摘要:
The present invention has an object to provide piezoelectric ceramics containing no lead, having a high Curie point, and further, having excellent piezoelectric properties, particularly large Qmax. The piezoelectric ceramics contain, as a main component, a bismuth layer-structured compound having (MII1-xLnx)Bi4Ti4O15 crystals (MII is an element selected from Sr, Ba, and Ca, Ln is an element selected from lanthanoids, and x is within a range of 0
摘要翻译:本发明的目的是提供一种不具有高居里点的不含铅的压电陶瓷,并且还具有优异的压电性能,特别大的Qmax。 作为主要成分的压电陶瓷含有具有(M 1,X 2)1-x L n x L z)Bi Bi的铋层结构化合物 > 4 sub> 5 sub> 15 sub> 15 sub> 15 sup>是从Sr,Ba和Ca中选出的一种元素,Ln是 元素,其选自镧系元素,x在0
摘要:
A piezoelectric ceramics having ceramic particles, wherein said ceramic particles comprises bismuth layer compound containing at least Sr, Ln (note that Ln is a lanthanoid element), Bi, Ti and O and including MIIBi4Ti4O15 type crystal (MII is an element composed of Sr and Ln) as a main component, and an oxide of Mn as a subcomponent; and an average particle diameter by the code length measuring method is 0.8 to 4.7 μm: by which it is possible to provide piezoelectric ceramics having a large Qmax in a third harmonic mode of thickness vertical vibration in a relatively high frequency band (for example, 16 to 65 MHz), a resonator an other piezoelectric element comprising the piezoelectric ceramics as a piezoelectric substance thereof.
摘要:
The present invention has an object to provide piezoelectric ceramics containing no lead, having a high Curie point, and further, having excellent piezoelectric properties, particularly large Qmax. The piezoelectric ceramics contain, as a main component, a bismuth layer-structured compound having (MII1-xLnx)Bi4Ti4O15 crystals (MII is an element selected from Sr, Ba, and Ca, Ln is an element selected from lanthanoids, and x is within a range of 0
摘要翻译:本发明的目的是提供一种不具有高居里点的不含铅的压电陶瓷,并且还具有优异的压电性能,特别大的Qmax。 作为主要成分的压电陶瓷含有具有(M 1,X 2)1-x L n x L z)Bi Bi的铋层结构化合物 > 4 sub> 5 sub> 15 sub> 15 sub> 15 sup>是从Sr,Ba和Ca中选出的一种元素,Ln是 元素,其选自镧系元素,x在0
摘要:
A piezoelectric ceramic composition which has a large electromechanical coupling factor and is excellent in heat resisting properties is provided. As additives, Cr, Al and Si are contained together in the piezoelectric ceramic composition including a perovskite compound which contains Pb, Zr and Ti as main components. Preferably, Cr, Al and Si are respectively contained in a content of 0.05 to 0.50 wt % in terms of Cr2O3, in a content of 0.005 to 1.500 wt % in terms of Al2O3, and in a content of 0.005 to 0.100 wt % in terms of SiO2. By simultaneously including these three elements and setting the contents thereof to fall within the above mentioned ranges, the electromechanical coupling factor kt can be 30% or more, and ΔFr, which is the rate of change in resonant frequency Fr between before and after application of an external thermal shock, can be 0.5% or less in absolute value.
摘要翻译:提供了具有大的机电耦合系数并且耐热性优异的压电陶瓷组合物。 作为添加剂,包含Pb,Zr和Ti作为主要成分的钙钛矿型化合物的压电陶瓷组合物中含有Cr,Al,Si。 优选地,Cr,Al和Si分别以Cr 2 Al 3 O 3含量为0.05〜0.50重量%,含量为0.005〜1.500重量% 以Al 2 O 3 3计,含量为0.005〜0.100重量%,以SiO 2 2计。 通过同时包含这三个要素并将其内容设定在上述范围内,机电耦合系数kt可以为30%以上,作为施加前后的谐振频率Fr的变化率的DeltaFr 外部热冲击的绝对值可以为0.5%以下。
摘要:
To obtain a piezoelectric ceramic composition having extremely high heat resisting property. Provided is a piezoelectric ceramic composition comprising a main component represented by Pba[(MnbNbc)dTieZrf]O3 (wherein 0.98≦a≦1.01, 0.340≦b≦0.384, 0.616≦c≦0.660, 0.08≦d≦0.12, 0.500≦e≦0.540, 0.37≦f≦0.41, bd+cd+e+f=1), and 1 to 10% by weight of Al in terms of Al2O3 as an additive. Preferably, b is such that 0.345≦b≦0.375 and c is such that 0.625≦c≦0.655, and the Al as the additive is preferably 2 to 6% by weight in terms of Al2O3.
摘要翻译:得到具有极高耐热性的压电陶瓷组合物。 本发明提供一种压电陶瓷组合物,其包含以下组分表示的主要成分:[(N,B)Nb C' (其中0.98 <= a <= 1.01,0.340 <= b <= 0.384,0.616 <= c 根据这个术语,<= 0.660,0.08 <= d <= 0.12,0.500 <= e <= 0.540,0.37 <= f <= 0.41,bd + cd + e + f = 1)和1〜10重量% 的Al 2 O 3 3作为添加剂。 优选地,b为0.345≤b≤0.375,c为0.625 <= c <= 0.655,作为添加剂的Al优选为2〜6重量% 3&gt; 3&lt; 3&gt ;.
摘要:
A piezoelectric ceramic composition excellent in heat resisting properties is provided. In the piezoelectric ceramic composition including a perovskite compound containing Pb, Zr and Ti as main components, the piezoelectric ceramic composition is made to include Cr as an additive from 0.025 to 0.250 wt % in terms of Cr2O3. In the piezoelectric ceramic composition of the present invention, Δk15 (here, Δk15 is the rate of change in electromechanical coupling factor k15, caused by external thermal shock), of the piezoelectric ceramic composition can be controlled to 3.0% or less in absolute value.
摘要翻译:提供耐热性优异的压电陶瓷组合物。 在包含以Pb,Zr和Ti为主要成分的钙钛矿化合物的压电陶瓷组合物中,压电陶瓷组合物包含Cr作为添加剂,以Cr 2 O 2计为0.025〜0.250重量% 3 SUB>。 在本发明的压电陶瓷组合物中,可以将压电陶瓷组合物的Deltak15(这里,Deltak15是由外部热冲击引起的机电耦合系数k15的变化率)控制在3.0%以下。
摘要:
There are provided steps of polarizing a ceramic composition including a perovskite compound containing Pb, Zr, Ti and Mn as main components and a heat treatment step for keeping the polarized ceramic composition within a temperature range lower than Tc (Tc denoting the Curie temperature of the ceramic composition) for 1 to 100 minutes.
摘要:
A piezoelectric ceramic composition is provided which contains Perovskite oxides expressed by General Formula 1 below and an aluminum compound, and in which the content ratio of the aluminum compound to the Perovskite oxides is from 1% by mass to 11% by mass, (Pbα-β-γ-δM1βM2γBiδ)[Ti{1-(x+y+z)}ZrxMnyNbz]O3 (1) wherein in the General Formula (1), M1 represents at least one kind of element selected from the group consisting of La, Ce, Pr, and Nd, M2 represents at least one kind of element selected from the group consisting of Sr, Ca, and Ba, and α, β, γ, δ, x, y, and z satisfy the following numerical conditions: 0.96≦α≦1.01 0.03≦β≦0.07 0≦γ≦0.10 0≦δ≦0.02 0≦x≦0.24 0.02≦y≦0.04 0.03≦z≦0.08
摘要:
Provided is a piezoelectric ceramic composition which enables the attainment of sufficiently high Qmax and good temperature characteristics of oscillation frequency F0 when applied in an oscillator utilizing third harmonic mode of thickness longitudinal vibration. The piezoelectric ceramic composition contains a composite oxide having a perovskite structure. The composite oxide has a composition expressed by the chemical formula (1), while satisfying 0.91≦α≦1.00, 0
摘要:
There are provided steps of polarizing a ceramic composition including a perovskite compound containing Pb, Zr, Ti and Mn as main components and a heat treatment step for keeping the polarized ceramic composition within a temperature range lower than Tc (Tc denoting the Curie temperature of the ceramic composition) for 1 to 100 minutes.