公开(公告)号：US09851649B2

公开(公告)日：2017-12-26

申请号：US14891032

申请日：2013-11-27

申请人： Keiji Makabe ,  Tsuyoshi Sugimoto ,  Akinori Saito ,  Suzuka Amemori ,  Toyoshi Sawada ,  Hiroshi Yamashita ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Daisuke Asahina ,  Satoyuki Sekiguchi

发明人： Keiji Makabe ,  Tsuyoshi Sugimoto ,  Akinori Saito ,  Suzuka Amemori ,  Toyoshi Sawada ,  Hiroshi Yamashita ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Daisuke Asahina ,  Satoyuki Sekiguchi

IPC分类号： G03G9/00 ,  G03G9/087 ,  G03G15/01

CPC分类号： G03G9/08788 ,  G03G9/08755 ,  G03G9/08791 ,  G03G9/08793 ,  G03G9/08795 ,  G03G9/08797 ,  G03G15/0126

摘要： A toner includes a binder resin including a copolymer resin containing structural units derived from crystalline and non-crystalline resins, respectively. Spin-spin relaxation time (t50) of the toner at 50° C. measured by pulse NMR is ≦0.05 msec., spin-spin relaxation time (t130) at 130° C. when warmed from 50° C. to 130° C. is >15 msec., and spin-spin relaxation time (t′70) at 70° C. when cooled from 130° C. to 70° C. is ≦1.00 msec. A binarized image obtained by binarizing a phase image of the toner observed by a tapping mode AFM based on intermediate value between maximum and minimum phase difference values in the phase image includes first phase difference images constituted by large phase-difference portions and a second phase difference image constituted by a small phase-difference portion. The first phase difference images are dispersed in the second phase difference image. The dispersion diameter of the first phase difference images is 150 nm or less.

公开(公告)号：US09594322B2

公开(公告)日：2017-03-14

申请号：US14471024

申请日：2014-08-28

申请人： Suzuka Amemori ,  Tsuyoshi Sugimoto ,  Akinori Saito ,  Toyoshi Sawada ,  Keiji Makabe

发明人： Suzuka Amemori ,  Tsuyoshi Sugimoto ,  Akinori Saito ,  Toyoshi Sawada ,  Keiji Makabe

IPC分类号： G03G9/087 ,  G03G9/08

CPC分类号： G03G9/08755 ,  G03G9/0821 ,  G03G9/08788 ,  G03G9/08793 ,  G03G9/08797

摘要： A toner is provided. The toner includes a crosslinked polyester resin, and a block copolymer. The crosslinked polyester resin includes a diol component, which includes an aliphatic diol component having 3 to 10 carbon atoms in an amount of 50% by mole, and a crosslinked component, which is at least one of a crosslinked component of an aliphatic alcohol having three or more valences and a crosslinked component of an aliphatic acid having three or more valences, and the block copolymer includes a crystalline segment (a) and a non-crystalline segment (b). The toner has a first glass transition temperature (Tg1st) of from 20° C. to 50° C., which is determined by subjecting the toner to differential scanning calorimetry (DSC) and measuring a glass transition temperature in a first temperature rising process in the differential scanning calorimetry (DSC).

摘要翻译： 提供调色剂。 调色剂包括交联聚酯树脂和嵌段共聚物。 交联聚酯树脂包括二醇组分，其包含50摩尔％的碳原子数为3〜10的脂肪族二醇成分和交联成分，所述交联成分为脂肪族醇的交联成分中的至少一种， 或更多的化合价和具有三价或更多价的脂族酸的交联组分，并且嵌段共聚物包括结晶链段（a）和非结晶链段（b）。 调色剂具有20℃至50℃的第一玻璃化转变温度（Tg1st），其通过将调色剂经受差示扫描量热法（DSC）和在第一升温过程中测量玻璃化转变温度来测定 差示扫描量热法（DSC）。

公开(公告)号：US09557671B2

公开(公告)日：2017-01-31

申请号：US14629954

申请日：2015-02-24

申请人： Ryuta Chiba ,  Shinya Nakayama ,  Hiroshi Yamada ,  Minoru Masuda ,  Akinori Saitoh ,  Hideyuki Santo ,  Shinsuke Nagai ,  Akihiro Takeyama ,  Hiroyuki Takeda ,  Tsuyoshi Sugimoto ,  Suzuka Amemori ,  Kohsuke Nagata

发明人： Ryuta Chiba ,  Shinya Nakayama ,  Hiroshi Yamada ,  Minoru Masuda ,  Akinori Saitoh ,  Hideyuki Santo ,  Shinsuke Nagai ,  Akihiro Takeyama ,  Hiroyuki Takeda ,  Tsuyoshi Sugimoto ,  Suzuka Amemori ,  Kohsuke Nagata

IPC分类号： G03G9/087 ,  G03G9/09

CPC分类号： G03G9/08755 ,  G03G9/08782 ,  G03G9/08795 ,  G03G9/08797 ,  G03G9/0906

摘要： A toner, including: base particles containing a polyester resin, a colorant, and a release agent, wherein the toner has a glass transition temperature (Tg1st) of 20° C. to 50° C. where the glass transition temperature (Tg1st) is measured in first heating of differential scanning calorimetry (DSC) of the toner, wherein tetrahydrofuran (THF) insoluble matter of the toner has a glass transition temperature [Tg2nd (THF insoluble matter)] of 30° C. or lower where the glass transition temperature [Tg2nd (THF insoluble to matter)] is measured in second heating of differential scanning calorimetry (DSC) of the THF insoluble matter, and wherein 50% or less of the colorant is present within a region of 1,000 nm from a surface of each of the base particles toward a center thereof.

摘要翻译： 一种调色剂，包括：含有聚酯树脂，着色剂和脱模剂的基础颗粒，其中调色剂的玻璃化转变温度（Tg1st）为20℃至50℃，玻璃化转变温度（Tg1st）为 在调色剂的差示扫描量热法（DSC）的第一次加热中测量，其中调色剂的四氢呋喃（THF）不溶物质的玻璃化转变温度[Tg2nd（THF不溶物））为30℃或更低，其中玻璃化转变温度 在THF不溶性物质的差示扫描量热法（DSC）的第二次加热中测量[Tg2nd（THF不溶于物质）]，其中50％以下的着色剂存在于距离每个 基础颗粒朝向其中心。

公开(公告)号：US20140093820A1

公开(公告)日：2014-04-03

申请号：US14026300

申请日：2013-09-13

申请人： Ayumi Satoh ,  Tsuyoshi Sugimoto ,  Akinori Saito ,  Daisuke Inoue ,  Naohiro Watanabe ,  Suzuka Amemori ,  Rintaro Takahashi

发明人： Ayumi Satoh ,  Tsuyoshi Sugimoto ,  Akinori Saito ,  Daisuke Inoue ,  Naohiro Watanabe ,  Suzuka Amemori ,  Rintaro Takahashi

IPC分类号： G03G9/08

CPC分类号： G03G9/0821 ,  G03G9/0804 ,  G03G9/0825 ,  G03G9/08755 ,  G03G9/08782 ,  G03G9/08795 ,  G03G9/08797

摘要： To provide a toner containing toner base particles, in each of which a colorant and a releasing agent are encapsulated with a binder resin, where the toner base particles are obtained by the method containing: mixing and emulsifying a mixture containing the binder resin, the colorant, the releasing agent, and an organic solvent in an aqueous medium in the presence of resin particles, wherein the aqueous medium contains a surfactant and an inorganic salt.

摘要翻译： 为了提供一种含有调色剂基础颗粒的调色剂基础颗粒，其中每一种着色剂和脱模剂都用粘合剂树脂包封，其中通过以下方法获得调色剂基础颗粒：其中混合并乳化含有粘合剂树脂的混合物，着色剂 ，脱模剂和水性介质中的有机溶剂，其中水性介质含有表面活性剂和无机盐。

公开(公告)号：US10859932B2

公开(公告)日：2020-12-08

申请号：US15522567

申请日：2015-10-08

申请人： Tsuyoshi Sugimoto ,  Shinya Nakayama ,  Hiroshi Yamada ,  Hideyuki Santo ,  Ryuta Chiba ,  Suzuka Amemori ,  Kohsuke Nagata

发明人： Tsuyoshi Sugimoto ,  Shinya Nakayama ,  Hiroshi Yamada ,  Hideyuki Santo ,  Ryuta Chiba ,  Suzuka Amemori ,  Kohsuke Nagata

IPC分类号： G03G9/087

摘要： A toner, including: a polyester resin, wherein the polyester resin has a structure represented by any one of formulas 1) to 3) below: 1) R1-(NHCONH-R2)n-, 2) R1-(NHCOO-R2)n-, and 3) R1-(OCONH-R2)n-, where n is 3 or more, R1 represents an aromatic organic group or an aliphatic organic group, and R2 represents a group derived from a resin that is polyester formed of polycarboxylic acid, polyol, or both thereof; or that is a modified polyester obtained by modifying polyester with isocyanate.

公开(公告)号：US09785074B2

公开(公告)日：2017-10-10

申请号：US15116478

申请日：2015-01-06

申请人： Kohsuke Nagata ,  Shinya Nakayama ,  Tsuyoshi Sugimoto ,  Hiroshi Yamada ,  Susumu Chiba ,  Shinsuke Nagai ,  Suzuka Amemori

发明人： Kohsuke Nagata ,  Shinya Nakayama ,  Tsuyoshi Sugimoto ,  Hiroshi Yamada ,  Susumu Chiba ,  Shinsuke Nagai ,  Suzuka Amemori

IPC分类号： G03G9/08 ,  G03G9/087 ,  C08G63/12 ,  C08G63/133 ,  G03G15/08

CPC分类号： G03G9/08755 ,  C08G63/12 ,  C08G63/133 ,  G03G9/08793 ,  G03G9/08795 ,  G03G9/08797 ,  G03G15/08

摘要： A polyester resin for a toner, the polyester resin including: a segment derived from an alcohol component; and a segment derived from a carboxylic acid component, wherein the alcohol component includes a trivalent or higher aliphatic alcohol, and wherein the polyester resin satisfies Expressions (1) to (3) below: 500 ≤ Weight ⁢ ⁢ average ⁢ ⁢ molecular ⁢ ⁢ weight ⁢ ⁢ ( Mw ) ( Valence ⁢ ⁢ of ⁢ ⁢ the ⁢ ⁢ trivalent ⁢ ⁢ or higher ⁢ ⁢ aliphatic ⁢ ⁢ alcohol ) × ( Amount ⁢ ⁢ of ⁢ ⁢ the ⁢ ⁢ trivalent ⁢ ⁢ or higher ⁢ ⁢ aliphatic ⁢ ⁢ alcohol ) ≤ 4 , 000 ; Expression ⁢ ⁢ ( 1 ) 4,000≦Weight average molecular weight (Mw)≦25,000   Expression (2); and 0.5≦(Amount of the trivalent or higher aliphatic alcohol)≦6.5   Expression (3), where, in the Expressions (1) and (3), the Amount of the trivalent or higher aliphatic alcohol denotes a percent by mole of the trivalent or higher aliphatic alcohol relative to the alcohol component.

公开(公告)号：US10088766B2

公开(公告)日：2018-10-02

申请号：US15538717

申请日：2015-11-30

申请人： Hideyuki Santo ,  Tsuyoshi Sugimoto ,  Shinya Nakayama ,  Suzuka Amemori ,  Hiroshi Yamada ,  Ryuta Chiba ,  Kohsuke Nagata

发明人： Hideyuki Santo ,  Tsuyoshi Sugimoto ,  Shinya Nakayama ,  Suzuka Amemori ,  Hiroshi Yamada ,  Ryuta Chiba ,  Kohsuke Nagata

IPC分类号： G03G9/097 ,  G03G9/087 ,  G03G9/08 ,  C01B33/44 ,  C01B33/40 ,  G03G9/09 ,  G03G5/147

摘要： A layered inorganic mineral including a surface treated with a fluorine-containing compound, where the layered inoganic mineral that can be favorably used for a toner that is excellent in high charging ability, charging stability, and low temperature fixing ability, and that can exhibits high reliability during cleaning.

公开(公告)号：US09921503B2

公开(公告)日：2018-03-20

申请号：US15122087

申请日：2015-01-06

申请人： Hiroshi Yamada ,  Tsuyoshi Sugimoto ,  Susumu Chiba ,  Shinsuke Nagai ,  Kohsuke Nagata ,  Shinya Nakayama ,  Yuka Mizoguchi ,  Suzuka Amemori

发明人： Hiroshi Yamada ,  Tsuyoshi Sugimoto ,  Susumu Chiba ,  Shinsuke Nagai ,  Kohsuke Nagata ,  Shinya Nakayama ,  Yuka Mizoguchi ,  Suzuka Amemori

IPC分类号： G03G9/08 ,  G03G9/087 ,  G03G9/09 ,  G03G15/08

CPC分类号： G03G9/08755 ,  G03G9/0806 ,  G03G9/08793 ,  G03G9/08795 ,  G03G9/08797 ,  G03G9/0904 ,  G03G15/08

摘要： A toner including: a pigment; polyester resin A that is insoluble in tetrahydrofuran (THF); and polyester resin B that is soluble in THF, wherein the toner satisfies requirements (1) to (3) below: (1) the polyester resin A includes one or more aliphatic diols including from 3 through 10 carbon atoms, as a component constituting the polyester resin A; (2) the polyester resin B includes at least an alkylene glycol in an amount of 40 mol % or more, as a component constituting the polyester resin B; and (3) a glass transition temperature (Tg1st) of the toner at first heating in differential scanning calorimetry (DSC) of the toner is from 20° C. through 50° C.

公开(公告)号：US20150248070A1

公开(公告)日：2015-09-03

申请号：US14629954

申请日：2015-02-24

申请人： Ryuta CHIBA ,  Shinya Nakayama ,  Hiroshi Yamada ,  Minoru Masuda ,  Akinori Saitoh ,  Hideyuki Santo ,  Shinsuke Nagai ,  Akihiro Takeyama ,  Hiroyuki Takeda ,  Tsuyoshi Sugimoto ,  Suzuka Amemori ,  Kohsuke Nagata

发明人： Ryuta CHIBA ,  Shinya Nakayama ,  Hiroshi Yamada ,  Minoru Masuda ,  Akinori Saitoh ,  Hideyuki Santo ,  Shinsuke Nagai ,  Akihiro Takeyama ,  Hiroyuki Takeda ,  Tsuyoshi Sugimoto ,  Suzuka Amemori ,  Kohsuke Nagata

IPC分类号： G03G9/00

CPC分类号： G03G9/08755 ,  G03G9/08782 ,  G03G9/08795 ,  G03G9/08797 ,  G03G9/0906

摘要： A toner, including: base particles containing a polyester resin, a colorant, and a release agent, wherein the toner has a glass transition temperature (Tg1st) of 20° C. to 50° C. where the glass transition temperature (Tg1st) is measured in first heating of differential scanning calorimetry (DSC) of the toner, wherein tetrahydrofuran (THF) insoluble matter of the toner has a glass transition temperature [Tg2nd (THF insoluble matter)] of 30° C. or lower where the glass transition temperature [Tg2nd (THF insoluble to matter)] is measured in second heating of differential scanning calorimetry (DSC) of the THF insoluble matter, and wherein 50% or less of the colorant is present within a region of 1,000 nm from a surface of each of the base particles toward a center thereof.

摘要翻译： 一种调色剂，包括：含有聚酯树脂，着色剂和脱模剂的基础颗粒，其中调色剂的玻璃化转变温度（Tg1st）为20℃至50℃，玻璃化转变温度（Tg1st）为 在调色剂的差示扫描量热法（DSC）的第一次加热中测量，其中调色剂的四氢呋喃（THF）不溶物质的玻璃化转变温度[Tg2nd（THF不溶物））为30℃或更低，其中玻璃化转变温度 在THF不溶性物质的差示扫描量热法（DSC）的第二次加热中测量[Tg2nd（THF不溶于物质）]，其中50％以下的着色剂存在于距离每个 基础颗粒朝向其中心。

公开(公告)号：US09134638B2

公开(公告)日：2015-09-15

申请号：US14350213

申请日：2012-10-17

申请人： Shingo Sakashita ,  Shinya Nakayama ,  Masahide Yamada ,  Atsushi Yamamoto ,  Hideyuki Santo ,  Yukiko Nakajima ,  Suzuka Amemori

发明人： Shingo Sakashita ,  Shinya Nakayama ,  Masahide Yamada ,  Atsushi Yamamoto ,  Hideyuki Santo ,  Yukiko Nakajima ,  Suzuka Amemori

IPC分类号： G03G9/087

CPC分类号： G03G9/08764 ,  C08G63/00 ,  C08G63/91 ,  C08L67/00 ,  G03G9/08755 ,  G03G9/08768 ,  G03G9/08793 ,  G03G9/08795 ,  G03G9/08797 ,  G03G9/132

摘要： A toner including at least a crystalline resin as a binder resin, wherein a tetrahydrofuran soluble content of the toner includes 5.0% or more as a peak area of a component having a molecular weight of 100,000 or greater in a molecular weight distribution measured by gel permeation chromatography, and the tetrahydrofuran soluble content of the toner has a weight-average molecular weight of 20,000 to 60,000.

摘要翻译： 包含至少一种作为粘合剂树脂的结晶树脂的调色剂，其中调色剂的四氢呋喃可溶物含量为通过凝胶渗透测定的分子量分布中分子量为100,000以上的成分的峰面积的5.0％以上 色谱法，调色剂的四氢呋喃可溶成分的重均分子量为20,000〜60,000。