摘要:
A polymerized toner of core-shell structure, comprising core particles composed of colored polymer particles, which comprise a polyfunctional ester compound formed of a trifunctional or still higher polyfunctional polyhydric alcohol and a carboxylic acid, and a colorant, and shell which is formed of a polymer having a glass transition temperature higher than that of a polymer component making up the core particles and covers each of the core particles, a production process thereof, an image forming process comprising using the polymerized toner, and an image forming apparatus containing the polymerized toner.
摘要:
Disclosed herein are a polymerized toner of core-shell structure, comprising core particles composed of colored polymer particles having a volume average particle diameter (dv) of 0.5-20 .mu.m and a ratio (dv/dp) of the volume average particle diameter (dv) to a number average particle diameter (dp) of at most 1.7, and shell which is formed of a polymer layer having an average film thickness of 0.001-0.1 .mu.m and covers each of the core particles, and a production process thereof.
摘要:
Disclosed herein are a polymerized toner of core-shell structure, comprising core particles composed of colored polymer particles having a volume average particle diameter (dv) of 0.5-20 .mu.m and a ratio (dv/dp) of the volume average particle diameter (dv) to a number average particle diameter (dp) of at most 1.7, and shell which is formed of a polymer layer having an average film thickness of 0.001-0.1 .mu.m and covers each of the core particles, and a production process thereof.
摘要:
A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of main-chain carbon-carbon double bonds of a ring-open polymer obtained by ring-opening polymerization of 2-norbornene. The hydrogenated norbornene ring-open polymer has a weight average molecular weight determined by gel permeation chromatography (GPC) of 50,000 to 200,000, a molecular weight distribution of 1.5 to 10.0, and a melting point of 110 to 145° C. A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of carbon-carbon double bonds of a ring-open polymer obtained by ring-opening copolymerization of 2-norbornene and a substituent-containing norbornene monomer, wherein the proportion of a repeating unit (A) derived from the 2-norbornene with respect to all repeating units is 90 to 99 wt % and the proportion of a repeating unit (B) derived from the substituent-containing norbornene monomer with respect to all repeating units is 1 to 10 wt %. A resin composition and a molding material.
摘要:
A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of main-chain carbon-carbon double bonds of a ring-open polymer obtained by ring-opening polymerization of 2-norbornene. The hydrogenated norbornene ring-open polymer has a weight average molecular weight determined by gel permeation chromatography (GPC) of 50,000 to 200,000, a molecular weight distribution of 1.5 to 10.0, and a melting point of 110 to 145° C. A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of carbon-carbon double bonds of a ring-open polymer obtained by ring-opening copolymerization of 2-norbornene and a substituent-containing norbornene monomer, wherein the proportion of a repeating unit (A) derived from the 2-norbornene with respect to all repeating units is 90 to 99 wt % and the proportion of a repeating unit (B) derived from the substituent-containing norbornene monomer with respect to all repeating units is 1 to 10 wt %. A resin composition and a molding material.
摘要:
A process for producing a polymer toner comprises the steps of pouring a polymerizable monomer composition containing at least a polymerizable monomer and a colorant, but containing no oil-soluble polymerization initiator into an aqueous dispersion medium containing a dispersing agent; adding an oil-soluble polymerization initiator to the polymerizable monomer composition while stirring the composition to form primary droplets thereof, thereby bringing the droplets of the polymerizable monomer composition into contact with droplets of the oil-soluble polymerization initiator to form droplets of a polymerizable monomer composition containing the oil-soluble polymerization initiator; further continuing the stirring to form secondary droplets having desired droplet sizes; and then conducting suspension polymerization of the polymerizable monomer composition.
摘要:
A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of main-chain carbon-carbon double bonds of a ring-open polymer which is obtained by ring-opening polymerization of 2-norbornene is disclosed. The hydrogenated norbornene ring-open polymer has a weight average molecular weight (Mw) determined by gel permeation chromatography (GPC) of 50,000 to 200,000, a molecular weight distribution (Mw/Mn) of 1.5 to 10.0, and a melting point of 110 to 145° C. Also disclosed is a hydrogenated norbornene ring-open polymer (hydrogenated polymer) obtained by hydrogenating 80% or more of carbon-carbon double bonds of a ring-open polymer which is obtained by ring-opening copolymerization of 2-norbornene and a substituent-containing norbornene monomer, wherein the proportion of a repeating unit (A) derived from the 2-norbornene with respect to all repeating units is 90 to 99 wt % and the proportion of a repeating unit (B) derived from the substituent-containing norbornene monomer with respect to all repeating units is 1 to 10 wt %. The hydrogenated ring-open polymer has a melting point of 110 to 145° C. A resin composition and a molding material containing these hydrogenated polymers, a molded article, a resin film, a resin sheet, a multilayer laminate, a packing material, a molded article for medical supplies, a blister molding sheet, a blister molded article, and a multilayer blow-molded container made of these hydrogenated polymers are also disclosed.
摘要:
A toner for development of electrostatic images, comprising colored particles containing at least a binder resin, a colorant and a softening agent, wherein the softening agent is an organic compound having a molecular weight of at least 1,000, a solubility of at least 5 g in 100 g of styrene as measured at 25° C., and an acid value of at most 10 mg KOH/g. The toner is excellent in fixing ability, shelf stability and flowability and permits forming images having high image quality. A production process thereof is also provided.
摘要:
A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of main-chain carbon-carbon double bonds of a ring-open polymer obtained by ring-opening polymerization of 2-norbornene. The hydrogenated norbornene ring-open polymer has a weight average molecular weight determined by gel permeation chromatography (GPC) of 50,000 to 200,000, a molecular weight distribution of 1.5 to 10.0, and a melting point of 110 to 145° C. A hydrogenated norbornene ring-open polymer obtained by hydrogenating 80% or more of carbon-carbon double bonds of a ring-open polymer obtained by ring-opening copolymerization of 2-norbornene and a substituent-containing norbornene monomer, wherein the proportion of a repeating unit (A) derived from the 2-norbornene with respect to all repeating units is 90 to 99 wt % and the proportion of a repeating unit (B) derived from the substituent-containing norbornene monomer with respect to all repeating units is 1 to 10 wt %. A resin composition and a molding material.
摘要:
A polymer composition includes (1) a crystalline norbornene-based polymer and (2) an amorphous alicyclic structure-containing polymer in a weight ratio of 90:10 to 50:50, the crystalline norbornene-based polymer (1) having a melting point of 110 to 145° C., an Mw measured by gel permeation chromatography of 50,000 to 200,000, and a ratio Mw/Mn of 1.5 to 10.0, and obtained by ring-opening polymerization of a polymerizable monomer mixture (1) containing 90 to 100 wt % of 2-norbornene and 0 to 10 wt % of a substituent-containing norbornene monomer, and hydrogenating the resulting polymer, and the amorphous alicyclic structure-containing polymer (2) having a Tg of 50° C. or more and not having a melting point, and obtained by polymerization of a polymerizable monomer mixture (2) containing a 2-norbornene compound and a dicyclopentadiene compound in an amount of 50 wt % or more and less than 90 wt % in total. A film obtained by molding the polymer composition has a steam permeability of 0.40 g/m2·day or less and a haze value of 20% or less when the film has a thickness of 100 μm. A medical container is obtained by molding the polymer composition.