公开(公告)号：US3935153A

公开(公告)日：1976-01-27

申请号：US566787

申请日：1975-04-10

申请人： Teizo Kudo ,  Yoshio Hashizume ,  Masatoshi Mikumo ,  Masanori Itoh

发明人： Teizo Kudo ,  Yoshio Hashizume ,  Masatoshi Mikumo ,  Masanori Itoh

IPC分类号： C08F279/02 ,  C08L25/06 ,  C08L51/04 ,  C08K5/11

CPC分类号： C08F279/02 ,  C08L25/06 ,  C08L51/04

摘要： Molding compositions having improved properties for low-pressure, low-shear molding techniques are prepared by carrying out a two-stage polymerization of an initial mixture comprising a polymerizable monomer selected from the group consisting of (1) a polymerizable aromatic monoalkenyl monomer or (2) a mixture of such aromatic monoalkenyl monomer with another polymerizable monovinyl monomer; in the presence of a butadiene rubber elastomer under bulk polymerization conditions, followed by suspension polymerization conditions; the process being characterized by the incorporation into the initial mixture of 1 to 10 wt. %, based on the polymerizable monomers, of a straight chain saturated polyester having an average molecular weight of 1,000 to 50,000.

摘要翻译： 通过进行包含选自（1）可聚合芳族单链烯基单体或（2）的可聚合单体的可聚合单体的初始混合物的两阶段聚合来制备具有改进的用于低压，低剪切模塑技术的性能的成型组合物 ）这种芳族单链烯基单体与另一种可聚合单乙烯基单体的混合物; 在本体聚合条件下在丁二烯橡胶弹性体存在下，随后进行悬浮聚合条件; 该方法的特征在于将初始混合物掺入1至10wt。 ％的基于可聚合单体的平均分子量为1,000至50,000的直链饱和聚酯。

公开(公告)号：US3954903A

公开(公告)日：1976-05-04

申请号：US513541

申请日：1974-10-10

申请人： Teizo Kudo ,  Yoshio Hashizume ,  Masanori Itoh ,  Makoto Shiga

发明人： Teizo Kudo ,  Yoshio Hashizume ,  Masanori Itoh ,  Makoto Shiga

IPC分类号： C08L67/00 ,  B29C31/00 ,  B29C41/00 ,  B29C41/04 ,  B29C41/52 ,  C08F279/00 ,  C08F279/04 ,  C08L7/00 ,  C08L21/00 ,  C08L25/00 ,  C08L51/00 ,  C08L51/02 ,  C08L55/02 ,  C08L67/06

CPC分类号： C08F279/04 ,  C08L55/02 ,  Y10S525/942

摘要： A new impact-resistant ABS resin composition is disclosed comprising (1) 100 parts by weight of a graft copolymer of vinyl aromatic monomer and vinyl cyanide monomer, said copolymer being grafted onto butadiene rubber particles of a size of from 0.5 to 2.0 .mu. dispersed in the graft copolymer and (2) 1 to 10 parts by weight of a straight chain saturated polyester having an average molecular weight of from 1000 to 50000. The composition is prepared by the bulk-suspension two stage polymerization of vinyl aromatic monomer and vinyl cyanide monomer in the presence of butadiene rubber component. The polyester is incorporated during either the bulk polymerization stage or the suspension polymerization stage, or it is blended with the ABS polymer after the two stage polymerization is completed.

摘要翻译： 公开了一种新的耐冲击ABS树脂组合物，其包含（1）100重量份的乙烯基芳族单体和乙烯基氰单体的接枝共聚物，所述共聚物接枝到尺寸为0.5至2.0μm的丁二烯橡胶颗粒上，分散在 接枝共聚物和（2）1至10重量份的平均分子量为1000-50000的直链饱和聚酯。该组合物通过乙烯基芳族单体和乙烯基氰单体的本体悬浮两阶段聚合制备 在丁二烯橡胶组分的存在下。 在本体聚合阶段或悬浮聚合阶段期间引入聚酯，或者在两阶段聚合完成后与ABS聚合物共混。

公开(公告)号：US4144287A

公开(公告)日：1979-03-13

申请号：US846352

申请日：1977-10-28

申请人： Teizo Kudo ,  Shoji Furukawa ,  Keizi Kubo

发明人： Teizo Kudo ,  Shoji Furukawa ,  Keizi Kubo

IPC分类号： C08L55/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L25/00 ,  C08L51/00 ,  C08L51/02 ,  C08L55/02 ,  C08L53/02

CPC分类号： C08L55/02

摘要： An impact-resistant resin composition comprises:100 parts by weight of a mixture of graft copolymers consisting of;50-90% by weight of a graft copolymer (A) obtained by polymerizing an aromatic monoalkenyl monomer and a vinyl cyan monomer in the presence of a diene type rubber component first under the bulk polymerization condition and subsequently continuing the polymerization under the suspension polymerization condition to substantially complete the polymerization, and having dispersed therein the rubber of an average particle size in the range of from 0.2 to 0.7 microns, and 10-50% by weight of a graft copolymer (B) obtained by polymerizing an aromatic monoalkenyl monomer, a vinyl cyan monomer and/or an alkyl ester monomer of acrylic acid or methacrylic acid in the presence of a diene type rubber latex under the emulsion polymerization condition; and3-30 parts by weight, based on 100 parts by weight of said mixture of said graft copolymers, of a chlorinated polyethylene having a degree of chlorination of from 25 to 45% by weight.

摘要翻译： 耐冲击树脂组合物包含：

公开(公告)号：US4150066A

公开(公告)日：1979-04-17

申请号：US851982

申请日：1977-11-16

申请人： Teizo Kudo ,  Shoji Furukawa

发明人： Teizo Kudo ,  Shoji Furukawa

IPC分类号： C08K5/136 ,  C08L55/02 ,  C08L51/04

CPC分类号： C08K5/136 ,  C08L55/02

摘要： A flame-retarding resin composition consists essentially of (A) a graft copolymer obtained by bulk and suspension-polymerizing an aromatic monoalkenyl monomer and a vinylcyano monomer and/or a monomeric alkyl ester of acrylic acid or methacrylic acid in the presence of a diene type rubber component, as an optional ingredient (B) a graft copolymer obtained by emulsion-polymerizing a monomeric mixture of the above mentioned monomers in the presence of a diene type rubber latex, (C) a chlorinated polyethylene having a degree of chlorination of 25 to 45 wt. %, (D) tetrabromo-bisphenol A or a derivative thereof and (E) antimony trioxide.

摘要翻译： 阻燃树脂组合物基本上由（A）在二烯型存在下，通过本体和芳族单烯基单体和乙烯基氰单体和/或丙烯酸或甲基丙烯酸的单体烷基酯进行悬浮聚合而获得的接枝共聚物 橡胶组分，作为任选的成分（B）通过在二烯型橡胶胶乳的存在下将上述单体的单体混合物乳液聚合而获得的接枝共聚物，（C）氯化度为25的氯化聚乙烯至 45重量％ ％，（D）四溴双酚A或其衍生物和（E）三氧化锑。