公开(公告)号：US08795940B2

公开(公告)日：2014-08-05

申请号：US13684883

申请日：2012-11-26

申请人： Tsuyoshi Sugimoto ,  Hiroshi Yamashita ,  Daisuke Asahina ,  Rintaro Takahashi ,  Masahide Yamada ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Shingo Sakashita

发明人： Tsuyoshi Sugimoto ,  Hiroshi Yamashita ,  Daisuke Asahina ,  Rintaro Takahashi ,  Masahide Yamada ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Shingo Sakashita

IPC分类号： G03G9/08

CPC分类号： G03G9/08 ,  G03G9/0804 ,  G03G9/0821 ,  G03G9/08755 ,  G03G9/08764 ,  G03G9/08795 ,  G03G9/08797

摘要： To provide a toner, including at least: a non-crystalline polyester resin; and a crystalline polyester resin, wherein the toner has a glass transition temperature in a first heating Tg1st and a glass transition temperature in a second heating Tg2nd, and a difference between Tg1st and Tg2nd (Tg1st-Tg2nd) is 10° C. or greater, and wherein the crystalline polyester resin is a modified crystalline polyester resin having a urethane skeleton or a urea skeleton, or both thereof.

摘要翻译： 提供至少包括非结晶性聚酯树脂的调色剂; 和结晶性聚酯树脂，其中调色剂在第一加热Tg1st中具有玻璃化转变温度，在第二加热Tg2nd中具有玻璃化转变温度，Tg1st和Tg2nd（Tg1st-Tg2nd）之间的差为10℃以上， 并且其中所述结晶性聚酯树脂是具有氨基甲酸酯骨架或脲骨架的改性结晶性聚酯树脂或其二者。

公开(公告)号：US20130157184A1

公开(公告)日：2013-06-20

申请号：US13684883

申请日：2012-11-26

申请人： Tsuyoshi SUGIMOTO ,  Hiroshi Yamashita ,  Daisuke Asahina ,  Rintaro Takahashi ,  Masahide Yamada ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Shingo Sakashita

发明人： Tsuyoshi SUGIMOTO ,  Hiroshi Yamashita ,  Daisuke Asahina ,  Rintaro Takahashi ,  Masahide Yamada ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Shingo Sakashita

IPC分类号： G03G9/08

CPC分类号： G03G9/08 ,  G03G9/0804 ,  G03G9/0821 ,  G03G9/08755 ,  G03G9/08764 ,  G03G9/08795 ,  G03G9/08797

摘要： To provide a toner, including at least: a non-crystalline polyester resin; and a crystalline polyester resin, wherein the toner has a glass transition temperature in a first heating Tg1st and a glass transition temperature in a second heating Tg2nd, and a difference between Tg1st and Tg2nd (Tg1st−Tg2nd) is 10° C. or greater, and wherein the crystalline polyester resin is a modified crystalline polyester resin having a urethane skeleton or a urea skeleton, or both thereof.

摘要翻译： 提供至少包括非结晶性聚酯树脂的调色剂; 和结晶性聚酯树脂，其中调色剂在第一加热Tg1st中具有玻璃化转变温度，在第二加热Tg2nd中具有玻璃化转变温度，Tg1st和Tg2nd（Tg1st-Tg2nd）之间的差为10℃以上， 并且其中所述结晶性聚酯树脂是具有氨基甲酸酯骨架或脲骨架的改性结晶性聚酯树脂或其二者。

公开(公告)号：US08895217B2

公开(公告)日：2014-11-25

申请号：US13751620

申请日：2013-01-28

申请人： Daisuke Asahina ,  Tsuyoshi Sugimoto ,  Rintaro Takahashi ,  Hiroshi Yamashita ,  Taichi Nemoto ,  Shingo Sakashita ,  Yoshitaka Yamauchi ,  Satoyuki Sekiguchi

发明人： Daisuke Asahina ,  Tsuyoshi Sugimoto ,  Rintaro Takahashi ,  Hiroshi Yamashita ,  Taichi Nemoto ,  Shingo Sakashita ,  Yoshitaka Yamauchi ,  Satoyuki Sekiguchi

IPC分类号： G03G9/087 ,  G03G9/08

CPC分类号： G03G9/08755 ,  G03G9/0804 ,  G03G9/08795 ,  G03G9/08797

摘要： An electrostatic image forming toner including: toner base particles each containing at least a colorant, a binder resin, and a releasing agent, wherein the binder resin contains a non-crystalline polyester resin A and a crystalline polyester resin B, wherein a ratio of B/(A+B)×100 is 10 or more but less than 50 where (A+B) is a total mass of the non-crystalline polyester resin A and the crystalline polyester resin B and “B” is a mass of the crystalline polyester resin B, and wherein the toner base particles have a TMA compression deformation amount (TMA %) of 10% or less which is measured at 50° C. and a relative humidity of 90%.

摘要翻译： 一种静电图像形成调色剂，包括：至少分别含有着色剂，粘合剂树脂和脱模剂的调色剂基础颗粒，其中所述粘合剂树脂含有非结晶性聚酯树脂A和结晶性聚酯树脂B，其中B /（A + B）×100为10以上且小于50，其中（A + B）为非结晶性聚酯树脂A和结晶性聚酯树脂B的总质量，“B”为结晶性 聚酯树脂B，并且其中调色剂基础颗粒具有在50℃和相对湿度为90％下测量的10％或更低的TMA压缩变形量（TMA％）。

公开(公告)号：US20130196263A1

公开(公告)日：2013-08-01

申请号：US13751620

申请日：2013-01-28

申请人： Daisuke Asahina ,  Tsuyoshi Sugimoto ,  Rintaro Takahashi ,  Hiroshi Yamashita ,  Taichi Nemoto ,  Shingo Sakashita ,  Yoshitaka Yamauchi ,  Satoyuki Sekiguchi

发明人： Daisuke Asahina ,  Tsuyoshi Sugimoto ,  Rintaro Takahashi ,  Hiroshi Yamashita ,  Taichi Nemoto ,  Shingo Sakashita ,  Yoshitaka Yamauchi ,  Satoyuki Sekiguchi

IPC分类号： G03G9/087

CPC分类号： G03G9/08755 ,  G03G9/0804 ,  G03G9/08795 ,  G03G9/08797

摘要： An electrostatic image forming toner including: toner base particles each containing at least a colorant, a binder resin, and a releasing agent, wherein the binder resin contains a non-crystalline polyester resin A and a crystalline polyester resin B, wherein a ratio of B/(A+B)×100 is 10 or more but less than 50 where (A+B) is a total mass of the non-crystalline polyester resin A and the crystalline polyester resin B and “B” is a mass of the crystalline polyester resin B, and wherein the toner base particles have a TMA compression deformation amount (TMA %) of 10% or less which is measured at 50° C. and a relative humidity of 90%.

摘要翻译： 一种静电图像形成调色剂，包括：至少分别含有着色剂，粘合剂树脂和脱模剂的调色剂基础颗粒，其中所述粘合剂树脂含有非结晶性聚酯树脂A和结晶性聚酯树脂B，其中B /（A + B）×100为10以上且小于50，其中（A + B）为非结晶性聚酯树脂A和结晶性聚酯树脂B的总质量，“B”为结晶性 聚酯树脂B，并且其中调色剂基础颗粒具有在50℃和相对湿度为90％下测量的10％或更低的TMA压缩变形量（TMA％）。

公开(公告)号：US09851649B2

公开(公告)日：2017-12-26

申请号：US14891032

申请日：2013-11-27

申请人： Keiji Makabe ,  Tsuyoshi Sugimoto ,  Akinori Saito ,  Suzuka Amemori ,  Toyoshi Sawada ,  Hiroshi Yamashita ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Daisuke Asahina ,  Satoyuki Sekiguchi

发明人： Keiji Makabe ,  Tsuyoshi Sugimoto ,  Akinori Saito ,  Suzuka Amemori ,  Toyoshi Sawada ,  Hiroshi Yamashita ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Daisuke Asahina ,  Satoyuki Sekiguchi

IPC分类号： G03G9/00 ,  G03G9/087 ,  G03G15/01

CPC分类号： G03G9/08788 ,  G03G9/08755 ,  G03G9/08791 ,  G03G9/08793 ,  G03G9/08795 ,  G03G9/08797 ,  G03G15/0126

摘要： A toner includes a binder resin including a copolymer resin containing structural units derived from crystalline and non-crystalline resins, respectively. Spin-spin relaxation time (t50) of the toner at 50° C. measured by pulse NMR is ≦0.05 msec., spin-spin relaxation time (t130) at 130° C. when warmed from 50° C. to 130° C. is >15 msec., and spin-spin relaxation time (t′70) at 70° C. when cooled from 130° C. to 70° C. is ≦1.00 msec. A binarized image obtained by binarizing a phase image of the toner observed by a tapping mode AFM based on intermediate value between maximum and minimum phase difference values in the phase image includes first phase difference images constituted by large phase-difference portions and a second phase difference image constituted by a small phase-difference portion. The first phase difference images are dispersed in the second phase difference image. The dispersion diameter of the first phase difference images is 150 nm or less.

公开(公告)号：US08883385B2

公开(公告)日：2014-11-11

申请号：US13705811

申请日：2012-12-05

申请人： Shingo Sakashita ,  Hiroshi Yamashita ,  Masahide Yamada ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Yukiko Nakajima

发明人： Shingo Sakashita ,  Hiroshi Yamashita ,  Masahide Yamada ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Yukiko Nakajima

IPC分类号： G03G9/097 ,  G03G9/08

CPC分类号： G03G9/08 ,  G03G9/0821 ,  G03G9/08755 ,  G03G9/08764 ,  G03G9/08782 ,  G03G9/08788 ,  G03G9/08793 ,  G03G9/08795 ,  G03G9/08797 ,  G03G9/097

摘要： A toner includes a binder resin, a coloring agent, and a releasing agent containing two or more kinds of alkyl monoester compounds having a different number of carbon atoms in a range of from 30 to 50 carbon atoms. The toner has a crystallinity of 10% or more as measured by x-ray diffraction and/or the binder resin is a crystalline resin in an amount of 50% by weight or more of the binder resin. The two or more kinds of alkyl monoester compounds include a component A accounting for the largest amount ranging from 30% by weight to less than 50% by weight of the releasing agent and a component B accounting for the second largest amount ranging from 10% by weight to less than 50% by weight of the releasing agent.

摘要翻译： 调色剂包括粘合剂树脂，着色剂和含有碳原子数不同于30至50碳原子的两种或更多种烷基单酯化合物的脱模剂。 调色剂通过x射线衍射测得的结晶度为10％以上，和/或粘合剂树脂为粘合剂树脂的50重量％以上的结晶性树脂。 两种或更多种烷基单酯化合物包括占脱模剂重量的30重量％至小于50重量％的最大量的组分A和占第二大量的组分B的10重量％ 重量至小于50重量％的脱模剂。

公开(公告)号：US20130157185A1

公开(公告)日：2013-06-20

申请号：US13705811

申请日：2012-12-05

申请人： Shingo SAKASHITA ,  Hiroshi Yamashita ,  Masahide Yamada ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Yukiko Nakajima

发明人： Shingo SAKASHITA ,  Hiroshi Yamashita ,  Masahide Yamada ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Yukiko Nakajima

IPC分类号： G03G9/00 ,  G03G15/08

CPC分类号： G03G9/08 ,  G03G9/0821 ,  G03G9/08755 ,  G03G9/08764 ,  G03G9/08782 ,  G03G9/08788 ,  G03G9/08793 ,  G03G9/08795 ,  G03G9/08797 ,  G03G9/097

摘要： A toner includes a binder resin, a coloring agent, and a releasing agent containing two or more kinds of alkyl monoester compounds having a different number of carbon atoms in a range of from 30 to 50 carbon atoms. The toner has a crystallinity of 10% or more as measured by x-ray diffraction and/or the binder resin is a crystalline resin in an amount of 50% by weight or more of the binder resin. The two or more kinds of alkyl monoester compounds include a component A accounting for the largest amount ranging from 30% by weight to less than 50% by weight of the releasing agent and a component B accounting for the second largest amount ranging from 10% by weight to less than 50% by weight of the releasing agent.

摘要翻译： 调色剂包括粘合剂树脂，着色剂和含有碳原子数不同于30至50碳原子的两种或更多种烷基单酯化合物的脱模剂。 调色剂通过x射线衍射测得的结晶度为10％以上，和/或粘合剂树脂为粘合剂树脂的50重量％以上的结晶性树脂。 两种或更多种烷基单酯化合物包括占脱模剂重量的30重量％至小于50重量％的最大量的组分A和占第二大量的组分B的10重量％ 重量至小于50重量％的脱模剂。

公开(公告)号：US08728703B2

公开(公告)日：2014-05-20

申请号：US13540063

申请日：2012-07-02

申请人： Hiroshi Yamashita ,  Satoyuki Sekiguchi ,  Daisuke Asahina ,  Tsuyoshi Sugimoto ,  Masaki Watanabe ,  Rintaro Takahashi

发明人： Hiroshi Yamashita ,  Satoyuki Sekiguchi ,  Daisuke Asahina ,  Tsuyoshi Sugimoto ,  Masaki Watanabe ,  Rintaro Takahashi

IPC分类号： G03G9/087

CPC分类号： G03G9/0806 ,  G03G9/08748 ,  G03G9/08753 ,  G03G9/08755 ,  G03G9/08757 ,  G03G9/08759 ,  G03G9/08791

摘要： An electrophotographic toner obtained from a dispersion or emulsion liquid of an oil phase containing a toner material in an aqueous medium, the toner including: a binder resin, wherein the toner material includes: (A) an epoxy resin prepolymer; (B) an adduct of a dihydric phenol with a polyalkylene oxide; (C) a phenolic compound, or an alcohol compound, or both thereof; and (D) a carboxylic acid compound, and wherein the binder resin includes a resin obtained by allowing the (A), the (B), the (C) and the (D) to react with each other.

摘要翻译： 一种电子照相调色剂，其由在水性介质中含有调色剂材料的油相的分散体或乳液液体获得，所述调色剂包括：粘合剂树脂，其中所述调色剂材料包括：（A）环氧树脂预聚物; （B）二元酚与聚环氧烷的加成物; （C）酚类化合物或醇化合物，或其二者; 和（D）羧酸化合物，其中粘合剂树脂包括通过使（A），（B），（C）和（D）彼此反应而获得的树脂。

公开(公告)号：US09239530B2

公开(公告)日：2016-01-19

申请号：US14025128

申请日：2013-09-12

申请人： Daisuke Asahina ,  Hiroshi Yamashita ,  Masana Shiba ,  Tsuyoshi Sugimoto ,  Yukari Fukuda ,  Rintaro Takahashi

发明人： Daisuke Asahina ,  Hiroshi Yamashita ,  Masana Shiba ,  Tsuyoshi Sugimoto ,  Yukari Fukuda ,  Rintaro Takahashi

IPC分类号： G03G9/087 ,  G03G9/08

CPC分类号： G03G9/08755 ,  G03G9/0821 ,  G03G9/08793 ,  G03G9/08795 ,  G03G9/08797

摘要： To provide a toner, which contains a colorant, a binder resin, and a releasing agent, wherein the toner satisfies the following (a) to (c): (a) the toner contains at least a polyester resin as the binder resin; (b) the toner has Tg1st of 25° C. to 50° C.; and (c) the toner has a TMA compressive deformation rate (TMA %) of 10% or lower at 50° C. under a condition having relative humidity of 70%, wherein the Tg1st is glass transition temperature of the toner for first heating, as the toner is measured by a DSC system (a differential scanning calorimeter).

摘要翻译： 为了提供含有着色剂，粘合剂树脂和脱模剂的调色剂，其中调色剂满足以下（a）至（c）：（a）调色剂至少含有作为粘合剂树脂的聚酯树脂; （b）调色剂的Tg1st为25℃至50℃。 和（c）在相对湿度为70％的条件下，调色剂在50℃下具有10％或更低的TMA压缩变形率（TMA％），其中Tg1st是用于第一次加热的调色剂的玻璃化转变温度， 因为调色剂通过DSC系统（差示扫描量热计）测量。

公开(公告)号：US08986916B2

公开(公告)日：2015-03-24

申请号：US13726997

申请日：2012-12-26

申请人： Hiroshi Yamashita ,  Masana Shiba ,  Satoyuki Sekiguchi ,  Yukari Fukuda ,  Daisuke Asahina ,  Rintaro Takahashi ,  Tsuyoshi Sugimoto

发明人： Hiroshi Yamashita ,  Masana Shiba ,  Satoyuki Sekiguchi ,  Yukari Fukuda ,  Daisuke Asahina ,  Rintaro Takahashi ,  Tsuyoshi Sugimoto

IPC分类号： G03G13/08 ,  G03G9/09

CPC分类号： G03G9/0906

摘要： A yellow toner including: a non-crystalline resin; C.I. Pigment Yellow 185; and a releasing agent, wherein the yellow toner has a glass transition temperature of more than 18° C. but less than 40° C.

摘要翻译： 黄色调色剂，包括：非结晶树脂; C.I. 颜料黄185; 和脱模剂，其中黄色调色剂的玻璃化转变温度大于18℃但小于40℃。