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    Use of metal complex compounds as catalysts for oxidation using molecular oxygen or air
    1.
    发明申请
    Use of metal complex compounds as catalysts for oxidation using molecular oxygen or air 审中-公开

    公开(公告)号：US20060019853A1

    公开(公告)日：2006-01-26

    申请号：US10531907

    申请日：2003-10-21

    申请人： Torsten Wieprecht ,  Gunther Schlingloff ,  Juntao Xia ,  Uwe Heinz ,  Abert Schneider ,  Marie-Josee Dubs ,  Frank Bachmann ,  Menno Hazekamp ,  Josef Dannacher

    发明人： Torsten Wieprecht ,  Gunther Schlingloff ,  Juntao Xia ,  Uwe Heinz ,  Abert Schneider ,  Marie-Josee Dubs ,  Frank Bachmann ,  Menno Hazekamp ,  Josef Dannacher

    IPC分类号： C07F15/00 ,  C11D3/28

    CPC分类号： C11D3/3932 ,  C11D3/168

    摘要： Use, as a catalyst for oxidation reactions using molecular oxygen and/or air, of at least one metal complex compound of formula (1) wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge of Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; —SR13, —SO2R13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —NR14R15; —(C1-C6alkylene)-NR14R15; —N(+)R14R15R16; —(C1-C6alkylene)-N(+)R14R15R16; —N(R13)—(C1-C6alkylene)-NR14R15; —N[(C1-C6alkylene)-NR14R15]2; —N(R13)—(C1-C6alkylene)-N(+)R14R15R16; —N[(C1-C6alkylene)-N(+)R14R15R16]2; —N(R13)—N—R14R15 or —N(R13)N″R14R15R16, wherein R13 is as defined above and R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15, together with the nitrogen atom linking them, form an unsubstituted or substituted 5-, 6- or 7-membered ring which may contain further hetero atoms. [LnMemXp]zYq  (1)

    Use of metal complex compounds as oxidation catalysts
    2.
    发明申请
    Use of metal complex compounds as oxidation catalysts 失效

    公开(公告)号：US20060100123A1

    公开(公告)日：2006-05-11

    申请号：US10520841

    申请日：2003-07-03

    申请人： Gunther Schlingloff ,  Torsten Wieprecht ,  Frank Bachmann ,  Josef Dannacher ,  Marie-Josee Dubs ,  Menno Hazenkamp ,  Uwe Heinz ,  Markus Frey ,  Albert Schneider

    发明人： Gunther Schlingloff ,  Torsten Wieprecht ,  Frank Bachmann ,  Josef Dannacher ,  Marie-Josee Dubs ,  Menno Hazenkamp ,  Uwe Heinz ,  Markus Frey ,  Albert Schneider

    IPC分类号： C11D3/00

    CPC分类号： C11D3/168 ,  C07D213/68 ,  C07D213/74 ,  C11D3/3932

    摘要： Use of metal complex compounds of formula (1) [LnMcmXp]zYq wherein Mc is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen: unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl: —SR13, —SO12R13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —NR14R15; —(C1-C6alkylene)-NR14R15; —NoR14R15R16; —(C1-C6alkylene)-NoR14R15R16; —N(R)15)—(C1-C6alkylene)-NR1R15; —N[(C1-C6alkylene)-NR14R15]2; —N(R13)—(C1-C6alkylene)-NoR14R15R16, —N[C1-C6alkylene)-NoR14R15R16]2; —N(R13)—N—R14R15 or —N(R13)—NoR14R15R16: wherein R13 is as defined above and R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further heterotatoms; with the proviso that (i) at least one of the substituents R1—R11 contains a quaternized atom which is not directly bonded to one of the three pyridine A, B or C and that (ii) Y is neither I′ nor Cl′ in the case that Me is Mn(II), R1—R5 and R7—R11 are hydrogen and R6 is formula (III) as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1), the novel ligands of formula (2) and their starting materials.

    Use of metal complex compounds as oxidation catalysts
    9.
    发明申请
    Use of metal complex compounds as oxidation catalysts 失效
    使用金属络合物作为氧化催化剂

    公开(公告)号：US20090068282A1

    公开(公告)日：2009-03-12

    申请号：US12288382

    申请日：2008-10-20

    申请人： Gunther Schlingloff ,  Torsten Wieprecht ,  Frank Bachmann ,  Josef Dannacher ,  Marie-Josee Dubs ,  Menno Hazenkamp ,  Grit Hansler (-Richter) ,  Brigitte Schmidt ,  Albert Schneider ,  Peter Weingartner

    发明人： Gunther Schlingloff ,  Torsten Wieprecht ,  Frank Bachmann ,  Josef Dannacher ,  Marie-Josee Dubs ,  Menno Hazenkamp ,  Grit Hansler (-Richter) ,  Brigitte Schmidt ,  Albert Schneider ,  Peter Weingartner

    IPC分类号： A01N59/00 ,  A01N25/00 ,  D21C3/20 ,  A01P1/00 ,  C07D213/22

    CPC分类号： B01J31/1815 ,  B01J23/34 ,  B01J2231/70 ,  B01J2231/72 ,  B01J2531/16 ,  B01J2531/46 ,  B01J2531/72 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847 ,  C07D213/61 ,  C07D213/68 ,  C07D213/74 ,  C07F13/005 ,  C11D3/3932 ,  D06L4/10 ,  D06L4/12 ,  D06P5/02 ,  D06P5/153 ,  D21C9/1036 ,  D21C9/163

    摘要： Use of metal complex compounds of formula [LnMemXp]zYq  (1), wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge Y), and L is a ligand of formula wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; —SR13, —SO2R13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —N(R13)—NR′13R″13 wherein R13, R′13 and R″13 are as defined above for R13; —NR14R15 or —N⊕R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).

    摘要翻译： 使用式<？in-line-formula description =“In-line Formulas”end =“lead”？> [LnMemXp] zYq（1），<？in-line-formula description =“In-line 其中Me为锰，钛，铁，钴，镍或铜，X为配位基或桥键基团，n和m各自独立地为1〜 8，p为0〜32的整数，z为金属络合物的电荷，Y为抗衡离子，q = z /（电荷Y），L为下式的配体，式中R1， R2，R3，R4，R5，R6，R7，R8，R9，R10和R11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基 -COOR 12或-SO 3 R 12，其中R 12在各种情况下为氢，阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13，-SO 2 R 13或-OR 13，其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -N（R13）-NR'13R''13其中R13，R'13和R'13如上对R13所定义; -NR14R15或-N⊕R14R15R16，其中R14，R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基，或者R14和R15与其键合的氮原子一起形成未取代或取代的5 可以任选地含有其它杂原子的6-或7-元环; 条件是R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11不同时为氢，作为氧化反应的催化剂，并且式（1）和新颖的新型金属络合物 式（2）的配体。