公开(公告)号：US06492521B2

公开(公告)日：2002-12-10

申请号：US10045333

申请日：2001-10-25

申请人： Thomas P. Sassi ,  Ram B. Gupta

发明人： Thomas P. Sassi ,  Ram B. Gupta

IPC分类号： C07D40112

CPC分类号： C08K5/3435 ,  C07D211/46

摘要： Compounds and methods of preparing compounds of the formula: RZ—CO—CRaRb—(CRcRd)n—NH—(Y)m—CO—A  (I) wherein n is an integer from 1 to 15, m is either 0 or 1; Ra, Rb, Rc, and Rd are each a hydrogen or a hydrocarbyl group; Y is CO—(CReRf)p, wherein Re and Rf are each a hydrogen or hydrocarbyl group and p is zero or an integer from 1 to 20 or CO—C6H4—, wherein the substitution pattern on the phenylene group is an ortho, meta, or para substitution pattern and one or more of the hydrogens of the phenylene group may be substituted by a hydrocarbyl group or a functional group; Z is —O— or —NG—, wherein G is H, C1-C12 alkyl or the radical R; wherein R is wherein R1 is hydrogen, C1-C18 alkyl, O, OH, CH2CN, C1-C18 alkoxy, C1-C18 hydroxyalkoxy, C5-C12 cycloalkoxy, C5-C12 hydroxycycloalkoxy, C3-C6 alkenyl, C1-C18 alkynyl, C7-C9 phenylalkyl, unsubstituted or substituted on the phenyl with 1, 2 or 3 C1-C4 alkyls, or an aliphatic C1-C8 acyl; R2 is hydrogen, C1-C8 alkyl, or benzyl; R3, R4, R5, and R6 are each a hydrogen, C1-C8 alkyl, benzyl or phenethyl, or two geminal R moieties, which together with the carbon to which they are attached form a C5-C10 cycloalkyl; and A is either ZR or a hydrocarbyl group, which are useful for stabilizing polymer compositions against photo- and thermal degradation.

摘要翻译： 化合物及其制备方法：其中n为1至15的整数，m为0或1; Ra，Rb，Rc和Rd各自为氢或烃基; Y是CO-（CReRf）p，其中Re和Rf各自为氢或烃基，p为0或1至20的整数或CO-C 6 H 4 - ，其中亚苯基上的取代模式为邻位，间位 或对位取代模式，并且亚苯基的一个或多个氢可以被烃基或官能团取代; Z是-O-或-NG-，其中G是H，C1-C12烷基或基团R; 其中R是其中R1是氢，C1-C18烷基，O，OH，CH2CN，C1-C18烷氧基，C1-C18羟基烷氧基，C5-C12环烷氧基，C5-C12羟基环烷氧基，C3-C6烯基，C1-C18炔基，C7- C 9苯基烷基，未取代或在苯基上被1,2或3个C 1 -C 4烷基取代，或脂族C 1 -C 8酰基; R2是氢，C1-C8烷基或苄基; R 3，R 4，R 5和R 6各自为氢，C 1 -C 8烷基，苄基或苯乙基，或两个偕R部分，与它们所连接的碳一起形成C5-C10环烷基; 并且A是ZR或烃基，其可用于稳定聚合物组合物以抵抗光和热降解。

公开(公告)号：US06265576B1

公开(公告)日：2001-07-24

申请号：US09197747

申请日：1998-11-20

申请人： Ram Baboo Gupta ,  Dennis John Jakiela ,  Thomas P. Sassi ,  Gottfried Haacke

发明人： Ram Baboo Gupta ,  Dennis John Jakiela ,  Thomas P. Sassi ,  Gottfried Haacke

IPC分类号： C07D25124

CPC分类号： C07D251/24 ,  C08K5/3492

摘要： This invention relates generally to amido or carbamate substituted trisaryl-1,3,5-triazines and the use thereof to protect against degradation by environmental forces, inclusive of ultraviolet light, actinic radiation, oxidation, moisture, atmospheric pollutants and combinations thereof. The new class of trisaryl-1,3,5-triazines comprises an aryl ring attached to the triazine ring (and preferably an aryl ring containing a hydroxyl group, either free or blocked to form a latent stabilizer, ortho- to the point of attachment to the triazine ring) substituted with a group comprising a bondable amido/carbamate containing group para- to the point of attachment to the triazine ring. These materials may, under the appropriate circumstances, be bonded to formulations comprising coatings, polymers, resins, organic compounds and the like via reaction of the bondable functionality with the materials of the formulation. A method for stabilizing a material by incorporating such amido or carbamate substituted trisaryl-1,3,5-triazines is also disclosed.

公开(公告)号：US06696570B2

公开(公告)日：2004-02-24

申请号：US10002516

申请日：2001-10-25

申请人： Thomas P. Sassi ,  Ram. B. Gupta

发明人： Thomas P. Sassi ,  Ram. B. Gupta

IPC分类号： C07D40112

CPC分类号： C07D211/46 ,  C07D211/58 ,  C08K5/3435

摘要： Oligomeric compounds and methods of making the compound having the formula: T—&Parenopenst;E—F&Parenclosest;i—&Parenopenst;E—F′&Parenclosest;j—&Parenopenst;E′—F&Parenclosest;k—&Parenopenst;E′—F′&Parenclosest;l—S  (II) wherein i, j, k, and l are integers from about 0 to 300 and the sum of i, j, k, and l is greater than 2, wherein the units F, F′ and T are derived from one or more multi-functional carbonyl compounds of general structure DO—CO—CRaRb—(—CRcRd—)n—NH—(Y)m—CO—OD  (IV) wherein n is an integer from 1 to 15, m is either 0 or 1; Ra, Rb, Rc, and Rd, are each a hydrogen or a hydrocarbyl group; Y is CO—(CReRf)p, wherein Re and Rf are each a hydrogen or hydrocarbyl group and p is zero or an integer from 1 to 20 or CO—C6H4—, wherein the substitution pattern on the phenylene group is an ortho, meta, or para substitution pattern, and one or more of the hydrogens of the phenylene group may be substituted by a hydrocarbyl group or a functional group; and D is a hydrocarbyl group and the units E, E′ and S are derived from one or more 1-substituted piperidin-4-ol or 4-aminopiperidines of general structure wherein Z is OH or NHG, wherein G is H or C1-C12 alkyl, R1 is —(CH2)s-OH, —(CH2)s—NH2, C1-C18 hydroxyalkoxy or C5-C12 hydroxycycloalkoxy; wherein s is an integer from 1 to 10; R2 represents hydrogen, C1-C8 alkyl, or benzyl; R3, R4, R5, and R6 are each a hydrogen, C1-C8 alkyl, benzyl or phenethyl, or two geminal R moieties, which together with the carbon to which they are attached form a C5-C10 cycloalkyl. The compounds are useful for stabilizing polymer compositions against photo- and thermal degradation.

摘要翻译： 低聚化合物和制备具有下式的化合物的方法：其中i，j，k和l为约0至300的整数，i，j，k和l的和大于2，其中单元F， F'和T衍生自一种或多种通式结构的多官能羰基化合物，其中n为1至15的整数，m为0或1; R a，R b，R c和R d各自为氢或烃基; Y是CO-（CR e R f）p，其中R e和R f各自是氢或烃基，p是0或1至20的整数或CO-C 6 H 4 - ， 其中亚苯基上的取代模式是邻位，间位或对位取代模式，亚苯基中的一个或多个氢可以被烃基或官能团取代; 并且D是烃基，并且单元E，E'和S衍生自一种或多种一般结构的1-取代的哌啶-4-醇或4-氨基哌啶，其中Z是OH或NHG，其中G是H或C1-C12 烷基，R 1是 - （CH 2）s -OH， - （CH 2）s -NH 2，C 1 -C 18羟基烷氧基或C 5 -C 12羟基环烷氧基; 其中s是1至10的整数; R 2表示氢，C 1 -C 8烷基或苄基; R 3，R 4，R 5和R 6各自为氢，C 1 -C 8烷基，苄基或苯乙基，或两个偕R部分，与它们所连接的碳一起 形成C5-C10环烷基。 该化合物可用于稳定聚合物组合物以抵抗光和热降解。

公开(公告)号：US06365652B2

公开(公告)日：2002-04-02

申请号：US09848195

申请日：2001-05-03

申请人： Ram Baboo Gupta ,  Dennis John Jakiela ,  Thomas P. Sassi ,  Gottfried Haacke

发明人： Ram Baboo Gupta ,  Dennis John Jakiela ,  Thomas P. Sassi ,  Gottfried Haacke

IPC分类号： C08K53492

CPC分类号： C07D251/24 ,  C08K5/3492

摘要： This invention relates generally to amido or carbamate substituted trisaryl-1,3,5-triazines and the use thereof to protect against degradation by environmental forces, inclusive of ultraviolet light, actinic radiation, oxidation, moisture, atmospheric pollutants and combinations thereof. The new class of trisaryl-1,3,5-triazines comprises an aryl ring attached to the triazine ring (and preferably an aryl ring containing a hydroxyl group, either free or blocked to form a latent stabilizer, ortho- to the point of attachment to the triazine ring) substituted with a group comprising a bondable amido/carbamate containing group para- to the point of attachment to the triazine ring. These materials may, under the appropriate circumstances, be bonded to formulations comprising coatings, polymers, resins, organic compounds and the like via reaction of the bondable functionality with the materials of the formulation. A method for stabilizing a material by incorporating such amido or carbamate substituted trisaryl-1,3,5-triazines is also disclosed.

摘要翻译： 本发明一般涉及酰氨基或氨基甲酸酯取代的三芳基-1,3,5-三嗪及其用于防止包括紫外光，光化辐射，氧化，水分，大气污染物及其组合在内的环境力的降解。 新一类的三芳基-1,3,5-三嗪包括连接到三嗪环上的芳环（和优选含有羟基的芳环，游离或封闭形成潜稳定剂，与附着点相邻 至三嗪环），其被包含与可结合的酰氨基/氨基甲酸酯的基团组成的基团取代成与三嗪环的连接点。 这些材料可以在适当的情况下通过可结合的官能团与制剂的材料的反应与包含涂料，聚合物，树脂，有机化合物等的制剂结合。 还公开了通过并入这种酰氨基或氨基甲酸酯取代的三芳基-1,3,5-三嗪来稳定材料的方法。

公开(公告)号：US08685256B2

公开(公告)日：2014-04-01

申请号：US13329963

申请日：2011-12-19

申请人： Morris Lewellyn ,  Alan S. Rothenberg ,  Haunn-Lin Tony Chen ,  Lino G. Magliocco ,  Thomas P. Sassi

发明人： Morris Lewellyn ,  Alan S. Rothenberg ,  Haunn-Lin Tony Chen ,  Lino G. Magliocco ,  Thomas P. Sassi

IPC分类号： C02F1/68 ,  C08F220/56 ,  C08L41/00 ,  C08L43/00 ,  C08L39/00 ,  C08F8/30 ,  C08F16/00 ,  C08F18/22 ,  C08F20/34 ,  C08F20/42 ,  C08F22/22 ,  C08F26/00 ,  C08F20/56 ,  C08C19/22 ,  C08F8/44 ,  B03D1/001

CPC分类号： C08F8/32 ,  C01F7/0653 ,  C08F20/56

摘要： Methods of producing microdispersions containing hydroxamated polymers by reacting water-in-oil microdispersions having vinyl polymers containing one or more pendant functional groups that react with hydroxylamine, with a hydroxylamine-free base substantially free of inorganic salt and containing less than 500 ppm hydrazine are disclosed herein, along with the microdispersions thereby obtained.

摘要翻译： 公开了通过使含有与羟胺反应的一个或多个侧基官能团的乙烯基聚合物的油包水微分散体与基本上不含无机盐并且含有小于500ppm肼的不含羟胺的碱反应来生产含有异羟肟化聚合物的微分散体的方法 在此，连同由此获得的微分散体一起。

公开(公告)号：US06727300B2

公开(公告)日：2004-04-27

申请号：US10087266

申请日：2001-10-25

申请人： Thomas P. Sassi

发明人： Thomas P. Sassi

IPC分类号： C08K53435

CPC分类号： C09K15/30 ,  C07D211/46 ,  C08K5/3435

摘要： Polymeric articles containing at least one polymeric material and a sufficient amount of at least one novel hindered amine light stabilizers to inhibit at least one of photo- or thermal degradation. The hindered amine light stabilizer may be a monomeric or an oligomeric hindered amine light stabilizer.

摘要翻译： 含有至少一种聚合物材料和足够量的至少一种新型受阻胺光稳定剂以抑制光或热降解中的至少一种的聚合制品。 受阻胺光稳定剂可以是单体或低聚受阻胺光稳定剂。

公开(公告)号：US06344505B1

公开(公告)日：2002-02-05

申请号：US09438754

申请日：1999-11-11

申请人： Donald H. Valentine, Jr. ,  John F. Stephen ,  Thomas P. Sassi

发明人： Donald H. Valentine, Jr. ,  John F. Stephen ,  Thomas P. Sassi

IPC分类号： C08K534

CPC分类号： C07D249/20 ,  C08K5/3475

摘要： Provided is a composition which contains a mono- or bis-benzotriazole compound, an N-oxide thereof, or a mixture of at least two of the preceding compounds. Representative bis-benzotriazole compounds include 3,3′-bis-(2H-benzotriazol-2-yl)-5,5′-di-tert-octyl-1,1′-biphenyl-2,2′-diols. Representative mono-benzotriazole compounds include 3-(2H-benzotriazol-2-yl)-5,5′-di-tert-octyl-1,1′-biphenyl-2,2′-diols. These mono- and bis-benzotriazole compounds are useful as stabilizers of degradable polymers against the degradative action of ultraviolet light. Also provided is a method of making these benzotriazole compounds by oxidative dimerization of the corresponding monomeric benzotriazole or by reductive cyclization of the corresponding azo- compound.

摘要翻译： 本发明提供含有单 - 或双 - 苯并三唑化合物，其N-氧化物或至少两种前述化合物的混合物的组合物。 代表性的双 - 苯并三唑化合物包括3,3'-双 - （2H-苯并三唑-2-基）-5,5'-二叔辛基-1,1'-联苯-2,2'-二醇。 代表性的单苯并三唑化合物包括3-（2H-苯并三唑-2-基）-5,5'-二叔辛基-1,1'-联苯-2,2'-二醇。 这些单 - 和双 - 苯并三唑化合物可用作抗降解聚合物的抗紫外线作用的稳定剂。 还提供了通过相应的单体苯并三唑的氧化二聚或通过相应的偶氮化合物的还原环化制备这些苯并三唑化合物的方法。