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公开(公告)号：US06962955B2
公开(公告)日：2005-11-08
申请号：US10616982
申请日：2003-07-11
IPC分类号： C08F8/12 , C08F116/06
CPC分类号： C08F8/12 , C08F2800/20 , C08J5/18 , Y10T428/31786 , C08F218/08 , C08F230/08
摘要： A polyvinyl alcohol having hydrolyzed silyl group functionalized monomer units. The polyvinyl alcohol satisfies the following formulae (I) and (II) and the pH of an aqueous 4% solution of the polyvinyl alcohol is between 4 and 8: 20
摘要翻译： 具有水解甲硅烷基官能化单体单元的聚乙烯醇。 聚乙烯醇满足下式（I）和（II），聚乙烯醇的4％水溶液的pH为4〜8：<？in-line-formula description =“In-line Formulas”end = “铅”→20
其中P是聚乙烯醇的粘度平均聚合度， S表示聚乙烯醇中的甲硅烷基官能化单体单元的含量，<η在线式描述=“In-line formula”end =“lead”≥> 0.1 / 100 <=（AB）/（B ）<= 50/100（II）<？在线公式描述=“在线公式”end =“tail”？>其中A是聚乙烯醇的硅原子含量，B是硅原子含量 用含氢氧化钠的甲醇洗涤的聚乙烯醇，然后通过索氏提取用甲醇洗涤。 在不存在氢氧化钠或酸的情况下，聚乙烯醇可以容易地溶于水; 该水溶液具有良好的粘度稳定性; 无机物的结合力高; 并且由其与无机物质的混合物形成的膜具有优异的耐水性。 聚乙烯醇对于喷墨记录材料和热敏记录材料的涂布剂是有利的。 -
2.发明申请公开(公告)号：US20050175795A1
公开(公告)日：2005-08-11
申请号：US11086337
申请日：2005-03-23
CPC分类号： C08F8/12 , C08F2800/20 , C08J5/18 , C08F218/08 , C08F230/08
摘要： A polyvinyl alcohol obtained by hydrolysis of a polyvinyl ester that contains silyl group functionalized monomer units. The polyvinyl alcohol satisfies the following formula (I) and the weight fraction of the polymer molecules contained in the polyvinyl alcohol having the degree of polymerization that is more than 3 times the weight-average degree of polymerization of the whole polyvinyl alcohol molecules is at most 25% by weight: 20
摘要翻译： 通过水解含有甲硅烷基官能化单体单元的聚乙烯酯得到的聚乙烯醇。 聚乙烯醇满足下式（I），聚乙烯醇聚合物中含有的聚乙烯醇聚合度的重量分数多于聚乙烯醇分子全部重均聚合度的3倍以上 25％重量：<？in-line-formula description =“In-line Formulas”end =“lead”？> 20
其中Pw是聚乙烯醇的重均聚合度，S是甲硅烷基官能化单体单元的含量（摩尔％）。 聚乙烯醇容易溶于水而不需要添加碱或酸; 水溶液具有良好的粘度稳定性; 由其水溶液形成的膜具有优异的耐水性; 无机物的结合力高; 聚乙烯醇与无机物的膜混合物具有优异的耐水性。 聚乙烯醇对于喷墨记录材料和热敏记录材料的涂布剂是有利的。 -
公开(公告)号：US07439300B2
公开(公告)日：2008-10-21
申请号：US10937780
申请日：2004-09-10
申请人： Hisamichi Yanai , Yoshihiro Tokuda , Jin Tokuyasu , Kimiko Miyata , Naoki Fujiwara , Takeshi Kusudou
发明人： Hisamichi Yanai , Yoshihiro Tokuda , Jin Tokuyasu , Kimiko Miyata , Naoki Fujiwara , Takeshi Kusudou
IPC分类号： C08F8/12 , C08F116/06
CPC分类号： C08J3/05 , C08F8/12 , C08J3/12 , C08J2329/04 , C08F118/08
摘要： The present invention provides polyvinyl alcohol based (PVA) whose solubility in water varies with a small temperature change to a sufficiently great degree. In manufacturing a polyvinyl alcohol based polymer by: progressing a transesterification reaction of a polyvinyl ester based polymer with alcohol in a liquid reaction mixture including the polyvinyl ester based polymer, the alcohol, and a basic compound; precipitating the polyvinyl ester based polymer, at least a part of which has been transesterified with the alcohol, out of the liquid reaction mixture; and further progressing the transesterification reaction in the liquid reaction mixture including the polyvinyl ester based polymer that has precipitated, the liquid reaction mixture has a temperature of 75° C. to 150° C. when the polyvinyl ester based polymer, at least a part of which has been transesterified, starts precipitating.
摘要翻译： 本发明提供了其在水中的溶解度随着温度变化小而充分变化的聚乙烯醇系（PVA）。 在制造聚乙烯醇类聚合物时，通过以下方法制造聚乙烯醇类聚合物：在含有聚乙烯基酯类聚合物，醇类和碱性化合物的液体反应混合物中进行聚乙烯酯系聚合物与醇的酯交换反应， 将至少一部分已经与醇酯交换的聚乙烯基酯类聚合物从液体反应混合物中沉淀出来; 并进一步进行包含已沉淀的聚乙烯基酯类聚合物的液体反应混合物中的酯交换反应，当聚乙烯基酯类聚合物的至少一部分时，液体反应混合物的温度为75℃〜150℃ 已被酯交酯反应开始沉淀。
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公开(公告)号：US5866655A
公开(公告)日：1999-02-02
申请号：US864738
申请日：1997-05-28
CPC分类号： C08F16/06 , C08F8/12 , C08F2800/10
摘要： A vinyl alcohol polymer with a side chain being a hydroxyalkyl group having 2 to 20 carbon atoms is disclosed. Conventional water-soluble vinyl alcohol polymers gives, where they have a high interfacial activity, an aqueous solution with much-foaming and hence a problem when used for commercial purposes. On the other hand, the vinyl alcohol polymer of the present invention gives, where it is water-soluble, an aqueous solution with less-foaming in spite of its high interfacial activity, and hence an excellent industrial applicability. The vinyl alcohol polymer of the present invention is useful as thermoplastic resin and dispersion stabilizer. In addition, the vinyl alcohol polymer of the present invention is usable for various purposes, e.g. surfactants for various uses, paper coating agent, quality-improving agent for paper such as paper ingredients and pigment binders, adhesive for wood, paper, aluminum foil and inorganic materials, binder for nonwoven fabric, paint, warp sizing agent, fiber-processingagent, sizing agent for hydrophobic fibers such as polyester fiber, various films and sheets, bottles and fibers.
摘要翻译： 公开了具有侧链为碳原子数2〜20的羟烷基的乙烯醇聚合物。 常规的水溶性乙烯醇聚合物在其具有高界面活性的情况下，具有大量起泡的水溶液，因此在用于商业目的时产生问题。 另一方面，本发明的乙烯醇聚合物尽管具有高的界面活性，但在水溶性的情况下给出了发泡少的水溶液，因此具有优异的工业实用性。 本发明的乙烯醇聚合物可用作热塑性树脂和分散稳定剂。 此外，本发明的乙烯醇聚合物可用于各种目的，例如， 用于各种用途的表面活性剂，纸张涂布剂，纸成分和颜料粘合剂等纸张质量改进剂，木材用粘合剂，纸，铝箔和无机材料，无纺布用粘合剂，油漆，经纱上浆剂，纤维加工剂， 疏水纤维如聚酯纤维，各种薄膜和片材，瓶子和纤维的上浆剂。
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公开(公告)号：US20080119623A1
公开(公告)日：2008-05-22
申请号：US12016479
申请日：2008-01-18
CPC分类号： C08F8/12 , C08F218/08 , C08F230/08
摘要： The present invention provides a method for producing a polymer by conducting polymerization in a polymerization reactor having an inner wall covered with an anti-fouling agent comprising an aqueous solution containing a polyvinyl alcohol obtained through saponification of a polyvinyl ester that contains monomer units having a silyl group. In the present invention, the polyvinyl alcohol satisfies the following formulae (I) and (II): 370
摘要翻译： 本发明提供一种聚合反应器的制造方法，该聚合反应器具有覆盖有防污垢剂的内壁的聚合反应器，该防污剂包含含有聚乙烯醇的水溶液，所述水溶液含有聚乙烯醇，所述聚乙烯醇含有具有甲硅烷基 组。 在本发明中，聚乙烯醇满足下式（I）和（II）：<？在线公式描述=“在线公式”end =“lead”？> 370
其中P表示聚乙烯醇的粘度平均聚合度，S表示单体单元的含量（摩尔％） 在聚乙烯醇中具有式（1）的甲硅烷基; <？in-line-formula description =“In-line formula”end =“lead”？> 0.2 / 100 <=（AB）/（B）<= 75/100（II）<？ =“In-line Formulas”end =“tail”？>其中A表示聚乙烯醇中的硅原子的含量（ppm），B表示用钠洗涤的聚乙烯醇中的硅原子的含量（ppm） 含氢氧化物的甲醇，然后通过索氏提取用甲醇洗涤。 -
公开(公告)号：US06472470B1
公开(公告)日：2002-10-29
申请号：US09452189
申请日：1999-12-02
IPC分类号： C08F812
CPC分类号： C08F8/12 , C08F2800/10 , C08F8/44 , C08F218/08 , C08F210/02 , C08F222/06
摘要： Vinyl alcohol polymers having an ethylene unit content of 2 to 19 mole %, a polymerization degree of 200 to 2,000, a degree of saponification of 80 to 99.99 mole % and a total content of carboxyl group and lactone rings of 0.02 to 0.4 mole % are excellent in thermal stability, water resistance, gas-barrier properties, water vapor-barrier property, stability of aqueous solution kept at low temperatures and biodegradability.
摘要翻译： 乙烯单元含量为2〜19摩尔％，聚合度为200〜2,000，皂化度为80〜99.99摩尔％，羧基和内酯环的总含量为0.02〜0.4摩尔％的乙烯醇聚合物为 热稳定性，耐水性，阻气性，水蒸汽阻隔性，保持在低温下的水溶液的稳定性和生物降解性优异。
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公开(公告)号：US07056977B2
公开(公告)日：2006-06-06
申请号：US10624588
申请日：2003-07-23
申请人： Takeshi Kusudou , Yousuke Kumaki , Naoki Fujiwara
发明人： Takeshi Kusudou , Yousuke Kumaki , Naoki Fujiwara
CPC分类号： C08F8/28 , C08F8/48 , Y10T428/3163 , Y10T428/31942 , C08F16/06
摘要： The invention provides a polyvinyl acetal having a degree of acetalization of from 45 to 80 mol %, which is obtained through acetalization of a polyvinyl alcohol having a degree of polymerization of from 30 to 1000 and a degree of hydrolysis of from 80.0 to 99.99 mol % and having a specific amount of an ionic group bonded to the terminal thereof via a sulfido bond. The polyvinyl acetal of the invention is useful for binders for ceramic forming and for binders for ink or paint.
摘要翻译： 本发明提供一种缩醛化度为45〜80摩尔％的聚乙烯醇缩醛，其通过聚合度为30〜1000，水解度为80.0〜99.99摩尔％的聚乙烯醇缩醛化而得到， 并且具有通过硫酸键与其末端键合的特定量的离子基团。 本发明的聚乙烯醇缩醛可用于陶瓷成型用粘合剂和用于油墨或油漆的粘合剂。
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公开(公告)号：US20050148736A1
公开(公告)日：2005-07-07
申请号：US11013402
申请日：2004-12-17
CPC分类号： C08F8/12 , C08F218/08 , C08F230/08
摘要： Disclosed is an anti-fouling agent which is superior in viscosity stability, water resistance of its film and ability of preventing a scale from depositing on the inner wall of a polymerization reactor and which can prevent the contamination of foreign substances into a polymeric product caused by exfoliation of a scale depositing on the inner wall of a polymerization reactor and exfoliation of the anti-fouling agent itself, the anti-fouling agent comprising an aqueous solution containing a polyvinyl alcohol that is obtained through saponification of a polyvinyl ester that contains monomer units having a specific silyl group and that satisfies the following formulae (I) and (II): 370
摘要翻译： 公开了一种抗粘结剂，其粘度稳定性，其膜的耐水性和防止水垢沉积在聚合反应器的内壁上并且能够防止外来物质被聚合产物污染的能力 在聚合反应器的内壁上沉积的垢的剥离和防污剂本身的剥离，防污剂包含含有聚乙烯醇的水溶液，所述水溶液是通过使含有单体单元的聚乙烯基酯皂化得到的， 特定的甲硅烷基，其满足下列式（I）和（II）：<？in-line-formula description =“In-line formula”end =“lead”？> 370
0.2 / 100 <=（AB）/（B）<= 75/100（II）<？ =“直列式”end =“tail”？>其中A表示聚乙烯醇中硅原子的含量（ppm），B表示用钠洗涤的聚乙烯醇中的硅原子的含量（ppm） 含氢氧化物的甲醇，然后通过索氏提取用甲醇洗涤。 -
9.发明申请POLYMER ELECTROLYTE MEMBRANE AND PROCESS FOR PREPARATION THEREOF, AND MEMBRANE-ELECTRODE ASSEMBLY AND POLYMER ELECTROLYTE FUEL CELL 有权聚合物电解质膜及其制备方法，以及膜电极组件和聚合物电解质燃料电池公开(公告)号：US20100098997A1
公开(公告)日：2010-04-22
申请号：US12523814
申请日：2008-01-11
申请人： Hiroyuki Ohgi , Tomohiro Ono , Shinji Nakai , Takeshi Nakano , Takeshi Kusudou , Naoki Fujiwara
发明人： Hiroyuki Ohgi , Tomohiro Ono , Shinji Nakai , Takeshi Nakano , Takeshi Kusudou , Naoki Fujiwara
IPC分类号： H01M8/10
CPC分类号： H01B1/122 , C08F8/12 , C08F293/005 , C08F2220/585 , C08F2800/20 , C08J5/2231 , C08J2331/04 , C08J2333/26 , C08J2387/00 , H01M8/1032 , H01M8/1067 , H01M8/1088 , H01M2300/0082 , Y02P70/56 , C08F218/08
摘要： A polymer electrolyte membrane comprising as a main ingredient a block copolymer (P) which comprises, as its constituents, a vinyl alcoholic polymer block (A) and a polymer block (B) having ion-conducting groups, which block copolymer(P) is cross-linking treated, and a membrane-electrode assembly and a fuel cell using the polymer electrolyte membrane, respectively. Preferred as polymer block (B) is one having a styrene or vinylnaphthalene skeleton or a 2-(meth)acrylamido-2-methylpropane skeleton. The ion-conducting group includes a sulfonic acid group, a phosphonic acid group or the like.
摘要翻译： 一种聚合物电解质膜，其包含嵌段共聚物（P）作为主要成分，所述嵌段共聚物（P）包含乙烯基醇聚合物嵌段（A）和具有离子传导性基团的聚合物嵌段（B）作为其组分，所述嵌段共聚物（P）为 交联处理，以及分别使用聚合物电解质膜的膜 - 电极组件和燃料电池。 聚合物嵌段（B）优选具有苯乙烯或乙烯基萘骨架或2-（甲基）丙烯酰胺基-2-甲基丙烷骨架。 离子传导性基团包括磺酸基，膦酸基等。
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公开(公告)号：US07439311B2
公开(公告)日：2008-10-21
申请号：US12016479
申请日：2008-01-18
CPC分类号： C08F8/12 , C08F218/08 , C08F230/08
摘要： The present invention provides a method for producing a polymer by conducting polymerization in a polymerization reactor having an inner wall covered with an anti-fouling agent comprising an aqueous solution containing a polyvinyl alcohol obtained through saponification of a polyvinyl ester that contains monomer units having a silyl group. In the present invention, the polyvinyl alcohol satisfies the following formulae (I) and (II): 370
摘要翻译： 本发明提供一种聚合反应器的制造方法，该聚合反应器具有覆盖有防污垢剂的内壁的聚合反应器，该防污剂包含含有聚乙烯醇的水溶液，所述水溶液含有聚乙烯醇，所述聚乙烯醇含有具有甲硅烷基 组。 在本发明中，聚乙烯醇满足下式（I）和（II）：<？在线公式描述=“在线公式”end =“lead”？> 370
其中P表示聚乙烯醇的粘度平均聚合度，S表示单体单元的含量（摩尔％） 在聚乙烯醇中具有式（1）的甲硅烷基; <？in-line-formula description =“In-line formula”end =“lead”？> 0.2 / 100 <=（AB）/（B）<= 75/100（II）<？ =“In-line Formulas”end =“tail”？>其中A表示聚乙烯醇中的硅原子的含量（ppm），B表示用钠洗涤的聚乙烯醇中的硅原子的含量（ppm） 含氢氧化物的甲醇，然后通过索氏提取用甲醇洗涤。
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