Organic electroluminescent materials and devices

    公开(公告)号:US10038151B2

    公开(公告)日:2018-07-31

    申请号:US14539412

    申请日:2014-11-12

    IPC分类号: H01L51/00 C07F15/00 H01L51/50

    摘要: A compound having a formula M(LA)x(LB)y(LC)z, where ligand LA is ligand LB is and ligand LC is is disclosed. In formula M(LA)x(LB)y(LC)z, M is a metal having an atomic number greater than 40; x is 1 or 2; A1-A8 are carbon or nitrogen; ring B is bonded to ring A through a C—C bond; M is bonded to ring A through a M-C bond; X is O, S, Se, CRR′, or NR1; rings C and D are each independently a 5 or 6-membered carbocyclic or heterocyclic ring; at least one R4 is a five-membered or six-membered heterocyclic ring which can be further substituted by RE; each R substituent is independently selected from a variety of moieties; and any adjacent R substitutents are optionally joined to form a ring. Formulations and devices, such as an OLEDs, that include the compound of formula M(LA)(LB)(LC)z are also described.

    Organic electroluminescent materials and devices

    公开(公告)号:US10457699B2

    公开(公告)日:2019-10-29

    申请号:US14268873

    申请日:2014-05-02

    摘要: A compound that has the structure according to Formula M(LA)x(LB)y(LC)z: wherein ligand LA is ligand LB is and ligand LC is and devices and formulations containing these compounds are disclosed. In Formula M(LA)x(LB)y(LC)z: M is a metal having an atomic number greater than 40; x is 1 or 2; x+y+z is the oxidation state of the metal M; X1-X4 and A1-A8 are C or N; at least one of A1-A8 is N; X is O, S, or Se; two adjacent RB form a six-member aromatic ring E fused to ring B; wherein ring E can be substituted by RE; each RA-RE and R1-R4 is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.