公开(公告)号：US20230158480A1

公开(公告)日：2023-05-25

申请号：US18100196

申请日：2023-01-23

Applicant: The Trustees of Princeton University

Inventor： Brad P. CARROW ,  Liye CHEN

IPC: B01J31/24 ,  C07F9/50 ,  C07B37/04 ,  B01J31/22 ,  C07F15/00

CPC classification number: B01J31/2485 ,  C07F9/5045 ,  C07B37/04 ,  B01J31/2295 ,  B01J31/2447 ,  B01J31/2208 ,  C07F15/006 ,  C07F9/5018 ,  C07F15/0073 ,  C07F15/0066 ,  C07F15/0006 ,  B01J2231/4211 ,  B01J2531/0288 ,  B01J2231/4205 ,  B01J2231/4233 ,  B01J2231/14 ,  B01J2531/0205 ,  B01J2231/4283 ,  B01J2531/824 ,  B01J2231/4261 ,  B01J2231/4227 ,  B01J2231/4272 ,  B01J2531/822 ,  B01J2540/442 ,  C07F1/00

Abstract: In one aspect, phosphine compounds comprising three adamantyl moieties (PAd3) and associated synthetic routes are described herein. Each adamantyl moiety may be the same or different. For example, each adamantyl moiety (Ad) attached to the phosphorus atom can be independently selected from the group consisting of adamantane, diamantane, triamantane and derivatives thereof. Transition metal complexes comprising PAd3 ligands are also provided for catalytic synthesis including catalytic cross-coupling reactions.

公开(公告)号：US20210162389A1

公开(公告)日：2021-06-03

申请号：US17167606

申请日：2021-02-04

Applicant: The Trustees of Princeton University

Inventor： Brad P. CARROW ,  Liye CHEN

IPC: B01J31/24 ,  C07F9/50 ,  C07B37/04 ,  B01J31/22 ,  C07F15/00

Abstract: In one aspect, phosphine compounds comprising three adamantyl moieties (PAd3) and associated synthetic routes are described herein. Each adamantyl moiety may be the same or different. For example, each adamantyl moiety (Ad) attached to the phosphorus atom can be independently selected from the group consisting of adamantane, diamantane, triamantane and derivatives thereof. Transition metal complexes comprising PAd3 ligands are also provided for catalytic synthesis including catalytic cross-coupling reactions.

公开(公告)号：US20180304248A1

公开(公告)日：2018-10-25

申请号：US15770709

申请日：2016-10-31

Applicant: The Trustees of Princeton University

Inventor： Brad P. CARROW ,  Liye CHEN

IPC: B01J31/24 ,  C07F9/50 ,  C07F15/00 ,  C07B37/04

CPC classification number: B01J31/2485 ,  B01J31/06 ,  B01J31/12 ,  B01J31/24 ,  C07B37/04 ,  C07F1/00 ,  C07F3/00 ,  C07F9/5018 ,  C07F9/5045 ,  C07F15/0006 ,  C07F15/006 ,  C07F15/0066 ,  C07F15/0073

Abstract: In one aspect, phosphine compounds comprising three adamantyl moieties (PAd3) and associated synthetic routes are described herein. Each adamantyl moiety may be the same or different. For example, each adamantyl moiety (Ad) attached to the phosphorus atom can be independently selected from the group consisting of adamantane, diamantane, triamantane and derivatives thereof. Transition metal complexes comprising PAd3 ligands are also provided for catalytic synthesis including catalytic cross-coupling reactions.