公开(公告)号：US06458999B1

公开(公告)日：2002-10-01

申请号：US09722197

申请日：2000-11-27

申请人： Thomas J. Daly ,  Michael Clumpner ,  Anthony J. O'Lenick, Jr.

发明人： Thomas J. Daly ,  Michael Clumpner ,  Anthony J. O'Lenick, Jr.

IPC分类号： C07C21742

CPC分类号： C07C217/08

摘要： The present invention is related to a series of derivatives of novel ether diamine compounds prepared by the cyanobutylation reaction of an alcohol having 3 to 22 carbon atoms with 2-pentenenitrile to form a branched alkyl ether nitrile. The etheraminonitriles formed by the process are hydrogenated to form alkylether amines. The resulting product can be reacted with 2-pentenenitrile and or acrylonitrile and in a subsequent step, hydrogenated to yield a diamine. Specifically, the present invention deals with two types of tertiary amines one made by the reaction of novel ether diamines compounds with ethylene oxide, propylene oxide or butylene oxide or mixtures thereof, producing alkoxylated tertiary amines and the other made by the reaction of novel ether amine compounds with formaldehyde and hydrogen producing methylated tertiary amines. The invention also disclosed novel amine oxides, and quaternary compounds made from said tertiary amines.

摘要翻译： 本发明涉及通过具有3至22个碳原子的醇与2-戊烯腈的氰基丁基化反应制备的一系列新型醚二胺化合物的衍生物，以形成支链烷基醚腈。 通过该方法形成的醚氨基腈被氢化形成烷基醚胺。 所得产物可与2-戊烯腈和/或丙烯腈反应，并在随后的步骤中氢化得到二胺。 具体地，本发明涉及通过新型醚二胺化合物与环氧乙烷，环氧丙烷或环氧丁烷或其混合物的反应制备的两种类型的叔胺，其产生烷氧基化叔胺，另一种通过新的醚胺 化合物与甲醛和氢气产生甲基化叔胺。 本发明还公开了新的氧化胺和由所述叔胺制成的季铵化合物。

公开(公告)号：US6114585A

公开(公告)日：2000-09-05

申请号：US459562

申请日：1999-12-13

申请人： Thomas J. Daly ,  Anita Mokadam Sorhaug ,  Robert E. Harbour, Jr. ,  Abraham A. Zahand ,  Michael Clumpner ,  Anthony J. O'Lenick, Jr.

发明人： Thomas J. Daly ,  Anita Mokadam Sorhaug ,  Robert E. Harbour, Jr. ,  Abraham A. Zahand ,  Michael Clumpner ,  Anthony J. O'Lenick, Jr.

IPC分类号： C07C217/08 ,  C07C217/28 ,  C07C217/42

CPC分类号： C07C217/08

摘要： The present invention relates to a series of novel ether amine compounds prepared by the cyanobutylation reaction of an alcohol having 12 to 26 carbon atoms with 2-pentenenitrile to form a branched alkyl ether nitrile. The etheraminonitriles formed by the process are hydrogenated to form alkylether amines. The resulting product can be reacted with 2-pentenenitrile and hydrogenated to yield a polyamine.

摘要翻译： 本发明涉及通过具有12-26个碳原子的醇与2-戊烯腈的氰基丁基化反应制备的一系列新的醚胺化合物，以形成支链烷基醚腈。 通过该方法形成的醚氨基腈被氢化形成烷基醚胺。 所得产物可与2-戊烯腈反应并氢化得到多胺。

公开(公告)号：US06426436B1

公开(公告)日：2002-07-30

申请号：US10051675

申请日：2002-01-22

申请人： Thomas J. Daly ,  Michael Clumpner ,  Anthony J. O'Lenick, Jr.

发明人： Thomas J. Daly ,  Michael Clumpner ,  Anthony J. O'Lenick, Jr.

IPC分类号： C07C21163

CPC分类号： C07C217/08

摘要： The present invention is related to a series of derivatives of novel ether diamine compounds prepared by the cynobutylation reaction of an alcohol having 3 to 22 carbon atoms with 2-pentenenitrile to form a branched alkyl ether nitrile. The etheraminonitriles formed by the process are hydrogenated to form alkylether amines. The resulting product can be reacted with 2-pentenenitrile and or acrylonitrile and in subsequent step, hydrogenated to yield a diamine. Specifically, the present invention deals with two types of tertiary amines one made by the reaction of novel ether diamines compounds with ethylene oxide, propylene oxide or butylene oxide or mixtures thereof, producing alkoxylated tertiary amines and the other made by the reaction of novel ether amine compounds with formaldehyde and hydrogen producing methylated tertiary amines. The invention also disclosed novel amine oxides, and quaternary compounds made from said tertiary amines.

摘要翻译： 本发明涉及通过具有3至22个碳原子的醇与2-戊烯腈的异辛基化反应制备的一系列新型醚二胺化合物的衍生物，以形成支链烷基醚腈。 通过该方法形成的醚氨基腈被氢化形成烷基醚胺。 所得产物可与2-戊烯腈和/或丙烯腈反应，并在随后的步骤中氢化得到二胺。 具体地，本发明涉及通过新型醚二胺化合物与环氧乙烷，环氧丙烷或环氧丁烷或其混合物的反应制备的两种类型的叔胺，其产生烷氧基化叔胺，另一种通过新的醚胺 化合物与甲醛和氢气产生甲基化叔胺。 本发明还公开了新的氧化胺和由所述叔胺制成的季铵化合物。

公开(公告)号：US06417401B1

公开(公告)日：2002-07-09

申请号：US10051656

申请日：2002-01-22

申请人： Thomas J. Daly ,  Michael Clumpner ,  Anthony J. O'Lenick, Jr.

发明人： Thomas J. Daly ,  Michael Clumpner ,  Anthony J. O'Lenick, Jr.

IPC分类号： C07C29104

CPC分类号： C07C217/08

摘要： The present invention is related to a series of derivatives of novel ether diamine compounds prepared by the cyanobutylation reaction of an alcohol having 3 to 22 carbon atoms with 2-pentenenitrile to form a branched alkyl ether nitrile. The etheraminonitriles formed by the process are hydrogenated to form alkylether amines. The resulting product can be reacted with 2-pentenenitrile and or acrylonitrile and in a subsequent step, hydrogenated to yield a diamine. Specifically, the present invention deals with two types of tertiary amines one made by the reaction of novel ether diamines compounds with ethylene oxide, propylene oxide or butylene oxide or mixtures thereof, producing alkoxylated tertiary amines and the other made by the reaction of novel ether amine compounds with formaldehyde and hydrogen producing methylated tertiary amines. The invention also disclosed novel amine oxides, and quaternary compounds made from said tertiary amines.

摘要翻译： 本发明涉及通过具有3至22个碳原子的醇与2-戊烯腈的氰基丁基化反应制备的一系列新型醚二胺化合物的衍生物，以形成支链烷基醚腈。 通过该方法形成的醚氨基腈被氢化形成烷基醚胺。 所得产物可与2-戊烯腈和/或丙烯腈反应，并在随后的步骤中氢化得到二胺。 具体地，本发明涉及通过新型醚二胺化合物与环氧乙烷，环氧丙烷或环氧丁烷或其混合物的反应制备的两种类型的叔胺，其产生烷氧基化叔胺，另一种通过新的醚胺 化合物与甲醛和氢气产生甲基化叔胺。 本发明还公开了新的氧化胺和由所述叔胺制成的季铵化合物。

公开(公告)号：US06331648B1

公开(公告)日：2001-12-18

申请号：US09566505

申请日：2000-05-08

申请人： Thomas J. Daly ,  Michael Clumpner ,  Anthony J. O'Lenick, Jr.

发明人： Thomas J. Daly ,  Michael Clumpner ,  Anthony J. O'Lenick, Jr.

IPC分类号： C07C21728

CPC分类号： C07C217/08

摘要： The present invention relates to a series of derivatives of novel ether amine compounds prepared by the cyanobutylation reaction of an alcohol having 3 to 22 carbon atoms with 2-pentenenitrile to form a branched alkyl ether nitrile. The alkyl ether nitrites formed by the process are hydrogenated to form alkylether amines. The resulting product can be reacted with 2-pentenenitrile and or acrylonitrile and in a subsequent step, hydrogenated to yield a diamine. Specifically, the present invention deals with two types of tertiary amines one made by the reaction of novel ether amine compounds with ethylene oxide, propylene oxide or butylene oxide or mixtures thereof producing alkoxylated tertiary amines and the other made by the reaction of novel ether amine compounds with formaldehyde and hydrogen producing methylated tertiary amines. The invention also discloses novel amine oxides, and quaternary compounds made from said tertiary amines.

摘要翻译： 本发明涉及通过具有3至22个碳原子的醇与2-戊烯腈的氰基丁基化反应制备的一系列新的醚胺化合物的衍生物，以形成支链烷基醚腈。 通过该方法形成的烷基醚亚硝酸盐被氢化形成烷基醚胺。 所得产物可与2-戊烯腈和/或丙烯腈反应，并在随后的步骤中氢化得到二胺。 具体地，本发明涉及通过新型醚胺化合物与环氧乙烷，环氧丙烷或环氧丁烷或其混合物的反应制备烷氧基化叔胺而制备的两种叔胺，另一种由新的醚胺化合物 与甲醛和氢气产生甲基化叔胺。 本发明还公开了新的氧化胺和由所述叔胺制成的季铵化合物。