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公开(公告)号：US4979893A
公开(公告)日：1990-12-25
申请号：US312799
申请日：1989-02-21
CPC分类号： C04B41/87 , C04B41/5025 , C09K11/025 , C09K11/7776 , C09K11/7794 , H01J61/35 , H01J61/72
摘要： The lumen maintenance of fluorescent lamps containing yttrium vanadate phosphors is markedly improved by the presence of a protective oxide layer for the phosphor. The protective oxide layer is produced by evaporating aluminum isopropoxide, in a vacuum, over phorphor particles forming a continuous aluminum isopropoxide over the phosphor particles. The isopropoxide coating is subsequently oxidized by lehring the phosphor at a temperature from about 500.degree. C. to 625.degree. C. forming an alumina coating on the phosphor particles.
摘要翻译： 通过存在荧光体的保护性氧化物层，能够显着地改善含有钒酸钇荧光体的荧光灯的流明维持。 保护性氧化物层通过在真空中蒸发异丙氧基铝，在磷光体颗粒上形成连续的异丙醇铝来形成磷晶体颗粒。 随后，在约500℃至625℃的温度下将异丙氧化物涂层氧化，在磷光体颗粒上形成氧化铝涂层。
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2.发明授权Process for preparing high-brightness yellow-emitting triboluminescent phosphors 失效制备高亮度黄光发光三氟发光荧光粉的方法
公开(公告)号：US4772417A
公开(公告)日：1988-09-20
申请号：US684680
申请日：1984-12-21
IPC分类号： C09K11/71
CPC分类号： C09K11/71
摘要： The present invention is directed to luminescent materials having the general formula:Ca(2-v-w-x-y-z) (NSF).sub.v Sr.sub.w Cd.sub.x Sn.sub.y Mn.sub.z P.sub.2 O.sub.7wherein:NSF is the non-stoicheometric factor;0.ltoreq.v.ltoreq.0.010.ltoreq.w.ltoreq.0.08;0.ltoreq.x.ltoreq.0.05;0.01.ltoreq.y.ltoreq.0.03; and0.05.ltoreq.z.ltoreq.0.15.
摘要翻译： 本发明涉及具有以下通式的发光材料：Ca（2-v-w-x-y-z）（NSF）vSrwCdxSnyMnzP2O7其中：NSF是非测定因子; 0
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公开(公告)号：US4749513A
公开(公告)日：1988-06-07
申请号：US103781
申请日：1987-10-02
IPC分类号： C09K11/77 , C09K11/85 , C09K11/475
CPC分类号： C09K11/7772
摘要： An efficient green emitting phosphor results from the coactivation of yttrium fluoride with gadolinium and erbium. The excitation energy absorbed by the Gd.sup.3+ centers is transferred non-radiatively to minority Er.sup.3+ centers, whose emission produces green light when excited by 275 nanometer or 378 nanometer radiation.
摘要翻译： 有效的绿色荧光粉是由钆和铒共同激活氟化钇所致。 由Gd3 +中心吸收的激发能量被非辐射转移到少量Er3 +中心，当发射通过275纳米或378纳米辐射激发时，其发射产生绿光。
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4.发明授权
公开(公告)号：US4446049A
公开(公告)日：1984-05-01
申请号：US435846
申请日：1982-10-21
IPC分类号： C09K11/73 , C09K11/435
CPC分类号： C09K11/73
摘要： Phosphors and a method for producing yellow-emitting tin-manganese coactivated calcium fluorophosphate phosphors having improved brightness comprises the steps of blending a powder mixture including the phosphates, carbonates, fluorides and oxides of calcium, tin, and manganese together with an ammonium salt, and firing the mixture at a temperature of between about 1100.degree. C. and about 1300.degree. C. for a period sufficient to produce a luminescent composition. The presence of an ammonium compound in the initial powder blend promotes the proper atmosphere during the firing step to insure the incorporation of proper levels of tin and manganese ions in the final phosphor.
摘要翻译： 荧光体和具有改善的亮度的发色黄色锡 - 锰共活化磷酸氟磷酸盐荧光体的制造方法包括以下步骤：将包括磷酸盐，碳酸盐，氟化物和钙，锡和锰的氧化物的粉末混合物与铵盐一起混合，以及 在约1100℃至约1300℃的温度下烧制混合物足够长的时间以产生发光组合物。 在初始粉末混合物中存在铵化合物在焙烧步骤期间促进适当的气氛，以确保在最终的荧光体中引入适当水平的锡和锰离子。
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公开(公告)号：US5524016A
公开(公告)日：1996-06-04
申请号：US257751
申请日：1994-06-09
CPC分类号： H01S3/16 , H01S3/067 , H01S3/1623 , H01S3/1655
摘要： A host acting as an optical emitter and a process of making the same for the .sup..about. 1.3 .mu.m to .sup..about. 1.55 .mu.m spectral region utilized in optical communications is disclosed. The host is Cr-activated willemite (Zn.sub.2 SiO.sub.4). Efficient band-emission at room temperature, with peak at 1.42 .mu.m, is observed on exiting the material in the near infrared, typically at 730 nm and 829 nm.
摘要翻译： 公开了用作光发射器的主机以及用于光通信中使用的差分为1.3微米到1.55微米光谱区域的差异的过程。 主体是Cr活化的硅锌矿（Zn2SiO4）。 在近红外线（通常在730nm和829nm）出射物质时，观察到在室温下高效带状发射峰值为1.42μm。
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6.发明授权A method of coating a layer of an yttrium vanadate phosphor contained in a fluorescent lamp with Y.sub.2 O.sub.3 or Al.sub.2 O.sub.3 and lamps made therefrom 失效用Y 2 O 3或Al 2 O 3或由其制成的灯在荧光灯中涂覆钒酸钇荧光体层的方法
公开(公告)号：US4952422A
公开(公告)日：1990-08-28
申请号：US161643
申请日：1988-02-29
CPC分类号： C04B41/009 , C04B41/5025 , C04B41/87 , C09K11/025 , C09K11/7776 , C09K11/7794
摘要： A fluorescent lamp containing a Y.sub.2 O.sub.3 or Al.sub.2 O.sub.3 coating on a layer of yttrium vanadate phosphor and a method of coating the layer of the yttrium vanadate phosphor with a continuous protective coating of Y.sub.2 O.sub.3 or Al.sub.2 O.sub.3 is described. The method comprises applying a coating of a metal, such as yttrium or aluminum, on the yttrium vanadate phosphor then lehring the metallic coating at about 500.degree. C. to about 625.degree. C. to form a continuous protective coating of Y.sub.2 O.sub.3 or Al.sub.2 O.sub.3 overlaying the layer of phosphor.
摘要翻译： 描述了在钇钒酸盐荧光体层上含有Y 2 O 3或Al 2 O 3涂层的荧光灯以及用Y 2 O 3或Al 2 O 3的连续保护涂层涂覆钒酸钇荧光体层的方法。 该方法包括将金属如钇或铝的涂层涂覆在钒酸钇荧光体上，然后在约500℃至约625℃下引导金属涂层，以形成覆盖Y 2 O 3或Al 2 O 3的连续保护涂层 磷光体层。
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7.发明授权Efficient UV-emitting phosphors based on cerium-activated calcium pyrophosphate and lamps containing the same 失效基于铈活化的焦磷酸钙的高效UV发光荧光体和含有它们的灯
公开(公告)号：US4757233A
公开(公告)日：1988-07-12
申请号：US684474
申请日：1984-12-21
IPC分类号： C09K11/77
CPC分类号： C09K11/7724
摘要： The present invention is directed to phosphors exhibiting efficient, narrow band UV emission, with peak emission at 330 nm (from excitation at 254). These phosphors are cerium-activated calcium pyrophosphate (beta-phase) of nominal formulationCa(.sub.2-w-x-y) (NSF).sub.w Ce.sub.x Na.sub.y P.sub.2 O.sub.7wherein:NSF is the non-stoicheometric factor;0.ltoreq.w.ltoreq.0.1;0.05.ltoreq.x.ltoreq.0.20; and0.05.ltoreq.y.ltoreq.0.20.
摘要翻译： 本发明涉及显示出有效的窄带UV发射的荧光体，其峰值发射在330nm（从254激发）。 这些荧光体是标称配方Ca（2-w-x-y）（NSF）wCexNayP2O7的铈活化的焦磷酸钙（β相），其中：NSF是非测定因子; 0
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8.发明授权Process for producing Ce-Mn coactivated fluoroapatite phosphors as the yellow emitting component for high efficacy lamp blends 失效用于生产Ce-Mn共活化的氟磷灰石磷光体作为高效率灯共混物的黄色发射成分的方法
公开(公告)号：US4647399A
公开(公告)日：1987-03-03
申请号：US859846
申请日：1986-04-30
IPC分类号： C09K11/77 , H01J61/44 , C09K11/463
CPC分类号： H01J61/44 , C09K11/7725
摘要： Yellow emitting fluorescent lamp phosphor compositions comprise cerium and manganese activated alkali-earth fluoroapatite compositions containing sodium having the approximate formula(Ca.sub.1-s Sr.sub.s).sub.t Ce.sub.v Na.sub.w Mn.sub.x (PO.sub.4).sub.y F.sub.zwhereins is from 0 to 1t is from about 3.43 to about 4.01v is about 0.3w is about 0.3x is from about 0.3 to about 0.4y is about 3.00z is from about 1.0 to about 4.0.An improved two step firing process for producing the disclosed phosphors is described and an improved fluorescent lamp employing the disclosed phosphors is also described.
摘要翻译： 黄色荧光灯荧光体组合物包含含有具有近似式（Ca1-sSrs）tCevNawMnx（PO4）yFz的钠和锰活化的碱土金属磷灰石组合物，其中s为0至1t约为3.43至约4.01v，约为 0.3w为约0.3x为约0.3至约0.4y约为3.00 z为约1.0至约4.0。 描述了用于制备所公开的磷光体的改进的两步烧制方法，并且还描述了采用所公开的磷光体的改进的荧光灯。
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公开(公告)号：US4307321A
公开(公告)日：1981-12-22
申请号：US135605
申请日：1980-03-31
申请人： Romano G. Pappalardo , John Walsh
发明人： Romano G. Pappalardo , John Walsh
CPC分类号： H01J61/44 , C09K11/7724
摘要： A luminescent phosphor composition having enhanced luminescent decay lifetime consists essentially of a non-stoichiometric cerium and manganese coactivated alkaline earth orthophosphate represented by the formulaSr.sub.(3-v-w-x-y-z) .quadrature..sub.v Mg.sub.w CA.sub.x (PO.sub.4).sub.2 :Ce.sub.y Mn.sub.zwhere0.001.ltoreq.v.ltoreq.0.050.180.ltoreq.w.ltoreq.0.350.ltoreq.x.ltoreq.0.080.015.ltoreq.y.ltoreq.0.050.01.ltoreq.z.ltoreq.0.10.An improved fluorescent lamp employing the disclosed phosphor is also described.
摘要翻译： 具有增强的发光衰变寿命的发光荧光体组合物基本上由由式Sr（3-vwxyz）＆squ＆vMgwCAx（PO4）2表示的非化学计量的铈和锰共活化碱土金属正磷酸盐组成：其中0.001
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公开(公告)号：US5854533A
公开(公告)日：1998-12-29
申请号：US963873
申请日：1992-10-19
申请人： Romano G. Pappalardo
发明人： Romano G. Pappalardo
CPC分类号： H01J61/44 , C09K11/725 , H01J61/48
摘要： A fluorescent lamp comprises a plurality of metameric blends of lamp phosphors for converting ultraviolet radiation to visible illumination.
摘要翻译： 荧光灯包括用于将紫外线辐射转换成可见光的多个荧光体的同色混合物。
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