测定的分子量分布中，具有重均分子量Mw为100,000以上的四氢呋喃可溶性物质，重均分子量Mw与数均分子量Mn的比，Mw / Mn不低于35，含有70％至94％的分子量小于150,000的低分子量成分，含有1％至10％的具有分子量 重量为15万至500,000，并含有5％至25％的分子量大于500,000的高分子量成分。 高分子量区域成分大于中等分子量区域成分。

    Toner for developing electrostatic image, image forming method and process-cartridge
    9.
    发明授权
    Toner for developing electrostatic image, image forming method and process-cartridge 失效
    用于显影静电图像，成像方法和处理盒的调色剂

    公开(公告)号：US5695902A

    公开(公告)日：1997-12-09

    申请号：US749635

    申请日：1996-11-15

    申请人： Yushi Mikuriya ,  Yuichi Mizoh ,  Tadashi Doujo

    发明人： Yushi Mikuriya ,  Yuichi Mizoh ,  Tadashi Doujo

    IPC分类号： G03G9/097 ,  G03G13/22

    CPC分类号： G03G9/09716 ,  G03G9/09708

    摘要： A toner for developing an electrostatic image is formed as a mixture of toner particles containing at least a binder resin and a colorant, and inorganic fine powder. The inorganic fine powder includes: (A) inorganic fine powder (A) treated at least with silicone oil, and (B) inorganic fine powder (B) comprising a composite metal oxide including at least Si as a constituent element and having a weight-average particle size of 0.3-5 .mu.m. Because of the inclusion of the two types of inorganic fine powders (A) and (B), the toner is stably provided with a high flowability and a high triboelectric charge under various environmental conditions including low-humidity to high-humidity conditions. The toner is suitably used in an image forming system including a contact-charging means, a contact-transfer means and a film (or surf)-fixing system.

    摘要翻译： 作为静电图像显影用调色剂形成为至少含有粘合剂树脂和着色剂的调色剂颗粒和无机细粉末的混合物。 无机细粉末包括：（A）至少用硅油处理的无机细粉末（A）和（B）无机细粉末（B），其包含至少包含Si作为构成元素的复合金属氧化物， 平均粒径0.3-5μm。 由于包含两种类型的无机细粉（A）和（B），调色剂在包括低湿度至高湿条件的各种环境条件下稳定地具有高流动性和高摩擦电荷。 调色剂适用于包括接触充电装置，接触转移装置和膜（或冲洗） - 混合系统的图像形成系统。