摘要:
A process for producing a lithium-containing composite oxide for a positive electrode active material for use in a lithium secondary battery, the oxide having the formula LipQqNxMyOzFa (wherein Q is at least one element selected from the group consisting of titanium, zirconium, niobium and tantalum, N is at least one element selected from the group consisting of Co, Mn and Ni, M is at least one element selected from the group consisting of Al, alkaline earth metal elements and transition metal elements other than Q and N, 0.9≦p≦1.1, 0≦q
摘要翻译:一种锂二次电池用正极活性物质的含锂复合氧化物的制造方法,其特征在于,具有式LipQqNxMyOzFa(其中,Q为选自钛,锆,铌和 钽,N是选自Co,Mn和Ni中的至少一种元素,M是选自Al,碱土金属元素和Q和N以外的过渡金属元素中的至少一种元素,0.9&nlE ; p&nlE; 1.1,0和nlE; q <0.03,0.97和nlE; x和nlE; 1.00,0和nlE; y <0.03,1.9&amp; nlE; z&nlE; 2.1,q + x + y = 1和0&lt; nlE; a&nlE; 0.02) 锂元素源和N元素源的混合物,当这些元素存在时,M元素源和/或氟源在含氧气氛中,其中Q元素源是具有 pH为0.5〜11。
摘要:
It is to provide a positive electrode active material for a lithium secondary battery, which has a large volume capacity density and high safety, is excellent in uniform coating properties and is excellent in the charge and discharge cyclic durability and low temperature characteristics even at a high charge voltage. A process for producing a lithium-containing composite oxide represented by the formula LipQqNxMyOzFa (wherein Q is at least one element selected from the group consisting of titanium, zirconium, niobium and tantalum, N is at least one element selected from the group consisting of Co, Mn and Ni, M is at least one element selected from the group consisting of Al, alkaline earth metal elements and transition metal elements other than the Q element and the N element, 0.9≦p≦1.1, 0
摘要翻译:本发明提供一种具有容量密度大,安全性高的锂二次电池用正极活性物质,均匀涂布性能优异,即使在高温下也具有优异的充放电循环耐久性和低温特性 充电电压。 一种由下式表示的含锂复合氧化物的制备方法:其中R 1,R 2,R 2,R 3, (其中Q是选自钛,锆,铌和钽中的至少一种元素,N是选自下组中的至少一种元素:其中Q是选自钛,锆,铌和钽中的至少一种元素, 由Co,Mn和Ni组成,M是选自Al,碱土金属元素和Q元素和N元素以外的过渡金属元素中的至少一种元素,0.9 <= p <= 1.1,0 < 来自锂源的q <= 0.03,0.97 <= x <1.00,0 <= y <0.03,1.9 <= z <= 2.1,q + x + y = 1和0 <= a <= 0.02) 元素源和N元素源,并且如果需要,选自由M元素源和氟源组成的组中的至少一种源,其特征在于将作为Q元素源的Q元素化合物水溶液用作pH值为 0.5至11。
摘要:
It is to provide a cathode active material for a lithium ion secondary battery, which has high safety, a high discharge voltage, a large capacity and excellent cyclic durability, and a process for producing it. A cathode active material for a lithium secondary battery, characterized by comprising a particulate lithium cobalt composite oxide represented by the formula LiaCobAlcMgdAeOfFg (1) (wherein A is Ti, Nb or Ta, O.90≦a≦1.10, 0.97≦b≦1.00, 0.000l≦c≦0.02, 0.000l≦d≦0.02, 0.000l≦e≦0.01, 1.98≦f≦2.02, 0≦g≦0.02, and 0.0003≦c+d+e≦0.03).
摘要翻译:提供一种具有高安全性,高放电电压,大容量,优异的循环耐久性的锂离子二次电池用正极活性物质及其制造方法。 一种用于锂二次电池的正极活性材料,其特征在于包括由式<?in-line-formula description =“In-line Formulas”end =“lead”→> Li表示的颗粒状锂钴复合氧化物 >>>> F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F F (1)<?in-line-formula description =“In-line Formulas”end =“tail”?>(其中A是Ti,Nb或Ta,O.90 <= a < = 1.10,0.97 <= b <= 1.00,0.0001 <= c <= 0.02,0.000l <= d <= 0.02,0.000l <= e <= 0.01,1.98 <= f <= 2.02,0 <= g <= 0.02,并且0.0003 <= c + d + e <= 0.03)。
摘要:
To provide a process for producing a lithium-cobalt composite oxide for a positive electrode of a lithium secondary battery, which has a large volume capacity density, high safety, high charge and discharge cycle durability, high press density and high productivity. A process for producing a lithium-cobalt composite oxide represented by the formula LipCoxMyOzFa (wherein M is a transition metal element other than Co, or an alkaline earth metal element, O.9≦p≦1.1, 0.980≦x≦1.000, 0≦y≦0.02, 1.9≦z≦2.1, x+y=1, and 0≦a≦0.02), characterized in that as a cobalt source, a mixture is used which comprises cobalt hydroxide in the form of substantially spherical secondary particles with an average particle size of from 8 to 20 μm formed by agglomeration of primary particles and tricobalt tetroxide in the form of secondary particles with an average particle size of from 2 to 10 μm formed by agglomeration of primary particles, in a cobalt atomic ratio of from 5:1 to 1:5, and firing is carried out at from 700 to 1,050° C.
摘要翻译:为了提供具有大容量密度,高安全性,高充放电循环耐久性,高压力密度和高生产率的锂二次电池正极用锂钴复合氧化物的制造方法。 一种由下式表示的锂 - 钴复合氧化物的制备方法:其中R 1,R 2,R 2, (其中M是除Co以外的过渡金属元素或碱土金属元素,O.9 <= p <= 1.1,0.980 <= x <=1.000,0≤y <= 0.02,1.9 <= z <= 2.1,x + y = 1,0 <= a <= 0.02),其特征在于,作为钴源,使用包含基本上为球形的氢氧化钴的混合物 平均粒度为8〜20μm的二次粒子是通过一次粒子和四氧化四铁的结合而形成的,该二次粒子是以原子粒子聚集形成的平均粒径为2〜10μm的二次粒子,以钴原子 比例为5:1至1:5,焙烧时间为700至1050℃。
摘要:
A positive electrode active material for a lithium secondary battery containing a lithium-cobalt composite oxide is produced by firing, as a cobalt source, a mixture of substantially spherical cobalt hydroxide or tricobalt tetraoxide having such a sharp particle size distribution that the average particle size D50 is from 7 to 20 μm, and cobalt oxyhydroxide having an average particle size of secondary particles formed by agglomeration of primary particles of from 7 to 20 μm, in a proportion of from 5:1 to 1:5 as the cobalt atomic ratio, at a temperature of from 700° C. to 1050° C. in an oxygen-comprising atmosphere.
摘要:
A positive electrode active material is produced by firing, as a cobalt source, a mixture of a) substantially spherical large particle size cobalt hydroxide or tricobalt tetraoxide having a sharp particle size distribution, and b) small particle size cobalt hydroxide or tricobalt tetraoxide, in a proportion of from 9:1 to 1:2 as the cobalt atomic ratio, at a temperature of from 700° C. to 1050° C. in an oxygen-comprising atmosphere.
摘要:
The present invention provides a lithium-containing composite oxide for a positive electrode for a lithium secondary battery, which has a large volume capacity density and high safety, and excellent durability for charge and discharge cycles and charge and discharge rate property, and its production method.The lithium-containing composite oxide is represented by the general formula LipNxMyOzFa (where N is at least one element selected from the group consisting of Co, Mn and Ni, M is at least one element selected from the group consisting of Al, Sn, alkaline earth metal elements and transition metal elements other than Co, Mn and Ni, 0.9≦p≦1.2, 0.965≦x
摘要翻译:本发明提供一种锂二次电池用正极用锂复合氧化物,其具有体积容量密度大,安全性高,充放电循环耐久性,充放电率特性及其制造方法 。 含锂复合氧化物由通式LipNxMyOzFa(其中N是选自Co,Mn和Ni中的至少一种元素)表示,M是选自Al,Sn,碱性中的至少一种元素 除Co,Mn和Ni以外的其它金属元素和过渡金属元素,0.9和nlE; p&nlE; 1.2,0.965和nlE; x <2.00,0
摘要:
A positive electrode active material for a lithium secondary battery containing a lithium-cobalt composite oxide, which has a large volume capacity density, has a high safety and is excellent in charge and discharge cyclic durability, and its production process, are provided.A lithium-cobalt composite oxide represented by the formula LipCoxMyOzFa (wherein M is a transition metal element other than Co or an alkaline earth metal element, 0.9≦p≦1.1, 0.980≦x≦1.000, 0≦y≦0.02, 1.9≦z≦2.1, x+y=1 and 0≦a≦0.02) and comprising a mixture containing substantially spherical hard first particles of lithium-cobalt composite oxide having such a sharp particle size distribution that the volume basis cumulative size D10 is at least 50% of the average particle size D50, and the volume basis cumulative size D90 is at most 150% of the average particle size D50, and second particles of lithium-cobalt composite oxide filling the space among the first particles, in a mass ratio of first particles/second particles of from 1/2 to 9/1, and process for producing the same.
摘要:
A positive electrode active material for a lithium secondary battery containing a lithium-cobalt composite oxide, which has a large volume capacity density, has a high safety and is excellent in charge and discharge cyclic durability, and its production process, are provided. A lithium-cobalt composite oxide represented by the formula LipCoxMyOzFa (wherein M is a transition metal element other than Co or an alkaline earth metal element, 0.9≦p≦1.1, 0.980≦x≦1.000, 0≦y≦0.02, 1.9≦z≦2.1, x+y=1 and 0≦a≦0.02) and comprising a mixture containing substantially spherical hard first particles of lithium-cobalt composite oxide having such a sharp particle size distribution that the volume basis cumulative size D10 is at least 50% of the average particle size D50, and the volume basis cumulative size D90 is at most 150% of the average particle size D50, and second particles of lithium-cobalt composite oxide filling the space among the first particles, in a mass ratio of first particles/second particles of from 1/2 to 9/1, and process for producing the same.
摘要翻译:提供了具有大体积容量密度的含有锂钴复合氧化物的锂二次电池用正极活性物质,其安全性高,充放电循环耐久性优异,其制造方法。 由下式表示的锂钴复合氧化物:由下式表示的锂 - 钴复合氧化物: a(其中M是除Co或碱土金属元素以外的过渡金属元素,0.9 <= p <= 1.1,0.980 <= x <= 1.000,0 <= y <= 0.02,1.9 < z <= 2.1,x + y = 1,0 <= a <= 0.02),并且包括含有基本上球形的硬质的第一个具有如此尖锐的粒度分布的锂 - 钴复合氧化物颗粒的混合物的混合物,体积基础累积尺寸D10为 平均颗粒尺寸D50的至少50%,体积基础累积尺寸D90为平均粒径D50的至多150%,并且以质量计填充第一颗粒之间的空间的第二种锂 - 钴复合氧化物颗粒 第一颗粒/第二颗粒的比率为1/2至9/1,及其制备方法。
摘要:
The present invention provides a lithium-containing composite oxide for a positive electrode for a lithium secondary battery, which has a large volume capacity density and high safety, and excellent durability for charge and discharge cycles and charge and discharge rate property, and its production method.The lithium-containing composite oxide is represented by the general formula LipNxMyOzFa (where N is at least one element selected from the group consisting of Co, Mn and Ni, M is at least one element selected from the group consisting of Al, Sn, alkaline earth metal elements and transition metal elements other than Co, Mn and Ni, 0.9≦p≦1.2, 0.965≦x
摘要翻译:本发明提供一种锂二次电池用正极用锂复合氧化物,其具有体积容量密度大,安全性高,充放电循环耐久性,充放电率特性及其制造方法 。 含锂复合氧化物由通式LipNxMyOzFa(其中N是选自Co,Mn和Ni中的至少一种元素)表示,M是选自Al,Sn,碱性中的至少一种元素 土壤金属元素和除Co,Mn和Ni之外的过渡金属元素,0.9 <= p <= 1.2,0.965 <= x <2.00,0