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公开(公告)号:US06399723B1
公开(公告)日:2002-06-04
申请号:US09619752
申请日:2000-07-19
申请人: Terry John Burkhardt , William T. Haygood, Jr. , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta , Udo M. Stehling , James R. Hart
发明人: Terry John Burkhardt , William T. Haygood, Jr. , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta , Udo M. Stehling , James R. Hart
IPC分类号: B01J3100
CPC分类号: C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , Y10S526/943 , C08F4/65927 , C08F2500/12 , C08F2500/03 , C08F2500/17 , C08F2500/15 , C08F2500/21
摘要: This invention relates to metallocene compositions and their use in the preparation of catalyst systems for olefin polymerization, particularly propylene polymerization. The metallocene compositions may be represented by the formula: wherein M1 is selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum and tungsten; R1 and R2 are identical or different, and are one of a hydrogen atom, a C1-C10 alkyl group, a C1-C10 alkoxy group, a C6-C10 aryl group, a C6-C10 aryloxy group, a C2-C40 alkenyl group, a C7-C40 arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, an OH group or a halogen atom, or a conjugated diene which is optionally substituted with one or more hydrocarbyl, tri(hydrocarbyl)silyl groups or tri(hydrocarbyl)silylhydrocarbyl groups, said diene having up to 30 atoms not counting hydrogen; R3 are identical or different and are each a hydrogen atom, a halogen atom, a C1-C10 alkyl group which may be halogenated, a C6-C10 aryl group which may be halogenated, a C2-C10 alkenyl group, a C7-C40-arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, a —NR′2, —SR′, —OR′, —OSiR′3 or —PR′2 radical, wherein R′ is one of a halogen atom, a C1-C10 alkyl group, or a C6-C10 aryl group; R4 to R7 are identical or different and are hydrogen, as defined for R3 or two or more adjacent radicals R5 to R7 together with the atoms connecting them form one or more rings; —B(R14)—, −Al(R14)—, —Ge—, —Sn—, —O—, —S—, —SO—, —SO2—, —N(R14)—, —CO—, —P(R14)—, or —P(O)(R14)—, or an amidoborane radical; wherein: R14, R15 and R16 are identical or different and are a hydrogen atom, a halogen atom, a C1-C20 alkyl group, a C1-C20 fluoroalkyl or silaalkyl group, a C6-C30 aryl group, a C6-C30 fluoroaryl group, a C1-C20 alkoxy group, a C2-C20 alkenyl group, a C7-C40 arylalkyl group, a C8-C40 arylalkenyl group, a C7-C40 alkylaryl group, or R14 and R15, together with the atoms binding them, form a cyclic ring; or, R13 is represented by the formula: wherein R17 to R24 are as defined for R1 and R2, or two or more adjacent radicals R17 to R24, including R20 and R21, together with the atoms connecting them form one or more rings; M2 is one or more carbons, silicon, germanium or tin; R8, R10 and R12 are identical or different and have the meanings stated for R4 to R7; R9 and R11 are identical or different and are a Group 14 radical having from 1 to 20 carbon atoms or are each primary, secondary or tertiary butyl groups, aryl groups, isopropyl groups, fluoroalkyl groups, trialkyl silyl groups, or other groups of similar size.
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公开(公告)号:US06380120B1
公开(公告)日:2002-04-30
申请号:US09619750
申请日:2000-07-19
申请人: Terry John Burkhardt , William T. Haygood, Jr. , Udo M. Stehling , James R. Hart , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta
发明人: Terry John Burkhardt , William T. Haygood, Jr. , Udo M. Stehling , James R. Hart , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta
IPC分类号: B01J3100
CPC分类号: C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , Y10S526/943 , C08F4/65927 , C08F2500/12 , C08F2500/03 , C08F2500/17 , C08F2500/15 , C08F2500/21
摘要: This invention relates to metallocene compositions and their use in the preparation of catalyst systems for olefin polymerization, particularly propylene polymerization. The metallocene compositions may be represented by the formula: wherein M1 is selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum and tungsten; R1 and R2 are identical or different, and are one of a hydrogen atom, a C1-C10 alkyl group, a C1-C10 alkoxy group, a C6-C10 aryl group, a C6-C10 aryloxy group, a C2-C40 alkenyl group, a C7-C40 arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, an OH group or a halogen atom, or a conjugated diene which is optionally substituted with one or more hydrocarbyl, tri(hydrocarbyl)silyl groups or hydrocarbyl, tri(hydrocarbyl)silylhydrocarbyl groups, said diene having up to 30 atoms not counting hydrogen; R3 are identical or different and are each a hydrogen atom, a halogen atom, a C1-C10 alkyl group which may be halogenated, a C6-C10 aryl group which may be halogenated, a C2-C10 alkenyl group, a C7-C40-arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, a —NR′2, —SR′, —OR′, —OSiR′3 or —PR′2 radical, wherein R′ is one of a halogen atom, a C1-C10 alkyl group, or a C6-C10 aryl group; R4 to R7 are identical or different and are hydrogen, as defined for R3 or two or more adjacent radicals R5 to R7 together with the atoms connecting them form one or more rings; —B(R14)—, —Al(R14)—, —Ge—, —Sn—, —O—, S—, —SO—, —SO2—, —N(R14)—, —CO—, —P(R14), or —P(O)(R14)—, or an amidoborane radical; wherein: R14, R15 and R16 are identical or different and are a hydrogen atom, a halogen atom, a C1-C20 allyl group, a C1-C20 fluoroalkyl or silaalkyl group, a C6-C30 aryl group, a C6-C30 fluoroaryl group, a C1-C20 alkoxy group, a C2-C20 alkenyl group, a C7-C40 arylalkyl group, a C8-C40 arylalkenyl group, a C7-C40 alkylaryl group, or R14 and R15, together with the atoms binding them, form a cyclic ring; or, R13 is represented by the formula: wherein R17 to R24 are as defined for R1 and R2, or two or more adjacent radicals R17 to R24, including R20 and R21, together with the atoms connecting them form one or more rings; M2 is one or more carbons, silicon, germanium or tin; R8, R10 and R12 are identical or different and have the meanings stated for R4 to R7; R9 and R11 are identical or different and are a Group 14A radical having from 1 to 20 carbon atoms or are each primary, secondary or tertiary butyl groups, aryl groups, isopropyl groups, fluoroalkyl groups, trialkyl silyl groups, or other groups of similar size.
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公开(公告)号:US06376411B1
公开(公告)日:2002-04-23
申请号:US09620302
申请日:2000-07-19
申请人: Terry John Burkhardt , William T. Haygood, Jr. , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta , Udo M. Stehling , James R. Hart
发明人: Terry John Burkhardt , William T. Haygood, Jr. , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta , Udo M. Stehling , James R. Hart
IPC分类号: B01J3100
CPC分类号: C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , Y10S526/943 , C08F4/65927 , C08F2500/12 , C08F2500/03 , C08F2500/17 , C08F2500/15 , C08F2500/21
摘要: This invention relates to metallocene compositions and their use in the preparation of catalyst systems for olefin polymerization, particularly propylene polymerization. The metallocene compositions may be represented by the formula: wherein M1 is selected from the group consisting of titanium, zirconium, hathium, vanadiurm, niobium, tantalum, chromium, molybdenum and tungsten; R1 and R2 are identical or different, and are one of a hydrogen atom, a C1-C10 alkyl group, a C1-C10 alkoxy group, a C6-C10 aryl group, a C6-C10 aryloxy group, a C2-C40 alkenyl group, a C7-C40 arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, an OH group or a halogen atom, or a conjugated diene or tri(hydrocarbyl)silylhydrocarbyl groups, said diene having up to 30 atoms not counting hydrogen; R3 are identical or different and are each a hydrogen atom, a halogen atom, a C1-C10 alkyl group which may be halogenated, a C6-C10 aryl group which may be halogenated, a C2-C10 alkenyl group, a C7-C40-arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, a —NR′2, —SR′, —OR′, —OSiR′3 or —PR′2 radical, wherein R′ is one of a halogen atom, a C1-C10 alkyl group, or a C6-C10 aryl group; R4 to R7 are identical or different and are hydrogen, as defined for R3 or two or more adjacent radicals R5 to R7 together with the atoms connecting them form one or more rings; —B(R14)—, —Al(R14)—, —Ge—, —Sn—, —O—, —S—, —SO—, —SO2—, —N(R14)—, —CO—, —P(R14)—, or —P(O)(R14)—, or an amidoborane radical; wherein: R14, R15and R16 are identical or different and are a hydrogen atom, a halogen atom, a C1-C20 alkyl group, a C1-C20 fluoroalkyl or silaalkyl group, a C6-C30 aryl group, a C6-C30 fluoroaryl group, a C1-C20 alkoxy group, a C2-C20 alkenyl group, a C7-C40 arylalkyl group, a C8-C40 arylalkenyl group, a C7-C40 alkylaryl group, or R14 and R15, together with the atoms binding them, form a cyclic ring; or, R13 is represented by the formula: wherein R17 to R24 are as defined for R1 and R2, or two or more adjacent radicals R17 to R24, including R20 and R21, together with the atoms connecting them form one or more rings; M2 is one or more carbons, silicon, germanium or tin; R8, R10 and R12 are identical or different and have the meanings stated for R4 to R7; R9 and R11 are identical or different and are a Group 14 radical having from 1 to 20 carbon atoms or are each primary, secondary or tertiary butyl groups, aryl groups, isopropyl groups, fluoroalkyl groups, trialkyl silyl groups, or other groups of similar size.
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公开(公告)号:US06376412B1
公开(公告)日:2002-04-23
申请号:US09620304
申请日:2000-07-19
申请人: Terry John Burkhardt , William T. Haygood, Jr. , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta , Udo M. Stehling , James R. Hart
发明人: Terry John Burkhardt , William T. Haygood, Jr. , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta , Udo M. Stehling , James R. Hart
IPC分类号: B01J3100
CPC分类号: C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , Y10S526/943 , C08F4/65927 , C08F2500/12 , C08F2500/03 , C08F2500/17 , C08F2500/15 , C08F2500/21
摘要: This invention relates to metallocene compositions and their use in the preparation of catalyst systems for olefin polymerization, particularly propylene polymerization. The metallocene compositions may be represented by the formula: wherein M1 is selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum and tungsten; R1 and R2 are identical or different, and are one of a hydrogen atom, a C1-C10 alkyl group, a C1-C10 alkoxy group, a C6-C10 aryl group, a C6-C10 aryloxy group, a C2-C40 alkenyl group, a C7-C40 arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, an OH group or a halogen atom, or a conjugated diene which is optionally substituted with one or more hydrocarbyl, tri(hydrocarbyl)silyl groups or hydrocarbyl, tri(hydrocarbyl)silylhydrocarbyl groups, said diene having up to 30 atoms not counting hydrogen; R3 are identical or different and are each a hydrogen atom, a halogen atom, a C1-C10 alkyl group which may be halogenated, a C6-C10 aryl group which may be halogenated, a C2-C10 alkenyl group, a C7-C40 -arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, a —NR′2, —SR′, —OR′, —OSiR′3 or —PR′2 radical, wherein R is one of a halogen atom, a C1-C10 alkyl group, or a C6-C10 aryl group; R4 to R7 are identical or different and are hydrogen, as defined for R3 or two or more adjacent radicals R5 to R7 together with the atoms connecting them form one or more rings; R13 is —B(R14)—, —Al(R14)—, —Ge—, —Sn—, —O—, —S—, —SO—, —SO2—, —N(R14)—, —CO—, —P(R14)—, or —P(O)(R14)—, or an amidoborane radical; wherein: R14, R15 and R16 are identical or different and are a hydrogen atom, a halogen atom, a C1-C20 alkyl group, a C1-C20 fluoroalkyl or silaalkyl group, a C6-C30 aryl group, a C6-C30 fluoroaryl group, a C1-C20 alkoxy group, a C2-C20 alkenyl group, a C7-C40 arylalkyl group, a C8-C40 arylalkenyl group, a C7-C40 alkylaryl group, or R14 and R15, together with the atoms binding them, form a cyclic ring; or, R13 is represented by the formula: wherein R17 to R24 are as defined for R1 and R2, or two or more adjacent radicals R17 to R24, including R20 and R21, together with the atoms connecting them form one or more rings; M2 is one or more carbons, silicon, germanium or tin; R8, R10 and R12 are identical or different and have the meanings stated for R4 to R7; R9 and R11 are identical or different and are a Group 14 radical having from 1 to 20 carbon atoms or are each primary, secondary or tertiary butyl groups, aryl groups, isopropyl groups, fluoroalkyl groups, trialkyl silyl groups, or other groups of similar size.
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公开(公告)号:US06376407B1
公开(公告)日:2002-04-23
申请号:US09619749
申请日:2000-07-19
申请人: Terry John Burkhardt , William T. Haygood, Jr. , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta , Udo M. Stehling , James R. Hart
发明人: Terry John Burkhardt , William T. Haygood, Jr. , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta , Udo M. Stehling , James R. Hart
IPC分类号: B01J3100
CPC分类号: C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , Y10S526/943 , C08F4/65927 , C08F2500/12 , C08F2500/03 , C08F2500/17 , C08F2500/15 , C08F2500/21
摘要: This invention relates to metallocene compositions and their use in the preparation of catalyst systems for olefin polymerization, particularly propylene polymerization. The metallocene compositions may be represented by the formula: wherein M1 is selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum and tungsten; R1 and R2 are identical or different, and are one of a hydrogen atom, a C1-C10 alkyl group, a C1-C10 alkoxy group, a C6-C10 aryl group, a C6-C10 aryloxy group, a C2-C40 alkenyl group, a C7-C40 arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, an OH group or a halogen atom, or a conjugated diene which is optionally substituted with one or more hydrocarbyl, tri(hydrocarbyl)silyl groups or tri(hydrocarbyl)silylhydrocarbyl groups, said diene having up to 30 atoms not counting hydrogen; R3 are identical or different and are each a hydrogen atom, a halogen atom, a C1-C10 alkyl group which may be halogenated, a C6-C10 aryl group which may be halogenated, a C2-C10 alkenyl group, a C7-C40-arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, a —NR′2, —SR′, —OR′, —OSiR′3 or —PR′2 radical, wherein R′ is one of a halogen atom, a C1-C10 alkyl group, or a C6-C10 aryl group; R4 to R7 are identical or different and are hydrogen, as defined for R3 or two or more adjacent radicals R5 to R7 together with the atoms connecting them form one or more rings; R13 is —B(R14)—, —Al(R14—), —Ge—, —Sn—, —O—, —S—, —SO—, —SO2—, —N(R14)—, —CO—, —P(R14)—, or —P(O)(R14)—, or an amidoborane radical; wherein: R14, R15 and R16 are identical or different and are a hydrogen atom, a halogen atom, a C1-C20 alkyl group, a C1-C20 fluoroalkyl or silaalkyl group, a C6-C30 aryl group, a C6-C30 fluoroaryl group, a C1-C20 alkoxy group, a C2-C20 alkenyl group, a C7-C40 arylalkyl group, a C8-C40 arylalkenyl group, a C7-C40 alkylaryl group, or R14 and R15, together with the atoms binding them, form a cyclic ring; or, R13 is represented by the formula: wherein R17 to R24 are as defined for R1 and R2, or two or more adjacent radicals R17 to R24, including R20 and R21, together with the atoms connecting them form one or more rings; M2 is one or more carbons, silicon, germanium or tin; R8, R10 and R12 are identical or different and have the meanings stated for R4 to R7; R9 and R11 are identical or different and are a Group 14 radical having from 1 to 20 carbon atoms or are each primary, secondary or tertiary butyl groups, aryl groups, isopropyl groups, fluoroalkyl groups, trialkyl silyl groups, or other groups of similar size.
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公开(公告)号:US06414095B1
公开(公告)日:2002-07-02
申请号:US09620303
申请日:2000-07-19
申请人: Terry John Burkhardt , William T. Haygood, Jr. , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta , Udo M. Stehling , James R. Hart
发明人: Terry John Burkhardt , William T. Haygood, Jr. , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta , Udo M. Stehling , James R. Hart
IPC分类号: C08F494
CPC分类号: C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , Y10S526/943 , C08F4/65927 , C08F2500/12 , C08F2500/03 , C08F2500/17 , C08F2500/15 , C08F2500/21
摘要: This invention relates to metallocene compositions and their use in the preparation of catalyst systems for olefin polymerization, particularly propylene polymerization The metallocene compositions may be represented by the formula: wherein M1 is selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum and tungsten; R1 and R2 are identical or different, and are one of a hydrogen atom, a C1-C10 alkyl group, a C1-C10 alkoxy group, a C6-C10 aryl group, a C6-C10 aryloxy group, a C2-C40 alkenyl group, a C7-C40 arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, an OH group or a halogen atom or a conjugated diene which is optionally substituted with one or more hydrocarbyl, tri(hydrocarbyl)silyl groups or tri(hydrocarbyl)silylhydrocarbyl groups, said diene having up to 30 atoms not counting hydrogen; R3 are identical or different and are each a hydrogen atom, a halogen atom, a C1-C10 alkyl group which may be halogenated, a C6-C10 aryl group which may be halogenated, a C2-C10 alkenyl group, a C7-C40-arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, a —NR′2, —SR′, —OR′, —OSiR′3 or —PR′2 radical, wherein R is one of a halogen atom, a C1-C10 alkyl group, or a C6-C10 aryl group; R4 to R7 are identical or different and are hydrogen, as defined for R3 or two or more adjacent radicals R5 to R7 together with the atoms connecting them form one or more rings; R13 is —B(R14)—, —Al(R14)—, —Ge—, —Sn—, —O—, —S—, —SO—, —SO2—, —N(R14)—, —CO—, —P(R14)—, or P(O)(R14)—, or an amidoborane radical; wherein: R14, R15and R16 are identical or different and are a hydrogen atom, a halogen atom, a C1-C20 alkyl group, a C1-C20 fluoroalkyl or silaalkyl group, a C6-C30 aryl group, a C6-C30 fluoroaryl group, a C1-C20 alkoxy group, a C2-C20 alkenyl group, a C7-C40 arylalkyl group, a C8-C40 arylalkenyl group, a C7-C40 alkylaryl group, or R14 and R15, together with the atoms binding them, form a cyclic ring; or, R13 is represented by the formula: wherein R17 to R24 are as defined for R1 and R2, or two or more adjacent radicals R17 to R24, including R20 and R21, together with the atoms connecting them form one or more rings; M2 is one or more carbons, silicon, germanium or tin; R8, R10 and R12 are identical or different and have the meanings stated for R4 to R7; R9 and R11 are identical or different and are a Group 14 radical having from 1 to 20 carbon atoms or are each primary, secondary or tertiary butyl groups, aryl groups, isopropyl groups, fluoroalkyl groups, triallyl silyl groups, or other groups of similar size.
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公开(公告)号:US06825372B2
公开(公告)日:2004-11-30
申请号:US10061972
申请日:2002-01-31
申请人: Terry John Burkhardt , William T. Haygood, Jr. , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta , Udo M. Stehling , James R. Hart
发明人: Terry John Burkhardt , William T. Haygood, Jr. , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta , Udo M. Stehling , James R. Hart
IPC分类号: C07F900
CPC分类号: C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , Y10S526/943 , C08F4/65927 , C08F2500/12 , C08F2500/03 , C08F2500/17 , C08F2500/15 , C08F2500/21
摘要: This invention relates to metallocene compositions and their use in the preparation of catalyst systems for olefin polymerization, particularly propylene polymerization. The metallocene compositions may be represented by the formula: wherein R9 and R11 are identical or different and are a Group 14 radical having from 1 to 20 carbon atoms or are each primary, secondary or tertiary butyl groups, aryl groups, isopropyl groups, fluoroalkyl groups, trialkyl silyl groups, or other groups of similar size.
摘要翻译: 本发明涉及茂金属组合物及其在制备用于烯烃聚合的催化剂体系,特别是丙烯聚合中的用途。 金属茂组合物可以由下式表示:其中R 9和R 11相同或不同,并且是具有1至20个碳原子的第14族基团或者各自为伯,仲或叔丁基,芳基 异丙基,氟代烷基,三烷基甲硅烷基或其他相似尺寸的基团。
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公开(公告)号:US06380330B1
公开(公告)日:2002-04-30
申请号:US09620198
申请日:2000-07-19
申请人: Terry John Burkhardt , William T. Haygood, Jr. , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta , Udo M. Stehling , James R. Hart
发明人: Terry John Burkhardt , William T. Haygood, Jr. , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta , Udo M. Stehling , James R. Hart
IPC分类号: B01J3100
CPC分类号: C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , Y10S526/943 , C08F4/65927 , C08F2500/12 , C08F2500/03 , C08F2500/17 , C08F2500/15 , C08F2500/21
摘要: This invention relates to metallocene compositions and their use in the preparation of catalyst systems for olefin polymerization, particularly propylene polymerization. The metallocene compositions may be represented by the formula: wherein M1 is selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium tantalum, chromium, molybdenum and tungsten; R1 and R2 are identical or different, and are one of a hydrogen atom, a C1-C10 alkyl group, a C1-C10 alkoxy group, a C6-C10 aryl group, a C6-C10 aryloxy group, a C2-C40 alkenyl group, a C7-C40 arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, an OH group or a halogen atom, or a conjugated diene which is optionally substituted with one or more hydrocarbyl, tri(hydrocarbyl)silyl groups or tri(hydrocarbyl)silylhydrocarbyl groups, said diene having up to 30 atoms not counting hydrogen; R3 are identical or different and are each a hydrogen atom, a halogen atom, a C1-C10 alkyl group which may be halogenated, a C6-C10 aryl group which may be halogenated, a C2-C10 alkenyl group, a C7-C40-arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, a —NR′2, —SR′, —OR′, —OSiR′3 or —PR′2 radical, wherein R′ is one of a halogen atom, a C1-C10 alkyl group, or a C6-C10 aryl group; R4 to R7 are identical or different and are hydrogen, as defined for R3 or two or more adjacent radicals R5 to R7 together with the atoms connecting them form one or more rings; —B(R14)—, —Al(R14)—, —Ge—, —Sn—, —O—, —S—, —SO—, —SO2—, —N(R14)—, —CO—, —P(R14)—, or —P(O)(R14)—, or an amidoborane radical; wherein: R14, R15 and R16 are identical or different and are a hydrogen atom, a halogen atom, a C1-C20 alkyl group, a C1-C20 fluoroalkyl or silaalkyl group, a C6-C30 aryl group, a C6-C30 fluoroaryl group, a C1-C20 alkoxy group, a C2-C20 alkenyl group, a C7-C40 arylalkyl group, a C8-C40 arylalkenyl group, a C7-C40 alkylaryl group, or R14 and R15, together with the atoms binding them, form a cyclic ring; or, R13 is represented by the formula: wherein R17 to R24 are as defined for R1 and R2, or two or more adjacent radicals R17 to R24, including R20 and R21, together with the atoms connecting them form one or more rings; M2 is one or more carbons, silicon, germanium or tin; R8, R10 and R12 are identical or different and have the meanings stated for R4 to R7; R9 and R11 are identical or different and are a Group 14 radical having from 1 to 20 carbon atoms or are each primary, secondary or tertiary butyl groups, aryl groups, isopropyl groups, fluoroalkyl groups, trialkyl silyl groups, or other groups of similar size.
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公开(公告)号:US06380124B1
公开(公告)日:2002-04-30
申请号:US09620522
申请日:2000-07-19
申请人: Terry John Burkhardt , William T. Haygood, Jr. , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta , Udo M. Stehling , James R. Hart
发明人: Terry John Burkhardt , William T. Haygood, Jr. , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta , Udo M. Stehling , James R. Hart
IPC分类号: B01J3100
CPC分类号: C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , Y10S526/943 , C08F4/65927 , C08F2500/12 , C08F2500/03 , C08F2500/17 , C08F2500/15 , C08F2500/21
摘要: This invention relates to metallocene compositions and their use in the preparation of catalyst systems for olefin polymerization, particularly propylene polymerization. The metallocene compositions may be represented by the formula: wherein M1 is selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum and tungsten; R1 and R2 are identical or different, and are one of a hydrogen atom, a C1-C10 alkyl group, a C1-C10 alkoxy group, a C6-C10 aryl group, a C6-C10 aryloxy group, a C2-C40 alkenyl group, a C7-C40 arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, an OH group or a halogen atom, or a conjugated diene which is optionally substituted with one or more hydrocarbyl, tri(hydrocarbyl)silyl groups or tri(hydrocarbyl)silylhydrocarbyl groups, said diene having up to 30 atoms not counting hydrogen; R3are identical or different and are each a hydrogen atom, a halogen atom, a C1-C10 alkyl group which may be halogenated, a C6-C10 aryl group which may be halogenated, a C2-C10 alkenyl group, a C7-C40-arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, a —NR′2, —SR′, —OR′, —SiR′3 or —PR′2 radical, wherein R′ is one of a halogen atom, a C1-C10 alkyl group, or a C6-C10 aryl group; R4 to R7 are identical or different and are hydrogen, as defined for R3or two or more adjacent radicals R5to R7 together with the atoms connecting them form one or more rings; R13 is —B(R14)—, —Al(R14)—, —Ge—, —Sn—, —O—, —S—, —SO—, —SO2—, —N(R14)—, —CO—, —P(R14)—, or —P(O)(R14)—, or amidoborane radical; wherein: R14, R15and R16 are identical or different and are a hydrogen atom, a halogen atom, a C1-C20 alkyl group, a C1-C20 fluoroalkyl or silaalkyl group, a C6-C30 aryl group, a C6-C30 fluoroaryl group, C1-C20 alkoxy group, a C2-C20 alkenyl group, a C7-C40 arylalkyl group, a C8-C40 arylalkenyl group, a C7-C40 alkylaryl group, or R14 and R15, together with the atoms binding them, form a cyclic ring; or, R13is represented by the formula: wherein R17 to R24 are as defined for R1 and R2, or two or more adjacent radicals R17 to R24, including R20 and R21, together with the atoms connecting them form one or more rings; M2 is one or more carbons, silicon, germanium or tin; R8, R10 and R12 are identical or different and have the meanings stated for R4 to R7; R9 and R11 are identical or different and are a Group 14 radical having from 1 to 20 carbon atoms or are each primary, secondary or tertiary butyl groups, aryl groups, isopropyl groups, fluoroalkyl groups, trialkyl silyl groups, or other groups of similar size.
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公开(公告)号:US06376409B1
公开(公告)日:2002-04-23
申请号:US09619764
申请日:2000-07-19
申请人: Terry John Burkhardt , William T. Haygood, Jr. , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta , Udo M. Stehling , James R. Hart
发明人: Terry John Burkhardt , William T. Haygood, Jr. , Robert Tan Li , James Charles Vizzini , Matthew Cornyn Kuchta , Udo M. Stehling , James R. Hart
IPC分类号: B01J3100
CPC分类号: C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , Y10S526/943 , C08F4/65927 , C08F2500/12 , C08F2500/03 , C08F2500/17 , C08F2500/15 , C08F2500/21
摘要: This invention relates to metallocene compositions and their use in the preparation of catalyst systems for olefin polymerization, particularly propylene polymerization. The metallocene compositions may be represented by the formula: wherein M1 is selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum and tungsten; R1 and R2 are identical or different, and are one of a hydrogen atom, a C1-C10 alkyl group, a C1-C10 alkoxy group, a C6-C10 aryl group, a C6-C10 aryloxy group, a C2-C40 alkenyl group, a C7-C40 arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, an OH group or a halogen atom, or a conjugated diene which is optionally substituted with one or more hydrocarbyl, tri(hydrocarbyl)silyl groups or tri(hydrocarbyl)silylhydrocarbyl groups, said diene having up to 30 atoms not counting hydrogen; R3 are identical or different and are each a hydrogen atom, a halogen atom, a C1-C10 alkyl group which may be halogenated, a C6-C10 aryl group which may be halogenated, a C2-C10 alkenyl group, a C7-C40-arylalkyl group, a C7-C40 alkylaryl group, a C8-C40 arylalkenyl group, a —NR′2, —SR′, —OR′, —OSiR′3 or —PR′2 radical, wherein R′ is one of a halogen atom, a C1-C10 alkyl group, or a C6-C10 aryl group; R4 to R7 are identical or different and are hydrogen, as defined for R3 or two or more adjacent radicals R5 to R7 together with the atoms connecting them form one or more rings; R13 is —B(R14)—, —Al(R14)—, —Ge—, —Sn—, —O—, —S—, —SO—, —SO2—, —N(R14)—, —CO—, —P(R14)—, or —P(O)(R14)—, or an amidoborane radical; wherein: R14, R15 and R16 are identical or different and are a hydrogen atom, a halogen atom, a C1-C20 alkyl group, a C1-C20 fluoroalkyl or silaalkyl group, a C6-C30 aryl group, a C6-C30 fluoroaryl group, a C1-C20 alkoxy group, a C2-C20 alkenyl group, a C7-C40 arylalkyl group, a C8-C40 arylalkenyl group, a C7-C40 alkylaryl group, or R14 and R15, together with the atoms binding them, form a cyclic ring; or, R13 is represented by the formula: wherein R17 to R24 are as defined for R1 and R2, or two or more adjacent radicals R17 to R24, including R20 and R21, together with the atoms connecting them form one or more rings; M2 is one or more carbons, silicon, germanium or tin; R8, R10 and R12 are identical or different and have the meanings stated for R4 to R7; R9 and R11 are identical or different and are a Group 14 radical having from 1 to 20 carbon atoms or are each primary, secondary or tertiary butyl groups, aryl groups, isopropyl groups, fluoroalkyl groups, trialkyl silyl groups, or other groups of similar size.
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