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1.发明授权Polymer and inorganic-organic hybrid composites and methods for making and using same 失效聚合物和无机 - 有机杂化复合材料及其制备和使用方法公开(公告)号：US06548590B1
公开(公告)日：2003-04-15
申请号：US09532993
申请日：2000-03-22
IPC分类号： C08K334
CPC分类号： C08K9/08
摘要： Composites which include a polymer matrix having natural free volume therein and an inorganic or organic material disposed in the natural free volume of the polymer matrix are disclosed. In addition, methods for making a composite are described. A polymer matrix having free volume therein is provided. The free volume is evacuated, and inorganic or organic molecules are infused into the evacuated free volume of the polymer matrix. The inorganic or organic molecules can then be polymerized under conditions effective to cause the polymerized inorganic or organic molecules to assemble into macromolecular networks. Alternatively, where the polymer matrix contains a functionality, the inorganic or organic molecules can be treated under conditions effective to cause the inorganic or organic molecules to interact with the polymer matrix's functionality. Use of the disclosed composites as photoradiation shields and filters, electromagnetic radiation shields and filters, antistatic layers, heterogeneous catalysts, conducting electrodes, materials having flame and heat retardant properties; components in the construction of electrolytic cells, fuel cells, and optoelectronic devices, is also described.
摘要翻译： 公开了包括其中具有天然自由体积的聚合物基质和设置在聚合物基质的天然自由体积中的无机或有机材料的复合材料。 此外，描述了制备复合材料的方法。 提供其中具有自由体积的聚合物基质。 抽空自由体积，将无机或有机分子注入聚合物基体的抽真空体积中。 然后无机或有机分子可以在有效地使聚合的无机或有机分子组装成大分子网络的条件下聚合。 或者，当聚合物基质含有官能团时，可以在有效使无机或有机分子与聚合物基质的官能团相互作用的条件下处理无机或有机分子。 使用所公开的复合材料作为光辐射屏蔽和滤光器，电磁辐射屏蔽和滤光器，抗静电层，非均相催化剂，导电电极，具有火焰和阻热特性的材料; 还描述了电解池，燃料电池和光电子器件的构造中的组件。
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2.发明授权Polymer and inorganic-organic hybrid composites and methods for making same 失效聚合物和无机 - 有机杂化复合材料及其制备方法
公开(公告)号：US5977241A
公开(公告)日：1999-11-02
申请号：US833290
申请日：1997-04-04
CPC分类号： H01M4/667 , C08F283/00 , C09D5/1612 , H01M8/1004 , H01M2/164 , Y10S525/903 , Y10T428/24999 , Y10T428/249991
摘要： Composites which include a polymer matrix having natural free volume therein and an inorganic or organic material disposed in the natural free volume of the polymer matrix are disclosed. In addition, methods for making a composite are described. A polymer matrix having free volume therein is provided. The free volume is evacuated, and inorganic or organic molecules are infused into the evacuated free volume of the polymer matrix. The inorganic or organic molecules can then be polymerized under conditions effective to cause the polymerized inorganic or organic molecules to assemble into macromolecular networks. Alternatively, where the polymer matrix contains a functionality, the inorganic or organic molecules can be treated underconditions effective to cause the inorganic or organic molecules to interact with the polymer matrix's functionality. Use of the disclosed composites as photoradiation shields and filters, electromagnetic radiation shields and filters, antistatic layers, heterogeneous catalytic substrates, conducting electrodes, materials having flame and heat retardant properties, and components in the construction of electrolytic cells, fuel cells, and optoelectronic devices is also described.
摘要翻译： 公开了包括其中具有天然自由体积的聚合物基质和设置在聚合物基质的天然自由体积中的无机或有机材料的复合材料。 此外，描述了制备复合材料的方法。 提供其中具有自由体积的聚合物基质。 抽空自由体积，将无机或有机分子注入聚合物基体的抽真空体积中。 然后无机或有机分子可以在有效地使聚合的无机或有机分子组装成大分子网络的条件下聚合。 或者，当聚合物基质含有官能团时，无机或有机分子可以在有效地使无机或有机分子与聚合物基质的官能团相互作用的条件下进行处理。 使用所公开的复合材料作为光辐射屏蔽和滤光器，电磁辐射屏蔽和滤光器，抗静电层，非均相催化基板，导电电极，具有火焰和阻热性质的材料，以及在电解池，燃料电池和光电子器件的构造中的组件 也被描述。
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公开(公告)号：US06608129B1
公开(公告)日：2003-08-19
申请号：US09533894
申请日：2000-03-22
IPC分类号： C08K318
CPC分类号： H01M4/667 , C08F283/00 , C09D5/1612 , H01M2/164 , H01M8/1004
摘要： Composites which include a polymer matrix having natural free volume therein and an inorganic or organic material disposed in the natural free volume of the polymer matrix are disclosed. In addition, methods for making a composite are described. A polymer matrix having free volume therein is provided. The free volume is evacuated, and inorganic or organic molecules are infused into the evacuated free volume of the polymer matrix. The inorganic or organic molecules can then be polymerized under conditions effective to cause the polymerized inorganic or organic molecules to assemble into macromolecular networks. Alternatively, where the polymer matrix contains a functionality, the inorganic or organic molecules can be treated under conditions effective to cause the inorganic or organic molecules to interact with the polymer matrix's functionality. Use of the disclosed composites as photoradiation shields and filters, electromagnetic radiation shields and filters, antistatic layers, heterogeneous catalysts, conducting electrodes, materials having flame and heat retardant properties, components in the construction of electrolytic cells, fuel cells, and optoelectronic devices, and antifouling coatings is also described.
摘要翻译： 公开了包括其中具有天然自由体积的聚合物基质和设置在聚合物基质的天然自由体积中的无机或有机材料的复合材料。 此外，描述了制备复合材料的方法。 提供其中具有自由体积的聚合物基质。 抽空自由体积，将无机或有机分子注入聚合物基体的抽真空体积中。 然后无机或有机分子可以在有效地使聚合的无机或有机分子组装成大分子网络的条件下聚合。 或者，当聚合物基质含有官能团时，可以在有效使无机或有机分子与聚合物基质的官能团相互作用的条件下处理无机或有机分子。 使用所公开的复合材料作为光辐射屏蔽和滤光器，电磁辐射屏蔽和滤光器，抗静电层，非均相催化剂，导电电极，具有火焰和阻热性能的材料，电解池结构中的组件，燃料电池和光电器件，以及 还描述了防污涂料。
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公开(公告)号：US5703173A
公开(公告)日：1997-12-30
申请号：US689707
申请日：1996-08-16
摘要： Novel metallohalopolymers comprising an oxyhalopolymer and a transition metal covalently bonded to an oxygen site on the oxyhalopolymer possess desirable properties of inertness, stability, hydrophobicity and high electronegativity like fluoropolymers such as PTFE. The metallohalopolymers also possess unusual superacidic properties making oxygen-containing sites on the polymeric backbone highly nucleophilic and reactive with transition metals for synthesis of stable metallized polymers without requiring exposure to destructive calcining temperatures or intermediate chelating organosilane linking agents. The transition metals can be covalently bonded directly to the polymeric support to form metallohalopolymers for use as catalysts in the synthesis of chemicals, biocides and useful articles of manufacture, such as filtration devices containing the biocidally active metallohalopolymers.
摘要翻译： 包含羟基卤聚合物和共价键合到氧基聚合物上的氧位的过渡金属的新型金属卤共聚物具有惰性，稳定性，疏水性和诸如PTFE等含氟聚合物的高电负性的所需性质。 金属卤化物还具有不寻常的超酸性质，使聚合物骨架上的含氧位置高度亲核，并与过渡金属反应，用于合成稳定的金属化聚合物，而不需要暴露于破坏性煅烧温度或中间螯合有机硅烷连接剂。 过渡金属可以直接共价结合到聚合物载体上以形成用作合成化学品，杀生物剂和有用制品的催化剂的金属卤聚合物，例如含有生物活性金属卤代聚合物的过滤装置。
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公开(公告)号：US07217754B2
公开(公告)日：2007-05-15
申请号：US10412616
申请日：2003-04-12
IPC分类号： C08K3/22
CPC分类号： H01M4/667 , C08F283/00 , C08K9/08 , C09D5/1612 , H01M2/164 , H01M8/1004
摘要： Composites which include a polymer matrix having natural free volume therein and an inorganic or organic material disposed in the natural free volume of the polymer matrix are disclosed. In addition, methods for making a composite are described. A polymer matrix having free volume therein is provided. The free volume is evacuated, and inorganic or organic molecules are infused into the evacuated free volume of the polymer matrix. The inorganic or organic molecules can then be polymerized under conditions effective to cause the polymerized inorganic or organic molecules to assemble into nanoparticles or other types of macromolecular networks. Alternatively, where the polymer matrix contains a functionality, the inorganic or organic molecules can be treated under conditions effective to cause the inorganic or organic molecules to interact with the polymer matrix's functionality. Use of the disclosed composites as photoradiation shields and filters, electromagnetic radiation shields and filters, antistatic layers, heterogeneous catalysts, conducting electrodes, materials having flame and heat retardant properties, components in the construction of electrolytic cells, fuel cells, and optoelectronic devices, and antifouling coatings is also described.
摘要翻译： 公开了包括其中具有天然自由体积的聚合物基质和设置在聚合物基质的天然自由体积中的无机或有机材料的复合材料。 此外，描述了制备复合材料的方法。 提供其中具有自由体积的聚合物基质。 抽空自由体积，将无机或有机分子注入聚合物基体的抽真空体积中。 然后无机或有机分子可在有效地使聚合的无机或有机分子组装成纳米颗粒或其它类型的大分子网络的条件下聚合。 或者，当聚合物基质含有官能团时，可以在有效使无机或有机分子与聚合物基质的官能团相互作用的条件下处理无机或有机分子。 使用所公开的复合材料作为光辐射屏蔽和滤光器，电磁辐射屏蔽和滤光器，抗静电层，非均相催化剂，导电电极，具有火焰和阻热性能的材料，电解池结构中的组件，燃料电池和光电器件，以及 还描述了防污涂料。
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公开(公告)号：US06428887B1
公开(公告)日：2002-08-06
申请号：US09239108
申请日：1999-01-27
IPC分类号： B32B1508
CPC分类号： B32B7/12 , C09J7/245 , C09J2427/006 , Y10T156/1097 , Y10T428/28 , Y10T428/31522 , Y10T428/3154
摘要： There is disclosed adhesive-oxyhalopolymer composites having surface hydrogen and oxygen or oxygen functionality groups wherein the oxygen or oxygen functionality sites are chemically bonded to an adhesive material forming a stable and permanent bond with surprisingly and unexpected superior bond strength. The adhesive-oxyhalopolymer composites comprise an oxyhalopolymer prepared from a halopolymer having from about 1 to 100 percent of surface halogens permanently substituted with hydrogen and oxygen or oxygen-containing groups of which from about 3 to about 30 percent of the substituted halogens are replaced with oxygen or oxygen-containing groups and from about 70 to about 97 percent of the substituted halogens are replaced with hydrogen atoms and the oxyhalopolymer is chemically bonded to an adhesive material.
摘要翻译： 公开了具有表面氢和氧或氧官能团基团的粘合剂 - 氧基聚合物复合材料，其中氧或氧官能度位点化学键合到形成稳定且永久的粘合剂的粘合剂材料，具有令人惊奇和意想不到的优异的粘结强度。 粘合剂 - 氧基聚合物复合材料包含由卤代聚合物制备的氧卤聚合物，所述卤代聚合物具有约1至100％的永久地被氢取代的表面卤素，并且氧或含氧基团，其中约3至约30％的取代的卤素被氧代替 或含氧基团，并且约70至约97％的取代的卤素被氢原子替代，并且氧基聚合物与粘合剂材料化学键合。
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7.发明申请Methods and materials for reducing damage from environmental electromagnetic effects 审中-公开降低环境电磁效应造成损害的方法和材料公开(公告)号：US20080131609A1
公开(公告)日：2008-06-05
申请号：US11807189
申请日：2007-05-26
IPC分类号： B05D1/36
CPC分类号： B32B15/08 , B32B15/02 , B32B15/14 , B32B27/304 , B32B27/322 , B32B2307/212 , B32B2605/08 , B32B2605/16 , B32B2605/18 , H05K9/0084
摘要： Disclosed is a method of reducing damage resulting from environmental electromagnetic effects on a non-metallic surface. The method includes disposing a polymeric sheet material over the non-metallic surface and disposing a metal layer between the non-metallic surface and the polymeric sheet material. Objects which includes a substrate having a non-metallic surface, a halopolymer sheet material disposed over the substrate's non-metallic surface, and a metal layer disposed between the halopolymer sheet material and the substrate's non-metallic surface are also described. Laminates are also disclosed. One such laminate includes a metal layer having a first surface and a second surface, a halopolymer sheet material bonded or adhered to the first surface of the metal layer, and an adhesive disposed on the second surface of the metal layer. Another such laminate includes a halopolymer fabric having a first surface and a second surface, a metal layer bonded or adhered to the first surface of the halopolymer fabric, and an adhesive disposed on the second surface of the halopolymer fabric.
摘要翻译： 公开了一种在非金属表面上减少由环境电磁效应引起的损伤的方法。 该方法包括在非金属表面上设置聚合物片材，并在非金属表面和聚合物片材之间设置金属层。 还描述了包括具有非金属表面的基底的物体，设置在基底非金属表面上的卤素聚合物片材和设置在卤素聚合物片材和基底的非金属表面之间的金属层。 还披露了层压板。 一种这样的层压体包括具有第一表面和第二表面的金属层，结合或粘附到金属层的第一表面的卤素聚合物片材料和设置在金属层的第二表面上的粘合剂。 另一种这样的层压体包括具有第一表面和第二表面的卤素聚合物织物，粘合或粘附到卤素聚合物织物的第一表面的金属层，以及设置在卤素聚合物织物的第二表面上的粘合剂。
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8.发明授权Methods and materials for reducing damage from environmental electromagnetic effects 失效降低环境电磁效应造成损害的方法和材料公开(公告)号：US07223312B2
公开(公告)日：2007-05-29
申请号：US10883481
申请日：2004-07-01
CPC分类号： B32B15/08 , B32B15/02 , B32B15/14 , B32B27/304 , B32B27/322 , B32B2307/212 , B32B2605/08 , B32B2605/16 , B32B2605/18 , H05K9/0084
摘要： Disclosed is a method of reducing damage resulting from environmental electromagnetic effects on a non-metallic surface. The method includes disposing a polymeric sheet material over the non-metallic surface and disposing a metal layer between the non-metallic surface and the polymeric sheet material. Objects which includes a substrate having a non-metallic surface, a halopolymer sheet material disposed over the substrate's non-metallic surface, and a metal layer disposed between the halopolymer sheet material and the substrate's non-metallic surface are also described. Laminates are also disclosed. One such laminate includes a metal layer having a first surface and a second surface, a halopolymer sheet material bonded or adhered to the first surface of the metal layer, and an adhesive disposed on the second surface of the metal layer. Another such laminate includes a halopolymer fabric having a first surface and a second surface, a metal layer bonded or adhered to the first surface of the halopolymer fabric, and an adhesive disposed on the second surface of the halopolymer fabric.
摘要翻译： 公开了一种在非金属表面上减少由环境电磁效应引起的损伤的方法。 该方法包括在非金属表面上设置聚合物片材，并在非金属表面和聚合物片材之间设置金属层。 还描述了包括具有非金属表面的基底的物体，设置在基底的非金属表面上的卤素聚合物片材和设置在卤素聚合物片材和基底的非金属表面之间的金属层。 还披露了层压板。 一种这样的层压体包括具有第一表面和第二表面的金属层，结合或粘附到金属层的第一表面的卤素聚合物片材料和设置在金属层的第二表面上的粘合剂。 另一种这样的层压体包括具有第一表面和第二表面的卤素聚合物织物，粘合或粘附到卤素聚合物织物的第一表面的金属层，以及设置在卤素聚合物织物的第二表面上的粘合剂。
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9.发明授权Oxyhalopolymer protective multifunctional appliqués and paint replacement films 有权氧化聚合物保护性多功能贴花和油漆更换膜公开(公告)号：US06790526B2
公开(公告)日：2004-09-14
申请号：US10211739
申请日：2002-08-02
申请人： Terrence G. Vargo , Timothy S. Koloski , John M. Brupbacher , Andrew W. Dalgleish , Garner S. Holdsworth
发明人： Terrence G. Vargo , Timothy S. Koloski , John M. Brupbacher , Andrew W. Dalgleish , Garner S. Holdsworth
IPC分类号： B32B900
CPC分类号： B32B7/12 , B32B15/08 , B32B2307/21 , B32B2307/30 , B32B2307/40 , B32B2319/00 , B32B2331/00 , B32B2361/00 , B32B2363/00 , B32B2367/00 , B32B2375/00 , B32B2605/00 , C09J5/02 , C09J7/245 , C09J2427/006 , Y10T428/28 , Y10T428/287 , Y10T428/31511 , Y10T428/31529 , Y10T428/3154 , Y10T428/31544 , Y10T428/31551 , Y10T428/31678 , Y10T428/31786 , Y10T428/31855 , Y10T428/31938
摘要： Novel appliqués comprising oxyhalopolymer-adhesive composites wherein the adhesive layer of the composite is chemically bonded to reactive sites on at least one side of the oxyhalopolymer layer, possess superior peel strengths, resistance to delamination and protective properties, including protection of surfaces from lightning strike to seamless protective liners for tanks. The appliques are suitable for printing architectural designs thereon. Multilayered specialty appliqués can be fabricated from the above fundamental oxyhalopolymer-adhesive composite structure, including layered adhesives for encapsulating tridimensional mechanical and electrical devices, such as RF, or microwave sensitive antennae for transmitting and receiving communications, providing protection from environmental electromagnetic effects (E3), shock and impact resistance, multidimensional deformable structures; housing for temperature control systems, etc. The properties of the appliqués can be modified by introducing various additives to the halopolymer and/or adhesive layers to customize electrical, and optical shielding, or reflectivity, corrosion resistance, and the like.
摘要翻译： 包含含氧卤聚合物 - 粘合剂复合材料的新型贴花，其中复合材料的粘合剂层化学键合在羟基卤聚合物层的至少一侧上的反应位点，具有优异的剥离强度，抗分层性和保护性能，包括保护表面免受雷击 坦克的无缝防护衬垫。 贴花适用于印刷其上的建筑设计。 多层专用贴花可以由上述基础氧基聚合物 - 粘合剂复合结构制成，包括用于封装三维机械和电气设备的分层粘合剂，例如用于发射和接收通信的RF或微波敏感天线，提供防止环境电磁效应的保护（E < 3>），冲击和抗冲击，多维可变形结构; 用于温度控制系统的壳体等。可以通过向卤代聚合物和/或粘合剂层中引入各种添加剂来定制贴花的性质，以定制电气，光学屏蔽或反射性，耐腐蚀性等。
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10.发明授权公开(公告)号：US06232386B1
公开(公告)日：2001-05-15
申请号：US08997012
申请日：1997-12-23
IPC分类号： C08J510
CPC分类号： C08F283/00 , C09D5/1612 , H01M2/164 , H01M4/667 , H01M8/1004
摘要： Oxyhalopolymer composites which include an oxyhalopolymer having free volume therein and an inorganic or organic material disposed in the free volume of the oxyhalopolymer are disclosed. Also disclosed is a surface-oxyhalogenated non-halopolymer composite. The composite includes a surface-oxyhalogenated non-halopolymer having free volume therein and an inorganic or organic material disposed in the free volume of the surface-oxyhalogenated non-halopolymer. Methods for making and using these composites are also described.
摘要翻译： 公开了包含其中具有自由体积的含氧卤聚合物和设置在氧基聚氧乙烯的自由体积中的无机或有机材料的氧基聚合物复合材料。 还公开了表面 - 卤代卤代聚合物复合材料。 复合材料包括其中具有自由体积的表面卤氧化非卤代聚合物和位于表面 - 卤代卤化非卤代聚合物的自由体积中的无机或有机材料。 还描述了制备和使用这些复合材料的方法。
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