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1.发明授权Method for processing a silver halide color photographic material using a color developer containing a chelating agent in the absence of benzyl alcohol 失效使用含有螯合剂的着色显影剂在不存在苄醇的情况下处理卤化银彩色照相材料的方法
公开(公告)号：US4835092A
公开(公告)日：1989-05-30
申请号：US15408
申请日：1987-02-17
CPC分类号： G03C7/413
摘要： A novel method for processing a silver halide color photographic material is provided, which comprises processing a silver halide color photographic material having at least one silver halide emulsion layer on a reflective support with a color-developing solution substantially free of benzyl alcohol and containing at least one compound represented by formula (I) ##STR1## wherein R.sub.1 represents a hydrogen atom, --CH.sub.2 COOH, or ##STR2## R.sub.2 represents a hydrogen atom or --COOH; n represents an integer of 0 or 1; and Z represents atoms necessary for the formation of an aromatic ring.
摘要翻译： 提供了一种用于处理卤化银彩色照相材料的新方法，其包括在反射性载体上处理具有至少一个卤化银乳剂层的卤化银彩色照相材料，其显色溶液基本上不含苄醇，并至少含有 一种由式（I）表示的化合物其中R 1表示氢原子，-CH 2 COOH或R 2表示氢原子或-COOH; n表示0或1的整数; Z表示形成芳环所需的原子。
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2.发明授权
公开(公告)号：US5006456A
公开(公告)日：1991-04-09
申请号：US202558
申请日：1988-06-06
申请人： Masakazu Morigaki , Takatoshi Ishikawa , Kazuto Andoh , Nobuo Seto , Toshio Koshimizu , Shinji Ueda
发明人： Masakazu Morigaki , Takatoshi Ishikawa , Kazuto Andoh , Nobuo Seto , Toshio Koshimizu , Shinji Ueda
CPC分类号： G03C7/407
摘要： A method for processing a silver halide color photographic light-sensitive material comprises the steps of developing the light-sensitive material with a color developer containing an aromatic primary amine color developing agent, desilvering, washing with water and/or stabilizing the material in which at least one processing solution used in at least one step of the processing contains at least one compound selected from the group consisting of sulfinic acids and salts and precursors thereof. This method makes it possible to effectively prevent the formation of stains due to not only the components of the light-sensitive material per se but also those attributable to the processing solutions, during processing or storage with time, and to enhance the stability of processing solutions.
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3.发明授权Method for processing silver halide color photographic materials wherein the color developer contains low concentrations of benzyl alcohol, hydroxylamine and sulfite 失效用于处理卤化银彩色照相材料的方法，其中显色剂含有低浓度的苄醇，羟胺和亚硫酸盐
公开(公告)号：US4774167A
公开(公告)日：1988-09-27
申请号：US17407
申请日：1987-02-24
CPC分类号： G03C7/413
摘要： A method for processing a silver halide color photographic material is provided, which comprises subjecting an imagewise exposed silver halide color photographic material having at least one silver halide emulsion layer on a reflective support to color development for a period not exceeding 2 minutes and 30 seconds using a color-developing solution containing substantially no benzyl alcohol, a sulfite in a concentration of 8.times.10.sup.-3 mol/liter or less, and a hydroxylamine in a concentration of 1.5.times.10.sup.-2 mol/liter or less, thereby achieving high color densities of the developed images and reduced fog. The effects of this method are particularly significant in photographic paper containing a pyrazoloazole type magenta coupler.
摘要翻译： 提供了一种处理卤化银彩色照相材料的方法，其包括使具有至少一个卤化银乳剂层的成像曝光的卤化银彩色照相材料在反射支撑体上曝光不超过2分30秒的时间，使用 基本上不含苄醇的显色溶液，浓度为8×10 -3 mol /升以下的亚硫酸盐和浓度为1.5×10 -2 mol /升以下的羟胺，从而实现了高浓度的 开发图像和减少雾。 该方法的效果在含有吡唑并噻唑类品红色成色剂的相纸中特别重要。
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4.发明授权
公开(公告)号：US5034308A
公开(公告)日：1991-07-23
申请号：US086790
申请日：1987-08-19
申请人： Akira Abe , Yoshihiro Fujita , Toshio Koshimizu , Kazuhiro Aikawa
发明人： Akira Abe , Yoshihiro Fujita , Toshio Koshimizu , Kazuhiro Aikawa
CPC分类号： G03C7/44 , G03C7/3046
摘要： A method for processing silver halide photosensitive materials comprising developing an exposed silver halide photosensitive material, fixing the developed photosensitive material and then washing it with a washing water, the washing water used in the water washing process being replenished in an amount of 2 to 50 times the volume of liquid carried over by the photosensitive material from a bath preceding the water washing bath per unit area thereof, the amount of calcium and magnesium compounds present in the water washing bath being reduced to not more than 5 mg/l, respectively, on the basis of elemental calcium and magnesium and the washing water containing at least one chelating agent having a stability constant of a chelate, which is formed between the chelating agent and calcium or magnesium, of at least 6 is herein disclosed. The method makes it possible to suppress the increase in turbidity due to the proliferation of bacteria and molds in washing bath even when the processing is continuously conducted while substantially saving the amount of washing water and further provides an excellent processed photosensitive materials.
摘要翻译： 一种用于处理卤化银感光材料的方法，包括曝光的卤化银感光材料的显影，固定显影的感光材料，然后用洗涤水清洗，水洗过程中使用的洗涤水的量为2至50倍 由感光材料从洗涤浴之前的浴中每单位面积的液体所携带的液体的体积，洗涤水中存在的钙和镁化合物的量分别减少到不超过5mg / l， 本文公开了元素钙和镁的基础以及含有至少一种螯合剂的至少一种螯合剂的洗涤水，螯合剂在螯合剂和钙或镁之间形成至少为6。 该方法即使在连续进行处理的同时可以抑制由于洗涤槽中的细菌和霉菌的增殖引起的浊度的增加，同时基本上节省了洗涤水的量并进一步提供了优良的加工感光材料。
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5.发明授权
公开(公告)号：US5055381A
公开(公告)日：1991-10-08
申请号：US57254
申请日：1987-06-03
申请人： Akira Abe , Yoshihiro Fujita , Toshio Koshimizu
发明人： Akira Abe , Yoshihiro Fujita , Toshio Koshimizu
IPC分类号： G03C7/30
CPC分类号： G03C7/3046
摘要： In a method for processing silver halide photosensitive materials comprising developing an exposed silver halide photosensitive material, fixing the developed material and washing it with a washing water, the amount of calcium and magnesium compounds present in the replenishing washing water is reduced to not more than 5 mg/l on the basis of the weight of elemental calcium or magnesium and washing water is replenished in an amount of 1 to 50 times the volume of liquid carried over by the photosensitive material from a bath preceding the washing bath per unit area thereof or that the replenishing washing water is introduced into a washing bath after reducing the amount of calcium and magnesium compounds to the range mentioned above and sterilizing the same. The method makes it possible to substantially reduce the amount of washing water while reliably suppressing turbidity and proliferation of microorganisms in the washing water during and after completion of processing.
摘要翻译： 在用于处理卤化银感光材料的方法中，包括显影曝光的卤化银感光材料，固定显影的材料并用洗涤水洗涤，补充洗涤水中存在的钙和镁化合物的量减少到不超过5 基于元素钙或镁的重量mg / l，洗涤水的补充量是由感光材料从洗涤浴每单位面积之前的浴中携带的液体的体积的1至50倍，或补充 在将钙和镁化合物的量减少至上述范围并对其进行消毒之后，将补充的洗涤水引入洗涤浴中。 该方法可以在可靠地抑制洗涤水中和处理完成后的洗涤水中的微生物的浊度和增殖的同时大幅减少洗涤水量。
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公开(公告)号：US4820623A
公开(公告)日：1989-04-11
申请号：US151848
申请日：1988-02-03
申请人： Toshio Koshimizu , Keiji Mihayashi
发明人： Toshio Koshimizu , Keiji Mihayashi
CPC分类号： G03C7/3012 , G03C7/44
摘要： A method for processing a silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer and containing a magenta dye forming coupler represented by formula (I) shown below and a compound represented by formula (II) shown below in the same layer is described, wherein the silver halide color photographic material is subjected to color development using a replenisher for a color developing solution, whose concentration of bromide is not more than 3.times.10.sup.-3 mol per liter and the amount of the replenisher for a color developing solution is not more than 900 ml per m.sup.2 of the silver halide color photographic material, wherein ##STR1## wherein R.sub.1 represents an aromatic group, an aliphatic group or a heterocyclic group; R.sub.2 represents a substituent; Za, Zb, Zc and Zd, which may be the same or different, each represents an unsubstituted methine group, a substituted methine group or --N.dbd.; and formula (II) is represented by(R'--COO.sup.-).sub.n M.sup.n+ (III)wherein R' represents a substituent which imparts a diffusion-resistant property to the compound represented by formula (II); M.sup.n+ represents a hydrogen ion, a metal ion or an ammonium ion; and n represents an integer from 1 to 4.According to the method of the present invention, the amount of replenisher for a color developing solution can be reduced without adverse affects on photographic properties. Further, the formation of precipitates in the color developing solution is prevented and adhesion of scum onto the photographic material does not occur.
摘要翻译： 一种用于处理卤化银彩色照相材料的方法，其包括其上具有至少一个卤化银乳剂层的载体，并含有下述式（I）表示的品红色染料形成成色剂和下述式（II）表示的化合物在 描述了相同的层，其中使用用于彩色显影液的补充剂对卤化银彩色照相材料进行显色，其中溴化物的浓度不大于3×10 -3 mol /升，并且用于显色的补充剂的量 溶液不超过900ml / m 2的卤化银彩色照相材料，其中R 1表示芳族基团，脂族基团或杂环基团的化合物（I） R2表示取代基; Za，Zb，Zc和Zd可以相同或不同，各自表示未取代的次甲基，取代的次甲基或-N =; 式（II）由（R'-COO-）n Mn +（III）表示，其中R'表示赋予由式（II）表示的化合物具有扩散阻力特性的取代基。 Mn +表示氢离子，金属离子或铵离子; n表示1〜4的整数。根据本发明的方法，可以减少显色液的补充量，而不影响照相性能。 此外，防止在显色溶液中形成沉淀物，并且不会发生浮渣对照相材料的附着。
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