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公开(公告)号：US4010238A
公开(公告)日：1977-03-01
申请号：US452659
申请日：1974-03-19
IPC分类号： B01D53/94 , B01J23/22 , B01J23/26 , B01J23/84 , B01J23/847 , B01J27/198 , B01J27/199 , B01J8/00 , C01B21/00
CPC分类号： B01J23/8472 , B01D53/9418 , B01J23/22 , B01J23/26 , B01D2251/2062 , B01D2255/20707 , B01D2255/20723 , B01D2255/20738 , B01D2255/20746 , B01D2255/20753 , B01D2255/20761 , B01D2255/20784 , B01D2255/2094
摘要： A process for the selective removal of nitrogen oxides from waste gases containing nitrogen oxides, which comprises contacting the waste gases with a metal oxide catalyst having the following formula:V.sub.x A.sub.y O.sub.zwherein V is vanadium; A is at least one element selected from the group consisting of copper, zinc, tin, lead, titanium, phosphorus, chromium, iron, cobalt and nickel; x and y are each a numeral of 0.5 to 12; and z is a numeral of 1 to 60, at a temperature of 150.degree. to 800.degree. C in the presence of ammonia.
摘要翻译： 一种用于从含有氮氧化物的废气中选择性除去氮氧化物的方法，其包括使废气与具有下式的金属氧化物催化剂接触：
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公开(公告)号：US4003978A
公开(公告)日：1977-01-18
申请号：US515888
申请日：1974-10-18
摘要： A method for treating ammonia-containing gases for removing ammonia therefrom, which comprises contacting the ammonia-containing gases with a metal oxide catalyst having the following formula:Cr.sub.x A.sub.y O.sub.zwherein Cr is chromium; A is at least one element selected from the group consisting of tin, antimony, vanadium, cobalt, silver, zinc, nickel, titanium, molybdenum, tungsten, sulfur, phosphorus, boron, germanium and zirconium; x is a numeral of 4 to 12; y is a numeral of 0.2 to 8 and z is a numeral of 6.2 to 42, in a vapor phase at a temperature of from 200.degree. to 500.degree. C in the presence of molecular oxygen, and thereby the ammonia is oxidized to harmless nitrogen gas.
摘要翻译： 一种用于处理含氨气体以从其中除去氨的方法，其包括使含氨气体与具有下式的金属氧化物催化剂接触：
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公开(公告)号：US3970702A
公开(公告)日：1976-07-20
申请号：US529100
申请日：1974-12-03
申请人： Tatsuo Shiraishi , Susumu Kishiwada , Shinkichi Shimizu , Shigern Honmaru , Hiroshi Ichihashi , Yoshihiko Nagaoka
发明人： Tatsuo Shiraishi , Susumu Kishiwada , Shinkichi Shimizu , Shigern Honmaru , Hiroshi Ichihashi , Yoshihiko Nagaoka
CPC分类号： C07C45/35
摘要： A catalytic process for the preparation of acrolein by the vapor phase oxidation of propylene which comprises contacting propylene and oxygen with a catalyst composition comprising a catalyst system of the formula:Mo.sub.a Bi.sub.b Fe.sub.c X.sub.d Ni.sub.e Tl.sub.f P.sub.g O.sub.hwherein X is one or more of Mg, Mn and Co and a, b, c, d, e, f, g and h represent, respectively, the number of atoms wherein a is 12, b is 0.1 to 5, c is 0.1 to 5, d is 0 to 12, e is 0.1 to 12, f is 1 or less but not 0, g is 0 to 5 and h depends on the number of the other atoms and is usually from 36 to 89. Acrolein is produced with the use of said catalyst in a high selectivity and an excellent yield per each pass even at a large space velocity.
摘要翻译： 用于通过丙烯气相氧化制备丙烯醛的催化方法，其包括使丙烯和氧与催化剂组合物接触，所述催化剂组合物包含下式的催化剂体系：
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4.发明授权Selective removal of nitrogen oxides from waste gases using V-Mo-W catalysts 失效使用V-Mo-W催化剂从废气中选择性除去氮氧化物
公开(公告)号：US4071601A
公开(公告)日：1978-01-31
申请号：US662284
申请日：1976-02-27
CPC分类号： B01J23/30 , B01D53/9418 , B01J23/22 , B01J23/28 , B01D2251/2062 , B01D2255/20723 , B01D2255/20769 , B01D2255/20776
摘要： A process for selective removal of nitrogen oxides from waste gases containing 1,500 ppm or less (gas volume) of nitrogen oxides by contacting the waste gases with a metal oxide catalyst containing vanadium oxide and at least one of molybdenum oxide and tungsten oxide with an atomic ratio of the oxide forming elements of:V.sub.12-x-y Mo.sub.x W.sub.yWherein 0.ltoreq.x.ltoreq.8, 0.ltoreq.y.ltoreq.5 and 0.3.ltoreq.x + y.ltoreq.8, at a temperature of 150.degree. to 700.degree. C in the presence of 0.3 to 4 mol of ammonia (on the basis of 1 mol of the nitrogen oxides).
摘要翻译： 通过使废气与含有氧化钒和氧化钼和氧化钨中的至少一种的金属氧化物催化剂接触，从而从含有1500ppm以下（废气体积）的氮氧化物的废气中选择性除去氮氧化物的方法，其原子比 的氧化物形成元素：
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公开(公告)号：US4058547A
公开(公告)日：1977-11-15
申请号：US302882
申请日：1972-11-01
IPC分类号： B01J23/887 , B01J27/192 , C07C120/14
CPC分类号： C07C253/26 , B01J23/8876 , B01J27/192 , Y02P20/52
摘要： In the production of acrylonitrile by a vapor phase reaction of propylene, ammonia and oxygen at an elevated temperature, a process which comprises contacting propylene, ammonia and oxygen with a catalyst composition comprising a catalyst system of the formula: Tl.sub.a P.sub.b Mo.sub.c Fe.sub.d Bi.sub.e X.sub.f O.sub.g wherein X represents one or more of the metals, Ni, Mg and Co, and a, b, c, d, e, f and g represent respectively the relative number of atoms of each component; provided that when c is 12, a is 2 or less, but not 0; b is 0 to 5; d is 0.1 to 5; e is 0.1 to 5; f is 2 to 15; and the value of g depends on the number of the other atoms and is usually from 38.3 to 81.5.
摘要翻译： 在通过丙烯，氨和氧在升高的温度下的气相反应生产丙烯腈的过程中，包括使丙烯，氨和氧与包含下式催化剂体系的催化剂组合物接触的方法：其中X代表一个或多个 更多的金属，Ni，Mg和Co，以及a，b，c，d，e，f和g分别表示各成分的相对原子数。 条件是当c为12时，a为2或更小，但不为0; b为0〜5; d为0.1〜5; e为0.1〜5; f为2〜15; g的值取决于其他原子的数量，通常为38.3〜81.5。
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6.发明授权Selective removal of nitrogen oxides from waste gases containing sulfur oxides 失效从含硫氧化物的废气中选择性除去氮氧化物
公开(公告)号：US4075283A
公开(公告)日：1978-02-21
申请号：US491760
申请日：1974-07-25
IPC分类号： B01D53/94 , B01D53/86 , B01J21/04 , B01J23/24 , B01J23/28 , B01J23/30 , B01J8/00 , C01B21/00
CPC分类号： B01J23/24 , B01D53/8628
摘要： A process for the selective removal of nitrogen oxides from waste gases containing sulfur oxides as well as nitrogen oxides, which comprises contacting the waste gases with a catalyst comprising active metal oxides consisting of vanadium oxide and at least one of molybdenum oxide and tungsten oxide as a catalytically active component and .alpha.-alumina having a specific surface area of 0.3 to 12 m.sup.2 /g and a pore volume of 0.1 cm.sup.3 /g or more as a carrier wherein the atomic ratio of the vanadium, molybdenum, tungsten and aluminum contained in the carrier alumina isV.sub.12-x-y Mo.sub.x W.sub.y Al.sub.zwherein 0.ltoreq.x.ltoreq.8, 0.ltoreq.y.ltoreq.5, 0.3.ltoreq.x + y.ltoreq.8 and 40.ltoreq.z.ltoreq.480, in the presence of ammonia of 0.3 to 4 mol on the basis of 1 mol of nitrogen oxides contained in the waste gases at a temperature of 150.degree. to 700.degree. C.
摘要翻译： 一种用于从含有硫氧化物和氮氧化物的废气中选择性除去氮氧化物的方法，其包括使废气与包含由氧化钒和至少一种氧化钼和氧化钨组成的活性金属氧化物的催化剂接触，所述活性金属氧化物作为 催化活性成分和比表面积为0.3〜12m2 / g，孔体积为0.1cm3 / g以上的α-氧化铝作为载体，其中载体中所含的钒，钼，钨和铝的原子比 氧化铝是V12-x-yMoxWyAlz WHEREIN 0
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公开(公告)号：US3968166A
公开(公告)日：1976-07-06
申请号：US582077
申请日：1975-05-30
申请人： Tatsuo Shiraishi , Susumu Kishiwada , Shinkichi Shimizu , Shigeru Honmaru , Akihiko Atsumi , Hiroshi Ichihashi , Yoshihiko Nagaoka
发明人： Tatsuo Shiraishi , Susumu Kishiwada , Shinkichi Shimizu , Shigeru Honmaru , Akihiko Atsumi , Hiroshi Ichihashi , Yoshihiko Nagaoka
IPC分类号： B01J27/188 , B01J27/192 , C07C45/35 , C07C45/04
CPC分类号： B01J27/192 , B01J27/188 , C07C45/35
摘要： A process for the preparation of acrolein by the vapor phase catalytic oxidation of propylene which comprises contacting propylene and oxygen with a catalyst composition comprising a catalyst system of the formula:Mo.sub.a Bi.sub.b Fe.sub.c Ni.sub.d Tl.sub.e P.sub.f X.sub.g Y.sub.h O.sub.iWherein X is one or more of Mg, Mn and Co, Y is one or more of Cu, Ca, Sr, Zn, Cd, Sn and Pb and a, b, c, d, e, f, g, h and i represent respectively the number of atoms and, when a is 12, b is 0.1 to 5, c is 0.1 to 12, d is 0.1 to 12, e is 1 or less but not 0, f is 0 to 5, g is 0 to 12, h is 0.1 to 12 and i is a number determined by the valence requirements of the other atoms present and from 36.5 to 95.8, provided that b plus c is from 0.2 to 12.5 and d plus g plus h is from 0.2 to 27. The process can provide acrolein in a high selectivity and an excellent single pass yield even at a large space velocity of the propylene feed.
摘要翻译： 一种通过丙烯气相催化氧化制备丙烯醛的方法，该方法包括使丙烯与氧与催化剂组合物接触，所述催化剂组合物包括下式的催化剂体系：
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公开(公告)号：US3951861A
公开(公告)日：1976-04-20
申请号：US429947
申请日：1974-01-02
申请人： Tatsuo Shiraishi , Susumu Kishiwada , Shinkichi Shimizu , Shigeru Honmaru , Akihiko Atsumi , Hiroshi Ichihashi , Yoshihiko Nagaoka
发明人： Tatsuo Shiraishi , Susumu Kishiwada , Shinkichi Shimizu , Shigeru Honmaru , Akihiko Atsumi , Hiroshi Ichihashi , Yoshihiko Nagaoka
IPC分类号： B01J23/88 , B01J27/188 , B01J27/192 , B01J27/14 , B01J23/14
CPC分类号： B01J23/8873 , B01J23/8872 , B01J23/8874 , B01J23/8875 , B01J23/8876 , B01J27/188 , B01J27/192
摘要： A catalytic process for the preparation of acrolein by the vapor phase oxidation of propylene which comprises contacting propylene and oxygen with a catalyst composition comprising a catalyst system of the formula:Mo.sub.a Bi.sub.b Fe.sub.c Ni.sub.d Tl.sub.e P.sub.f X.sub.g Y.sub.h O.sub.i wherein X is one or more of Mg, Mn and Co, Y is one or more of Cu, Ca, Sr, Zn, Cd, Sn and Pb and a, b, c, d, e, f, g, h and i represent respectively the number of atoms, provided that, when a is 12, b is 0.1 to 5, c is 0.1 to 12, d is 0.1 to 12, e is 1 or less but not 0, f is 0 to 5, g is 0 to 12, h is 0.1 to 12 and i is from 36 to 112. By such a process, acrolein is produced in a high selectivity and an excellent yield per each pass even at a large space velocity.
摘要翻译： 用于通过丙烯气相氧化制备丙烯醛的催化方法，其包括使丙烯和氧与催化剂组合物接触，所述催化剂组合物包含下式的催化剂体系：
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9.发明授权
公开(公告)号：US3970739A
公开(公告)日：1976-07-20
申请号：US530302
申请日：1974-12-06
申请人： Tatsuo Shiraishi , Hiroshi Fukusen , Sachio Oishi , Shinkichi Shimizu , Hiroyuki Nishikawa , Tetsu Wakabayashi
发明人： Tatsuo Shiraishi , Hiroshi Fukusen , Sachio Oishi , Shinkichi Shimizu , Hiroyuki Nishikawa , Tetsu Wakabayashi
CPC分类号： B01D53/8628 , C01B3/025 , C02F1/586 , Y10S210/919
摘要： The process involves stripping ammonium nitrogens and organic materials, as gases, which are present in process waste waters to be discharged from plants wherein gases for use in ammonia synthesis are manufactured by reforming hydrocarbons with steam, decomposing the organic materials selectively in the presence of a catalyst at a temperature of about 120.degree. to 400.degree. C., mixing the remaining gases with the flue gases from said plants so as to provide a gaseous mixture having ammonia therein in an amount of about 0.3 to 10 moles per mole of nitrogen oxides present in the flue gases, reacting the gaseous mixture over a catalyst at a temperature of about 150.degree. to 700.degree. C. and oxidizing the unreacted ammonia, if any, in the presence of a catalyst at a temperature of about 150.degree. to 700.degree. C. to render the nocuous substances innocuous.
摘要翻译： 该方法包括剥离存在于工艺废水中的铵氮和有机材料，以从工厂排出的工业废气，其中用于氨合成的气体通过用蒸汽重整烃来制造，在有机物的存在下有选择地分解有机材料 催化剂，在约120-400℃的温度下，将剩余的气体与来自所述设备的烟道气混合，以提供其中具有氨的气体混合物，其量为每摩尔存在的氮氧化物约0.3至10摩尔 在烟道气中，在约150-700℃的温度下使催化剂上的气体混合物反应，并在催化剂存在下，在约150-700℃的温度下氧化未反应的氨（如果有的话） 使无害物质无害化。
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公开(公告)号：US4092354A
公开(公告)日：1978-05-30
申请号：US456270
申请日：1974-03-29
IPC分类号： B01J23/00 , B01J23/887 , C07B61/00 , C07C51/00 , C07C51/25 , C07C57/055 , C07C67/00 , C07C51/32
CPC分类号： B01J23/8877 , C07C51/252 , B01J2523/00
摘要： A process for production of acrylic acid by the gas phase catalytic oxidation of acrolein with molecular oxygen in the presence of a catalyst, characterized in that the catalyst is a metal oxide catalyst containing as the metal elements Mo, V, Cu and X in a ratio of 12 : 0.1-16 : 0.1-8 : 0.01-12 as the number of atoms (wherein X represents at least one element selected from the group consisting of Fe, Co, Ni and Mg), whereby acrylic acid can be produced at a greatly lowered reaction temperature in a markedly increased yield with an improved perpass yield.
摘要翻译： 一种在催化剂存在下通过气相催化氧化丙烯醛与分子氧生产丙烯酸的方法，其特征在于催化剂是一种金属氧化物催化剂，其中含有以Mo，V，Cu和X的比例的金属元素 作为原子数（其中X表示选自Fe，Co，Ni和Mg中的至少一种元素）的12：0.1-16：0.1-8：0.01-12，由此可以在 大大降低了反应温度，显着提高了产率，并提高了产量。
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