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    Organic dye compound having both pyridiniotriazinyl and vinylsulfone type fiber-reactive groups
    1.
    发明授权
    Organic dye compound having both pyridiniotriazinyl and vinylsulfone type fiber-reactive groups 失效
    具有吡啶并三嗪基和乙烯基砜型纤维反应性基团的有机染料化合物

    公开(公告)号：US4626589A

    公开(公告)日：1986-12-02

    申请号：US699182

    申请日：1985-02-07

    申请人： Takashi Omura ,  Yutaka Kayane ,  Mikoto Takahashi ,  Tetsuya Miyamoto ,  Akira Takeshita ,  Naoki Harada ,  Katsumasa Otake

    发明人： Takashi Omura ,  Yutaka Kayane ,  Mikoto Takahashi ,  Tetsuya Miyamoto ,  Akira Takeshita ,  Naoki Harada ,  Katsumasa Otake

    IPC分类号： C09B62/002 ,  C09B62/04 ,  C09B62/44 ,  C09B62/503 ,  D06P1/38 ,  C09B44/02 ,  C09B44/08 ,  C09B62/523 ,  C09B62/527

    CPC分类号： C09B62/4403 ,  D06P1/38

    摘要： A compound of the formula, ##STR1## wherein D is an organic dye moiety, R.sub.1 and R.sub.2 are independently hydrogen or a substituted or unsubstituted lower alkyl group, R.sub.3 is hydrogen or a substituted or unsubstituted lower alkyl, phenyl or naphthyl group, X.sub.1 and X.sub.2 are independently hydrogen, halogen or a lower alkyl, cyano, carbamoyl, vinyl, .beta.-hydroxyethyl, .beta.-sulfoethyl, .beta.-sulfatoethyl, carboxyl, carboxylic acid ester or sulfonic acid group, and Z is appended to the above-defined D or R.sub.3 and stands for --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Y, in which Y is a group capable of being split by the action of an alkali, which is useful for dyeing hydroxyl or amido group-containing fiber materials with excellent build-up properties, thereby giving dyed products having excellent various fastness properties.

    摘要翻译： 下式的化合物，其中D是有机染料部分，R1和R2独立地是氢或取代或未取代的低级烷基，R3是氢或取代或未取代的低级烷基，苯基或萘基，X1和 X 2独立地是氢，卤素或低级烷基，氰基，氨基甲酰基，乙烯基，β-羟基乙基，β-磺基乙基，β-磺基乙基，羧基，羧酸酯或磺酸基，并且Z附加到上述定义的D或 R3代表-SO2CH = CH2或-SO2CH2CH2Y，其中Y是能够通过碱的作用分裂的基团，其可用于染色具有优异累积性质的含羟基或含酰胺基的纤维材料，因此 给出具有优异的各种牢度特性的染色产品。

    Fiber-reactive phthalocyanine compound having both vinylsulfone type and dihalogenotriazinyl groups
    3.
    发明授权
    Fiber-reactive phthalocyanine compound having both vinylsulfone type and dihalogenotriazinyl groups 失效
    具有乙烯基砜型和二卤代三嗪基的纤维反应性酞菁化合物

    公开(公告)号：US4684721A

    公开(公告)日：1987-08-04

    申请号：US835788

    申请日：1986-03-03

    申请人： Tetsuya Miyamoto ,  Takashi Omura ,  Naoki Harada ,  Akira Takeshita

    发明人： Tetsuya Miyamoto ,  Takashi Omura ,  Naoki Harada ,  Akira Takeshita

    IPC分类号： C09B62/517 ,  C09B62/44 ,  D06P1/38 ,  C09B47/04

    CPC分类号： C09B62/4418

    摘要： A phthalocyanine compound represented by the following formula, ##STR1## wherein Pc is a metal-containing or metal-free phthalocyanine residue, R.sup.1 is a hydrogen atom or substituted or unsubstituted lower alkyl group, A is a substituted or unsubstituted phenylene or naphthylene group, Y is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z, in which Z is a splittable group by the action of an alkali, W is a bridging group of the following formula, ##STR2## in which R.sup.2 and R.sup.3 are independently a hydrogen atom or a methyl or ethyl group, and n is an integer of from 2 through 6, X is a halogen atom, a is 0 or a number of not more than 2 (0.ltoreq.a.ltoreq.2), and b and c are independently a number of 1 through 3 (1.ltoreq.b.ltoreq.3, 1.ltoreq.c.ltoreq.3), provided that the total of a, b and c is not more than 4 (a+b+c.ltoreq.4), which is useful for dyeing or printing materials, particularly cellulose fiber materials, in a brilliant turquoise blue color excellent in various fastness properties.

    摘要翻译： 由下式表示的酞菁化合物其中Pc是含金属或不含金属的酞菁残基，R1是氢原子或取代或未取代的低级烷基，A是取代或未取代的亚苯基或亚萘基， Y是-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Z，其中Z是通过碱的作用可裂解的基团，W是下式的桥接基团，其中R 2和R 3独立地是氢原子或甲基 或乙基，n为2〜6的整数，X为卤素原子，a为0或2以下的数（0

    Pyridone monoazo compound having vinylsulfone type fiber-reactive group
    4.
    发明授权
    Pyridone monoazo compound having vinylsulfone type fiber-reactive group 失效
    具有乙烯基砜型纤维反应性基团的吡啶酮单偶氮化合物

    公开(公告)号：US4701524A

    公开(公告)日：1987-10-20

    申请号：US795123

    申请日：1985-11-05

    申请人： Yutaka Kayane ,  Hirokazu Sawamoto ,  Takashi Omura ,  Naoki Harada ,  Akira Takeshita

    发明人： Yutaka Kayane ,  Hirokazu Sawamoto ,  Takashi Omura ,  Naoki Harada ,  Akira Takeshita

    IPC分类号： C09B62/51 ,  D06P1/38 ,  D06P1/384 ,  C09B62/45 ,  C09B62/53 ,  D06P3/66

    CPC分类号： C09B62/51

    摘要： A monoazo compound, or a salt thereof, of the formula, ##STR1## wherein W is a hydrogen atom or a carbamoyl group, R.sub.1 is a lower alkyl group, R.sub.2 and R.sub.3 are independently a hydrogen atom or a lower alkyl group, A is an unsubstituted or substituted phenylene or naphthylene group, Y is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z, in which Z is a group capable of being split by the action of an alkali, and X is an aromatic or aliphatic group substituted with one or two members selected from sulfonic acid group and carboxylic acid group, which is useful for dyeing fiber materials to give dyed products of a characteristic yellow color excellent in various fastness properties.

    摘要翻译： 下式的单偶氮化合物或其盐，其中W是氢原子或氨基甲酰基，R1是低级烷基，R2和R3独立地是氢原子或低级烷基，A是 未取代或取代的亚苯基或亚萘基，Y是-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 Z，其中Z是能够被碱作用的基团，X是被一个或两个成员取代的芳族或脂族基团 选自磺酸基和羧酸基，其可用于染色纤维材料以得到具有优异的各种牢度性质的特征黄色的染色产品。

    Fiber reactive yellow dye of acetoacetonilide having vinyl sulfone-type reactive group
    6.
    发明授权
    Fiber reactive yellow dye of acetoacetonilide having vinyl sulfone-type reactive group 失效
    具有乙烯基砜型反应性基团的乙酰乙酰苯胺的纤维活性黄色染料

    公开(公告)号：US4843149A

    公开(公告)日：1989-06-27

    申请号：US797488

    申请日：1985-11-13

    申请人： Yutaka Kayane ,  Hirokazu Sawamoto ,  Takashi Omura ,  Naoki Harada ,  Akira Takeshita

    发明人： Yutaka Kayane ,  Hirokazu Sawamoto ,  Takashi Omura ,  Naoki Harada ,  Akira Takeshita

    IPC分类号： C09B62/44

    CPC分类号： C09B62/4413 ,  Y10S534/01

    摘要： A monoazo compound, or a salt thereof, represented by the formula, ##STR1## wherein D is a sulfophenyl group substituted with a methyl, ethyl, methoxy, ethoxy, phenoxy, acetylamino, pripionylamino, benzoylamino, carboxybenzoylamino, maleinylamino or succinylamino group, a naphthyl group substituted with two or three sulfo groups of a group of the formula ##STR2## any one of X.sub.1 or X.sub.2 is a sulfo group and the other is a methoxy or ethoxy group, Y is a fluorine or chlorine atom or an arylamino group substituted with one or two sulfo groups, R is a hydrogen atom or an unsubstituted or substituted lower alkyl group, A is an unsubstituted or substitued phenylene or naphthylene group, and Z is --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub..sub.2 CH.sub.2 Z.sub.1 in which Z.sub.1 is a group capable of being split by the action of an alkali, which is useful as a fiber-reactive dye for dyeing materials in a greenish yellow color excellent in various fastness properties.

    摘要翻译： 其中D为被甲基，乙基，甲氧基，乙氧基，苯氧基，乙酰氨基，丙酰氨基，苯甲酰基氨基，羧基苯甲酰氨基，马来酰氨基或琥珀酰氨基取代的磺基苯基的单偶氮化合物或其盐， 被两个或三个下式的基团取代的萘基：X 1或X 2中的任一个是磺基，另一个是甲氧基或乙氧基，Y是氟或氯原子或芳基氨基取代的 具有一个或两个磺基，R为氢原子或未取代或取代的低级烷基，A为未取代或取代的亚苯基或亚萘基，Z为-SO2CH = CH2或-SO2CH2CH2Z1，其中Z1为能够 通过碱的作用分裂，其可用作用于以各种牢度性能优异的绿黄色染色材料的纤维活性染料。

    Anthraquinone compound
    7.
    发明授权
    Anthraquinone compound 失效
    蒽醌化合物

    公开(公告)号：US4977261A

    公开(公告)日：1990-12-11

    申请号：US141762

    申请日：1988-01-11

    申请人： Yutaka Kayane ,  Takashi Omura ,  Naoki Harada ,  Yasuji Mori ,  Yosuke Yamamoto ,  Tetsuya Miyamoto ,  Takehiro Kusumoto

    发明人： Yutaka Kayane ,  Takashi Omura ,  Naoki Harada ,  Yasuji Mori ,  Yosuke Yamamoto ,  Tetsuya Miyamoto ,  Takehiro Kusumoto

    IPC分类号： C09B62/505

    CPC分类号： C09B62/505

    摘要： A compound of the following formula in the free acid form, ##STR1## wherein and R and R.sub.1 are each hydrogen or alkyl, A is a divalent group of the formula, ##STR2## wherein R.sub.3, R.sub.4 and R.sub.5 are each hydrogen, methyl, ethyl, methoxy or ethoxy, m is 0 or 1, n, u and v are each 0, 1 or 2, p is 0, 1, 2 or 3, q and s are each an integer of 2 to 6, and r is 1 or 2, B.sub.1 is phenylene or naphthylene, Z.sub.1 is vinyl, .beta.-sulfatoethyl or the like, l is 0, 1 or 2, and X is a group of the formula, ##STR3## wherein R.sub.2 is hydrogen or alkyl, B.sub.2 is phenylene or naphtylene, Z.sub.2 is vinyl, .beta.-sulfatoethyl or the like, R.sub.6 and R.sub.7 are each hydrogen, alkyl, phenyl, naphthyl or benzyl, and R, A and l are as defined above, which is useful for dyeing or printing fiber materials to give a dyed or printed product of a brilliant blue color superior in fastness properties such as light fastness and perspiration-light fastness, with superior build-up property.

    Fiber reactive asymmetric dioxazine compounds and their use as fiber reactive dyes
    8.
    发明授权
    Fiber reactive asymmetric dioxazine compounds and their use as fiber reactive dyes 失效
    纤维反应性不对称二嗪化合物及其作为纤维活性染料的用途

    公开(公告)号：US5438137A

    公开(公告)日：1995-08-01

    申请号：US128725

    申请日：1993-09-30

    申请人： Tetsuya Miyamoto ,  Miyao Takahashi ,  Takahiko Fujisaki ,  Shinei Ikeou ,  Takashi Omura ,  Naoki Harada

    发明人： Tetsuya Miyamoto ,  Miyao Takahashi ,  Takahiko Fujisaki ,  Shinei Ikeou ,  Takashi Omura ,  Naoki Harada

    IPC分类号： C09B62/44 ,  C09B62/503 ,  C07D498/04

    CPC分类号： C09B62/5033 ,  C09B62/4405

    摘要： An asymmetric dioxazine compound of the following formula in the free acid form, ##STR1## wherein R is hydrogen, halogen, sulfo or alkoxy, R.sub.1, R.sub.2 and R.sub.3 are each hydrogen or alkyl, X.sub.1 and X.sub.2 are each hydrogen, halogen, alkyl, alkoxy or phenoxy, Y is alkylene, phenylene or naphthylene, Z is --SO.sub.2 CH.dbd.CH.sub.2, --SO.sub.2 CH.sub.2 CH.sub.2 OSO.sub.3 H or the like, V is hydrogen, alkyl, acyl or substituted triazinyl, and Q is halogen, alkoxy, amino or a group similar to that of ##STR2## provided that R is hydrogen, and Q is amino or a group similar to that of ##STR3## when V is substituted triazinyl, which is useful for dyeing or printing fiber materials to give dyed or printed products of a brilliant blue color superior in fastness properties, particularly those such as chlorine fastness with superior build-up property.

    摘要翻译： 游离酸形式的下式的不对称二恶嗪化合物，其中R是氢，卤素，磺基或烷氧基，R 1，R 2和R 3各自为氢或烷基，X 1和X 2各自为氢，卤素，烷基， 烷氧基或苯氧基，Y是亚烷基，亚苯基或亚萘基，Z是-SO2CH = CH2，-SO2CH2CH2OSO3H等，V是氢，烷基，酰基或取代的三嗪基，Q是卤素，烷氧基，氨基或类似的基团 条件是R为氢，Q为氨基或V为与IMA相似的基团，当V为取代的三嗪基时，可用于染色或印刷纤维材料以得到亮蓝色的染色或印刷产品 耐牢度特性优异，特别是具有优异聚集性能的耐氯牢度。