公开(公告)号：US5136015A

公开(公告)日：1992-08-04

申请号：US506956

申请日：1990-04-10

申请人： Tatsuo Yonemoto ,  Masahiro Matsumura ,  Yoshihisa Sugawa ,  Eiichiro Saito ,  Hiroshi Yamamoto ,  Keiko Kashihara

发明人： Tatsuo Yonemoto ,  Masahiro Matsumura ,  Yoshihisa Sugawa ,  Eiichiro Saito ,  Hiroshi Yamamoto ,  Keiko Kashihara

IPC分类号： C08J5/24 ,  B32B5/00 ,  B32B27/04 ,  C08G73/12 ,  H05K1/03

CPC分类号： C08J5/24 ,  B32B27/04 ,  C08G73/121 ,  H05K1/0346 ,  C08J2379/08 ,  Y10T428/31721

摘要： An addition type imide resin prepolymer is obtained by a reaction of unsaturated bisimide of 1.0 mol to diamine of 0.25 to 0.43 mol and an addition of polyamine having three or more benzene rings. The prepolymer is thereby made to contain substantially no unreacted diamine component which affects human body of operators, and to have remarkably excellent heat resistance and adhesive properties, while effective to restrain a production of any component of a molecular weight exceeding 15,000.

摘要翻译： 通过使1.0摩尔的不饱和双酰亚胺与二胺的摩尔比为0.25〜0.43摩尔，加入具有3个以上苯环的多胺，可以得到加成型酰亚胺树脂预聚物。 从而使预聚物基本上不含有影响操作者的人体的未反应的二胺成分，并且具有显着优异的耐热性和粘合性，同时有效地抑制任何分子量超过15,000的成分的生产。

公开(公告)号：US6143369A

公开(公告)日：2000-11-07

申请号：US773947

申请日：1996-12-30

申请人： Yoshihisa Sugawa ,  Yasuo Tohrin ,  Yoshinobu Marumoto ,  Joji Sakakibara ,  Ken-ichi Shinotani ,  Kohei Kotera ,  Kenji Ogasawara ,  Keiko Kashihara ,  Tomoaki Iwami

发明人： Yoshihisa Sugawa ,  Yasuo Tohrin ,  Yoshinobu Marumoto ,  Joji Sakakibara ,  Ken-ichi Shinotani ,  Kohei Kotera ,  Kenji Ogasawara ,  Keiko Kashihara ,  Tomoaki Iwami

IPC分类号： B29B15/12 ,  H05K1/03 ,  B05D1/36 ,  B05D1/18

CPC分类号： B29B15/122 ,  H05K1/0326

摘要： Process of impregnating a layer substrate having openings which is substantially defined by opposing two main surfaces with a resin composition in the form of liquid, and the process is characterized in that one of the main surfaces and the resin composition are kept in such a contact condition that the substrate is located on the resin composition. A prepreg and a laminate are also provided which are produced by the use of the substrate which has been prepared by the above process.

摘要翻译： 将具有基本上由相对的两个主表面限定的开口的层基材浸渍成液体形式的树脂组合物的工艺，其特征在于，主表面和树脂组合物中的一个保持在这样的接触条件 基材位于树脂组合物上。 还提供了通过使用通过上述方法制备的基材制备的预浸料和层压材料。

公开(公告)号：US4680377A

公开(公告)日：1987-07-14

申请号：US805989

申请日：1985-12-05

申请人： Masahiro Matsumura ,  Kenzi Ogasawara ,  Atsuhiro Nakamoto ,  Yoshihisa Sugawa

发明人： Masahiro Matsumura ,  Kenzi Ogasawara ,  Atsuhiro Nakamoto ,  Yoshihisa Sugawa

IPC分类号： B32B15/08 ,  B32B15/088 ,  B32B27/04 ,  C08G73/00 ,  C08G73/12 ,  C08J5/24 ,  C08K5/18 ,  C08K5/3415 ,  C08L79/08 ,  H01L23/538 ,  H05K1/03 ,  C08G73/10

CPC分类号： C08J5/24 ,  C08G73/121 ,  C08L79/08 ,  C08J2379/08 ,  H05K1/0346

摘要： Superior polyimide prepolymers particularly suitable for fabrication of multi-layer printed boards are produced by reacting unsaturated bisimides with diamines to consist essentially of 41-55% of unreacted reactants, 39-54% of components having a molecular weight of between 400 and 15,000, and 3.0-6.8% of components having a molecular weight of more than 15,000. The resulting prepolymers enable the preparation of their solution having enough working life for successfully impregnating a given substrate therewith in the preparation of prepregs. The prepregs, prepared from the above prepolymers in such a way as to contain within the resin content thereof 29-35% of unreacted reactants, 51-65% of the components having a molecular weight of between 400 and 15,000, and 5-14% of the components having a molecular weight of more than 15,000, allow the fabrication of laminate products with remarkable dimension stability under a low molding pressure to eliminate the presence of voids in the products, in addition to that the prepregs ensure a high bond strength as well as elongated working life which is responsible for prevention of a blister in the finished laminate and for easy control of the laminate forming process.

摘要翻译： 特别适用于制造多层印刷电路板的优异的聚酰亚胺预聚物是通过使不饱和双酰亚胺与二胺反应制得的，基本上由41-55％的未反应的反应物组成，39-54％的分子量为400至15,000的组分，以及 3.0-6.8％的分子量大于15,000的组分。 得到的预聚物使得它们的溶液的制备具有足够的使用寿命，用于在预浸料的制备中成功地浸渍给定的基材。 由上述预聚物制备的预浸料以含有29-35％未反应的反应物的树脂含量，51-65％的分子量为400至15,000的组分和5-14％ 的分子量大于15,000的组分，允许在低成型压力下制造具有显着尺寸稳定性的层压产品，以消除产品中空隙的存在，此外，预浸料还确保了高的粘结强度 作为延长的工作寿命，其负责防止成品层压体中的起泡，并且易于控制层压体形成过程。