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公开(公告)号：US20050113541A1
公开(公告)日：2005-05-26
申请号：US10970005
申请日：2004-10-22
申请人： Takahiro Tsumori , Daisuke Hattori , Akihiko Kanzaki , Yoshikazu Fujii , Shigeru Yamaguchi , Hiroshi Yamazaki , Tsuyoshi Hirata
发明人： Takahiro Tsumori , Daisuke Hattori , Akihiko Kanzaki , Yoshikazu Fujii , Shigeru Yamaguchi , Hiroshi Yamazaki , Tsuyoshi Hirata
IPC分类号： C04B24/00 , C04B24/12 , C04B24/26 , C08F283/06 , C08F290/06 , C08G65/00 , C11D3/37 , C08L51/00
CPC分类号： C11D3/3788 , C04B24/2647 , C04B24/2658 , C04B2103/408 , C08F283/06 , C08F290/062
摘要： An object of the present invention is to provide a polymer which is suitable as a detergent builder in that it exerts an excellent detergency and it has no adverse effect on the environment, and is suitable as a cement admixture in that it is excellent in cement dispersibility, and workability is better. As a means of achieving this object, a polymer of the present invention is: a polymer obtained by a polymerization reaction using a polyaminepolyether compound, an unsaturated carboxylic monomer and polyalkylene glycols as a raw material, characterized in that an amount of a polyaminepolyether compound is 50% by weight or larger relative to a total amount of a polyaminepolyether compound and polyalkylene glycols; or a polymer obtained by a polymerization reaction using a polyaminepolyether compound and an unsaturated carboxylic monomer as a raw material, characterized in that an amount of an unsaturated carboxylic monomer is less than 15% by weight relative to a total amount of a polyaminepolyether compound and an unsaturated carboxylic monomer, or an unsaturated carboxylic monomer contains acrylic acid as an essential component, and an amount of remaining acrylic acid after the reaction is less than 3% by weight.
摘要翻译： 本发明的目的是提供一种适合作为洗涤剂助洗剂的聚合物，因为其具有优异的去污力，并且对环境没有不利影响，并且适合作为水泥混合物，因为它具有优异的水泥分散性 ，可操作性更好。 作为实现该目的的手段，本发明的聚合物是：使用聚氨基多醚化合物，不饱和羧酸单体和聚亚烷基二醇作为原料的聚合反应得到的聚合物，其特征在于，聚氨基聚醚化合物的量为 相对于聚氨基聚醚化合物和聚亚烷基二醇的总量为50重量％以上; 或通过使用聚氨基聚醚化合物和不饱和羧酸单体作为原料的聚合反应获得的聚合物，其特征在于，不饱和羧酸单体的量相对于聚氨基聚醚化合物的总量小于15重量％ 不饱和羧酸单体或不饱和羧酸单体含有丙烯酸为必须成分，反应后剩余的丙烯酸含量少于3重量％。
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2.发明申请Water-soluble amphoteric copolymer, production method thereof, and application thereof 有权水溶性两性共聚物及其制备方法及其应用公开(公告)号：US20070021313A1
公开(公告)日：2007-01-25
申请号：US11481965
申请日：2006-07-07
IPC分类号： C11D3/02
CPC分类号： C08L33/14 , C08L33/24 , C11D3/3723 , C08L2666/04
摘要： To provide: a water-soluble amphoteric copolymer having excellent hydrophilicity and high adsorption capability, and capable of exhibiting dramatically excellent dispersibility even under high hardness conditions and being preferably used in a detergent composition application, for example; an application thereof; and a production method of such a water-soluble amphoteric copolymer. A water-soluble amphoteric copolymer produced by a copolymerization of a monomer component comprising a cationic monomer (a), an anionic monomer (b), and an unsaturated polyalkylene glycol monomer (c), wherein the monomer (b) is a carboxyl group-containing monomer and/or a sulfonic acid group-containing monomer (d), and the monomer (b) is more than 50% by mole relative to 100% by mole of a total amount of the monomers (a), (b), and (c) if the monomer (b) consists of the carboxyl-group containing monomer, and at least one species of monomer among the monomers (a), (d), and (c) is 30% by mole or less relative to 100% by mole of a total amount of the monomers (a), (d), and (c) if the monomer (b) comprises the sulfonic acid group-containing monomer (d).
摘要翻译： 提供：具有优异的亲水性和高吸附能力的水溶性两性共聚物，即使在高硬度条件下也能显示出显着优异的分散性，并且优选用于洗涤剂组合物应用中; 其应用; 以及这种水溶性两性共聚物的制造方法。 通过使包含阳离子单体（a），阴离子单体（b）和不饱和聚亚烷基二醇单体（c）的单体组分共聚制备的水溶性两性共聚物，其中单体（b）是羧基 - 含有单体和/或含磺酸基的单体（d），单体（b）相对于单体（a），（b），（b）的总量相对于100摩尔％大于50摩尔％ （c）如果单体（b）由含羧基的单体组成，并且单体（a），（d）和（c）中的至少一种单体相对于 如果单体（b）包含含磺酸基的单体（d），则单体（a），（d）和（c）的总量为100摩尔％。
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3.发明授权Water-soluble amphoteric copolymer, production method thereof, and application thereof 有权水溶性两性共聚物及其制备方法及其应用公开(公告)号：US07723283B2
公开(公告)日：2010-05-25
申请号：US11481965
申请日：2006-07-07
CPC分类号： C08L33/14 , C08L33/24 , C11D3/3723 , C08L2666/04
摘要： To provide: a water-soluble amphoteric copolymer having excellent hydrophilicity and high adsorption capability, and capable of exhibiting dramatically excellent dispersibility even under high hardness conditions and being preferably used in a detergent composition application, for example; an application thereof; and a production method of such a water-soluble amphoteric copolymer. A water-soluble amphoteric copolymer produced by a copolymerization of a monomer component comprising a cationic monomer (a), an anionic monomer (b), and an unsaturated polyalkylene glycol monomer (c), wherein the monomer (b) is a carboxyl group-containing monomer and/or a sulfonic acid group-containing monomer (d), and the monomer (b) is more than 50% by mole relative to 100% by mole of a total amount of the monomers (a), (b), and (c) if the monomer (b) consists of the carboxyl-group containing monomer, and at least one species of monomer among the monomers (a), (d), and (c) is 30% by mole or less relative to 100% by mole of a total amount of the monomers (a), (d), and (c) if the monomer (b) comprises the sulfonic acid group-containing monomer (d).
摘要翻译： 提供：具有优异的亲水性和高吸附能力的水溶性两性共聚物，即使在高硬度条件下也能显示出显着优异的分散性，并且优选用于洗涤剂组合物应用中; 其应用; 以及这种水溶性两性共聚物的制造方法。 通过使包含阳离子单体（a），阴离子单体（b）和不饱和聚亚烷基二醇单体（c）的单体组分共聚制备的水溶性两性共聚物，其中单体（b）是羧基 - 含有单体和/或含磺酸基的单体（d），单体（b）相对于单体（a），（b），（b）的总量相对于100摩尔％大于50摩尔％ （c）如果单体（b）由含羧基的单体组成，并且单体（a），（d）和（c）中的至少一种单体相对于 如果单体（b）包含含磺酸基的单体（d），则单体（a），（d）和（c）的总量为100摩尔％。
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4.发明授权(Meth) acrylic acid type polymer and unsaturated polyalkylene glycol type copolymer, and methods for production thereof 有权（甲基）丙烯酸型聚合物和不饱和聚亚烷基二醇型共聚物及其制备方法公开(公告)号：US07132487B2
公开(公告)日：2006-11-07
申请号：US11216772
申请日：2005-08-31
IPC分类号： C08F2/00
CPC分类号： C08F20/06 , C08F290/062
摘要： This invention concerns a (meth)acrylic acid type polymer, wherein the value S representing the quantity of an sulfur element introduced which is defined by the formula, S=(quantity of S contained in polymer)/(total quantity of S)×100, is not less than 35. This (meth) acrylic acid type polymer is a water-soluble polymer of a low molecular weight which has only a small impurity content, entails no precipitation of an impurity during the preservation at a low temperature, and excels in dispersibility, chelating ability, and an anti-gelling property.
摘要翻译： 本发明涉及一种（甲基）丙烯酸型聚合物，其中代表由式S =（聚合物中所含的S的量）/（S的总量）×100所定义的引入的硫元素的量的值S， 不小于35.这种（甲基）丙烯酸类聚合物是低分子量的水溶性聚合物，其杂质含量小，在低温保存期间不会产生杂质沉淀，并且在 分散性，螯合能力和抗胶凝性。
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公开(公告)号：US20060004162A1
公开(公告)日：2006-01-05
申请号：US11216772
申请日：2005-08-31
IPC分类号： C08F2/00
CPC分类号： C08F20/06 , C08F290/062
摘要： This invention concerns a (meth)acrylic acid type polymer, wherein the value S representing the quantity of an sulfur element introduced which is defined by the formula, S=(quantity of S contained in polymer)/(total quantity of S)×100, is not less than 35. This (meth) acrylic acid type polymer is a water-soluble polymer of a low molecular weight which has only a small impurity content, entails no precipitation of an impurity during the preservation at a low temperature, and excels in dispersibility, chelating ability, and an anti-gelling property.
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6.发明授权(Meth)acrylic acid type polymer and unsaturated polyalkylene glycol type copolymer, and methods for production thereof 失效（甲基）丙烯酸型聚合物和不饱和聚亚烷基二醇型共聚物及其制备方法公开(公告)号：US07285611B2
公开(公告)日：2007-10-23
申请号：US11518654
申请日：2006-09-11
IPC分类号： C08F2/00
CPC分类号： C08F20/06 , C08F290/062
摘要： This invention concerns a (meth)acrylic acid type polymer, wherein the value S representing the quantity of an sulfur element introduced which is defined by the formula, S=(quantity of S contained in polymer)/(total quantity of S)×100, is not less than 35. This (meth)acrylic acid type polymer is a water-soluble polymer of a low molecular weight which has only a small impurity content, entails no precipitation of an impurity during the preservation at a low temperature, and excels in dispersibility, chelating ability, and an anti-gelling property.
摘要翻译： 本发明涉及一种（甲基）丙烯酸型聚合物，其中代表由式S =（聚合物中所含的S的量）/（S的总量）×100所定义的引入的硫元素的量的值S， 不小于35.这种（甲基）丙烯酸类聚合物是低分子量的水溶性聚合物，其杂质含量小，在低温保存期间不会产生杂质沉淀，并且在 分散性，螯合能力和抗胶凝性。
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公开(公告)号：US07160849B2
公开(公告)日：2007-01-09
申请号：US10414291
申请日：2003-04-16
CPC分类号： C11D3/378 , C11D1/143 , C11D1/146 , C11D1/22 , C11D1/29 , C11D1/72 , C11D3/3757 , C11D3/3788
摘要： A detergent composition containing at least 0.1% by weight of at least one polymer selected from the group consisting of 1) a polycarboxylic acid-based polymer containing a polyalkylene glycol chain in the structure thereof, 2) a sulfonic acid group-terminated (meth)acrylic acid-based polymer, and 3) an acrylic acid (salt)-maleic acid (salt)-based copolymer having a clay dispersibility under a condition of 50 ppm of calcium carbonate of 0.3 or more; and at least 0.5% by weight of a longer alkyl chain mid-chain branched surfactant compound. The detergent composition can enhance anti-gelling properties to calcium ions, improve the dispersibility to solid particles at low temperatures or under high-hardness conditions, and improve detergency against stains such as mud and carbon black.
摘要翻译： 含有至少0.1重量％的至少一种选自以下的聚合物的洗涤剂组合物：1）在其结构中含有聚亚烷基二醇链的聚羧酸基聚合物，2）磺酸基封端的（甲基） 丙烯酸类聚合物，和3）在50ppm碳酸钙为0.3以上的条件下具有粘土分散性的丙烯酸（盐）马来酸（盐）基共聚物; 和至少0.5重量％的较长的烷基链中链支化表面活性剂化合物。 洗涤剂组合物可以增强对钙离子的抗胶凝性能，提高在低温或高硬度条件下对固体颗粒的分散性，并且改善对污渍（如泥浆和炭黑）的污渍的去污力。
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8.发明申请(Meth) acrylic acid type polymer and unsaturated polyalkylene glycol type copolymer, and methods for production thereof 失效（甲基）丙烯酸型聚合物和不饱和聚亚烷基二醇型共聚物及其制备方法公开(公告)号：US20070004885A1
公开(公告)日：2007-01-04
申请号：US11518654
申请日：2006-09-11
IPC分类号： C08F4/00
CPC分类号： C08F20/06 , C08F290/062
摘要： This invention concerns a (meth)acrylic acid type polymer, wherein the value S representing the quantity of an sulfur element introduced which is defined by the formula, S=(quantity of S contained in polymer)/(total quantity of S)×100, is not less than 35. This (meth)acrylic acid type polymer is a water-soluble polymer of a low molecular weight which has only a small impurity content, entails no precipitation of an impurity during the preservation at a low temperature, and excels in dispersibility, chelating ability, and an anti-gelling property.
摘要翻译： 本发明涉及一种（甲基）丙烯酸型聚合物，其中代表由式S =（聚合物中所含的S的量）/（S的总量）×100所定义的引入的硫元素的量的值S， 不小于35.这种（甲基）丙烯酸类聚合物是低分子量的水溶性聚合物，其杂质含量小，在低温保存期间不会产生杂质沉淀，并且在 分散性，螯合能力和抗胶凝性。
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9.发明授权(Meth)acrylic acid type polymer and unsaturated polyalkylene glycol type copolymer, and methods for production thereof 有权（甲基）丙烯酸型聚合物和不饱和聚亚烷基二醇型共聚物及其制备方法公开(公告)号：US06998453B2
公开(公告)日：2006-02-14
申请号：US10262985
申请日：2002-10-02
IPC分类号： C08F2/00
CPC分类号： C08F20/06 , C08F290/062
摘要： This invention concerns a (meth)acrylic acid type polymer, wherein the value S representing the quantity of an sulfur element introduced which is defined by the formula, S=(quantity of S contained in polymer)/(total quantity of S)×100, is not less than 35. This (meth)acrylic acid type polymer is a water-soluble polymer of a low molecular weight which has only a small impurity content, entails no precipitation of an impurity during the preservation at a low temperature, and excels in dispersibility, chelating ability, and an anti-gelling property.
摘要翻译： 本发明涉及一种（甲基）丙烯酸型聚合物，其中代表由式S =（聚合物中所含的S的量）/（S的总量）×100所定义的引入的硫元素的量的值S， 不小于35.这种（甲基）丙烯酸类聚合物是低分子量的水溶性聚合物，其杂质含量小，在低温保存期间不会产生杂质沉淀，并且在 分散性，螯合能力和抗胶凝性。
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10.发明申请公开(公告)号：US20050215463A1
公开(公告)日：2005-09-29
申请号：US11090211
申请日：2005-03-28
申请人： Akihiko Kanzaki , Yoshikazu Fujii , Akiko Hemmi , Satoshi Yamada , Shuichi Toriya , Shigeru Yamaguchi
发明人： Akihiko Kanzaki , Yoshikazu Fujii , Akiko Hemmi , Satoshi Yamada , Shuichi Toriya , Shigeru Yamaguchi
IPC分类号： C11D3/37 , C08F283/04
CPC分类号： C08F283/04 , C11D3/3757 , C11D3/378
摘要： The present invention provides a detergent and fabric care additive containing a high molecular weight carboxylic acid polymer excellent in solubility in the use of a fabric treatment product such as a detergent and fabric care additive. A detergent and fabric care additive containing a carboxylic acid polymer powder, wherein the carboxylic acid polymer powder satisfies the following conditions (a) and (b) [(a) at least one of conditions that a 0.2% by weight aqueous solution has a viscosity of 10 mPa·s or higher and that a 1% by weight aqueous solution has pH lower than 6 and a 10% by weight aqueous solution has a viscosity of 300 mPa·s or higher and (b) at least one of conditions that 50% by weight or more of the carboxylic acid polymer powder passes through 20 mesh of a sieve according to JIS (Z8801) and that the average particle diameter is 600 μm or smaller]. A detergent and fabric care additive containing a carboxylic acid polymer powder, wherein the carboxylic acid polymer powder satisfies the following conditions (c) and (d) [(c) a 0.2% by weight aqueous solution of the carboxylic acid polymer powder has a viscosity of 10 mPa·s or higher and (d) the carboxylic acid polymer powder contains a carboxyl group and a sulfonic acid group and the ratio of the sulfonic acid group-containing monomer relative to 100% by mole of all monomers comprising the polymer is not less than 0.5% by mole and not more than 90% by mole].
摘要翻译： 本发明提供了一种洗涤剂和织物护理添加剂，其含有在使用织物处理产品如洗涤剂和织物护理添加剂时溶解性优异的高分子量羧酸聚合物。 一种含有羧酸聚合物粉末的洗涤剂和织物保养添加剂，其中羧酸聚合物粉末满足以下条件（a）和（b）[（a）0.2重量％水溶液具有粘度 10mPa.s或更高，并且1重量％的水溶液的pH低于6，10重量％的水溶液的粘度为300mPa.s或更高，（b）至少一个条件为50 羧酸聚合物粉末的重量％以上根据JIS（Z8801）通过20目筛，平均粒径为600μm以下]。 含有羧酸聚合物粉末的洗涤剂和织物保养添加剂，其中羧酸聚合物粉末满足以下条件（c）和（d）[（c）0.2重量％羧酸聚合物粉末水溶液的粘度 （d）羧酸聚合物粉末含有羧基和磺酸基，并且含有磺酸基的单体相对于包含聚合物的所有单体相对于100摩尔％的比例不是 小于0.5摩尔％且不超过90摩尔％]。
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