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公开(公告)号：US4495272A
公开(公告)日：1985-01-22
申请号：US513181
申请日：1983-07-12
CPC分类号： G03C7/3275
摘要： A silver halide color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer containing a cyan color image forming polymer coupler latex capable of forming a dye upon coupling with an oxidation product of an artomatic primary amine developing agent wherein the cyan color image forming polymer coupler latex contains at least one repeating unit represented by the general formula (I) described below and at least one repeating unit represented by the general formula (II) described below. ##STR1## wherein R.sub.1 represents a hydrogen atom, a lower alkyl group containing from 1 to 4 carbon atoms or a chlorine atom; and Q represents a cyan coupler residue capable of forming a dye upon coupling with an oxidized aromatic primary amine developing agent, ##STR2## wherein R.sub.2 represents a hydrogen atom, a lower alkyl group containing from 1 to 4 carbon atoms or a chlorine atom; and R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom, an unsubstituted or substituted alkyl group which may be a straight chain, a branched chain or a cyclic, or an unsubstituted or substituted phenyl group.The cyan color image forming polymer coupler latex has an excellent color forming property, and the silver halide color photographic light-sensitive material containing the cyan color image forming polymer coupler latex has good film strength and a reduced layer thickness and provides a cyan image having improved color reproduction properties and sharpness and a good fastness to heat with or without humidity. A method of forming a color image using the silver halide color photographic light-sensitive material is also described.
摘要翻译： 一种卤化银彩色照相感光材料，其包含其上具有卤化银乳剂层的载体，所述卤化银乳剂层含有能与模拟伯胺显影剂的氧化产物偶联形成染料的青色成像聚合物偶联剂胶乳，其中所述青色 图像形成聚合物成色剂胶乳含有至少一种由下述通式（I）表示的重复单元和至少一个由下述通式（II）表示的重复单元。 （I）其中R 1表示氢原子，含有1至4个碳原子的低级烷基或氯原子; Q表示在与氧化芳族伯胺显影剂偶联时能够形成染料的青色成色剂残基，其中R 2表示氢原子，含有1至4个碳原子的低级烷基或氯 原子; 和可以相同或不同的R 3和R 4各自表示氢原子，可以是直链，支链或环状或未取代或取代的苯基的未取代或取代的烷基。 青色成像聚合物成色剂胶乳具有优异的成色性，含有青色成像聚合物成色剂胶乳的卤化银彩色照相感光材料具有良好的膜强度和降低的层厚度，并提供了改进的青色图像 色彩再现性能和清晰度，以及具有或不具有湿度的耐热牢度。 还描述了使用卤化银彩色照相感光材料形成彩色图像的方法。
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公开(公告)号：US4511647A
公开(公告)日：1985-04-16
申请号：US549947
申请日：1983-11-09
申请人： Tsumoru Hirano , Morio Yagihara , Makoto Umemoto
发明人： Tsumoru Hirano , Morio Yagihara , Makoto Umemoto
CPC分类号： G03C7/34 , G03C7/3275
摘要： A silver halide color photographic light-sensitive material is disclosed. Their material is comprised of a support having thereon a silver halide emulsion layer containing a cyan color image forming polymer coupler latex. This latex is comprised of a recurring unit of a cyan coupler monomer capable of forming a dye upon coupling with an oxidation product of an aromatic primary amine developing agent represented by the general formula (I) and a recurring unit of an ethylenically unsaturated monomer containing an acid component represented by the general formula (II) and a recurring unit of methyl acrylate. ##STR1## The cyan color image forming polymer coupler latex has excellent color forming properties and photographic material containing the coupler latex provides a cyan image having good fastness to heat and the combination of heat and humidity. A method for forming a color image utilizing the disclosed photographic material containing the novel couple of latex is also disclosed.
摘要翻译： 公开了一种卤化银彩色照相感光材料。 它们的材料由其上具有含有青色成像聚合物成色剂胶乳的卤化银乳剂层的载体组成。 该胶乳由能够与通式（I）表示的芳族伯胺显影剂的氧化产物偶联的能够形成染料的青色成色剂单体的重复单元和含有通式（I）的烯键式不饱和单体的重复单元组成， 由通式（II）表示的酸成分和丙烯酸甲酯的重复单元。 （II）青色成像聚合物成色胶乳具有优异的成色性能，并且含有成色剂胶乳的照相材料提供具有良好耐热牢度和热和湿度组合的青色图像。 还公开了利用所公开的含有胶乳新组合的照相材料形成彩色图像的方法。
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公开(公告)号：US4496650A
公开(公告)日：1985-01-29
申请号：US571628
申请日：1984-01-17
申请人： Morio Yagihara , Tsumoru Hirano , Makoto Umemoto
发明人： Morio Yagihara , Tsumoru Hirano , Makoto Umemoto
CPC分类号： G03C7/3275 , Y10S430/132
摘要： A silver halide color photographic light-sensitive material comprised of a support having thereon a silver halide emulsion layer containing a cyan color image forming polymer coupler latex is disclosed. The cyan color image forming polymer coupler latex is comprised of at least one repeating unit capable of forming a dye upon coupling with an oxidation product of an aromatic primary amine developing agent represented by the general formula (Ia) and at least one repeating unit represented by the general formula (II): ##STR1## the substituents within the general formulae are disclosed within the specification. The cyan color image forming polymer coupler latex has excellent color forming properties and the silver halide color photographic light-sensitive material which contains the latex provides a photograph in which the occurrence of color stain due to light is substantially prevented. A method of forming a color image using the silver halide color photographic light-sensitive material is also described.
摘要翻译： 公开了一种卤化银彩色照相感光材料，其由其上具有含有青色成像聚合物成色剂胶乳的卤化银乳剂层的载体组成。 青色成像聚合物成色剂胶乳由至少一种能够与由通式（Ia）表示的芳族伯胺显影剂的氧化产物偶联而形成染料的重复单元和至少一种由 通式（II）：通式（II）中的取代基在说明书内公开。 青色成像聚合物成色剂胶乳具有优异的成色性能，并且含有胶乳的卤化银彩色照相感光材料提供了基本上防止由于光引起的着色的发生的照片。 还描述了使用卤化银彩色照相感光材料形成彩色图像的方法。
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公开(公告)号：US4455366A
公开(公告)日：1984-06-19
申请号：US501725
申请日：1983-06-06
申请人： Tsumoru Hirano , Makoto Umemoto , Morio Yagihara
发明人： Tsumoru Hirano , Makoto Umemoto , Morio Yagihara
CPC分类号： G03C7/3275
摘要： A silver halide color, photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer containing a cyan color image forming polymer coupler latex which is capable of forming a dye upon coupling with an oxidation product of an aromatic primary amine developing agent and which is a polymer or copolymer having a repeating unit derived from a monomer represented by the following general formula (I): ##STR1## wherein R.sub.1 represents a hydroden atom, a lower alkyl group containing from 1 to 4 carbon atoms or a chlorine atom; R.sub.2 represents a hydrogen atom or an unsubstituted or substituted alkyl group having from 1 to 4 carbon atoms; A.sub.1 represents an unsubstituted or substituted alkylene group which may be a straight chain or a branched chain; A.sub.2 represents an unsubstituted or substituted alkylene group which may be a straight chain or a branched chain, an unsubstituted or substituted aralkylene group or an unsubstituted or substituted phenylene group; B.sub.1 represents --O--, --S--, --SO--, --SO.sub.2 --, --CONH-- or --COO--; B.sub.2 represents --NHCO-- or --OCO--; X represents a halogen atom; Y represents a hydrogen atom or a lower alkyl group having from 1 to 5 carbon atoms; Z represents a hydrogen atom, a halogen atom or a substituted alkoxy group; l represents 0 or 1; m represents 0 or 1; and n represents 0 or 1.
摘要翻译： 一种卤化银色素，照相感光材料，其包含其上具有卤化银乳剂层的载体，其含有青色成像聚合物偶联剂胶乳，其能够在与芳族伯胺显影剂的氧化产物偶联时形成染料和 其是具有源自由以下通式（I）表示的单体的重复单元的聚合物或共聚物：其中R 1表示氢原子，含有1至4个碳原子的低级烷基或 氯原子 R 2表示氢原子或未取代或取代的具有1至4个碳原子的烷基; A1表示可以是直链或支链的未取代或取代的亚烷基; A2表示可以是直链或支链的未取代或取代的亚烷基，未取代或取代的亚芳基或未取代或取代的亚苯基; B1表示-O - ， - S - ， - SO - ， - SO2-，-CONH-或-COO-; B2表示-NHCO-或-OCO-; X表示卤原子; Y表示氢原子或具有1至5个碳原子的低级烷基; Z表示氢原子，卤原子或取代的烷氧基; l表示0或1; m表示0或1; n表示0或1。
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公开(公告)号：US4444870A
公开(公告)日：1984-04-24
申请号：US415295
申请日：1982-09-07
申请人： Tsumoru Hirano , Keiji Mihayashi , Morio Yagihara
发明人： Tsumoru Hirano , Keiji Mihayashi , Morio Yagihara
CPC分类号： G03C7/3275 , Y10S525/902
摘要： A silver halide color photographic light-sensitive material comprising a support having thereon a layer containing at least one copolymer coupler latex having a layered structure capable of forming a dye upon coupling with an oxidation product of an aromatic primary amine developing agent. The polymer coupler latex having a layered structure has an exceptionally good color forming property and is capable of forming a dye with a high yield and without the formation of undesired stains and fogs. The silver halide color photographic light-sensitive material containing the polymer coupler latex has good film strength and a reduced layer thickness and provides a color image having an improved sharpness. A method of forming a color image using the silver halide color photographic light-sensitive material is also disclosed.
摘要翻译： 一种卤化银彩色摄影感光材料，其包括其上具有包含至少一种具有能与芳族伯胺显影剂的氧化产物偶合形成染料的层状结构的共聚物成色胶乳的层的载体。 具有层状结构的聚合物成色剂胶乳具有非常好的成色性，能够以高产率形成染料，并且不形成不期望的污渍和雾。 含有聚合物偶联胶乳的卤化银彩色照相感光材料具有良好的膜强度和降低的层厚度，并提供了具有改善的清晰度的彩色图像。 还公开了使用卤化银彩色照相感光材料形成彩色图像的方法。
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公开(公告)号：US4668613A
公开(公告)日：1987-05-26
申请号：US724866
申请日：1985-04-19
申请人： Morio Yagihara , Tsumoru Hirano , Tatsuya Yamamoto , Kei Sakanoue
发明人： Morio Yagihara , Tsumoru Hirano , Tatsuya Yamamoto , Kei Sakanoue
CPC分类号： G03C7/3275
摘要： A silver halide color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer containing a polymer coupler which is capable of forming a dye upon coupling with an oxidation product of an aromatic primary amine developing agent and which is polymerized using a polymerization initiator represented by the following general formula (I): ##STR1## wherein R.sub.1 represents a straight chain or branched chain alkyl group having from 1 to 5 carbon atoms; an R.sub.2 represents a straight chain or branched chain alkyl group having from 1 to 20 carbon atoms.The polymer coupler according to the present invention has a good stability to humidity and heat during storage of the silver halide color photographic light-sensitive material containing thereof and provides decreased formation of fog in non-image areas of color photographs obtained by means of color development processing of the silver halide color photographic light-sensitive material.
摘要翻译： 一种卤化银彩色照相感光材料，其包含其上具有含有聚合物偶联剂的卤化银乳剂层的载体，其能够在与芳族伯胺显影剂的氧化产物偶联时形成染料，并使用聚合 由下列通式（I）表示的引发剂：其中R 1表示具有1至5个碳原子的直链或支链烷基; R 2表示具有1至20个碳原子的直链或支链烷基。 根据本发明的聚合物成色剂在含有卤化银彩色摄影感光材料的储存期间对湿度和热量具有良好的稳定性，并且在通过显色获得的彩色照片的非图像区域中减少了雾的形成 处理卤化银彩色照相感光材料。
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公开(公告)号：US4409320A
公开(公告)日：1983-10-11
申请号：US377271
申请日：1982-05-10
申请人： Morio Yagihara , Tsumoru Hirano , Keiji Mihayashi , Takashi Ozawa
发明人： Morio Yagihara , Tsumoru Hirano , Keiji Mihayashi , Takashi Ozawa
IPC分类号： G03C7/38 , C07D231/52 , C08F20/00 , C08F20/34 , C08F20/52 , C08F20/58 , C08F20/60 , C09B26/02 , G03C7/327 , G03C7/00 , G03C1/40
CPC分类号： G03C7/327 , C07D231/52 , C08F20/60
摘要： A silver halide color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer containing a magenta color image forming polymer coupler latex which is capable of forming a dye upon coupling with an oxidation product of an aromatic primary amine developing agent and which is a polymer or copolymer having a repeating unit derived from a monomer represented by the following general formula (I) ##STR1## wherein R represents a hydrogen atom, a lower alkyl group containing from 1 to 4 carbon atoms or a chlorine atom; and X represents a halogen atom, an acylamino group, a carbamoyl group, a sulfonamido group, a sulfamoyl group, a cyano group or an alkoxycarbonyl group and which is present at the 4-position or 5-position of the phenyl group. The magenta color image forming polymer coupler latex has a good color forming property and is capable of forming a dye with a high yield and without formation of undesired stains and fogs, and the silver halide color photographic light-sensitive material containing the magenta color image forming polymer coupler latex has good film strength and a reduced layer thickness and provides a stable magenta image having an improved sharpness and a good fastness to light, heat, and humidity. A method of forming a color image using the silver halide color photographic light-sensitive material is also described.
摘要翻译： 一种卤化银彩色照相感光材料，其包括其上具有卤化银乳剂层的载体，所述卤化银乳剂层含有品红色图像形成聚合物偶联剂胶乳，其能够在与芳族伯胺显影剂的氧化产物偶联时形成染料， 是具有衍生自由下列通式（I）表示的单体的重复单元的聚合物或共聚物其中R表示氢原子，含有1至4个碳原子的低级烷基或氯原子 ; X表示卤素原子，酰氨基，氨基甲酰基，亚磺酰氨基，氨磺酰基，氰基或烷氧基羰基，其存在于苯基的4-位或5-位上。 品红色成像聚合物成色剂胶乳具有良好的成色性能，能够以高产率形成染料并且不形成不期望的污渍和雾，并且含有品红色图像形成的卤化银彩色照相感光材料 聚合物成色剂胶乳具有良好的膜强度和降低的层厚度，并提供稳定的品红色图像，其具有改善的清晰度和对光，热和湿度的良好牢度。 还描述了使用卤化银彩色照相感光材料形成彩色图像的方法。
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公开(公告)号：US4367282A
公开(公告)日：1983-01-04
申请号：US328151
申请日：1981-12-07
申请人： Morio Yagihara , Tsumoru Hirano , Keiji Mihayashi
发明人： Morio Yagihara , Tsumoru Hirano , Keiji Mihayashi
IPC分类号： G03C7/38 , C07D231/52 , C07D521/00 , C08F20/36 , C08F20/60 , C09B26/02 , G03C7/327 , G03C7/00 , G03C1/40
CPC分类号： C07D231/12 , C07D231/52 , C07D233/56 , C07D249/08 , C08F20/36 , C08F20/60 , G03C7/3275
摘要： A silver halide color photographic light-sensitive material is described comprising a support having thereon a silver halide emulsion layer containing a 2-equivalent magenta color image forming polymer coupler latex which is capable of forming a dye upon coupling with an oxidation product of an aromatic primary amine developing agent and which is a polymer or copolymer having a repeating unit derived from a monomer represented by formula (I) ##STR1## wherein R represents a hydrogen atom, a lower alkyl group containing from 1 to 4 carbon atoms or a chlorine atom; X represents --CONH--, --NH--, --NHCONH-- or --NHCOO--; Y represents --CONH-- or --COO--; A represents an unsubstituted or substituted alkylene group which may be a straight chain or a branched chain or an unsubstituted or substituted phenylene group; Ar represents an unsubstituted or substituted phenyl group; Za, Zb, Zc and Zd can each represent a methine group, a substituted methine group or -N.dbd.; m represents 0 or 1; and n represents 0 or 1.The 2-equivalent magenta color image forming polymer coupler latex has a good color forming property and is capable of forming a dye with a high yield and without formation of undesired stains and fogs and provides a stable magenta image having a good fastness to light, heat, and humidity. A method of forming a color image using the silver halide color photographic light-sensitive material is also described.
摘要翻译： 描述了一种卤化银彩色照相感光材料，其包括其上具有含有2-当量的品红色成像聚合物成色剂胶乳的卤化银乳剂层的载体，其能够在与芳族原料的氧化产物偶联时形成染料 胺显影剂，其是具有衍生自由式（I）表示的单体的重复单元的聚合物或共聚物其中R表示氢原子，含有1至4个碳原子的低级烷基或 氯原子 X表示-CONH-，-NH-，-NHCONH-或-NHCOO-; Y表示-CONH-或-COO-; A表示未取代或取代的亚烷基，其可以是直链或支链或未取代或取代的亚苯基; Ar表示未取代或取代的苯基; Za，Zb，Zc和Zd各自表示次甲基，取代的次甲基或-N =; m表示0或1; 并且n表示0或1. 2-等价的品红色成像聚合物成色胶乳具有良好的成色性能，能够以高产率形成染料，并且不形成不期望的污渍和雾，并提供稳定的品红色图像，其具有 耐光，耐热，耐湿性好。 还描述了使用卤化银彩色照相感光材料形成彩色图像的方法。
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公开(公告)号：US4436808A
公开(公告)日：1984-03-13
申请号：US469660
申请日：1983-02-25
申请人： Morio Yagihara , Tsumoru Hirano , Keiji Mihayashi
发明人： Morio Yagihara , Tsumoru Hirano , Keiji Mihayashi
CPC分类号： G03C7/3275
摘要： A silver halide color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer containing a magenta color image forming polymer coupler latex which is capable of forming a dye upon coupling with an oxidation product of an aromatic primary amine developing agent and which is a homopolymer or copolymer having a repeating unit derived from a monomer coupler represented by the following general formula (I): ##STR1## wherein R.sub.1 represents hydrogen, a lower alkyl group containing from 1 to 4 carbon atoms or a chlorine atom; R.sub.2 and R.sub.3, which may be the same or different, each represents an unsubstituted or substituted alkylene group which may be a straight chain or a branched chain, an unsubstituted or substituted arylene group or an unsubstituted or substituted aralkylene group; X represents --CONH-- or --COO--; Y represents --O--, --S--, --SO--, --SO.sub.2 --, --CONH-- or --COO--; Ar represents an unsubstituted or substituted phenyl group; R.sub.4 represents an unsubstituted or substituted anilino group, an unsubstituted or substituted acylamino group or an unsubstituted or substituted ureido group; l represents 0 or 1; m represents 0 or 1; and n represents 0 or 1.The magenta color image forming polymer coupler latex has a good color forming property and is capable of forming a dye with a high yield and without formation of undesired stains and fogs, and the silver halide color photographic light-sensitive material containing the magenta color image forming polymer coupler latex has good film strength and a reduced layer thickness and provides a stable magenta image having improved graininess and sharpness and a good fastness to light, heat, and humidity. A method of forming a color image using the silver halide color photographic light-sensitive material is also described.
摘要翻译： 一种卤化银彩色照相感光材料，其包括其上具有卤化银乳剂层的载体，所述卤化银乳剂层含有品红色图像形成聚合物偶联剂胶乳，其能够在与芳族伯胺显影剂的氧化产物偶联时形成染料， 是具有源自由以下通式（I）表示的单体成色剂的重复单元的均聚物或共聚物：其中R 1表示氢，含有1至4个碳原子的低级烷基或氯原子 ; R 2和R 3可以相同或不同，表示可以是直链或支链的未取代或取代的亚烷基，未取代或取代的亚芳基或未取代或取代的芳亚烷基; X表示-CONH-或-COO-; Y表示-O - ， - S - ， - SO-，-SO 2 - ， - CONH-或-COO-; Ar表示未取代或取代的苯基; R4表示未取代或取代的苯胺基，未取代或取代的酰氨基或未取代或取代的脲基; l表示0或1; m表示0或1; 并且n表示0或1.品红色成像聚合物成色剂胶乳具有良好的成色性能，能够以高产率形成染料并且不形成不期望的污渍和雾，并且卤化银彩色照相感光 含有品红色成像聚合物偶联剂胶乳的材料具有良好的膜强度和降低的层厚度，并且提供了具有改善的颗粒度和清晰度以及对光，热和湿度的良好牢度的稳定的品红色图像。 还描述了使用卤化银彩色照相感光材料形成彩色图像的方法。
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公开(公告)号：US4518687A
公开(公告)日：1985-05-21
申请号：US539857
申请日：1983-10-07
申请人： Tsumoru Hirano , Makoto Umemoto , Mitsunori Hirano
发明人： Tsumoru Hirano , Makoto Umemoto , Mitsunori Hirano
CPC分类号： G03C7/3275
摘要： A silver halide color photographic light-sensitive material is disclosed. The material is comprised of a support base having thereon a silver halide emulsion layer containing a cyan dye-forming oleophilic polymer coupler. The polymer coupler is comprised of three repeating units including a repeating unit of a cyan coupler corresponding to general formula (I), an ethylene type unsaturated monomer repeating unit corresponding to general formula (II) which contains an acid component and an ethylene type unsaturated monomer repeating unit corresponding to general formula (III). The cyan dye-forming oleophilic polymer coupler is present in the form of a dispersed product, said polymer coupler having been dissolved in an organic solvent followed by emulsion dispersion of a gelatine aqueous solution in the presence of a surfactant. The general formulae and their substituents are described in the specification. By utilizing the particularly disclosed polymer coupler, the material forms a color image having excellent fastness which respect to heat and wet heat when the image is in the form of a color photograph after development. The novel cyan color image forming oleophilic polymer coupler also makes it possible to obtain remarkably excellent color forming property in the photographic image.
摘要翻译： 公开了一种卤化银彩色照相感光材料。 该材料由其上具有包含形成青色染料的亲油聚合物偶合剂的卤化银乳剂层的支撑基底组成。 聚合物成色剂由三种重复单元组成，包括对应于通式（I）的青色成色剂的重复单元，对应于通式（II）的乙烯型不饱和单体重复单元，其含有酸组分和乙烯型不饱和单体 对应于通式（III）的重复单元。 形成青色染料的亲油聚合物偶联剂以分散产物的形式存在，所述聚合物成色剂已经溶解在有机溶剂中，然后在表面活性剂存在下将明胶水溶液乳液分散。 通式及其取代基在说明书中描述。 通过利用特别公开的聚合物成色剂，当显影后的图像为彩色照片时，该材料形成了具有优异的耐热湿热性能的色牢度。 新颖的青色成像亲油聚合物成色剂也使得可以在摄影图像中获得显着优异的成色性能。
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