Process for preparing carbonaceous material carrying ultrafinely dispersed metal
    2.
    发明授权
    Process for preparing carbonaceous material carrying ultrafinely dispersed metal 失效
    制备含有超细分散金属的碳质材料的方法

    公开(公告)号:US06194344B1

    公开(公告)日:2001-02-27

    申请号:US09414288

    申请日:1999-10-07

    IPC分类号: B01J2118

    摘要: A process for the preparation of a high-softening-point pitch rich in mesopores having a softening point measured by temperature gradient method of 150° C. or higher, a weight loss by heating up to 300° C. of 5 wt. % or less and mesopores of 100 mm3/g or greater, in terms of minute pore volume calculated by the Dollimore-Heal method, and a process for making carbonaceous materials carrying metal thereon are disclosed. The high-softening-point pitch rich in mesopores can easily provide carbonaceous material carrying metal thereon by using no oxidizing agent such as nitric acid, and, therefore, the high-softening-point pitch rich in mesopores is especially suitable for the production of carbonaceous materials carrying metal thereon or highly crystalline graphitized carbonaceous materials in a short heating time. The process for the production of a high-softening-point pitch rich in mesopores comprises forming micro-shaped carbonaceous materials having a size of 100 &mgr;m or less, and contacting the micro-shaped carbonaceous materials with an extracting organic solvent so as to remove 20-90 wt. % of light components from the micro-shaped carbonaceous materials. A carbonaceous material carrying metal thereon can easily be prepared by contacting the high-softening point pitch rich in mesopores with an aqueous solution of an anionic surface active agent, and then contacting the material treated with the surface active agent with an aqueous solution of metal salts.

    摘要翻译: 制备富含中温孔的高软化点沥青的方法,其具有通过温度梯度法测定的软化点为150℃以上,通过加热至300℃的重量减少为5重量% %以下,中孔为100mm 3 / g以上,以通过Dollimore-Heal法计算的微细孔容积,以及在其上载持金属的碳质材料的制造方法。 富含中孔的高软化点沥青可以容易地通过不使用硝酸等氧化剂提供携带金属的碳质材料,因此,富孔介质的高软化点沥青特别适用于生产碳质 在短时间内在其上携带金属的材料或高度结晶的石墨化碳质材料。 用于生产富中孔的高软化点沥青的方法包括形成尺寸为100μm或更小的微型碳质材料,并使微型碳质材料与萃取有机溶剂接触以除去20 -90重量% 来自微型碳质材料的轻组分的%。 通过使富含中孔的高软化点沥青与阴离子表面活性剂的水溶液接触,然后使用表面活性剂处理的材料与金属盐水溶液接触,可容易地制备载有金属的碳质材料 。