公开(公告)号：US10981157B2

公开(公告)日：2021-04-20

申请号：US15770709

申请日：2016-10-31

申请人： The Trustees of Princeton University

发明人： Brad P. Carrow ,  Liye Chen

IPC分类号： B01J31/24 ,  C07F9/50 ,  C07B37/04 ,  B01J31/22 ,  C07F15/00 ,  C07F1/00 ,  C07F3/00

摘要： In one aspect, phosphine compounds comprising three adamantyl moieties (PAd3) and associated synthetic routes are described herein. Each adamantyl moiety may be the same or different. For example, each adamantyl moiety (Ad) attached to the phosphorus atom can be independently selected from the group consisting of adamantane, diamantane, triamantane and derivatives thereof. Transition metal complexes comprising PAd3 ligands are also provided for catalytic synthesis including catalytic cross-coupling reactions.

公开(公告)号：US20240001353A1

公开(公告)日：2024-01-04

申请号：US18367813

申请日：2023-09-13

申请人： The Trustees of Princeton University

发明人： Brad P. Carrow ,  Liye Chen

IPC分类号： B01J31/24 ,  C07F9/50 ,  C07B37/04 ,  B01J31/22 ,  C07F15/00

CPC分类号： B01J31/2485 ,  C07F9/5045 ,  C07B37/04 ,  B01J31/2295 ,  B01J31/2447 ,  B01J31/2208 ,  C07F15/006 ,  C07F9/5018 ,  C07F15/0073 ,  C07F15/0066 ,  C07F15/0006 ,  B01J2231/4211 ,  B01J2531/0288 ,  B01J2231/4205 ,  B01J2231/4233 ,  B01J2231/14 ,  B01J2531/0205 ,  B01J2231/4283 ,  B01J2531/824 ,  B01J2231/4261 ,  B01J2231/4227 ,  B01J2231/4272 ,  B01J2531/822 ,  B01J2540/442 ,  C07F1/00

摘要： In one aspect, phosphine compounds comprising three adamantyl moieties (PAd3) and associated synthetic routes are described herein. Each adamantyl moiety may be the same or different. For example, each adamantyl moiety (Ad) attached to the phosphorus atom can be independently selected from the group consisting of adamantane, diamantane, triamantane and derivatives thereof. Transition metal complexes comprising PAd3 ligands are also provided for catalytic synthesis including catalytic cross-coupling reactions.

公开(公告)号：US11583844B2

公开(公告)日：2023-02-21

申请号：US17167606

申请日：2021-02-04

申请人： The Trustees of Princeton University

发明人： Brad P Carrow ,  Liye Chen

IPC分类号： B01J31/24 ,  C07F9/50 ,  C07B37/04 ,  B01J31/22 ,  C07F15/00 ,  C07F1/00 ,  C07F3/00

摘要： In one aspect, phosphine compounds comprising three adamantyl moieties (PAd3) and associated synthetic routes are described herein. Each adamantyl moiety may be the same or different. For example, each adamantyl moiety (Ad) attached to the phosphorus atom can be independently selected from the group consisting of adamantane, diamantane, triamantane and derivatives thereof. Transition metal complexes comprising PAd3 ligands are also provided for catalytic synthesis including catalytic cross-coupling reactions.

公开(公告)号：US11794180B2

公开(公告)日：2023-10-24

申请号：US18100196

申请日：2023-01-23

申请人： The Trustees of Princeton University

发明人： Brad P. Carrow ,  Liye Chen

IPC分类号： B01J31/24 ,  C07F9/50 ,  C07B37/04 ,  B01J31/22 ,  C07F15/00 ,  C07F1/00 ,  C07F3/00

CPC分类号： B01J31/2485 ,  B01J31/2208 ,  B01J31/2295 ,  B01J31/2447 ,  C07B37/04 ,  C07F9/5018 ,  C07F9/5045 ,  C07F15/0006 ,  C07F15/006 ,  C07F15/0066 ,  C07F15/0073 ,  B01J2231/14 ,  B01J2231/4205 ,  B01J2231/4211 ,  B01J2231/4227 ,  B01J2231/4233 ,  B01J2231/4261 ,  B01J2231/4272 ,  B01J2231/4283 ,  B01J2531/0205 ,  B01J2531/0288 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2540/442 ,  C07F1/00 ,  C07F3/00

摘要： In one aspect, phosphine compounds comprising three adamantyl moieties (PAd3) and associated synthetic routes are described herein. Each adamantyl moiety may be the same or different. For example, each adamantyl moiety (Ad) attached to the phosphorus atom can be independently selected from the group consisting of adamantane, diamantane, triamantane and derivatives thereof. Transition metal complexes comprising PAd3 ligands are also provided for catalytic synthesis including catalytic cross-coupling reactions.