公开(公告)号：US20110149367A1

公开(公告)日：2011-06-23

申请号：US12991201

申请日：2009-05-07

申请人： Toshihiko Nagamura ,  Takeshi Sakano ,  Masaaki Ozawa ,  Akihiro Tanaka ,  Osamu Hirata ,  Keisuke Odoi

发明人： Toshihiko Nagamura ,  Takeshi Sakano ,  Masaaki Ozawa ,  Akihiro Tanaka ,  Osamu Hirata ,  Keisuke Odoi

IPC分类号： G02F1/15 ,  C08F259/00 ,  C09K3/00

CPC分类号： C08F8/30 ,  C09K9/02 ,  C09K2211/1029 ,  G02F1/15 ,  G02F2001/1515

摘要： The present invention relates to an electrochromic polymer compound composed of a hyperbranched polymer having electrochromic characteristics derived from a quaternary pyridinium salt, a terephthalic acid diester or a biphenyl-4,4′-diester structure, and a varnish, a thin film structure and an electrochromic device that are obtained by the polymer compound. The electrochromic material has high response speed, high coloring efficiency, and excellent repetition stability and can be used for a long time, and has excellent solubility in various solvents.

摘要翻译： 本发明涉及由具有源自季吡啶盐，对苯二甲酸二酯或联苯-4,4'-二酯结构的电致变色特征的超支化聚合物和清漆，薄膜结构和 通过高分子化合物获得的电致变色装置。 电致变色材料具有高响应速度，高着色效率和优异的重复稳定性，并且可长时间使用，并且在各种溶剂中具有优异的溶解性。

公开(公告)号：US08773745B2

公开(公告)日：2014-07-08

申请号：US12991201

申请日：2009-05-07

申请人： Toshihiko Nagamura ,  Masaaki Ozawa ,  Akihiro Tanaka ,  Osamu Hirata ,  Keisuke Odoi ,  Takeshi Sakano

发明人： Toshihiko Nagamura ,  Masaaki Ozawa ,  Akihiro Tanaka ,  Osamu Hirata ,  Keisuke Odoi ,  Takeshi Sakano

IPC分类号： G02F1/15 ,  C08F8/30 ,  C09K9/02

CPC分类号： C08F8/30 ,  C09K9/02 ,  C09K2211/1029 ,  G02F1/15 ,  G02F2001/1515

摘要： The present invention relates to an electrochromic polymer compound composed of a hyperbranched polymer having electrochromic characteristics derived from a quaternary pyridinium salt, a terephthalic acid diester or a biphenyl-4,4′-diester structure, and a varnish, a thin film structure and an electrochromic device that are obtained by the polymer compound. The electrochromic material has high response speed, high coloring efficiency, and excellent repetition stability and can be used for a long time, and has excellent solubility in various solvents.

摘要翻译： 本发明涉及由具有源自季吡啶盐，对苯二甲酸二酯或联苯-4,4'-二酯结构的电致变色特征的超支化聚合物和清漆，薄膜结构和 通过高分子化合物获得的电致变色装置。 电致变色材料具有高响应速度，高着色效率和优异的重复稳定性，并且可长时间使用，并且在各种溶剂中具有优异的溶解性。

公开(公告)号：US09029474B2

公开(公告)日：2015-05-12

申请号：US12450778

申请日：2008-04-23

申请人： Masaaki Ozawa ,  Keisuke Odoi ,  Hironori Atarashi ,  Kei-ichi Akabori ,  Toshihiko Nagamura ,  Keiji Tanaka

发明人： Masaaki Ozawa ,  Keisuke Odoi ,  Hironori Atarashi ,  Kei-ichi Akabori ,  Toshihiko Nagamura ,  Keiji Tanaka

IPC分类号： C08L51/00 ,  C08L41/00 ,  C08J7/12 ,  C08L101/00

CPC分类号： C08J7/12 ,  C08L101/005

摘要： The present invention relates to a process for producing a polymer structure comprising: mixing and unifying a matrix polymer made of a linear polymer and a highly-branched polymer having hydrophilic functional groups at molecular ends and to form a structure containing the matrix polymer and the highly-branched polymer; and subjecting the obtained structure to either immersion in water and/or a hydrophilic solvent or exposure to an atmosphere of vapor of water and/or a hydrophilic solvent at a temperature ranging from a temperature lower than Tg of the matrix polymer by 30° C. to decomposition temperature of the matrix polymer; wherein the hydrophilic functional groups at the molecular ends of the highly-branched polymer are distributed in outermost surface of the polymer structure at an enhanced density. The present invention also relates to a process for producing a polymer structure in which vinyl polymer chains are grafted to at least a part of the hydrophilic functional groups.

摘要翻译： 本发明涉及一种聚合物结构体的制造方法，其特征在于，在分子末端将由线性聚合物构成的基质聚合物和具有亲水性官能团的高支化聚合物混合均匀并形成含有基体聚合物的结构， 支链聚合物 并将得到的结构物浸入水和/或亲水性溶剂中或在低于基体聚合物的Tg的温度范围内暴露于水和/或亲水性溶剂的气体的气氛中30℃。 到基体聚合物的分解温度; 其中高度支化聚合物的分子末端的亲水官能团以增强的密度分布在聚合物结构的最外表面。 本发明还涉及其中乙烯基聚合物链接枝至至少一部分亲水官能团的聚合物结构的方法。

公开(公告)号：US20090163657A1

公开(公告)日：2009-06-25

申请号：US12083690

申请日：2006-10-24

申请人： Keiji Tanaka ,  Toshihiko Nagamura ,  Masaaki Ozawa ,  Akihiro Tanaka

发明人： Keiji Tanaka ,  Toshihiko Nagamura ,  Masaaki Ozawa ,  Akihiro Tanaka

IPC分类号： C08F28/00 ,  C08F14/00

CPC分类号： C08L101/005 ,  C08J3/005 ,  C08J2300/202

摘要： There is provided a novel, simple, general-purpose technique capable of being applied to the modification of the polymer surface and/or interface.A polymer structure whose surface and/or interface is modified is obtained by mixing a branched polymer (preferably a dendritic polymer, a comb-like polymer or a hyperbranched polymer) into a linear polymer as a matrix polymer to concentrate the branched polymer on the surface and/or interface of the matrix polymer.

摘要翻译： 提供了一种可应用于聚合物表面和/或界面的改性的新颖简单的通用技术。 其表面和/或界面被改性的聚合物结构是通过将支化聚合物（优选树枝状聚合物，梳状聚合物或超支化聚合物）混合为线性聚合物作为基质聚合物而获得的，以将支化聚合物浓缩在表面上 和/或基质聚合物的界面。

公开(公告)号：US07994228B2

公开(公告)日：2011-08-09

申请号：US12441193

申请日：2007-09-14

申请人： Toshihiko Nagamura

发明人： Toshihiko Nagamura

IPC分类号： B01J39/20 ,  C08F18/22 ,  C08F244/00

CPC分类号： C08G73/0233 ,  C08G73/0627 ,  C08L79/02 ,  C08L79/04

摘要： Provided is a novel ion-pair charge-transfer complex polymer suitable for use as a photo-functional material which shows extremely fast photoresponses in the wide wavelength range from visible to near infrared regions, and thermally stable, wherein the acceptor is a substituted bipyridinium cation expressed by the formula (I) below. In the formula, X represents a group bonded at the 4- or 2-position relative to the nitrogen atoms of the bipyridinium group and selected from the group consisting of phenyl, biphenyl, thienyl, bithienyl, terthienyl, furyl, fluorenyl, pyrenyl, perylenyl, and vinyl groups, or X may not be present so that the pyridinium groups are directly connected; and Z represents a polymer preferably from the ring-opening polymerization of an oxazoline derivative (e.g. one substituted with phenyl group). The anion as the donor is selected, for example, from chloride, bromide, iodide, tetraphenylborate or derivatives thereof.

摘要翻译： 提供了一种新颖的离子对电荷转移络合物聚合物，其适用于光能功能材料，其在从可见光到近红外区域的宽波长范围内显示极快的光响应，并且热稳定，其中受体是取代的双吡啶鎓阳离子 由下式（I）表示。 在该式中，X表示相对于联吡啶基的氮原子在4-或2-位键合的基团，选自苯基，联苯基，噻吩基，二噻吩基，噻吩基，呋喃基，芴基，芘基，苝基 和乙烯基，或者X可以不存在，使得吡啶鎓基团直接相连; Z表示优选由恶唑啉衍生物（例如被苯基取代的）的开环聚合形成的聚合物。 作为供体的阴离子选自例如氯化物，溴化物，碘化物，四苯基硼酸盐或其衍生物。

公开(公告)号：US20060146388A1

公开(公告)日：2006-07-06

申请号：US11366470

申请日：2006-03-03

申请人： Toshihiko Nagamura ,  Ikuo Matsukura

发明人： Toshihiko Nagamura ,  Ikuo Matsukura

IPC分类号： G02B26/00

CPC分类号： G02F1/0126 ,  G02F2202/13 ,  G02F2203/12

摘要： To provide a spatial optical modulation element having a long life free from a deterioration of optical modulation characteristics even if a high power laser beam with an ultra-short pulse is used as a modulation drive light. A spatial optical modulation element 1 wherein disposed between a prism 2 and an optical functional material layer 3 made of an optical functional material with the refractive index changeable by light irradiation, is a low refractive index layer 4 made of a transparent material with a refractive index lower than the refractive index of the dielectric. A spatial optical modulation method characterized in that using such a spatial optical modulation element 1, at the interface between the prism and the low refractive index layer, reflection of a to-be-modulated light 5 entering through the prism, is controlled by a modulation drive light 6.

摘要翻译： 为了提供即使使用具有超短脉冲的高功率激光束作为调制驱动光，也具有长寿命而不损失光调制特性的空间光调制元件。 设置在棱镜2和由光学功能材料制成的光学功能材料层3之间的空间光学调制元件1具有可通过光照射而变化的折射率的低折射率层4，其由具有折射率的透明材料制成 低于电介质的折射率。 一种空间光学调制方法，其特征在于，使用这样的空间光调制元件1，在棱镜与低折射率层之间的界面处，通过​​棱镜进入的被调制光5的反射通过调制 驱动灯6。

公开(公告)号：US07151625B2

公开(公告)日：2006-12-19

申请号：US11411805

申请日：2006-04-27

申请人： Toshihiko Nagamura ,  Ikuo Matsukura

发明人： Toshihiko Nagamura ,  Ikuo Matsukura

IPC分类号： G02F1/00 ,  G02F1/29 ,  G02F1/361

CPC分类号： B82Y20/00 ,  G02F1/011 ,  G02F1/0126 ,  G02F1/293 ,  G02F1/315 ,  G02F1/355 ,  G02F2202/13 ,  G02F2202/36 ,  G02F2203/12

摘要： To provide a spatial optical modulation element having a long life free from a deterioration of optical modulation characteristics even if a high power laser beam with an ultra-short pulse is used as a modulation drive light, and having a high response speed when e.g. a light having a wavelength of 1.55 μm is used.A spatial optical modulation element wherein disposed between a prism 2 and an optical functional material layer 3 made of an optical functional material with the complex index of refraction changeable by light irradiation, is a low refractive index layer 4 made of a transparent material with a refractive index lower than the refractive index of the prism 2, and carbon nanotubes are used as the optical function material.

摘要翻译： 即使使用具有超短脉冲的高功率激光作为调制驱动光，也具有高的响应速度的情况下，提供具有长寿命的光学调制特性的寿命长的空间光调制元件。 使用波长为1.55μm的光。 由棱镜2和光学功能材料层3构成的空间光学调制元件是具有通过光照射而变化的复折射率的光学功能材料层3，是由具有折射率的透明材料制成的低折射率层4 指数低于棱镜2的折射率，碳纳米管用作光学功能材料。

公开(公告)号：US07576829B2

公开(公告)日：2009-08-18

申请号：US10593170

申请日：2005-03-15

申请人： Hirotsugu Kikuchi ,  Tisato Kajiyama ,  Toshihiko Nagamura ,  Yoshiaki Hisakado

发明人： Hirotsugu Kikuchi ,  Tisato Kajiyama ,  Toshihiko Nagamura ,  Yoshiaki Hisakado

IPC分类号： C09K19/02

CPC分类号： C09K19/544 ,  C09K19/02 ,  C09K19/0275 ,  C09K19/586 ,  C09K2019/546 ,  G02F1/134363 ,  G02F1/13718 ,  G02F2001/13775 ,  G02F2001/13793

摘要： Presents a liquid crystal display device that does not require a surface orientation treatment, dramatically improves the response rate of dynamic image displays and does not experience light leaks when the display is black, which means to yield a dark field of vision. The liquid crystal display device comprises polymer-stabilized blue phase liquid crystals sandwiched between a pair of clear substrates. The liquid crystal display device obtained using polymer-stabilized blue phase liquid crystals exhibits large double refraction changes when an electrical field is applied in an in-plane direction to the cell substrates. The polymer-stabilized blue phases liquid crystals comprises a low molecular weight liquid crystal that allows a blue phase to appear between cholesteric and isotropic phases and polymer network formed in the low molecular weight liquid crystals. Furthermore, a liquid crystal display device that does not leak light when the display is black (yields a dark field of vision) can be obtained by optimizing the type and amount of a chiral dopant added to the liquid crystals.

摘要翻译： 提供不需要表面取向处理的液晶显示装置，显着提高动态图像显示的响应速度，并且当显示器为黑色时不会发生光泄漏，这意味着产生暗视野。 液晶显示装置包括夹在一对透明基板之间的聚合物稳定的蓝相液晶。 当使用聚合物稳定的蓝相液晶获得的液晶显示装置在向面板方向施加电场时显示出大的双折射变化。 聚合物稳定的蓝相液晶包括低分子量液晶，其允许在胆甾型和各向同性相之间出现蓝相，并在低分子量液晶中形成聚合物网络。 此外，通过优化添加到液晶中的手性掺杂剂的类型和量，可以获得当显示器黑色时不会发光的液晶显示装置（产生暗视野）。

公开(公告)号：US07453620B2

公开(公告)日：2008-11-18

申请号：US11366470

申请日：2006-03-03

申请人： Toshihiko Nagamura ,  Ikuo Matsukura

发明人： Toshihiko Nagamura ,  Ikuo Matsukura

IPC分类号： G02B1/03

CPC分类号： G02F1/0126 ,  G02F2202/13 ,  G02F2203/12

摘要： To provide a spatial optical modulation element having a long life free from a deterioration of optical modulation characteristics even if a high power laser beam with an ultra-short pulse is used as a modulation drive light. A spatial optical modulation element 1 wherein disposed between a prism 2 and an optical functional material layer 3 made of an optical functional material with the refractive index changeable by light irradiation, is a low refractive index layer 4 made of a transparent material with a refractive index lower than the refractive index of the dielectric. A spatial optical modulation method characterized in that using such a spatial optical modulation element 1, at the interface between the prism and the low refractive index layer, reflection of a to-be-modulated light 5 entering through the prism, is controlled by a modulation drive light 6.

摘要翻译： 为了提供即使使用具有超短脉冲的高功率激光束作为调制驱动光，也具有长寿命而不损失光调制特性的空间光调制元件。 设置在棱镜2和由光学功能材料制成的光学功能材料层3之间的空间光学调制元件1具有可通过光照射而变化的折射率的低折射率层4，其由具有折射率的透明材料制成 低于电介质的折射率。 一种空间光学调制方法，其特征在于，使用这样的空间光调制元件1，在棱镜与低折射率层之间的界面处，通过​​棱镜进入的被调制光5的反射通过调制 驱动灯6。

公开(公告)号：US20090286891A1

公开(公告)日：2009-11-19

申请号：US12441193

申请日：2007-09-14

申请人： Toshihiko Nagamura

发明人： Toshihiko Nagamura

IPC分类号： B01J39/20

CPC分类号： C08G73/0233 ,  C08G73/0627 ,  C08L79/02 ,  C08L79/04

摘要： Provided is a novel ion-pair charge-transfer complex polymer suitable for use as a photo-functional material which shows extremely fast photoresponses in the wide wavelength range from visible to near infrared regions, and thermally stable.An ion-pair charge-transfer complex polymer wherein the acceptor is a substituted bipyridinium cation expressed by the formula (I) below. In the formula, X represents a group bonded at the 4- or 2-position relative to the nitrogen atoms of the bipyridinium group and selected from the group consisting of phenyl, biphenyl, thienyl, bithienyl, terthienyl, furyl, fluorenyl, pyrenyl, perylenyl, and vinyl groups, or X may not be present so that the pyridinium groups are directly connected; and Z represents a polymer preferably from the ring-opening polymerization of an oxazolinee derivative (e.g. one substituted with phenyl group). The anion as the donor is selected, for example, from chloride, bromide, iodide, tetraphenylborate or derivatives thereof.

摘要翻译： 提供了一种适合用作光功能材料的新型离子对电荷转移络合物聚合物，其在从可见光到近红外区域的宽波长范围内显示出极快的光响应，并且热稳定。 一种离子对电荷转移复合聚合物，其中受体是由下式（I）表示的取代的双吡啶鎓阳离子。 在该式中，X表示相对于联吡啶基的氮原子在4-或2-位键合的基团，选自苯基，联苯基，噻吩基，二噻吩基，噻吩基，呋喃基，芴基，芘基，苝基 和乙烯基，或者X可以不存在，使得吡啶鎓基团直接相连; Z表示优选恶唑啉衍生物（例如被苯基取代的）的开环聚合的聚合物。 作为供体的阴离子选自例如氯化物，溴化物，碘化物，四苯基硼酸盐或其衍生物。