Thermal recording medium
    1.
    发明授权
    Thermal recording medium 失效
    热敏记录介质

    公开(公告)号:US07081435B2

    公开(公告)日:2006-07-25

    申请号:US10500360

    申请日:2003-01-15

    IPC分类号: B41M5/30

    CPC分类号: B41M5/3336

    摘要: The present invention is the thermally sensitive recording medium comprising a thermally sensitive color developing layer containing colorless or pale colored basic leuco dye and a color developing agent as a main components on a substrate, wherein said thermally sensitive recording layer contains acrylic emulsion and colloidal silica, further contains at least one kind of diphenylsulfone bridgeable compound represented by general formula A as the color developing agent, wherein, X and Y can be different or same and indicates a saturated or an unsaturated liner or grafted hydrocarbon group of carbon number 1–12 which can possess an ether bond, or indicate, wherein, R indicates a methylene group or an ethylene group, T indicates a hydrogen atom or an alkyl group of carbon number 1–4, and R1–R6 independently indicate a halogen-atom, an alkyl group of carbon number 1–6, or an alkenyl group, further, m, n, p, q, r, t indicate an integer number of 0–4 and when are bigger than 2, R1–R6 can be different, and a is an integer of 0–10.

    摘要翻译: 本发明是一种热敏记录介质,其包括含有无色或浅色基础无色染料和彩色显影剂作为主要成分的热敏彩色显影层,其中所述热敏记录层含有丙烯酸乳液和胶体二氧化硅, 还含有至少一种由通式A表示的二苯砜可桥联化合物作为显色剂,其中X和Y可以不同或相同,表示碳数为1-12的饱和或不饱和的内衬或接枝烃基,其中 可以具有醚键,或表示其中,R表示亚甲基或亚乙基,T表示氢原子或碳数为1-4的烷基,R 1 -R < 独立地表示卤素原子,碳数为1-6的烷基或烯基,m,n,p,q,r,t表示0-4的整数 何时是bigg 2以上,R 1〜R 6可以不同,a为0〜10的整数。

    Thermal recording medium
    2.
    发明申请
    Thermal recording medium 失效
    热敏记录介质

    公开(公告)号:US20050043175A1

    公开(公告)日:2005-02-24

    申请号:US10500360

    申请日:2003-01-15

    IPC分类号: B41M5/333 B41M5/337 B41M5/20

    CPC分类号: B41M5/3336

    摘要: The present invention is the thermally sensitive recording medium comprising a thermally sensitive color developing layer containing colorless or pale colored basic leuco dye and a color developing agent as a main components on a substrate, wherein said thermally sensitive recording layer contains acrylic emulsion and colloidal silica, further contains at least one kind of diphenylsulfone bridgeable compound represented by general formula A as the color developing agent, wherein, X and Y can be different or same and indicates a saturated or an unsaturated liner or grafted hydrocarbon group of carbon number 1-12 which can possess an ether bond, or indicate, wherein, R indicates a methylene group or an ethylene group, T indicates a hydrogen atom or an alkyl group of carbon number 1-4, and R1-R6 independently indicate a halogen-atom, an alkyl group of carbon number 1-6, or an alkenyl group, further, m, n, p, q, r, t indicate an integer number of 0-4 and when are bigger than 2, R1-R6 can be different, and a is an integer of 0-10.

    摘要翻译: 本发明是一种热敏记录介质,其包括含有无色或浅色基础无色染料和彩色显影剂作为主要成分的热敏彩色显影层,其中所述热敏记录层含有丙烯酸乳液和胶体二氧化硅, 还含有至少一种由通式A表示的二苯砜可桥联化合物作为显色剂,其中X和Y可以不同或相同,表示碳数为1-12的饱和或不饱和的内衬或接枝烃基,其中 可以具有醚键,或表示其中,R表示亚甲基或亚乙基,T表示氢原子或碳数为1-4的烷基,R1-R6独立地表示卤素原子,烷基 碳数1-6的基团或烯基,m,n,p,q,r,t表示0-4的整数,当大于2时,R 1 -R 6可以b e不同,a是0-10的整数。

    Thermal sensitive recording medium
    5.
    发明授权
    Thermal sensitive recording medium 失效
    热敏记录介质

    公开(公告)号:US5811368A

    公开(公告)日:1998-09-22

    申请号:US759705

    申请日:1996-12-06

    摘要: In a thermal sensitive recording medium comprising a thermal sensitive color developing layer which includes a basic leuco dye and an organic color developer on a substrate, characterized by the said thermal color developing layer includes 0.01-0.9 parts of aminobenzenesulfonamide derivatives indicated by general formula (I) based on 1 part of color developer and also includes at least one kind of methylolated fatty acid amide indicated by general formula (II) in proportion of 0.01-2 parts based on 1 part of color developer. ##STR1## (wherein, "X" indicates an oxygen or sulfur atom, "R" indicates non-substituted or substituted phenyl group, naphthyl group, aralkyl group, lower alkyl group of carbon number 1-6, cycloalkyl group of carbon number 3-6 or lower alkenyl group of carbon number 2-6. "Z" indicates lower alkyl group of carbon number 1-6 or electron attractive group. "n" indicates an integer from 0 to 4 and "P" indicates an integer from 1 to 5, wherein satisfies the numerical formula of n+p.ltoreq.5) R.sub.1 --CONHCH.sub.2 OH (II) (wherein, "R.sub.1 " indicates alkyl group of carbon number 11-21).

    摘要翻译: 在包含热敏彩色显影层的热敏记录介质中,其包含基底上的无色染料和有机彩色显影剂,其特征在于所述热显色层包括0.01-0.9份由通式(I)表示的氨基苯磺酰胺衍生物 ),并且还包括基于1份显色剂的0.01-2份比例的由通式(II)表示的至少一种羟甲基化脂肪酸酰胺。 (I)(I)(其中,“X”表示氧或硫原子,“R”表示未取代或取代的苯基,萘基,芳烷基,碳数1-6的低级烷基,环烷基 碳数3-6的碳原子数为3-6以下的碳原子数为2-6的“Z”表示碳原子数1-6的低级烷基或吸电子基团,“n”表示0〜4的整数,“P”表示 1〜5的整数,其中满足n + p = 5)R1-CONHCH2OH(II)的数学式(其中,“R1”表示碳数为11-21的烷基)。

    Thermally sensitive recording medium
    6.
    发明授权
    Thermally sensitive recording medium 失效
    热敏记录介质

    公开(公告)号:US06303540B1

    公开(公告)日:2001-10-16

    申请号:US09431052

    申请日:1999-11-01

    IPC分类号: B41M530

    CPC分类号: B41M5/3336 B41M5/3375

    摘要: A thermally sensitive recording medium which has thermally sensitive recording layer containing colorless or pale colored basic leuco dye and organic color developer as main components on a substrate, wherein said thermally sensitive recording layer contains diphenylsulfone bridgeable type compound represented by general formula (1) and at least one compound represented by general formula (1). In general formula (2), X and Y can be different and indicates a saturated or an unsaturated liner or grafted hydrocarbon group of carbon number 1-12 which can possess ether bond, or indicates wherein R indicates a methylene group or an ethylene group, T indicates a hydrogen atom or an alkyl group of carbon number 1-4, and R1-R6 independently indicate a halogen atom, an alkyl group of carbon number 1-6, or an alkenyl group, further, m, n, p, q, r, t indicate an integer number of 0-4 and when are bigger than 2, R1-R6 can be different, and a is an integer of 0-10. In general formula (2), R7 represents an alkyl group of carbon number 1-6 or an electron attracting group, u is an integer of 0-2.

    摘要翻译: 一种热敏记录介质,其具有含有无色或浅色基础无色染料和有机彩色显影剂作为主要成分的热敏记录层,其中所述热敏记录层含有通式(1)表示的二苯砜桥连型化合物, 至少一种由通式(1)表示的化合物。在通式(2)中,X和Y可以不同,表示可以具有醚键的碳数1-12的饱和或不饱和的内衬或接枝烃基,或表示在 R表示亚甲基或亚乙基,T表示氢原子或碳数为1-4的烷基,R1-R6独立地表示卤素原子,碳原子数为1-6的烷基或烯基 此外,m,n,p,q,r,t表示0-4的整数,当大于2时,R1-R6可以不同,a是0-10的整数。在通式( 2),R7表示 碳数1-6的烷基或吸电子基团,u为0-2的整数。

    Thermal recording sheet
    7.
    发明授权
    Thermal recording sheet 失效
    热敏记录纸

    公开(公告)号:US5405821A

    公开(公告)日:1995-04-11

    申请号:US111924

    申请日:1993-08-26

    摘要: A thermal recording sheet superior in dynamic sensitivity, dot reproducibility, image quality and image storage stability, and having no trouble of turning yellow of the sheet caused by NOx gas.A thermal recording sheet comprising an intermediate layer and a thermal color developing layer provided in turn on a substrate, wherein the intermediate layer contains a pigment having an oil absorption (according to JIS K5101) of less than 80 ml/100 g, and a compound of the following general formula (I): ##STR1## wherein R denotes propyl, isopropyl, or n-butyl, and calcium carbonate are contained in the thermal color developing layer as an organic color developer and a pigment, respectively.

    摘要翻译: 具有动态灵敏度,点再现性,图像质量和图像存储稳定性优异的热记录片材,并且不会由于NOx气体而导致黄色片材变黄。 一种热敏记录片材,包括依次在基底上设置的中间层和热显色层,其中中间层含有吸油量(根据JIS K5101)小于80ml / 100g的颜料和化合物 的下列通式(I):其中R表示丙基,异丙基或正丁基,和碳酸钙分别作为有机显色剂和颜料包含在热显色层中。