摘要:
The disclosed is a dielectric ceramic composition in which dielectric particles 2a are formed. The dielectric particle 2a has a core 22a comprised of hexagonal barium titanate, and a shell 24a formed on an outer circumference of the core 22a and comprised of cubical or tetragonal barium titanate. The purpose of the present invention is to provide a new dielectric ceramic composition, in which permittivity is hardly lowered due to size effect, a good balance between high insulation resistance and permittivity can easily be achieved, and changes in insulation resistance and specific permittivity due to temperature are small; and an electronic component such as a multilayer ceramic capacitor using the dielectric ceramic composition as its dielectric layer.
摘要:
Dielectric ceramic composition includes a hexagonal type barium titanate as a main component shown by a generic formula (Bai-αMα)A(Ti1-βMnβ)BO3 and having hexagonal structure wherein an effective ionic radius of 12-coordinated “M” is −20% or more to +20% or less with respect to an effective ionic radius of 12-coordinated Ba2+ and the A, B, α and β satisfy relations of 0.900≦(A/B)≦1.040, 0.003≦α≦0.05, 0.03≦β≦0.2, and as subcomponents, with respect to the main component, certain contents of alkaline earth oxide such as MgO and the like, Mn3O4 and/or Cr2O3, CuO, Al2O3, rare earth element oxide and glass component including SiO2. According to the present invention, it can be provided the hexagonal type barium titanate powder and dielectric ceramic composition which are preferable for producing electronic components such as a capacitor and the like showing high specific permittivity, having advantageous insulation property and sufficient reliability.
摘要翻译:介电陶瓷组合物包括六方晶系钛酸钡作为主要成分,由通式(Bai-αMα)A(Ti1-&bgr; Mn&bgr))BO3表示,并具有六方结构,其中12配位“M”的有效离子半径为 相对于12配位Ba2 +和A,B,α和bgr的有效离子半径为-20%以上至+ 20%以下。 满足0.900&nlE的关系;(A / B)≦̸ 1.040,0.003≦̸α≦̸ 0.05,0.03≦̸&bgr≦̸ 0.2,作为副成分,对于主要成分,碱土金属氧化物的某些含量 MgO等,Mn 3 O 4和/或Cr 2 O 3,CuO,Al 2 O 3,稀土元素氧化物和包含SiO 2的玻璃成分。 根据本发明,可以提供六方晶系的钛酸钡粉末和电介质陶瓷组合物,该六方晶系钛酸钡粉末和电介质陶瓷组合物优选用于制造具有高比介电常数的诸如电容器等的电子部件,具有有利的绝缘性和足够的可靠性。
摘要:
A titanium-containing oxide glass having a bulky form and substantially having a chemical composition represented by the formula: (M1)1-x(M2)x(Ti1-y1(M3)y1)y2O2 [wherein M1 represents an element selected from Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Na and Ca; M2 represents at least one element selected from Mg, Ba, Ca, Sr, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Na, Sc, Y, Hf, Bi and Ag; M3 represents at least one element selected from V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, Nb, Mo, Ru, Rh, Pd, Al, Si, P, Ga, Ge, In, Sn, Sb and Te; and x, y1, y2 and z satisfy the following requirements: 0≦x≦0.5, 0≦y1