公开(公告)号：US07323282B2

公开(公告)日：2008-01-29

申请号：US11758466

申请日：2007-06-05

申请人： Manabu Ohno ,  Motoya Fukushima ,  Hitoshi Itabashi ,  Yasushi Katsuta ,  Emi Tosaka ,  Norikazu Fujimoto

发明人： Manabu Ohno ,  Motoya Fukushima ,  Hitoshi Itabashi ,  Yasushi Katsuta ,  Emi Tosaka ,  Norikazu Fujimoto

IPC分类号： G03G15/20

CPC分类号： G03G9/0918 ,  G03G9/0819 ,  G03G9/0821 ,  G03G9/0827 ,  G03G9/08726

摘要： The toner having a significantly improved dispersibility of a colorant in toner particles is provided. The present invention provides a dry toner comprising: (i) a binder resin; (ii) a colorant; (iii) at least one of metallophthalocyanine and a metallophthalocyanine derivative having a central metal selected from the group consisting of Cr, Fe, Co, Ni, Zn, Mn, Mg, and Al; and (iv) a polymer containing 0.5 to 20% by mass of a base unit derived from a specific polymerizable monomer having an amide group.

摘要翻译： 提供具有明显改善着色剂在调色剂颗粒中的分散性的调色剂。 本发明提供一种干燥调色剂，其包含：（i）粘合剂树脂; （ii）着色剂; （iii）金属酞菁和金属酞菁衍生物中的至少一种，具有选自Cr，Fe，Co，Ni，Zn，Mn，Mg和Al的中心金属; 和（iv）含有0.5〜20质量％的衍生自具有酰胺基的特定聚合性单体的碱单元的聚合物。

公开(公告)号：US06806016B2

公开(公告)日：2004-10-19

申请号：US10352963

申请日：2003-01-29

申请人： Manabu Ohno ,  Satoshi Yoshida ,  Satoshi Handa ,  Akira Hashimoto ,  Keiji Komoto

发明人： Manabu Ohno ,  Satoshi Yoshida ,  Satoshi Handa ,  Akira Hashimoto ,  Keiji Komoto

IPC分类号： G03G1308

CPC分类号： G03G9/0819 ,  G03G9/0827 ,  G03G9/08782

摘要： A toner suitable for use in electrophotography, etc., is composed of toner particles each containing a binder resin, a colorant and a wax component. The toner has a number-average particle size of 2-6 &mgr;m and a standard deviation in particle size of below 2.6 &mgr;m based on a number-basis distribution of circle-equivalent diameters, an average circularity of 0.970-0.995 and a standard deviation in circularity of below 0.030 based on a circularity frequency distribution, and a residual monomer content of at most 500 ppm. The toner particles have such a microtexture as to provide a particle cross section as observed through a transmission electron microscope (TEM) exhibiting a matrix of the binder resin and a particle of the wax dispersed in a discrete form in the matrix of the binder resin.

摘要翻译： 适用于电子照相术等的调色剂由各自含有粘合剂树脂，着色剂和蜡组分的调色剂颗粒组成。 调色剂的数均粒径为2-6μm，粒径小于2.6μm的标准偏差基于圆当量直径的数均分布，平均圆形度为0.970-0.995，标准偏差为 圆形度低于0.030，基于圆形度频率分布，残留单体含量为500ppm以下。 调色剂颗粒具有这样的微观结构，以提供通过透射电子显微镜（TEM）观察到的颗粒横截面，该透射电子显微镜（TEM）显示粘合剂树脂的基体和以分散形式分散在粘合剂树脂的基体中的蜡的颗粒。

公开(公告)号：US06667140B2

公开(公告)日：2003-12-23

申请号：US09942570

申请日：2001-08-31

申请人： Emi Tosaka ,  Motoya Fukushima ,  Manabu Ohno ,  Yasushi Katsuta

发明人： Emi Tosaka ,  Motoya Fukushima ,  Manabu Ohno ,  Yasushi Katsuta

IPC分类号： G03G909

CPC分类号： G03G5/0638 ,  G03G5/0609 ,  G03G5/0612 ,  G03G5/0618 ,  G03G5/0653 ,  G03G9/08782 ,  G03G9/091

摘要： A color toner (magenta toner) showing not only color image forming performances such as color reproducibility, gradation characteristic, light-fastness, full-color image forming characteristic and a chargeability but also excellent in matching with various members of an electrophotographic apparatus is produced from a binder resin, a wax component and a specific monoazo pigment composition. The monoazo pigment composition is characterized by a principal monoazo pigment of a specific structure and specified amounts of a &bgr;-naphthol derivative and an aromatic amine, usable as materials for synthesizing the monoazo pigment.

公开(公告)号：US06346356B1

公开(公告)日：2002-02-12

申请号：US09572642

申请日：2000-05-17

申请人： Manabu Ohno ,  Toshiyuki Ugai ,  Ryoichi Fujita ,  Shinya Yachi ,  Yasushi Katsuta ,  Kenichi Nakayama

发明人： Manabu Ohno ,  Toshiyuki Ugai ,  Ryoichi Fujita ,  Shinya Yachi ,  Yasushi Katsuta ,  Kenichi Nakayama

IPC分类号： G03G9097

CPC分类号： G03G9/09733 ,  G03G9/0806 ,  G03G9/0821 ,  G03G9/0825 ,  G03G9/0827 ,  G03G9/097

摘要： A toner is comprised of toner particles containing at least a binder resin, a colorant, a wax component and an oxycarboxylic acid. The toner satisfies the following conditions: 1.05≦A/B≦3.00, and 0.15≦B≦3.50 wherein A (mg) is a weight of oxycarboxylic acid extracted with methanol from 1 g of the toner, and B (mg) is a weight of oxycarboxylic acid extracted with an aqueous 0.1 mol/liter sodium hydroxide solution from 1 g of the toner.

摘要翻译： 调色剂由至少含有粘合剂树脂，着色剂，蜡组分和羟基羧酸的调色剂颗粒构成。 调色剂满足以下条件：A（mg）是由1g调色剂用甲醇提取的羟基羧酸的重量，B（mg）是用0.1mol / l氢氧化钠水溶液提取的羟基羧酸的重量 从1克调色剂。

公开(公告)号：US06337169B1

公开(公告)日：2002-01-08

申请号：US09606172

申请日：2000-06-29

申请人： Akira Hashimoto ,  Satoshi Yoshida ,  Manabu Ohno ,  Yasukazu Ayaki ,  Satoshi Handa ,  Keiji Komoto

发明人： Akira Hashimoto ,  Satoshi Yoshida ,  Manabu Ohno ,  Yasukazu Ayaki ,  Satoshi Handa ,  Keiji Komoto

IPC分类号： G03G1316

CPC分类号： G03G9/0821 ,  G03G9/0825 ,  G03G9/0827 ,  G03G9/087 ,  G03G9/08782

摘要： A toner suitable for use in electrophotography, etc., is composed of toner particles each containing a binder resin, a colorant and a wax component. Each toner particle has such a microtexture as to provide a cross section as observed through a transmission electron microscope (TEM) exhibiting a matrix of the binder resin, a particle of the wax enclosed with the matrix; and the binder resin dispersed in a particulate form in the wax particle, and the toner particles have a residual monomer content of at most 500 ppm by weight of the toner particles. The colorant may also be dispersed in the wax particle enclosed within the matrix of the binder resin.

摘要翻译： 适用于电子照相术等的调色剂由各自含有粘合剂树脂，着色剂和蜡组分的调色剂颗粒组成。 每个调色剂颗粒具有这样的微观结构，以提供通过透射电子显微镜（TEM）观察到的横截面，该透射电子显微镜（TEM）显示粘合剂树脂的基体，由基体包围的蜡的颗粒; 和以颗粒形式分散在蜡颗粒中的粘合剂树脂，调色剂颗粒的残留单体含量为调色剂颗粒重量的至多500ppm。 着色剂也可以分散在封闭在粘合剂树脂的基体内的蜡颗粒中。

公开(公告)号：US06177223B1

公开(公告)日：2001-01-23

申请号：US09221140

申请日：1998-12-28

申请人： Akira Hashimoto ,  Satoshi Yoshida ,  Manabu Ohno ,  Yasukazu Ayaki ,  Satoshi Handa ,  Keiji Komoto

发明人： Akira Hashimoto ,  Satoshi Yoshida ,  Manabu Ohno ,  Yasukazu Ayaki ,  Satoshi Handa ,  Keiji Komoto

IPC分类号： G03G1316

CPC分类号： G03G9/0821 ,  G03G9/0825 ,  G03G9/0827 ,  G03G9/087 ,  G03G9/08782

摘要： A toner suitable for use in electrophotography, etc., is composed of toner particles each containing a binder resin, a colorant and a wax component. Each toner particle has such a microtexture as to provide a cross section as observed through a transmission electron microscope (TEM) exhibiting a matrix of the binder resin, a particle of the wax enclosed with the matrix; and the binder resin dispersed in a particulate form in the wax particle, and the toner particles have a residual monomer content of at most 500 ppm by weight of the toner particles. The colorant may also be dispersed in the wax particle enclosed within the matrix of the binder resin.

摘要翻译： 适用于电子照相术等的调色剂由各自含有粘合剂树脂，着色剂和蜡组分的调色剂颗粒组成。 每个调色剂颗粒具有这样的微观结构，以提供通过透射电子显微镜（TEM）观察到的横截面，该透射电子显微镜（TEM）显示粘合剂树脂的基体，由基体包围的蜡的颗粒; 和以颗粒形式分散在蜡颗粒中的粘合剂树脂，调色剂颗粒的残留单体含量为调色剂颗粒重量的至多500ppm。 着色剂也可以分散在封闭在粘合剂树脂的基体内的蜡颗粒中。

公开(公告)号：US5962176A

公开(公告)日：1999-10-05

申请号：US791350

申请日：1997-01-30

申请人： Manabu Ohno ,  Yukari Ishibashi ,  Nobuyuki Okubo ,  Shunji Suzuki

发明人： Manabu Ohno ,  Yukari Ishibashi ,  Nobuyuki Okubo ,  Shunji Suzuki

IPC分类号： G03G9/087

CPC分类号： G03G9/08711 ,  G03G9/08702 ,  G03G9/08791

摘要： A toner for developing an electrostatic image is constituted by a composition containing a binder resin component and a coloring agent, wherein the binder resin component contains a low-molecular weight component having a molecular weight of at most 5.times.10.sup.4 and a branching index g' of below 1. The low-molecular weight polymer component is preferably obtained by polymerizing a second monomer in mixture with a prepolymer in the presence of a polymerization initiator comprising a peroxide having a functional group of: ##STR1## and mixed with a high-molecular weight polymer component obtained by polymerization in the presence of a poly-functional polymerization initiator, and a low-molecular weight wax. The resultant toner is characterized by a good balance between the fixability and anti-offset characteristic.

摘要翻译： 用于显影静电图像的调色剂由含有粘合剂树脂组分和着色剂的组合物构成，其中粘合剂树脂组分含有分子量至多为5×10 4的低分子量组分和支链指数g'低于 低分子量聚合物组分优选通过在包含具有官能团的过氧化物的聚合引发剂存在下与预聚物聚合来获得，并与由高分子量聚合物组分获得的高分子量聚合物组分 在多官能聚合引发剂和低分子量蜡存在下进行聚合。 所得到的调色剂的特征在于定影性和抗偏移特性之间的良好平衡。

公开(公告)号：US5830612A

公开(公告)日：1998-11-03

申请号：US711935

申请日：1996-09-11

申请人： Akio Yamada ,  Satoru Sagou ,  Hitoshi Watanabe ,  Satoru Yamazaki ,  Kiichi Sakamoto ,  Manabu Ohno ,  Kenichi Kawakami ,  Katsuhiko Kobayashi

发明人： Akio Yamada ,  Satoru Sagou ,  Hitoshi Watanabe ,  Satoru Yamazaki ,  Kiichi Sakamoto ,  Manabu Ohno ,  Kenichi Kawakami ,  Katsuhiko Kobayashi

IPC分类号： G03F1/00 ,  G03F1/20 ,  H01J37/304 ,  H01J37/317 ,  G03F9/00 ,  G03C5/00

CPC分类号： B82Y10/00 ,  B82Y40/00 ,  G03F1/86 ,  H01J37/3045 ,  H01J37/3174 ,  G03F1/20 ,  H01J2237/2817 ,  H01J2237/31794

摘要： A method of detecting deficiency of an aperture used in a charged-particle-beam exposure process employing at least two exposure columns is disclosed, where each of the two exposure columns passes a charged-particle beam through the aperture formed through a mask to shape a cross section of the charged-particle beam before exposing the charged-particle beam onto an object. The method includes the steps of mounting masks having the same aperture to the at least two exposure columns; scanning, in each of the at least two exposure columns, the charged-particle beam over an area containing a mark on a surface substantially at the same height as the object after passing the charged-particle beam through the same aperture; obtaining, in each of the at least two exposure columns, a signal waveform corresponding to the scan by detecting charged particles scattered by the mark; and comparing the signal waveform between the at least two exposure columns.

摘要翻译： 公开了一种检测在使用至少两个曝光柱的带电粒子束曝光工艺中使用的孔的缺陷的方法，其中两个曝光柱中的每一个通过带电粒子束穿过通过掩模形成的孔以形成 在将带电粒子束暴露在物体上之前的带电粒子束的横截面。 该方法包括以下步骤：将具有相同孔径的掩模安装到至少两个曝光柱; 在所述至少两个曝光柱中的每一个中，在将带电粒子束通过相同的孔之后，将包含在与物体基本上处于相同高度的表面上的标记的区域上的带电粒子束扫描; 在所述至少两个曝光列中的每一个中，通过检测由所述标记散射的带电粒子来获得对应于所述扫描的信号波形; 以及比较所述至少两个曝光列之间的信号波形。

公开(公告)号：US5744276A

公开(公告)日：1998-04-28

申请号：US220044

申请日：1994-03-30

申请人： Manabu Ohno ,  Hiroyuki Suematsu ,  Akihiko Nakazawa ,  Nobuyuki Okubo ,  Shunji Suzuki

发明人： Manabu Ohno ,  Hiroyuki Suematsu ,  Akihiko Nakazawa ,  Nobuyuki Okubo ,  Shunji Suzuki

IPC分类号： G03G9/08 ,  G03G9/087 ,  G03G9/09 ,  G03G9/097 ,  G03G13/20

CPC分类号： G03G9/09783 ,  G03G13/20 ,  G03G9/0821 ,  G03G9/08711 ,  G03G9/08791 ,  G03G9/08793 ,  G03G9/08795 ,  G03G9/091 ,  G03G2215/021 ,  G03G2221/183

摘要： An electrophotographic toner composition suitable for heat-fixation and showing good storage characteristics is constituted by polymer components, a colorant and a metal-containing organic compound. The toner composition shows a melt index (at 125.degree. C., 10 kg-load) of 5-25 g/10 min., and the polymer components are characterized by (a) containing substantially no THF (tetrahydrofuran)-insoluble content, (b) including a THF-soluble content thereof providing a GPC (gel permeation chromatography) chromatogram showing i) a main peak in a molecular weight region of 2.times.10.sup.3 -3.times.10.sup.4, and a sub-peak or shoulder in a molecular weight region of at least 10.sup.5, and ii) an areal percentage of 3-10% in a molecular weight region of at least 10.sup.6, and (c) including a polymer component (H) in a molecular weight region of at least 10.sup.5 obtained by polymerization using a polyfunctional polymerization initiator and a monofunctional polymerization initiator.

摘要翻译： 适合于热定影和显示良好储存特性的电子照相调色剂组合物由聚合物组分，着色剂和含金属的有机化合物构成。 调色剂组合物显示5-25g / 10min的熔融指数（125℃，10kg负载），聚合物组分的特征在于（a）基本上不含THF（四氢呋喃） - 不溶物含量， （b）包括其可溶于THF的含量，提供GPC（凝胶渗透色谱）色谱图，其显示i）分子量区域中的主峰为2×103-3×104，以及至少分子量区域中的亚峰或肩峰 105，和ii）分子量区域中至少为106的3-10％的面积百分比，和（c）包括通过使用多官能聚合的聚合获得的至少105的分子量区域中的聚合物组分（H） 引发剂和单官能聚合引发剂。

公开(公告)号：US5605778A

公开(公告)日：1997-02-25

申请号：US627112

申请日：1996-04-03

申请人： Tsutomu Onuma ,  Satoshi Matsunaga ,  Manabu Ohno ,  Minoru Shimojo

发明人： Tsutomu Onuma ,  Satoshi Matsunaga ,  Manabu Ohno ,  Minoru Shimojo

IPC分类号： G03G9/087 ,  G03G9/097

CPC分类号： G03G9/08782 ,  G03G9/08797

摘要： A toner for developing electrostatic images is prepared from a binder resin, a colorant or magnetic material, and a wax component. The toner is provided with improved low-temperature fixability anti-electrostatic offset characteristic, anti-blocking characteristic and anti-offset characteristic by controlling the thermal characteristic of the wax component so as to provide a DSC (differential scanning colorimeter) curve on temperature increase, showing a minimum onset temperature of heat absorption of at least 50.degree. C. and at least two heat absorption peaks including a largest and a second largest peaks, different from each other in peak temperature by at least 15.degree. C., wherein low-temperature heat absorption peak P.sub.1 of the two peaks shows a half-value width of at most 20.degree. C. and a higher-temperature heat absorption peak P.sub.2 shows a half-value width of at most 20.degree. C., and wherein the peak P.sub.1 shows a higher half-width temperature and the peak P.sub.2 shows a lower half-width temperature different form the higher half-width temperature of the peak P.sub.1 by at least 5.degree. C.

摘要翻译： 用于静电图像显影的调色剂由粘合剂树脂，着色剂或磁性材料和蜡组分制备。 通过控制蜡组分的热特性，调色剂具有改进的低温定影性抗静电偏移特性，抗粘连特性和防偏移特性，从而提供升温时的DSC（差示扫描色度计）曲线， 显示出至少50℃的最小起始吸热温度和至少两个包括最大和第二最大峰的吸热峰，峰值温度彼此不同，至少15℃，其中低温 两个峰的吸热峰P1表现出至多20℃的半值宽度，较高温度的吸收峰P2显示​​出最多20℃的半值宽度，其中峰P1显示 较高的半峰宽温度，峰P2表示峰值P1的较高半峰宽温度至少5℃不同的较低半宽度温度。