公开(公告)号：US5516870A

公开(公告)日：1996-05-14

申请号：US433181

申请日：1995-05-03

申请人： Timothy N. Biggs ,  Gary E. Le Grow

发明人： Timothy N. Biggs ,  Gary E. Le Grow

IPC分类号： C07F7/18 ,  C07F7/08 ,  C07F7/21 ,  C08G77/10 ,  C08G77/12 ,  C08G77/22 ,  C08G77/34 ,  C08G77/38 ,  C08G77/08

CPC分类号： C08G77/34 ,  C07F7/0829 ,  C08G77/12 ,  C08G77/38

摘要： Linear or straight-chain trimethylsiloxy endcapped methylhydrogen polysiloxanes are made by contacting hexamethyldisiloxane with a highly pure methylhydrogen cyclic siloxane, in the presence of anhydrous trifluoromethane sulfonic acid catalyst at room temperature. Trimethylsiloxy endcapped alkylmethyl siloxanes are made by reacting the linear or straight-chain trimethylsiloxy endcapped methylhydrogen polysiloxanes with an alpha-olefin, in the presence of a platinum catalyst. Alkylmethyl cyclic siloxanes containing zero parts per million residual .ident.SiH, are made by reacting anhydrous alpha-olefins and a highly pure methylhydrogen cyclic siloxane, in the presence of dried platinum supported on carbon catalyst.

摘要翻译： 线性或直链三甲基甲硅烷氧基封端的甲基氢聚硅氧烷是通过在无水三氟甲烷磺酸催化剂存在下在室温下使六甲基二硅氧烷与高纯度甲基氢环状硅氧烷接触来制备的。 三甲基甲硅烷氧基封端的烷基甲基硅氧烷通过在铂催化剂存在下使直链或直链的三甲基甲硅烷氧基封端的甲基氢聚硅氧烷与α-烯烃反应来制备。 在负载在碳催化剂上的干燥铂存在下，通过使无水α-烯烃和高纯度的甲基氢环状硅氧烷反应制备含有百万分之零残余= SiH的烷基甲基环状硅氧烷。

公开(公告)号：US5578692A

公开(公告)日：1996-11-26

申请号：US596973

申请日：1996-02-05

申请人： Timothy N. Biggs ,  Gary E. Le Grow

发明人： Timothy N. Biggs ,  Gary E. Le Grow

IPC分类号： C07F7/08 ,  C08G77/12 ,  C08G77/38 ,  C08G77/08

CPC分类号： C08G77/12 ,  C07F7/0879 ,  C08G77/38

摘要： Linear or straight-chain trimethylsiloxy endcapped methylhydrogen polysiloxanes are made by contacting hexamethyldisiloxane with a highly pure methylhydrogen cyclic siloxane, in the presence of anhydrous trifluoromethane sulfonic acid catalyst at room temperature. Trimethylsiloxy endcapped alkylmethyl siloxanes are made by reacting the linear or straight-chain trimethylsiloxy endcapped methylhydrogen polysiloxanes with an alpha-olefin, in the presence of a platinum catalyst. Alkylmethyl cyclic siloxanes containing zero parts per million residual .tbd.SiH, are made by reacting anhydrous alpha-olefins and a highly pure methylhydrogen cyclic siloxane, in the presence of dried platinum supported on carbon catalyst.

公开(公告)号：US5554708A

公开(公告)日：1996-09-10

申请号：US529789

申请日：1995-09-18

申请人： Timothy N. Biggs ,  Gary E. Le Grow

发明人： Timothy N. Biggs ,  Gary E. Le Grow

IPC分类号： C07F7/18 ,  C07F7/08 ,  C07F7/21 ,  C08G77/10 ,  C08G77/12 ,  C08G77/22 ,  C08G77/34 ,  C08G77/38 ,  C08G77/08

CPC分类号： C08G77/34 ,  C07F7/0829 ,  C08G77/12 ,  C08G77/38

摘要： Linear or straight-chain trimethylsiloxy endcapped methylhydrogen polysiloxanes are made by contacting hexamethyldisiloxane with a highly pure methylhydrogen cyclic siloxane, in the presence of anhydrous trifluoromethane sulfonic acid catalyst at room temperature. Trimethylsiloxy endcapped alkylmethyl siloxanes are made by reacting the linear or straight-chain trimethylsiloxy endcapped methylhydrogen polysiloxanes with an alpha-olefin, in the presence of a platinum catalyst. Alkylmethyl cyclic siloxanes containing zero parts per million residual .tbd.SiH, are made by reacting anhydrous alpha-olefins and a highly pure methylhydrogen cyclic siloxane, in the presence of dried platinum supported on carbon catalyst.

摘要翻译： 线性或直链三甲基甲硅烷氧基封端的甲基氢聚硅氧烷是通过在无水三氟甲烷磺酸催化剂存在下在室温下使六甲基二硅氧烷与高纯度甲基氢环状硅氧烷接触来制备的。 三甲基甲硅烷氧基封端的烷基甲基硅氧烷通过在铂催化剂存在下使直链或直链的三甲基甲硅烷氧基封端的甲基氢聚硅氧烷与α-烯烃反应来制备。 含有零百万份残留物3BOND SiH的烷基甲基环状硅氧烷通过在负载在碳催化剂上的干燥铂存在下，使无水α-烯烃和高纯度甲基氢环状硅氧烷反应而制得。

公开(公告)号：US06353073B1

公开(公告)日：2002-03-05

申请号：US09532715

申请日：2000-03-22

申请人： Timothy N. Biggs ,  Benigno A. Janeiro

发明人： Timothy N. Biggs ,  Benigno A. Janeiro

IPC分类号： C08G7708

CPC分类号： C08G77/26 ,  C08L83/08

摘要： The present invention provides near quantitative yields of greater than about 95% isomeric purity of poly(3-aminopropylmethylsiloxane)-poly(dimethylsiloxane) copolymers of the general formulae: Me3Si(H2NCH2CH2CH2MeSiO)w(Me2SiO)xOSiMe3 (H2NCH2CH2CH2MeSiO)y(Me2SiO)z wherein Me is methyl, w may range from 1 to about 100, x may range from 1 to about 100, y may range from 1 to about 6, z may range from 1 to about 6 and y+z may range from 3 to about 7. The present invention also provides a simple method for rapidly producing poly(3-aminopropylmethylsiloxane)-poly(dimethylsiloxane) copolymers of the general formulae: Me3Si(H2NCH2CH2CH2MeSiO)w(Me2SiO)xOSiMe3 (H2NCH2CH2CH2MeSiO)y(Me2SiO)z wherein Me is methyl, w may range from 1 to about 100, x may range from 1 to about 100, y may range from 1 to about 6, z may range from 1 to about 6, and y+z may range from 3 to about 7, the method comprising heating of poly(3-aminopropylmethylsiloxane) of at least 95% isomeric purity, a cyclodimethylsiloxane with a basic catalyst, and destroying the catalyst when the copolymerization reaction is complete.

摘要翻译： 本发明提供了以下通式的聚（3-氨基丙基甲基硅氧烷） - 聚（二甲基硅氧烷）共聚物的大约95％异构纯度的近似定量产率：其中Me是甲基，w可以在1至约100的范围内，x可以是 1至约100，y可以为1至约6，z可以为1至约6，y + z可为3至约7.本发明还提供了一种用于快速生产聚（3- 氨基丙基甲基硅氧烷） - 聚（二甲基硅氧烷）共聚物，其中Me是甲基，w可以在1至约100的范围内，x可以在1至约100的范围内，y可以在1至约6的范围内，z可以为1 至约6，y + z可以在3至约7的范围内，该方法包括加热至少95％异构纯度的聚（3-氨基丙基甲基硅氧烷），具有碱性催化剂的环二甲基硅氧烷，并且当共聚反应时破坏催化剂 做完了。

公开(公告)号：US06339137B1

公开(公告)日：2002-01-15

申请号：US09532714

申请日：2000-03-22

申请人： Timothy N. Biggs ,  Benigno A. Janeiro

发明人： Timothy N. Biggs ,  Benigno A. Janeiro

IPC分类号： C08G7708

CPC分类号： C07F7/21 ,  C08G77/045 ,  C08G77/26 ,  C08G77/34

摘要： The present invention provides near quantitative yields of greater than about 95% isomeric purity of poly(3-aminopropylmethylsiloxanes) of the general formulae: Me3Si(H2NCH2CH2CH2MeSiO)xOSiMe3 (H2NCH2CH2CH2MeSiO)y wherein Me is methyl, x may range from 2 to about 100 and y may range from 3 to about 7. The present invention also provides a simple method for rapidly producing poly(3-aminopropylmethylsiloxanes) of the general formulae: Me3Si(H2NCH2CH2CH2MeSiO)xOSiMe3 (H2NCH2CH2CH2MeSiO)y wherein Me is methyl, x may range from 2 to over 100 and y may range from 3 to about 7, the method comprising heating of 3-(3-aminopropyl)-1,1,1,3,5,5,5-heptamethyltrisiloxane, of at least 95% isomeric purity, with a basic catalyst, removing hexamethyldisiloxane, and decomposing the catalyst.

摘要翻译： 本发明提供了以下通式的聚（3-氨基丙基甲基硅氧烷）大于约95％异构纯度的近定量产率：其中Me为甲基，x可为2至约100，y可为3至约7。 本发明还提供了一种用于快速生产下列通式的聚（3-氨基丙基甲基硅氧烷）的简单方法：其中Me是甲基，x可以在2至100以上，y可以在3至约7的范围内，该方法包括加热 具有至少95％异构纯度的3-（3-氨基丙基）-1,1,1,3,5,5,5-七甲基三硅氧烷，与碱性催化剂，去除六甲基二硅氧烷并分解催化剂。

公开(公告)号：US5493041A

公开(公告)日：1996-02-20

申请号：US505725

申请日：1995-07-21

申请人： Timothy N. Biggs ,  Gary E. LeGrow

发明人： Timothy N. Biggs ,  Gary E. LeGrow

IPC分类号： C08G77/12 ,  C08G77/22 ,  C08G77/38 ,  C08G77/50 ,  C07F7/08

CPC分类号： C08G77/38 ,  C08G77/12 ,  C08G77/50

摘要： The crosslinking and simultaneous alkylation of poly(hydridomethylsiloxanes) form crosslinked siloxanes having n-alkylmethyl groups. Without changing the chain length of the poly(hydridomethylsiloxane) starting material, a family of lightly crosslinked siloxanes having n-alkylmethyl groups, with a range of viscosities, can be produced using one or more alpha-olefins along with a small amount of an unconjugated alpha, omega-diene added as a crosslinker. The poly(hydridomethyl siloxanes) are made from highly pure silanol-free hexamethyldisiloxane and highly pure mixtures of silanol-free tetramethylcyclotetrasiloxane (D.sup.H 4) and pentamethylcyclopentasiloxane D.sup.H 5 containing no more than about 100 parts per million (ppm) water, with anhydrous trifluoromethane sulfonic acid (triflic acid, CF.sub.3 SO.sub.3 H), at room temperature, to provide linear poly(hydridomethylsiloxanes) having degrees of polymerization of up to about 250.

摘要翻译： 聚（羟甲基硅氧烷）的交联和同时烷基化形成具有正烷基甲基的交联硅氧烷。 在不改变聚（羟基甲基硅氧烷）起始材料的链长度的情况下，可以使用一种或多种α-烯烃以及少量未共轭的α-烯烃制备具有一定粘度范围的具有正烷基甲基的轻度交联的硅氧烷族 α，ω-二烯作为交联剂加入。 聚（氢化甲基硅氧烷）由高纯度无硅烷醇六甲基二硅氧烷和不含硅烷醇的四甲基环四硅氧烷（DH4）和含有不超过约100ppm（ppm）水的五甲基环五硅氧烷DH5与无水三氟甲磺酸（ 三氟甲磺酸，CF 3 SO 3 H），以提供具有高达约250的聚合度的线性聚（羟甲基硅氧烷）。