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1.发明授权公开(公告)号：US07232873B2
公开(公告)日：2007-06-19
申请号：US10820798
申请日：2004-04-09
IPC分类号： C08F130/04 , C04B24/04 , C04B24/16
CPC分类号： C08F220/06 , C04B24/163 , C04B24/2647 , C04B24/2688 , C04B28/02 , C04B2103/408 , C08F220/28 , C08F290/062 , C04B40/0263
摘要： A polycarboxylic acid cement dispersant that can exhibit high dispersing ability and allow deforming in early stages in the case of producing concrete products, whereby the turnover of a formwork is increased so as to improve productivity, and the method of producing such as concrete product are provided. The polycarboxylic acid cement dispersant which provides a cement composition having a penetration resistance value exponent of 55 MPa or more and a slump retention exponent of 80% or more, and the method of producing a concrete product which makes use of a copolymer derived by using monomer components comprising the monomer (A) as polyalkylene glycol unsaturated monomer, the monomer (B) as unsaturated carboxylic monomer, and the monomer (C) as sulfonic acid group-containing monomer.
摘要翻译： 在生产混凝土制品的情况下可以表现出高分散能力并能够在早期阶段发生变形的多元羧酸水泥分散剂，从而提高模板的更换以提高生产率，并且提供诸如混凝土产品的生产方法 。 提供具有55MPa以上的穿透电阻值指数和80％以上的塌陷保持指数的水泥组合物的多元羧酸水泥分散剂，以及使用通过使用单体得到的共聚物的混凝土制品的制造方法 包含作为聚亚烷基二醇不饱和单体的单体（A），作为不饱和羧酸单体的单体（B）和作为含磺酸基的单体的单体（C）的组分。
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2.发明授权公开(公告)号：US07872076B2
公开(公告)日：2011-01-18
申请号：US10577355
申请日：2004-11-05
申请人： Hiroyuki Ikeuchi , Kazushi Torii , Taku Iwamura , Sayaka Machida , Hiroko Okochi
发明人： Hiroyuki Ikeuchi , Kazushi Torii , Taku Iwamura , Sayaka Machida , Hiroko Okochi
IPC分类号： C08F120/06 , C08K5/053
摘要： An object of the present invention is to provide a particulate water-absorbent resin composition and its production process, wherein the particulate water-absorbent resin composition is an enhanced one in both of the “liquid permeability” and “liquid-sucking-up property” (which have hitherto been antithetical physical properties) of the water-absorbent resin. As a means of achieving this object, a first particulate water-absorbent resin composition according to the present invention is a particulate water-absorbent resin composition comprising a water-absorbent resin (A) of a crosslinked structure obtained by polymerizing an acid-group-containing unsaturated monomer, with the composition being characterized by: having a particle size such that particles in the range of 850 to 150 μm (but not including 850 μm) account for not less than 90 weight % of the entirety; and containing a tetra- or more functional polyol (B) at least on surfaces.
摘要翻译： 本发明的目的在于提供一种颗粒状吸水性树脂组合物及其制造方法，其特征在于，所述颗粒状吸水性树脂组合物是“液体渗透性”和“吸液性” （其迄今为止为对称物理性质）的吸水性树脂。 作为实现该目的的手段，本发明的第一粒状吸水性树脂组合物是含有吸水性树脂（A）的颗粒状吸水性树脂组合物，所述吸水性树脂（A）是将酸 - 所述组合物的特征在于：具有使得在850〜150μm（但不包括850μm）范围内的颗粒占整个体积不小于90重量％的粒径; 并且至少在表面上含有四官能以上的多元醇（B）。
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3.发明申请公开(公告)号：US20070149760A1
公开(公告)日：2007-06-28
申请号：US11641885
申请日：2006-12-20
申请人： Kenji Kadonaga , Yorimichi Dairoku , Shin-ichi Fujino , Hiroko Okochi , Yoshio Irie , Hideyuki Tahara
发明人： Kenji Kadonaga , Yorimichi Dairoku , Shin-ichi Fujino , Hiroko Okochi , Yoshio Irie , Hideyuki Tahara
IPC分类号： C08F6/00
CPC分类号： B01J8/10 , B01F7/0045 , B01F7/00466 , B01F7/10 , B01J2208/00212 , B01J2208/00867 , B01J2219/182 , C08J3/245 , Y10S524/916
摘要： A method for surface crosslinking water-absorbing resin of the present invention includes a step (1) of obtaining a wet mixture, a step (2) of obtaining a dried particulate composition, and a step (3) of carrying out a surface crosslinking reaction. With this, since a processing time of each step becomes short, it is possible to mass produce the water-absorbing resin having excellent physical properties. Moreover, a method for manufacturing the water-absorbing resin of the present invention includes a modifying step and a cooling step. The modifying step and/or the cooling step are/is carried out by using stirring means including a rotation axis having a plurality of stirring boards, and the stirring means includes the stirring board having a specific thickness and/or a scraping blade having a specific shape. With this, it is possible to suppress the generation of the fine powder in the modifying step and/or the cooling step.
摘要翻译： 本发明的表面交联吸水性树脂的方法包括获得湿混合物的步骤（1），获得干燥的颗粒组合物的步骤（2）和进行表面交联反应的步骤（3） 。 由此，由于每个步骤的处理时间变短，因此可以大量生产具有优异物理性能的吸水性树脂。 此外，本发明的吸水性树脂的制造方法包括改性工序和冷却工序。 通过使用包括具有多个搅拌板的旋转轴的搅拌装置进行修改步骤和/或冷却步骤，并且搅拌装置包括具有特定厚度的搅拌板和/或具有特定厚度的刮板 形状。 由此，可以抑制修饰工序和/或冷却工序中的细粉的产生。
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公开(公告)号：US20080139693A1
公开(公告)日：2008-06-12
申请号：US10577355
申请日：2004-11-05
申请人： Hiroyuki Ikeuchi , Kazushi Torii , Taku Iwamura , Sayaka Machida , Hiroko Okochi
发明人： Hiroyuki Ikeuchi , Kazushi Torii , Taku Iwamura , Sayaka Machida , Hiroko Okochi
IPC分类号： C08K5/053
摘要： An object of the present invention is to provide a particulate water-absorbent resin composition and its production process, wherein the particulate water-absorbent resin composition is an enhanced one in both of the “liquid permeability” and “liquid-sucking-up property” (which have hitherto been antithetical physical properties) of the water-absorbent resin. As a means of achieving this object, a first particulate water-absorbent resin composition according to the present invention is a particulate water-absorbent resin composition comprising a water-absorbent resin (A) of a crosslinked structure obtained by polymerizing an acid-group-containing unsaturated monomer, with the composition being characterized by: having a particle size such that particles in the range of 850 to 150 μm (but not including 850 μm) account for not less than 90 weight % of the entirety; and containing a tetra- or more functional polyol (B) at least on surfaces.
摘要翻译： 本发明的目的在于提供一种颗粒状吸水性树脂组合物及其制造方法，其特征在于，所述颗粒状吸水性树脂组合物是“液体渗透性”和“吸液性” （其迄今为止为对称物理性质）的吸水性树脂。 作为实现该目的的手段，本发明的第一粒状吸水性树脂组合物是含有吸水性树脂（A）的颗粒状吸水性树脂组合物，所述吸水性树脂（A）是将酸 - 所述组合物的特征在于：具有使得在850〜150μm（但不包括850μmum）的范围内的颗粒占整个体积不小于90wt％的粒径; 并且至少在表面上含有四官能以上的多元醇（B）。
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5.发明申请Method for manufacturing water-absorbing resin composition and water-absorbing resin composition 审中-公开吸水性树脂组合物和吸水性树脂组合物的制造方法公开(公告)号：US20070203280A1
公开(公告)日：2007-08-30
申请号：US11449666
申请日：2006-06-09
申请人： Hiroko Okochi
发明人： Hiroko Okochi
IPC分类号： C08K3/22
CPC分类号： C08K3/22
摘要： As water-absorbing resin materials used, for example, as water-absorbing materials of paper diapers, the present invention realizes a water-absorbing resin composition whose basic water-absorbing performances, productivity, etc. are not spoiled but whose liquid diffusibility that is a practically important characteristic is improved drastically. A method for manufacturing the water-absorbing resin composition of the present invention includes the step of mixing the water-absorbing resin A and the inorganic fine particle B, which has been irradiated with ultraviolet rays, on condition that the amount of the inorganic fine particle B is from 0.01 part by weight to 10 parts by weight when the amount of the water-absorbing resin A is 100 parts by weight. Thus, it is possible to manufacture the water-absorbing resin composition whose liquid distribution velocity (LDV) is from 2.0 mm/s to 10 mm/s.
摘要翻译： 作为吸水性树脂材料，例如作为纸尿布的吸水材料，可以实现吸水性能，生产性等不受损害的吸水性树脂组合物，其液体扩散性为 实际上重要的特征大大改善。 本发明的吸水性树脂组合物的制造方法包括将无机微粒的量与吸收性树脂A和被紫外线照射的无机微粒B混合的工序 当吸水性树脂A的量为100重量份时，B为0.01重量份至10重量份。 因此，可以制造液体分布速度（LDV）为2.0mm / s至10mm / s的吸水性树脂组合物。
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公开(公告)号：US20050288182A1
公开(公告)日：2005-12-29
申请号：US11152195
申请日：2005-06-15
申请人： Kazushi Torii , Masatoshi Nakamura , Hiroko Okochi
发明人： Kazushi Torii , Masatoshi Nakamura , Hiroko Okochi
CPC分类号： C08F220/06 , B01J20/26 , B01J20/261 , B01J20/267 , B01J2220/68 , C08F222/1006
摘要： The water absorbent resin composition and the production method thereof according to the present invention are characterized by including: water absorbent resin particles having an internal cross-linked structure obtained by polymerizing a water-soluble unsaturated monomer; a nitrogenous ketone compound (A) (containing no carboxyl group) having a structure represented by formula (1); and a bivalent and/or trivalent and/or tetravalent water-soluble metal salt, wherein a total amount of the nitrogenous ketone compound (A) and the bivalent and/or trivalent and/or tetravalent water-soluble metal salt ranges from 0.01 to 100 parts by mass with respect to 100 parts by mass of the water absorbent resin particles, thereby providing a water absorbent resin composition, having an excellent absorption capacity represented by a centrifuge retention capacity (CRC), an absorbency against pressure of 4.83 kPa (AAP) etc., having excellent liquid permeability and liquid diffusion properties, having excellent fluidity at the time of moisture absorption, having an excellent damage resistance property, effectively suppressing occurrence of dusts, hardly bringing about permeation of added metal compounds into water absorbent resin particles, hardly bringing about segregation of added metal compounds.
摘要翻译： 本发明的吸水性树脂组合物及其制造方法的特征在于包括：通过使水溶性不饱和单体聚合而得到的具有内部交联结构的吸水性树脂粒子; 具有式（1）所示结构的含氮酮化合物（A）（不含羧基）; 和二价和/或三价和/或四价水溶性金属盐，其中含氮酮化合物（A）和二价和/或三价和/或四价水溶性金属盐的总量为0.01至100 相对于100质量份的吸水性树脂粒子为质量份，由此提供具有由离心保留容量（CRC）表示的优异的吸收能力，相对于4.83kPa（AAP）的吸收性的吸水性树脂组合物， 等等，具有优异的液体渗透性和液体扩散性，在吸湿时具有优异的流动性，具有优异的耐损伤性能，有效地抑制了灰尘的发生，几乎不会使添加的金属化合物渗透到吸水性树脂颗粒中 导致添加的金属化合物的分离。
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7.发明授权公开(公告)号：US07851550B2
公开(公告)日：2010-12-14
申请号：US11641885
申请日：2006-12-20
申请人： Kenji Kadonaga , Yorimichi Dairoku , Shin-ichi Fujino , Hiroko Okochi , Yoshio Irie , Hideyuki Tahara
发明人： Kenji Kadonaga , Yorimichi Dairoku , Shin-ichi Fujino , Hiroko Okochi , Yoshio Irie , Hideyuki Tahara
CPC分类号： B01J8/10 , B01F7/0045 , B01F7/00466 , B01F7/10 , B01J2208/00212 , B01J2208/00867 , B01J2219/182 , C08J3/245 , Y10S524/916
摘要： A method for surface crosslinking water-absorbing resin of the present invention includes a step (1) of obtaining a wet mixture, a step (2) of obtaining a dried particulate composition, and a step (3) of carrying out a surface crosslinking reaction. With this, since a processing time of each step becomes short, it is possible to mass produce the water-absorbing resin having excellent physical properties. Moreover, a method for manufacturing the water-absorbing resin of the present invention includes a modifying step and a cooling step. The modifying step and/or the cooling step are/is carried out by using stirring means including a rotation axis having a plurality of stirring boards, and the stirring means includes the stirring board having a specific thickness and/or a scraping blade having a specific shape. With this, it is possible to suppress the generation of the fine powder in the modifying step and/or the cooling step.
摘要翻译： 本发明的表面交联吸水性树脂的方法包括获得湿混合物的步骤（1），获得干燥的颗粒组合物的步骤（2）和进行表面交联反应的步骤（3） 。 由此，由于每个步骤的处理时间变短，因此可以大量生产具有优异物理性能的吸水性树脂。 此外，本发明的吸水性树脂的制造方法包括改性工序和冷却工序。 通过使用包括具有多个搅拌板的旋转轴的搅拌装置进行修改步骤和/或冷却步骤，并且搅拌装置包括具有特定厚度的搅拌板和/或具有特定厚度的刮板 形状。 由此，可以抑制修饰工序和/或冷却工序中的细粉的产生。
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