公开(公告)号：US20140065402A1

公开(公告)日：2014-03-06

申请号：US14016903

申请日：2013-09-03

Applicant: Technion Research and Development Foundation Ltd.

Inventor： Ran Yosef SUCKEVERIENE ,  Moshe NARKIS

IPC: H01B1/04 ,  H01B13/00

CPC classification number: H01B1/04 ,  B82Y30/00 ,  G06F3/044 ,  H01B1/24 ,  H01B13/0026 ,  H01L51/444 ,  Y10S977/742 ,  Y10S977/783 ,  Y10S977/788 ,  Y10S977/842 ,  Y10S977/897 ,  Y10T428/31663 ,  Y10T428/31765 ,  Y10T428/31786 ,  Y10T428/31993

Abstract: The present invention relates to hybrid electrically conducting systems comprising a matrix of a conducting polymer (polyaniline-PANI), and highly conducting carbonaceous nanoparticles, e.g., carbon nanotubes (CNT) or graphenes. The PANI/carbon nano-composites are prepared by a novel process comprising the steps of (a) polymerizing aniline and carbonaceous nanoparticles by inverse emulsion polymerization conducted under sonication, so as to obtain PANI/carbon nano-composites; (b) de-doping the PANI/carbon nano-composites obtained in step (a); (c) re-doping the PANI/carbon nano-composites obtained in step (b); and (d) forming a film from the re-doped PANI/carbon nano-composites. The PANI/carbon nano-composites are used for the preparation of thin, transparent, and conductive films which can be applied to a variety of substrates and used for commercial applications.

Abstract translation: 本发明涉及包含导电聚合物（聚苯胺-PANI）基质和高导电性碳质纳米颗粒例如碳纳米管（CNT）或石墨烯的混合导电体系。 PANI /碳纳米复合材料通过一种新方法制备，包括以下步骤：（a）通过在超声处理下进行的反相乳液聚合使苯胺和碳质纳米颗粒聚合，以获得PANI /碳纳米复合材料; （b）去掺杂步骤（a）中获得的PANI /碳纳米复合材料; （c）重新掺杂步骤（b）中获得的PANI /碳纳米复合材料; 和（d）从再掺杂的PANI /碳纳米复合材料形成膜。 PANI /碳纳米复合材料用于制备薄，透明和导电膜，可以应用于各种基材并用于商业应用。