摘要:
Objects of the present invention are to improve the adhesion and processing characteristics of electrode composite layers and to provide a lithium secondary battery by which a decrease in battery capacity during high-temperature storage at 50° C. or higher is suppressed. The lithium secondary battery of the present invention comprises a positive electrode capable of storing and releasing lithium ions, a negative electrode capable of storing and releasing lithium ions, a separator disposed between the positive electrode and the negative electrode, and an electrolyte, wherein the negative electrode or the electrolyte contains a nonvolatile liquid.
摘要:
A lithium secondary battery is intended to suppress deterioration upon storage at high temperature of 50° C. or higher without deteriorating the output characteristics at a room temperature. The battery includes a positive electrode capable of occluding and releasing lithium ions, a negative electrode capable of occluding and releasing lithium ions, a separator disposed between the positive electrode and the negative electrode, and an electrolyte. The electrolyte contains a compound having a double bond in the molecule and a compound having a plurality of polymerizable functional groups in the molecule, and the electrolyte contains a compound represented by formula (4): (in which Z1 and Z2 each represent any one of an allyl group, a methallyl group, a vinyl group, an acryl group, and a methacryl group).
摘要:
This invention provides a lithium-ion battery in which a coating film forming agent degradation reaction is prevented.A lithium-ion battery 100 in which electrodes 1 and 2 and an electrolyte are accommodated in a battery container 13, and which has a means of for adding a coating film forming agent 20 for adding a coating film forming agent 21 that forms a coating film on the surface of each of electrodes 1 and 2 to an electrolyte in a battery container 13 is provided. With the use of such means of adding a coating film forming agent 20, a reaction of electrochemical degradation of a coating film forming agent 21 is prevented, allowing long-term preservation. Also, with the addition of a coating film forming agent 21 to an electrolyte, a deteriorated coating film on the surface of each of electrodes 1 and 2 is repaired such that a lithium-ion battery 100 can be regenerated, resulting in extension of battery life.
摘要:
A lithium secondary battery is intended to suppress deterioration upon storage at high temperature of 50° C. or higher without deteriorating the output characteristics at a room temperature. The battery includes a positive electrode capable of occluding and releasing lithium ions, a negative electrode capable of occluding and releasing lithium ions, a separator disposed between the positive electrode and the negative electrode, and an electrolyte. The electrolyte contains a compound having a double bond in the molecule and a compound having a plurality of polymerizable functional groups in the molecule, and the electrolyte contains a compound represented by formula (4): (in which Z1 and Z2 each represent any one of an allyl group, a methallyl group, a vinyl group, an acryl group, and a methacryl group).
摘要:
This invention provides a lithium-ion battery in which a coating film forming agent degradation reaction is prevented. A lithium-ion battery 100 in which electrodes 1 and 2 and an electrolyte are accommodated in a battery container 13 , and which has a means of for adding a coating film forming agent 20 for adding a coating film forming agent 21 that forms a coating film on the surface of each of electrodes 1 and 2 to an electrolyte in a battery container 13 is provided. With the use of such means of adding a coating film forming agent 20, a reaction of electrochemical degradation of a coating film forming agent 21 is prevented, allowing long-term preservation. Also, with the addition of a coating film forming agent 21 to an electrolyte, a deteriorated coating film on the surface of each of electrodes 1 and 2 is repaired such that a lithium-ion battery 100 can be regenerated, resulting in extension of battery life.
摘要:
Disclosed is a lithium-ion secondary battery which includes a carbonaceous material in an anodic active material mix, and a cyclic carbonate and a chain carbonate both in an electrolytic solution. The solvent contains an additive which is a substance having a LUMO energy determined through molecular orbital calculation of lower than the LUMO energy of ethylene carbonate determined through molecular orbital calculation and having a HOMO energy lower than the HOMO energy of vinylene carbonate determined through molecular orbital calculation, the electrolytic solution contains LiPF6 or LiBF4 as an electrolyte, and the electrolytic solution shows a reduction-reaction current of −0.05 mA/cm2 (provided that a reaction current on the reducing side be negative) or less at a potential lower than 1 V and shows an oxidation-reaction current of 0.5 mA/cm2 (provided that a reaction current on the oxidizing side be positive) or more at a potential higher than 5.7 V in an LSV measurement at a potential sweep rate of 1 mV/s using a glassy-carbon disk electrode as a working electrode, a platinum electrode as a counter electrode, and a lithium electrode as a reference electrode.
摘要翻译:公开了一种在阳极活性材料混合物中包含碳质材料的锂离子二次电池,以及在电解液中的环状碳酸酯和链状碳酸酯。 溶剂含有一种添加剂,该物质具有通过分子轨道计算确定的低于通过分子轨道计算确定的碳酸亚乙酯的LUMO能量并且具有低于通过分子轨道计算确定的碳酸亚乙烯酯的HOMO能量的HOMO能量确定的LUMO能量的物质 电解液含有作为电解质的LiPF 6或LiBF 4,电解液的电位低于1V时,电解液的还原反应电流为-0.05mA / cm 2(条件是还原侧的反应电流为负)以下 并且在电位扫描速度为1mV / s的LSV测量中,使用以下公式示出氧化反应电流为0.5mA / cm 2(条件是氧化侧的反应电流为正),电位高于5.7V的电位 作为工作电极的玻璃碳片电极,作为对电极的铂电极和作为参考电极的锂电极。
摘要:
A lithium secondary battery includes a positive electrode which can occlude and discharge lithium ion, a negative electrode which can occlude and discharge lithium ion, a separator which is disposed between the positive electrode and the negative electrode, and an electrolyte. In order to suppress a deterioration for a period of high temperature storage at 50° C. or more, the electrolyte includes a compound within whose molecule a plurality of polymerizable functional groups are included.The electrolyte can include a compound represented by the formula 3: wherein each of Z1 and Z2 represents a polymerizable functional group including any one selected from the group consisting of allyl group, methallyl group, vinyl group, acryl group and methacryl group.
摘要:
An image forming apparatus includes movable first and second image bearing members, latent image forming units that form electrostatic latent images and latent index patterns, a movable belt member contacting the image bearing members, toner image transfer members that transfer toner images, obtained by depositing toner on the latent images, onto the belt member, latent pattern detectors that detect the latent index patterns, an adjusting portion that adjusts relative positions between the latent index patterns on the basis of detection results of the detectors, and a setting portion that sets a latent pattern transfer voltage, during image formation, on the basis of a detection result of one of the latent pattern detectors on condition that a plurality of test voltages are applied to one of the latent pattern transfer member during non-image formation.
摘要:
A fluid container unit including: a container coupling for coupling a supply/discharge port of a first container with a supply/discharge port of a second container; a single nozzle member having a nozzle tube; a connection cap having a first end for holding a base portion of the nozzle member and a second end for covering one side of the container coupling by fitting around an outer periphery thereof; an intermediate adaptor having a pair of pusher elements facing the first and the second supply/discharge ports, respectively; and a supply/discharge port opening mechanism for moving the intermediate adaptor toward the container coupling and opening the supply/discharge ports by the pusher elements. The pusher elements are movably held in a direction along a longitudinal axis of the nozzle tube in the connection cap.
摘要:
An image forming apparatus includes a plurality of image bearing members; an electrostatic image forming portion; a belt member; an electrostatic image transfer member for transferring an electrostatic index image, onto an electrostatic image transfer area located adjacent to an image area of a toner image with respect to a widthwise direction of the belt member, formed on the upstreammost image bearing member with respect to a rotational direction of the belt member; an antenna potential sensor for detecting an induced current of the electrostatic index image; a controller for controlling superposition of the toner images through detection of the electrostatic index image; and a setting portion on the basis of a detection result of the electrostatic index image which is formed during non image formation.